• 제목/요약/키워드: AL-complex

검색결과 681건 처리시간 0.028초

유기 발광 소자를 위한 금속 착물의 합성 및 그 박막 제조에 관한 연구 (Study on Synthesis of Metal Complex and Preparation of Its Thin Films for Organic Electroluminescent Device)

  • 황장환;김영관;김정수;손병청
    • 한국응용과학기술학회지
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    • 제14권2호
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    • pp.81-85
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    • 1997
  • Tris(8-hydroxyquinoline)-aluminum complex($AlQ_3$) having greenish luminescent characteristics was synthesized and it was confirmed with UV-Vis absorption spectroscopy, elemental analysis, and FT-IR spectroscopy that $AlQ_3$ was successfully synthesized. Thin films of $AlQ_3$ having multilayer structure were prepared by spin coating method and vacuum evaporation technique. Photopluminescent characteristics of these films were investigated by Luminescence spectroscopy and Current-Voltage(I-V) characteristics of these films were also investigated.

$ITO/Alq_3(60nm)/Al$의 유기 발광 소자에서 바이어스 전압과 주파수에 따른 전기적 특성 (Voltage and frequency dependent electrical properties in organic light-emitting diodes of $ITO/Alq_3/Al$)

  • 정동회;오현석;허성우;이원재;송민종;이준웅;김태완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.464-468
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    • 2003
  • Complex impedances with frequency and voltage variation were analyzed in $ITO/Alq_3(60nm)/Al$ device structure. At low frequency, complex impedance is mostly expressed by resistive component, and at the high frequency by resistance and capacitive component. We have also evaluated resistance, capacitance and permittivity.

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NEIGHBORHOOD PROPERTIES FOR CERTAIN p-VALENT ANALYTIC FUNCTIONS ASSOCIATED WITH q - p-VALENT BERNARDI INTEGRAL OPERATOR OF COMPLEX ORDER

  • ALDAWISH, I.;AOUF, M.K.;SEOUDY, T.M.;FRASIN, B.A.
    • Journal of applied mathematics & informatics
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    • 제40권3_4호
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    • pp.753-764
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    • 2022
  • In this paper, we introduce and investigate two new subclasses of p-valent analytic functions of complex order defined by using q-p-valent Bernardi integral operator. Also we obtain coefficient estimates and consequent inclusion relationships involving the (q, m, 𝛿)-neighborhoods of these subclasses.

여천공단 주변지역 토양의 화학적 성질 (Chemical Properties of Soils in the Vicinity of Yoch의on Industrial Complex)

  • 문형태;표재훈;김준호
    • The Korean Journal of Ecology
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    • 제21권1호
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    • pp.1-6
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    • 1998
  • Effects of air pollutants on the chemical properties of soil in Yoch'on inductrial complex were investigated. Soil pH showed severe acidity with average value of 4.3$\pm$0.13. Soil pH decreaed along the increase in altitute of Mt. Jeseok. Soil organic matter and total N was 19.2$\pm$3.6% and 4.7$\pm$0.25mg/g, respectively, which were higher than those of unpolluted area, Kongju. Available P was 41.2$\pm$3.7 $\mu$g/g, which was 4 times greater than that of unpolluted area, Kongju. Average content of total-S was 283.5$\pm$14.1 $\mu$g/g, which was 10 times greater than that of unpolluted area. Content of available Al was o.43$\pm$0.03 mg/g, which was 2 times greater than that of unpolluted area. Available Al increased as the soil pH decrease. Contents of exchangeable K, Ca and Mg were significantly lower than those in unpolluted area, because of severe leaching in acid soil.

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CR-WARPED PRODUCT SUBMANIFOLDS OF NEARLY KAEHLER MANIFOLDS

  • Al-Luhaibi, Nadia S.;Al-Solamy, Falleh R.;Khan, Viqar Azam
    • 대한수학회지
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    • 제46권5호
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    • pp.979-995
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    • 2009
  • As warped product manifolds provide an excellent setting to model space time near black holes or bodies with large gravitational field, the study of these manifolds assumes significance in general. B. Y. Chen [4] initiated the study of CR-warped product submanifolds in a Kaehler manifold. He obtained a characterization for a CR-submanifold to be locally a CR-warped product and an estimate for the squared norm of the second fundamental form of CR-warped products in a complex space form (cf [6]). In the present paper, we have obtained a necessary and sufficient conditions in terms of the canonical structures P and F on a CR-submanifold of a nearly Kaehler manifold under which the submanifold reduces to a locally CR-warped product submanifold. Moreover, an estimate for the second fundamental form of the submanifold in a generalized complex space is obtained and thus extend the results of Chen to a more general setting.

TRIP강에서 Al이 미세구조와 상변태에 미치는 영향 (Effects of Al in TRIP steels on microstructure and phase transformation)

  • 임남석;김성일;박찬경
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 추계학술대회 논문집
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    • pp.213-216
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    • 2009
  • In this study, three cold-rolled TRIP steels containing different Al content (0.04wt%, 1.0 wt.% and 2.00wt%) were fabricated to understand the complex effects of Al in TRIP steel. The influences of Al on microstructural evolution of cold-rolled TRIP steels have been analyzed by using advanced analysis techniques, such as transmission electron microscope (TEM) and three dimensional atom probe tomography (3D-APT). TEM results revealed that second phases such as bainte and retained austenite decrease with increase of Al content. In addition, 3D-APT was used to characterize atomic-scale distribution of alloying elements at the constituent phases. Through these analysis techniques, the advanced characteristics of constituent microstructure in TRIP steels were identified depending on Al contents in TRIP steels.

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CaO-Gd2O3-Al2O3계에서의 PDP용 Eu3+와 Tb3+ 활성 형광체의 탐색 (Screening of Eu3+-and Tb3+-Activated Phosphors for PDP in the System of CaO-Gd2O3-Al2O3)

  • 박상미;김창해;박희동;장호겸;박준택
    • 대한화학회지
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    • 제46권4호
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    • pp.336-345
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    • 2002
  • 본 연구에서는 조합화학을 이용하여 $CaO-Gd_2O_3-Al_2O_3$계에서 $Eu^{3+}$$Tb^{3+}$활성 적색 및 녹색 PDP용 형광체를 탐색하였으며 탐색된 형광체의 합성온도, 최적조성,발광 특성 등을 조사하였다. $CaO-Gd_2O_3-Al_2O_3$의 삼성분계의 형광특성 라이브러리를 작성하기 위하여 210개의 다른 조성을 가진 시료를 고분자 착체 중합법으로 합성하였다. 합성된 형광체 분말을 VUV PL로 측정하여 형광 특성 라이브러리를 작성하였고 발광특성이 잘 나타난 시료를 XPD를 이용하여 결정 구조를 확인하였다. 적색 형광체로서 탐색된 $Ca_{\alpha}$G$d_{0.95-\alpha-\beta}$$Al_\beta$$O_\delta$ : Eu(0.02< $\alpha+\beta$ <0.04)형광체는 색순도 면에서 상용형광체보다 개선된 특성을 보였으며 녹색 형광체로서 탐색된 $CaGdAl_3O_7$ : Tb, Ca$Al_{12}$$O_{19}$ : Tb, $Gd_4Al_2$$O_9$ : Tb, $Gd_3Al_5$$O_{12}$ : Tb 형광체 중에서 $CaGdAl_3O_7$ : Tb, Ca$Al_{12}$$O_{19}$ : Tb형광체는 상용 형광체에 비해 잔광시간이 짧은 특성을 보였다

산화물 표면의 U(VI) 흡착에 미치는 살리실산과 피콜린산의 영향 (Effect of Salicylic and Picolinic Acids Acids on the Adsorption of U(VI) onto Oxides)

  • 박경균;정의창;조혜륜;송규석
    • 방사성폐기물학회지
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    • 제7권4호
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    • pp.219-227
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    • 2009
  • 세 종류의 산화물($TiO_2$(아나타제), $SiO_2$(비결정성) 및 $Al_2O_3$(비결정성)) 표면에 U(VI)이 흡착될 때 유기산이 미치는 영향을 연구하였다. 유기산으로는 살리실산과 피콜린산을 사용하였다. 유기산의 존재 여부에 따라 달라지는 U(VI)의 흡착률 변화를 pH 함수로 측정하였다. 또한 U(VI)의 존재 여부에 따라 달라지는 유기산의 흡착량을 pH 함수로 측정하였다. $TiO_2$의 경우, 살리실산과 피콜린산이 U(VI)과 수용성 착물을 형성함으로써 U(VI)의 흡착률을 저하시킨다. $SiO_2$의 경우, 살리실산은 U(VI) 흡착에 영향을 주지 않지만, 피콜린산은 오히려 U(VI) 흡착을 증가시킨다. 이 현상을 삼성분 표면착물(ternary surface complex) 생성으로 해석하였으며 U(VI) 흡착에 의존하는 피콜린산의 흡착량 변화, 그리고 흡착된 U(VI)의 형광 특성 변화로 이를 확인하였다. $Al_2O_3$의 경우, 살리실산과 피콜린산 모두 U(VI) 흡착과 무관하게 높은 흡착량을 보였으나 U(VI) 흡착을 감소시키지는 않았다. 따라서 삼성분 표면착물 생성을 배제할 수 없으나 이를 확인하기 위해서는 분광 분석과 같은 추가 연구가 필요하다.

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MOCVD에 의한 Al 박막 증착 중의 표면 반사도 측정을 통한 박막 성장 메커니즘 분석 (Analysis of Growth Mechanism of Al Thin Film by in-situ Surface Reflectance Measurement During MOCVD Process)

  • 김기수;서문규
    • 한국전기전자재료학회논문지
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    • 제28권2호
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    • pp.104-108
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    • 2015
  • Al thin films were deposited on TiN/Si(100) via metal-organic chemical vapor deposition using N-methylpyrrolidine alane as a precursor. Characterization of the deposited films were investigated with SEM, XRD, ${\alpha}$-step, AFM, 4-point probe. The early stage of Al thin film deposition was analyzed by in-situ surface reflectance measurement with laser and photometer apparatus. The surface reflectance were changed greatly during the initial 30~40 seconds. There were two increases and two decreases in the surface reflectance, thus the sequence of Al films were deposited at 8 significant points of the surface reflectance change. Surface topograph and cross-sectional view of each film were analyzed with SEM. Al films were grown in the complex mechanism of Volmer-Weber and Stranski-Krastanov process.