• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.357-361
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• 1999

GOD electrochemically immobilized in PPy/GOD complex have an effect on redox properties of the complex. In the cyclicvoltammetry, GOD shows the redox reaction at the potential below -0.6Y vs. Ag/AgCI. That leads to new peaks in the cyclicvoltammograms in additional to typical PPy peaks. The pH of electrolyte solution during potential swing decreased to 4.4, and then increased to 10. That suggests the redox of GOD for the cycling. As the concentration of GOD was increased, the anodic wave of the new peaks was strong as much as increased. GOD obstructs the diffusion of electrolyte anion because of its net chain. Insulating property of GOD is cause that it made the faradic impedance of complex large in charge transfer. It suggests that increase of the concentration of GOD be against electrochemical coupling. Therefore, the concentration of GOD and electrochemical coupling should be dealt with each other. The apparent Michaelis-lenten constant ( K\`$_{M}$ ) was determined by 30.7 mmol d $m^{-3}$ fur the PPy/GOD complex. The value is of the same order of magnitude as that for soluble glucose oxidase from Aspergillus Niger.r.

• Journal of Oral Medicine and Pain
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• 제20권1호
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• pp.229-246
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• 1995

The deoxyribonucleic acid(DNA) was isolated from the pulp, dentin and enamel of the 4 fresh teeth and the 7 teeth left in room temperature for 10 years. Then it was examed to find out the usefulness for forensic dental medicine. Samples of the tooth-derived DNA amplified by polymerase chain reaction(PCR), electrophosed for sex determination by detection of X-Y homologous amelogenin gene and D1S80 locus detection. The following results have been achieved. DNA extraction was possible in pulp and dentin of the fresh teeth, so it could be applicatable to detection of X-Y homologous amelogenin gene for sex determination, amplification of D1S80 locus by PCR. Sex determination was possible in pulp and dentin of the teeth left at room temperature for 10 years. Also, possible the detection fo AMP-FLPs to increase PCR cycling up to 40. DNA was isolated from all pulp of the fresh teeth and the teeth left in room temperature for 10 years, and also isolated from the dentin of the fresh teeth, partially isolated(3/7) from the dentin of the teeth left in room temperature for 10 years, but DNA was not isolated from enamel. From the above investigation, DNA extraction, sex determination, amplification of D1S80 locus were successfully accomplished even though the teeth were left for 10 years at room temperature. Therefore, teeth, especially pulp, are highly reliable and applicable as molecular biological samples for individual identification.

• 공업화학
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• 제27권4호
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• pp.421-426
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• 2016

본 연구에서는 폴리옥소메탈레이트(polyoxometalate, POM)가 도핑된 폴리피롤(polypyrrole, Ppy)을 3차원 구조의 탄소천(carbon cloth, CC) 표면 위에 전기화학적 증착법을 이용하여 합성하고 이의 의사커패시터 특성을 순환전압전류법과 정전류 충전-방전법을 사용하여 분석하였다. POM-Ppy의 코팅은 전기화학적 증착 시간에 따라서 얇은 conformal형태의 코팅으로 조절되었다. 제조된 POM-Ppy/CC의 재료 특성은 전자주사현미경과 X-선 분광분석을 사용하여 분석하였다. POM-Ppy/CC의 3차원 나노복합체 구조는 높은 비정전용량($561mF/cm^2$), 고속 충방전(85% 용량 유지율) 및 장수명 특성(97% 용량 유지율)을 나타내었다.

• 수산해양기술연구
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• 제47권1호
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• pp.46-58
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• 2011

A steady-state analysis and a simple dynamic model as simplified methods are developed, and results of energy consumption loads are compared with results obtained using computer to evaluate the analytical solution. Before obtaining simplified model a mathematical model is formulated for the effect of wall mass on the thermal performance of four different houses having various wall construction. This analytical study was motivated by the experimental work of Burch et al. An analytical solution of one-dimensional, linear, partial differential equation for wall temperature profiles and room air temperatures is obtained using the Laplace transform method. Typical Meteorological Year data are processed to yield hourly average monthly values. This study is conducted using weather data from four different locations in the United States: Albuquerque, New mexico; Miami, Florida; Santa Maria, California; and Washington D.C. for both winter and summer conditions. The steady state analysis that does not include the effect of thermal mass can provide an accurate estimate of energy consumption in most cases except for houses #2 and #4 in mild weather areas. This result shows that there is an effect of mass on the thermal performance of heavily constructed house in mild weather conditions. The simple dynamic model is applicable for high cycling rates and accurate values of inside wall temperature and ambient air temperature.

• 한국정밀공학회지
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• 제20권4호
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• pp.165-173
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• 2003

As the cycling time of new products have become more and more short in recent years, the demand for lowering the cost and reducing the production time becomes stronger. In order for the demand, the rapid prototyping and rapid tooling technology have been used. It has been widely known that RP technology has advantages with fabricating 3-D object having a complicated geometric shape. RP products, however, have a limitation with applying to the real die and mold because soft materials such as resin, paper and wax has been mostly used in RP technology. So in this paper, the RP products have been copied to semi-metallic soft tools using the mixture of metal fillers and epoxy resin. In order to evaluate the effect of the fillers on the characteristics of semi-metallic soft tools, three fillers are used including commercial aluminum powder, cast iron powder recycled by machining chips, and aluminum short fiber made by self-excited vibration technique. Besides, in the case of aluminum powder, the change of characteristics of semi-metallic soft tools is also tested according to the volume fraction of the powder.

• Journal of Electrochemical Science and Technology
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• 제12권2호
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• pp.285-295
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• 2021

The inverse spinel Cobalt ferrite (CoFe₂O₄, CFO) is considered to be a promising alternative to commercial graphite anodes for lithium ion batteries (LIBs). However, the further development of CFO is limited by its unstable structure during battery cycling and low electrical conductivity. In an effort to address the challenge, we construct three-dimensional hierarchical flower-like CFO nanoclusters (CFO NCs)-decorated carbonized cotton carbon fiber (CFO NCs/CCF) composite. This structure is consisted of microfibers and nanoflower cluster composited of CFO nanoparticle, in which CCF can be used as a long-range conductive matrix, while flower-like CFO NCs can provide abundant active sites, large electrode/electrolyte interface, short lithium ion diffusion path, and alleviated structural stress. As anode materials in LIBs, the flower-like CFO NCs/CCF exhibits excellent electrochemical performance. After 100 cycles at a current density of 0.3 A g^-1, the CFO NCs/CCF delivers a discharge/charge capacity of 1008/990 mAh g^-1. Even at a high current density of 15 A g^-1, it still maintains a charge/discharge capacity of 362/361 mAh g^-1.

• 한국운동역학회지
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• 제18권2호
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• pp.59-64
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• 2008

본 연구는 3축 가속도 센서를 허리에 부착하여 실시간으로 스포츠 동작분류를 할 수 있는 모니터 링에 관한 연구를 실시하였다. 이 모니터링 시스템은 스포츠 동작의 기본이라고 할 수 있는 걷기, 달리기, 자세변화 동지 정지상태의 동작들과 추가적으로 사이클링 동작을 분류할 수 있도록 하였다. 또한 운동 시에 발생할 수 있는 낙상을 감지하여 위급상황에 대한 정보도 나타나게 하였다. 가속도센서모듈은 인체에 부착된 형태로 스포츠 활동을 모니터링하기 위하여 소형으로 설계되었으며 활동에 방해가 되지 않게 허리에 부착되었다. 측정된 데이터는 RF통신을 통해 PC로 전송되며 알고리즘을 통해 실시간으로 동작분류를 시행하게 된다. 개발된 알고리즘을 검증하기 위한 실험으로 5명의 피험자를 대상으로 서로 다른 속도의 걷기, 달리기, 사이클링 동작을 각각 100초간 실시하였으며 낙상과 자세변화 동작(앉았다 일어서기, 누웠다 일어서기, 서있다 앉기, 누웠다 앉기, 서있다 눕기, 앉았다 눕기)은 각각 20회씩 실행하였다. 그 결과 동작분류 정확도는 95.4%를 나타내었다. 이번 연구에서 스포츠 모니터링을 통하여 정확한 자신의 운동 정보를 알려주고 운동 시에 발생하는 낙상에 대한 위급상황을 알려줌으로써 스포츠 활동에 도움을 주고자 하였으며, 추가적인 연구로 각각의 스포츠 활동에 대한 정확한 에너지 소비 추정 알고리즘을 개발 중에 있다.

• 한국응용약물학회:학술대회논문집
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• 한국응용약물학회 1997년도 춘계학술대회
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• pp.109-109
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• 1997

Inhibitory effect on DNA topoisomerase-I, rate of glutathione conjugation and cytotoxicity of naphthoquinone derivatives were correlated. During 5 min exposure of the derivatives to glutathione (GSH), it was found that 14% of 5,8-dimethoxy-1,4-naphthoquinone(DMNQ) was converted into a GSH-conjugate, whereas 5,8-dihydroxy-1,4-naphthoquinone(DHNQ) did not interact with GSH, implying that DMNQ exerted higher electrophilicity than DHNQ. However, DHNQ (IC$\_$50/, 0.15 ${\mu}$M) showed stronger cytotoxicity in L1210 cells than DMNQ(IC$\_$50/, 0.45 ${\mu}$M). The stronger cytotoxicity of DHNQ, compared to DMNQ, could be ascribed to more rapid redox cycling. Both naphthoquinones (IC$\_$50/, 60-65 ${\mu}$M) exhibiting about the same inhibitory effect on DNA topoisomerase-I were more potent than 1,4-naphthoquinone(1,4-NQ, IC$\_$50/, 134 ${\mu}$M). Thus, 5,8-oxy groups in the structure seem to be important for the inhibition of the enzyme. DMNQ showed a broader dose range while maintaining a good antitumor activity against S-180 fluid tumor. For these reasons, DMNQ was taken as useful pharmacophore for structural modification. Introduction of 1-hydroxyalkyl groups at C-2 of DMNQ lowered all of the activities mentioned above, while acetylation of 1-hydroxyalkyl moiety enhanced the activities by 4-5 times. Introduction of the same side chains at C-6 exhibited stronger activities than 2-substituted ones. Based on these results it was suggested that the quinonoid moiety in 6-substituted DMNQ was more exposed to cellular nucleophiles such as DNA, thiols of enzymes and so on. The synthesis of DHNQ or DMNQ derivatives are going on, and the corelationship between structure-activity will be discussed.

• 세라미스트
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• 제21권2호
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• pp.4-18
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• 2018

Lastly, neuromorphic computing chip has been extensively studied as the technology that directly mimics efficient calculation algorithm of human brain, enabling a next-generation intelligent hardware system with high speed and low power consumption. Three-terminal based synaptic transistor has relatively low integration density compared to the two-terminal type memristor, while its power consumption can be realized as being so low and its spike plasticity from synapse can be reliably implemented. Also, the strong electrical interaction between two or more synaptic spikes offers the advantage of more precise control of synaptic weights. In this review paper, the results of synaptic transistor mimicking synaptic behavior of the brain are classified according to the channel material, in order of silicon, organic semiconductor, oxide semiconductor, 1D CNT(carbon nanotube) and 2D van der Waals atomic layer present. At the same time, key technologies related to dielectrics and electrolytes introduced to express hysteresis and plasticity are discussed. In addition, we compared the essential electrical characteristics (EPSC, IPSC, PPF, STM, LTM, and STDP) required to implement synaptic transistors in common and the power consumption required for unit synapse operation. Generally, synaptic devices should be integrated with other peripheral circuits such as neurons. Demonstration of this neuromorphic system level needs the linearity of synapse resistance change, the symmetry between potentiation and depression, and multi-level resistance states. Finally, in order to be used as a practical neuromorphic applications, the long-term stability and reliability of the synapse device have to be essentially secured through the retention and the endurance cycling test related to the long-term memory characteristics.

• 전기화학회지
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• 제3권3호
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• pp.173-177
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• 2000

리튬 이차 전지의 성능은 부극으로 쓰이는 탄소재료의 표면의 미세 구조에 크게 의존한다. 본 연구에서는 이러한 표면 구조의 개질을 위해 유동상 화학증착법을 도입하여 금속 및 금속 산화물을 탄소재료 표면에 코팅하여 그 성능을 전기 화학적으로 평가하였다. 주석산화물을 코팅한 탄소 전극은 원래의 탄소 전극에 비해 용량의 상승을 나타내었으나 사이클이 진행됨에 따라 주석산화물이 코팅된 전지의 용량은 심각한 부피 변화에 의해 저하되어 사이클 수명이 감소되었다. 그러나, 부피 변화를 완화시켜주는 비활성 매트릭스 역할을 하는 구리를 주석 산화물 위에 코팅함으로 인해 부피 변화에 의한 용량 저하를 감소시킬 수 있었다.