• Title/Summary/Keyword: Additive Layer

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Determination of the Thermolelectric Properties of NaxCo2O4 by Controlling the Concentration of Na and Additive (NaxCo2O4의 열전특성에 미치는 Na 함량변화와 첨가제의 효과)

  • Choi, Soon-Mok;Jeong, Seong-Min;Seo, Won-Seon
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.689-694
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    • 2009
  • Layer-structured $Na_xCo_2O_4$ was synthesized from $Na_2CO_3\;and\;Co_3O_4$ powders. The chemical concentrations of Na and additive were controlled to enhance the thermoelectric properties over the temperature range from 400 K to 1,150 K. As a result, we obtained the maximum thermoelectric properties at a single phase region with Na content of x=1.5. When Na content was smaller than x=1.5, the thermoelectric properties was low due to formation of second phases of CoO and other oxides. Additionally, Mn was doped to improve thermoelectric properties by means of decreasing thermal conductivity. The results showed that the concentrations of both Na and Mn are all governing factors to determine the thermoelectric properties of $Na_xCo_2O_4$ system.

Novel high performanced and fouling resistant PSf/ZnO membranes for water treatment

  • Sarihan, Adem;Eren, Erdal
    • Membrane and Water Treatment
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    • v.8 no.6
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    • pp.563-574
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    • 2017
  • Antibacterial effective, high performanced, novel ZnO embedded composite membranes were obtained by blendig ZnO nanoparticles with polysulfone. IR, TG/DTG, XRD and SEM analysis were performed to characterize structure and morphology of ZnO nanoparticles and composite membranes. Contact angle, EWC, porosity and pore structure properties of composite membranes were investigated. Cross-flow filtration studies were performed to investigation of performances of prepared membranes. It was found from the cross section SEM images that ZnO nanoparticles dispersed homogenously up to additive amount of 2% and the membrane skin layer thicknesses increased in the presence of ZnO. Contact angle of pure PSf membranes were reduced from $70^{\circ}$ to $55^{\circ}$ after addition of 4% ZnO. Porosity of composite membrane contains 1% ZnO was higher about 22% than pure PSf membrane. BSA rejection ratio and PWF of 0.5% ZnO embedded composite membrane became 2.2 and 2.3 times higher than pure PSf membrane. It was determined from flux recovery ratios that ZnO additive increased the fouling resistance of composite membranes. Also, the bacterial killing ability of ZnO is well known and there are many researches related to this in the literature. Therefore, it is expected that prepared composite membranes will show antibacterial effect.

Study on Characteristics of Electrodeposited Thin Copper Film by Inorganic Additives in Pyrophosphate Copper Plating Bath (피로인산동욕의 무기첨가제에 의한 전해동박의 특성에 관한 연구)

  • Koo, Seokbon;Hur, Jinyoung;Lee, Hongkee
    • Journal of the Korean institute of surface engineering
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    • v.47 no.1
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    • pp.1-6
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    • 2014
  • The copper deposit on steel plate was prepared by pyrophosphate copper plating solution made with variation of inorganic additive. $NH_4OH$ and $NH_4NO_3$ were used as inorganic additives. The copper layer characteristics - tensile strength, crystallite size and crystal orientation - were evaluated by X-ray diffraction and Universal Test Machine. The presence of ammonium nitrate results in reduction of average roughness value from $0.08{\mu}m$ to $0.03{\mu}m$. In pyrophosphate copper plating solution without Inorganic additive, tensile strength of electrodeposit copper foil was reduced from 600 MPa to 180 MPa after 7 days aging. However, when adding ammonium nitrate, there was almost no change of tensile strength, intensity of crystal orientation - (111), (200) and (220) - and crystallite size (2~30 nm).

Fabrication of Thin Film Dielectric by Hybrid Sol (Hybrid Sol을 이용한 박막 유전체 제작)

  • Kim, Yong-Suk;Yoo, Won-Hee;Chang, Byeung-Gyu;Oh, Yong-Soo
    • Korean Journal of Materials Research
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    • v.17 no.4
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    • pp.185-191
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    • 2007
  • The purpose of this study is to evaluate the thin fihn dielectric made of hybrid sol, which consist of barium titanate powder, polymeric sol and other polymers. This sol will be used dielectric applied to small, thin electric passive components such as MLCC(Multi Layer Ceramic Condenser), resister, inductor. This sol is composed of mixed fine barium titanate powder and polymeric sol including Ba, Ti-precursor, solvent, chelating agent, chemical reaction catalyst, the additive sols to improve fired densification and temperature reliability. First at all, we mixed hybrid sol to be dispersed and be stabilized by ball milling for 24hrs. By spin coating method, we makes thin film dielectric on the convectional green sheet for MLCC. After heat treatments, we analyzes the structure morphology, physical, electrical properties and X5R Temperature properties.

De-noising in Power Line Communication Using Noise Modeling Based on Deep Learning (딥 러닝 기반의 잡음 모델링을 이용한 전력선 통신에서의 잡음 제거)

  • Sun, Young-Ghyu;Hwang, Yu-Min;Sim, Issac;Kim, Jin-Young
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.18 no.4
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    • pp.55-60
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    • 2018
  • This paper shows the initial results of a study applying deep learning technology in power line communication. In this paper, we propose a system that effectively removes noise by applying a deep learning technique to eliminate noise, which is a cause of reduced power line communication performance, by adding a deep learning model at the receive part. To train the deep learning model, it is necessary to store the data. Therefore, it is assumed that the existing data is stored, and the proposed system is simulated. we compare the theoretical result of the additive white Gaussian noise channel with the bit error rate and confirm that the proposed system model improves the communication performance by removing the noise.

A Study on the Formation of Trench Gate for High Power DMOSFET Applications (고 전력 DMOSFET 응용을 위한 트렌치 게이트 형성에 관한 연구)

  • 박훈수;구진근;이영기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.7
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    • pp.713-717
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    • 2004
  • In this study, the etched trench properties including cross-sectional profile, surface roughness, and crystalline defects were investigated depending on the various silicon etching and additive gases, For the case of HBr$He-O_2SiF_4$ trench etching gas mixtures, the excellent trench profile and minimum defects in the silicon trench were achieved. Due to the residual oxide film grown by the additive oxygen gas, which acts as a protective layer during trench etching, the undercut and defects generation in the trench were suppressed. To improve the electrical characteristics of trench gate, the hydrogen annealing process after trench etching was also adopted. Through the hydrogen annealing, the trench corners might be rounded by the silicon atomic migration at the trench corners having high potential. The rounded trench corner can afford to reduce the gate electric field and grow a uniform gate oxide. As a result, dielectric strength and TDDB characteristics of the hydrogen annealed trench gate oxide were remarkably increased compared to the non-hydrogen annealed one.

Sintering agents with 2-dimensional layered structure and the enhancement of sinterability of cerium oxide using them (2차원 층상구조를 갖는 소결조제와 이를 활용한 세륨산화물 소결성 향상)

  • Park, Ji Young;Oh, Jae Myoung;Park, Hee Jung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.1
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    • pp.1-5
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    • 2019
  • The physical properties of ceramic materials including oxides are greatly influenced by the material density. Therefore, various efforts have been made to increase the material density. One of the most popular strategies is to use sintering additives in sintering materials. The conventional sintering additive was a spherical powder having a three-dimensional structure. In this study, sintering additive with 2-dimensional (2D) layer structure was used to increase the sintering density of cerium oxide and its effect was confirmed. In this study, 1 nm-thick $TiO_x$ and $MnO_x$ nanosheets were used as sintering additives.

Microstructure and Thermal Insulation Properties of Ultra-Thin Thermal Insulating Substrate Containing 2-D Porous Layer (2차원 기공층을 포함하는 초박형 단열기판의 미세구조 및 단열 특성)

  • Yoo, Chang Min;Lee, Chang Hyun;Shin, Hyo Soon;Yeo, Dong Hun;Kim, Sung Hoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.11
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    • pp.683-687
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    • 2017
  • We investigated the structure of an ultra-thin insulating board with low thermal conductivity along z-axis, which was based on the idea of void layers created during the glass infiltration process for the zero-shrinkage low-temperature co-fired ceramic (LTCC) technology. An alumina and four glass powders were chosen and prepared as green sheets by the tape casting method. After comparison of the four glass powders, bismuth glass was selected for the experiment. Since there is no notable reactivity between alumina and bismuth glass, alumina was selected as the supporting additive in glass layers. With 2.5 vol% of alumina powder, glass green sheets were prepared and stacked alternately with alumina green sheet to form the 'alumina/glass (including alumina additive)/alumina' structure. The stacked green sheets were sintered into an insulating substrate. Scanning electron microscopy revealed that the additive alumina formed supporting bridges in void layers. The depth and number of the stacking layers were varied to examine the insulating property. The lowest thermal conductivity obtained was 0.23 W/mK with a $500-{\mu}m-thick$ substrate.

Effect of Propionic Acid Additive on Preparation of Phase Inversion Polysulfone Membrane (폴리설폰 상전환막의 제조에 있어 프로피오닉산 첨가제의 영향)

  • Han, Myeong-Jin;Choi, Seung-Rag;Park, So-Jin;Seo, Bum-Kyoung;Lee, Kune-Woo;Nam, Suk-Tae
    • Membrane Journal
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    • v.18 no.4
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    • pp.317-324
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    • 2008
  • Polysulfone membranes were prepared via the phase inversion process. With propionic acid as a nonsolvent additive, polysulfone casting solutions were solidified in an isopropanol bath. Propionic acid (PA) worked as a thermodynamic enhancer for phase separation and as a rheological suppressor for kinetic hindrance. Morphology of the prepared membranes significantly varied with propionic acid content in the casting solution. The dense skin layer, which was identified in the membrane prepared without PA, almost disappeared in the membrane prepared trom PA 10wt%. With 30wt% PA, the membrane revealed the morphological gradient from a nodular skin structure to a sponge-like substructure, including the finger-like cavity. Water permeability increased with PA content, and polyethylene glycol rejection decreased with the nonsolvent content.

The structural and dielectric polarization characteristics of composite oxide material in $(Ba Ca)TiO_3$-Zn (복합산화물 $(Ba Ca)TiO_3$-ZnO의 구조적 및 유전분극 특성)

  • 홍경진;임장섭;정우성;민용기;김용주;김태성
    • Electrical & Electronic Materials
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    • v.10 no.3
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    • pp.239-246
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    • 1997
  • The ZnO is stabilize dielectric constant over a broad temperature range because its addition makes the relaxation time short. In this study, the composite oxide material (B $a_{0.85}$ $Ca_{0.15}$)Ti $O_{3}$ was mixed by ZnO additive material and the dielectric polarization characteristics was studied. The relative density was over 90[%] at all specimen in the structural characteristics. Among of the specimen, the relative density of (B $a_{0.85}$ $Ca_{0.15}$)Ti $O_{3}$ with ZnO (0.4mol) has a 95[%]. The grain size of composite oxide material with an increasing ZnO increased and it was 1.0[.mu.m]-1.22[.mu.m]. In the electrical characteristics, the charge and discharge current was increased by ZnO addition. The dielectric relaxation time was increased by space charge polarization at above 110[.deg. C] and the dielectric relaxation time was fixed by space charge polarization of para-dielectric layer at below 110[.deg. C]. The dielectric relaxation time was maximum when the grain size was small. The dielectric relaxation time is decreased with an additive material ZnO and interface polarization, existing void at the grain and grain boundary. The remnant polarization is increased and the coercive electric field is decreased by ZnO.

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