• Structural Engineering and Mechanics
• /
• 제82권2호
• /
• pp.259-270
• /
• 2022

The paper investigates the residual stresses arising in a thermoviscoelastic cylinder as a result of layer-by-layer deposition of material on its lateral surface. Internal stresses are caused by incompatible deformations that accumulate in the assembly as a result of joining parts with different temperatures. For the analysis of internal stresses, an analytical solution to the axisymmetric quasi-static problem of thermoelasticity for a growing cylinder is constructed. It is shown that the distribution of residual stresses depends on the scenario of the surfacing process. In this case, the supply of additional heat to the growing body can significantly reduce the unevenness of temperature fields and reduce the intensity of residual stresses. The most effective is uneven heating, which can be realized, by the action of an alternating current with a tunable excitation frequency. The temperature and residual stresses fields on the growing surface is analyzed numerically for Titanium and Copper materials.

• Tribology and Lubricants
• /
• 제36권5호
• /
• pp.267-273
• /
• 2020

This study experimentally investigates hydrophobic surfaces fabricated via additive manufacturing. Additive manufacturing, commonly known as 3D printing, is the process of joining materials to fabricate parts from 3D model data, usually in a layer-upon-layer manner. Digital light processing is used to fabricate hydrophobic surfaces in this study. This method uses photo-curable resins and ultraviolet (UV) sources. Moreover, this technique generally has faster shaping speeds and is advantageous for the fabrication of small components because it enables the fabrication of one layer at a time. Two photo-curable resins with different compositions are used to fabricate micro-patterns of hydrophobic surfaces. The resins are composed of a photo-initiator, monomer, and oligomer. Experiments are conducted to determine suitable process conditions for the fabrication of hydrophobic surfaces depending on the type of resin. The most important factors affecting the process conditions are the UV exposure time and slice thickness. The fabrication capability according to the process conditions is evaluated using the side and top views of the micro-patterns observed using a microscope. The micro-patterns are collapsed and intertwined when the exposure time is short because sufficient light (heat) is not applied to cure the photo-curable resin with a given slice thickness. On the other hand, the micro-patterns are attached to each other when the exposure time is prolonged because the over-curing time can cure the periphery of a given shape. When the slice is thicker, the additional curing area is enlarged in each slice owing to the straightness of UV light, and the slice surface becomes rough.

• 한국재료학회지
• /
• 제31권10호
• /
• pp.552-561
• /
• 2021

For the purpose of manufacturing a high efficiency TiO₂ photocatalyst, B-doped TiO₂ photocatalysts are synthesized using a plasma electrolytic oxidation method in 0.5 M H₂SO₄ electrolyte with different concentrations of H₃BO₃ as additive. For the B doped TiO₂ layer fabricated from sulfuric electrolyte having a higher concentration of H₃BO₃ additive, the main XRD peaks of (101) and (200) anatase phase shift gradually toward the lower angle direction, indicating volume expansion of the TiO₂ anatase lattice by incorporation of boron, when compared with TiO₂ layers formed in sulfuric acid with lower concentration of additive. Moreover, XPS results indicate that the center of the binding energy peak of B1s increases from 191.45 eV to 191.98 eV, which suggests that most of boron atoms are doped interstitially in the TiO₂ layer rather than substitutionally. The B doped TiO₂ catalyst fabricated in sulfuric electrolyte with 1.0 M H₃BO₃ exhibits enhanced photocurrent response, and high efficiency and rate constant for dye degradation, which is ascribed to the synergistic effect of the new impurity energy band induced by introducing boron to the interstitial site and the improvement of charge transfer reaction.

• 한국기계가공학회지
• /
• 제15권6호
• /
• pp.89-94
• /
• 2016

Consumer orientation requires that companies understand consumer needs and produce products that meet their expectations. This study proposes a new additive method that creates a polymer/metal bonding layer and thus can lighten the weight of helmets to develop a consumer-oriented 3D printing helmet. The composite solution is experimentally prepared with copper formate and a photopolymer resin. Stereolithography apparatus and photothermal reactions are introduced to fabricate an adhesive hybrid layer of copper metal and polymer. A UV pulse laser with a 355 nm wavelength was installed to simplify this process. Resistance, adhesion, and accuracy were investigated to evaluate the properties of the layer produced.

• 한국결정성장학회지
• /
• 제32권3호
• /
• pp.89-95
• /
• 2022

본 연구에서는 페놀수지를 사용하여 흑연표면에 유리질 카본 코팅을 진행하였다. 코팅액은 균일한 표면을 가지는 유리질 카본 코팅층 형성을 위해 페놀수지와 경화제, 희석제, 첨가제 등을 혼합하였다. 코팅된 페놀수지는 25~60℃에서 건조 100~200℃에서 경화 500~1,500℃에서 열처리하여 유리질 카본으로 전환하였다. 유리질 카본의 특성 분석을 위해 FTIR, XRD, SEM 분석, 밀도/기공율/접촉각 측정을 진행하였다. 유리질 카본 형성에 있어 최적 온도는 약 1,000℃로 확인되었다. 그리고 첨가제의 함량이 높아질수록 코팅 표면의 결함감소, 기공율 감소, 접촉각 증가, 밀도 증가 등의 효과를 보였다. 첨가제를 통한 유리질 카본 코팅층 형성 방법은 흑연 코팅 및 다른 분야에 적용이 가능할 것으로 기대된다.

• 한국결정성장학회지
• /
• 제22권5호
• /
• pp.213-217
• /
• 2012

Carbon coils could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and $H_2$ as source gases under thermal chemical vapor deposition system. By the incorporation of $SF_6$ additive in cyclic modulation manner, the dominant formation of the nanosized carbon coils could be achieved with maintaining the minimized sulfur additive amount. The geometry variation of the as-grown carbon coils, such as linear type, microsized coil type, wavelike nanosized coil type, and nanosized coil type, were investigated according to the different cyclic modulation manner of $SF_6$ flow. $SF_6$ gas incorporation develops the coil-type geometry. Furthermore, the higher flow rate of $SF_6$ gas increased the amount of the nanosized carbon coils. The slightly increased etching ability by $SF_6$ addition seems to be the cause for these results.

• 한국기계가공학회지
• /
• 제21권7호
• /
• pp.10-20
• /
• 2022

Recently, metal additive manufacturing (AM) is being investigated as a new manufacturing technology. In metal AM, powder bed fusion (PBF) is a promising technology that can be used to manufacture small and complex metallic components by selectively fusing each powder layer using an energy source such as laser or an electron beam. PBF includes selective laser melting (SLM) and electron beam melting (EBM). SLM uses high power-density laser to melt and fuse metal powders. EBM is similar to SLM but melts metals using an electron beam. When these processes are applied, the mechanical properties and microstructures change due to the many parameters involved. Therefore, this study is conducted to investigate the effects of the parameters on the mechanical properties and microstructures such that the processes can be performed more economically and efficiently.

• 대한금속재료학회지
• /
• 제47권9호
• /
• pp.586-590
• /
• 2009

The effects of additives on the surface morphology and physical properties of copper electrodeposited on polyimide(PI) film were investigated here. Two kinds of additives, an activator(additive A) and a leveler(additive B),were used in this study. Electrochemical experiments, in conjunction with scanning electron microscopy(SEM), X-ray diffraction(XRD) and a four-point probe, were performed to characterize the morphology and mechanical characteristics of copper electrodeposited in the presence of the additives. The surface roughness, crystal growth orientation and resistivity could be controlled using various quantities of additive B. High resistivity and lower peel strength were observed on the surface of the copper layer electroplated onto the electrolyte with no additive B. However, a uniform surface, lower resistivity and high flexibility were obtained with a combination of 20 ppm of additive A and 100 ppm of additive B.

• 한국표면공학회지
• /
• 제34권4호
• /
• pp.289-296
• /
• 2001

Ni-P electroformed layers were investigated for developing a steam generator tube repair technology in PWRs. The effects of an additive, RPP (Reagent over Pitting Protection) and agitation on mechanical properties and microstructure of the layer were evaluated. The addition of the RPP showed to inhibit the formation of pores, to refine the grain size, and to increase the residual stress in the layer. However, the agitation of the solution during electroforming was observed to increase pores in local regions of the electroformed layer, resulting in decreasing its mechanical properties. The heat treatment of the layer at $343^{\circ}C$ for 1 hr. precipitated the very fine particles of Ni3P in the layer, which inhibited grain growth and increased microhardness.

• 전기화학회지
• /
• 제20권1호
• /
• pp.13-17
• /
• 2017

본 연구에서는 고전압용 전기화학 커패시터에 응용을 위한 유기 전해액 개발에 관한 연구를 실시하였다. 사용한 기준 전해액으로는 1M의 $SBPBF_4$염이 포함된 EC:DMC(1:1) 복합 전해액을 사용하였으며, 고전압 안정성을 위해 기준 전해액에 첨가제 GBL을 5 wt.% 첨가했다. 0-3.5 V 전압 범위에서 초기 250 사이클까지의 효율이 약 2.5배 향상된 것을 확인할 수 있었으며, 2000 사이클 이후에는 약 3배 이상의 커패시턴스 효율이 유지되는 것을 확인하였다. 고전압에서 GBL이 전해액 보다 먼저 분해를 일으켜 전해액이 분해되는 현상을 억제하며 안정성을 향상시키는 효과가 있는 것으로 판단된다. 또한 분해된 GBL이 전극 표면에 흡착하여 안정한 SEI 층을 형성해줌으로서, 전극 표면을 보호하여 전해질과의 부반응을 억제해주는 역할을 하는 것으로 판단된다.