• 한국세라믹학회지
• /
• 제42권2호
• /
• pp.132-139
• /
• 2005

마이크로파 유전체 세라믹스 $BaO-Nd_{2}O_3-TiO_{2}(BNT)$계 상용분말과 PbO-base의 결정화 유리프릿 복합체를 출발원료로 하여 테입 케스팅법으로 그린시트를 제초하기 위해 첨가유기물의 조성 변화에 따른 슬러리의 분산특성 및 유동특성 그리고 최종그린시트의 그린/소결밀도 변화를 연구하였다. 분산제량의 증가는 분산에 유효하였으나, 일정량 이상이 첨가되면 분산을 저해하는 요인으로 작용하였으며 복합체 분말에 1.75 wt$\%$의 fish oil을 첨가하였을 때 분산특성이 가장 우수하였다 준비된 모든 조성의 슬러리에서 의가소성거동(shear thinning)이 나타났고 파우더, 바인더 그리고 유기물의 전체 함량이 증가할수록 상대점도는 증가하는 경향을 나타내었다. 복합체 분말과 용매의 비율 65 : 35, 결합제는 6 wt$\%$, 가소제는 3 wt$\%$에서 테이프의 특성이 가장 우수하였다. 이때 슬러리의 점도는 677cps, 그린/소결밀도는 $3.3g/cm^3,\;5.56g/cm^3$로 각각 나타났다.

• 한국전기전자재료학회논문지
• /
• 제14권11호
• /
• pp.879-884
• /
• 2001

In this paper, the structural and dielectric properties of (Sr$_{l-x}$Ca$_{x}$)TiO$_3$ (0$\leq$x$\leq$0.2) -based grain boundary layer ceramics were investigated by XRD, SEM and HP4194A. The ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were 1420~152$0^{\circ}C$ and 4 hours, respectively. The average grain size and the lattice constant were decreased with increasing content of Ca. The average grain size was increased with increase of sintering temperature. The relative density of all specimens was 96~98%. The 2nd Phase formed by the thermal diffusion of CuO from the surface leads to very excellent dielectric properties, that is, $\varepsilon$$_{r}$>50000, tan $\delta$<0.05, $\Delta$C<$\pm$10%. The appropriate Ca content was under 15 ㏖%.s under 15 ㏖%.%.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
• /
• pp.34-37
• /
• 2001

In this study, the capacitance-voltage properties of $(Sr_{1-x}\cdot Ca_x)TiO_3(0.05{\leq}x{\leq}0.20)$-based grain boundary layer ceramics were investigated. The ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were $1480\sim1500^{\circ}C$ and 4 hours. respectively. The 2nd phase formed by the thermal diffusion of CuO from the surface leads to very excellent dielectric properties, that is, ${\varepsilon}_r$ >50000, tan$\delta$ <0.05, ${\Delta}C$ < ${\pm}10%.$ The capacitance is almost unchanged below about 20[V] but it decreases slowly about 20[V]. The results of the capacitance-voltage properties indicated that the grain boundary was composed of the continuous insulating layers.

• 대한건축학회논문집:구조계
• /
• 제35권10호
• /
• pp.199-206
• /
• 2019

This study aims to recycle redmud which is a byproduct in the alumina industry. Redmud ceramics were prepared according to the type of raw materials by blending redmud with the raw materials used in the conventional clay bricks. In this paper, the compressive strength, water absorption ratio, and shrinkage of redmud ceramics prepared by mixing clay bricks were evaluated. Compressive strength and absorption ratio of redmud ceramics were compared with the clay brick criteria of KS L 4201. At the firing temperature of $1200^{\circ}C$, the specimens containing redmud only and the redmud with sandy loam and black clay were found to satisfy the 1st class of clay brick. The quality standard of compressive strength and absorption ratio was obtained by firing redmud with black clay and sandy loam at $1200^{\circ}C$. Also, when the redmud was mixed with black clay and feldspar, the 2nd class was satisfied when the sample was fired at $1100^{\circ}C$.

• 자원리싸이클링
• /
• 제29권6호
• /
• pp.73-78
• /
• 2020

선탄 폐석의 유리 소재 원료로의 활용을 위해 선탄 폐석의 고온 상 전위 거동 및 Na2CO3의 첨가에 따른 유리질(비정질)화 실험을 실시하였다. 실험 결과 700~1,100 ℃에서 소성된 선탄폐석에는 mullite가 생성되고, 1,450 ℃에서는 mullite와 cristobalite만이 존재하였다. 선탄 폐석의 유리질화는 Na2CO3 첨가됨에 따라 진행되었으며, Na2CO3 10 wt.% 첨가 후 1,450 ℃ 온도에서 소성된 선탄 폐석의 유리질화는 97.9 wt.%로 나타났다. 그러나 Na2CO3가 20 wt.% 첨가된 선탄 폐석의 시료의 경우, 1,100 ℃에서의 2차 재소성 과정에서 nepheline(Na2O·Al2O3·2SiO2)이 생성되었으며, 이를 통해 선탄폐석의 유리질화를 위한 최적의 Na2CO3 첨가량은 10 wt.%로 나타났다.

• 한국세라믹학회지
• /
• 제35권3호
• /
• pp.264-272
• /
• 1998

The effect of catalytic condition on the properties of SiO2 aerogels has been investigated and then the dri-ed aerogels were partially densified to induce mechanical strength by heat treatment in order to prepare Type-VI silica by Sol-Gel method. Aerogel made by 1-step base process had the highest skeletal density lowest shrinkage and the smallest particle size. But in case of using acid catalyst in both 1st and 2nd step had the lowest skeletal density highest shrinkage and the largest particle size The aerogel synthesized by 1-step base process was most transparent because of its homogeneous microstructure. During heat treatments cracks occurred below 200$^{\circ}C$ for aerogel with the skeletal density lower than 1.9 g/cm3 but the with the higher skeletal density did not cracked up to 800$^{\circ}C$ shrinkage and skeletal density increased as heating temperature increased due to condensation and viscous sintering mechanism.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 하계학술대회 논문집
• /
• pp.993-996
• /
• 2001

In the composition of 0.16BaO-0.15(Nd$\_$0.87/,Bi$\_$0.13/)$_2$O$_3$-0.69TiO$_2$$.$Glass [EG-2782] 3wt% addition sintered at 1080$^{\circ}C$, we could obtained microwave properties of dielectric constant $\varepsilon$$\_$r/= 80.1, quality factor Q ${\times}$ f = 810 (at 3.5 GHz]) and temperature coefficient of resonant frequency $\tau$$\_$f/ = -1.3 [ppm/$^{\circ}C$]

• 한국전기전자재료학회논문지
• /
• 제29권12호
• /
• pp.781-785
• /
• 2016

With trend of the miniaturization and the high-functionalizing of mobile communication system, low-loss microwave dielectric materials are widely used for high frequency communication components. These dielectric materials should be co-sintered with highly electric-conducting metal such as silver or copper for high-frequency and thick film process application. Sintering temperature of $Ca(Li_{1/3}Nd_{2/3})_{0.2}Ti_{0.8}]O_{3-{\delta}}$, which has excellent dielectric properties such as ${\varepsilon}_r$ above 40, quality factor ($Q{\cdot}f_0$) above 16,000 GHz, and TCF (temperature coefficient of resonant frequency) of $-20{\sim}-10ppm/^{\circ}C$, is reported as high as $1,175^{\circ}C$, so it could not be co-sintered with silver or copper. Therefore in this study, low-temperature melting glasses of Zn-B-O and Zn-B-Si-O systems were added to $Ca[(Li_{1/3}Nb_{2/3})_{0.8}Ti_{0.2}]O_{3-{\delta}}$ to lower its sintering temperature under $900^{\circ}C$ without losing excellency of dielectric properties. With 15 weight % of Zn-B-Si-O glass and sintered at $875^{\circ}C$, specimen showed density of $4.11g/cm^3$, ${\varepsilon}_r$ of 40.1, $Q{\cdot}f_0$ of 4,869 GHz, and TCF of $-5.9ppm/^{\circ}C$. With 15 weight % of Zn-B-O glass and sintered at $875^{\circ}C$, specimen showed density of $4.14g/cm^3$, ${\varepsilon}_r$ of 40.4, $Q{\cdot}f_0$ of 7,059 GHz, and TCF of $-0.92ppm/^{\circ}C$.

• 한국재료학회지
• /
• 제15권3호
• /
• pp.177-182
• /
• 2005

Large amounts of the waste SiC sludge containing small amounts of Si and organic lubricant were produced during the wire cutting process of the single silicon crystal ingots. The waste SiC sludge was purified by the washing process and the purified SiC powders were used to fabricate continuously porous $SiC-Si_3N_4$ composites using a fibrous monolithic process, in which carbon, $6wt\%\;Y_2O_3-2\;wt\%\;A1_2O_3$ and ethylene vinyl acetate were added as a pore-forming agent, sintering additives, and binder, respectively. In the burning-out process, carbon was fully removed and continuously porous $SiC-Si_3N_4$ composites were successfully fabricated. The green bodies containing SiC, Si particles and sintering additives were nitrided at $1410^{\circ}C$ in a flowing $N_2+10\%\;H_2$ gas mixture. Continuously porous composites were combined with SiC, ${\alpha}Si_3N_4,\;\beta-Si_3N_4$ and a few $\%$ of Fe phases. The pore size of the 2nd and the 3rd passed $SiC-Si_3N_4$ composites was $260\;{\mu}m$ and $35\;{\mu}m$ in diameter, respectively.

• 한국세라믹학회지
• /
• 제43권8호
• /
• pp.504-508
• /
• 2006

Functionally gradient porous $Al_2O_3-(t-ZrO_2)/HAp$ composites consist of 3 layers were fabricated using the multi-pass extrusion process at the various temperatures. The continuous pores were homogeneously formed in the $2^{nd}$ passed samples and their size was about $180{\mu}m$ in diameter. In the porous composites sintered at $1200-1400^{\circ}C$, the relative density and bending strength increased with the sintering temperature. The maximum values of relative density and bending strength in the $2^{nd}$ passed $Al_2O_3-(t-ZrO_2)/HAp$ composites were 62.2% and 107.8 MPa, respectively. In order to investigate the growth behavior of osteogenic cells on the functionally gradient porous $Al_2O_3-(t-ZrO_2)/HAp$ composites, an in vitro test was performed, using human osteoblast-like MG-63 cells. The cells were well attached and grown on the rough surface of the inside of the functionally gradient porous body.