• Title/Summary/Keyword: 1계 최적화

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Analysis of Trace Levels of Lodinated Trihalomethanes in Water Using Headspace - GC/ECD (Headspace - GC/ECD를 이용한 수중의 미량 요오드계 트리할로메탄류 분석)

  • Son, Hee-Jong;Song, Mi-Jung;Kim, Kyung-A;Yoom, Hoon-Sik;Choi, Jin-Taek
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.1
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    • pp.35-41
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    • 2014
  • Trihalomethanes (THMs) are formed as a results of the reaction of residual chlorine, used as a disinfectant in drinking water, with the organic matter in raw water. Although chlorinated and brominated THMs are the most common disinfection byproducts (DBPs) reported, iodinated THMs (I-THMs) can be formed when iodide is present in raw water. I-THMs have been usually associated with several medicinal or pharmaceutical taste and odor problems and is a potential health concern since they have been reported to be more toxic than their brominated and chlorinated analogs. Currently, there is no published standard analytical method for I-THMs in water. An automated headspace-gas chromatography/electron capture detector (GC/ECD) technique was developed for routine analysis of 10 THMs including 6 I-THMs in water samples. The optimization of the method is discussed. The limits of detection (LOD) and limits of quantification (LOQ) range from 12 ng/L to 56 ng/L and from 38 ng/L to 178 ng/L for 10 THMs, respectively. Matrix effects in river water, sea water and wastewater treatment plant (WWTP) final effluent water were investigated and it was shown that the method is suitable for the analysis of trace levels of I-THMs, in a wide range of waters. The method developed in the present study has the advantage of being rapid, simple and sensitive.

Synthesis of an Aspartame Precursor Using Thermolysin in Organic Two-Phase System (유기용매 이상계에서 Thermolysin에 의한 아스파탐 전구체 생산)

  • 이인영;안경섭;이선복
    • Microbiology and Biotechnology Letters
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    • v.20 no.1
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    • pp.61-67
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    • 1992
  • The synthesis of N-benzyloxycarbonyl-L-aspartyl-L-phenylalanine methyl ester(ZAPM), a precursor of aspartame, from N-benzyloxycarbonyl-L-aspartic acid(Z-Asp) and L-phenylalanine methyl ester hydrochloride(L-PM-HCl) was investigated in ethylacetate-MES buffer two-phase system using thermolysin. In organic two-phase system, the degree of spontaneous hydrolysis of L-PM. HCl was significantly reduced with increasing the volume ratio of organic to aqueous phase. Stability of thermolysin in organic two-phase system was found to be higher than that in MES buffer solution. More than 90% of initial enzyme activity was maintained after 10 days of incubation in case that the volume of organic phase was equal to that of buffer phase, while the half life of thermolysin was about 2 days in aqueous buffer solution. The results of partitioning of substrates and product in organic two-phase system showed that the difference in partition coefficients between substrates and product was maximum at pH 5.5. The optimal pH for 2-APM synthesis in organic two-phase system was found to be 5.5-5.8, which is consistent with the value expected from the partition experiments. As the concentration of substrates was increased the conversion yield of Z-APM was increased with concomitant reduction of L-PMqHC1 hydrolysis. In case that the concentration of L-PM-HCl and Z-Asp were 160 mM and 80 mM respectively, the conversion yield of Z-APM reached 90% after 28 hrs of reaction. The yield obtained at different volume ratio of organic phase compares well with the predicted equilibrium constant in biphasic system.

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Development of Algorithm for Advanced Driver Assist based on In-Wheel Hybrid Driveline (인휠 전기 구동 기반의 능동안전지원 알고리즘 개발)

  • Hwang, Yun-Hyoung;Yang, In-Beom
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.12
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    • pp.1-8
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    • 2017
  • This paper presents the development of an adaptive cruise control (ACC) system, which is one of the typical advanced driver assist systems, for 4-wheel drive hybrid in-wheel electric vehicles. The front wheels of the vehicle are driven by a combustion engine, while its rear wheels are driven by in-wheel motors. This paper proposes an adaptive cruise control system which takes advantage of the unique driveline configuration presented herein, while the proposed power distribution algorithm guarantees its tracking performance and fuel efficiency at the same time. With the proposed algorithm, the vehicle is driven only by the engine in normal situations, while the in-wheel motors are used to distribute the power to the rear wheels if the tracking performance decreases. This paper also presents the modeling of the in-wheel motors, hybrid in-wheel driveline, and integrated ACC control system based on a commercial high-precision vehicle dynamics model. The simulation results obtained with the model are presented to confirm the performance of the proposed algorithm.

Integrated Optical Waveguide Isolator Based Multimode Interference Using Magnetooptic Characteristics (자기 광학적 특성을 이용한 다중 모드 간섭에 기반한 집적 광 도파로 아이솔레이터)

  • Yang, Jeong-Su
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.148-152
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    • 2005
  • A novel interferometric isolator has been proposed and designed to fabrticate waveguide magnetooptic isolator operating at a wavelength of $1.55{\cal}um$. The device consists of MMI (multimode interference) couplers and has a magnetooptic guiding layer with different layer structure in arms of the inteferometer. The layer structures in the arms of inteferometer are $HfO_2/CeY_2Fe_5O_{12}/NOG$ and $SiO_2/CeY_2Fe_5O_{12}/NOG$, respectively. This configuration give rise to different nonreciprocal phase shift. In consequence, the isolator operates under a unidirectional magnetic field. The optimized structure of the isolator was determined by a 3D beam propagation method.

Optimization of Ingot Mold Design Parameters for Austenite Heat-resistant Steel Through Computational Simulation (전산모사를 통한 오스테나이트계 내열강용 잉곳 몰드 설계 파라미터 최적화)

  • Hwang, SooBeen;Park, JongHwa;Jo, SangHyun;Park, SeongIk;Kim, YunJae;Kim, Donggyu
    • Journal of Korea Foundry Society
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    • v.42 no.1
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    • pp.3-11
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    • 2022
  • In this study, the parameters on the shrinkage defect of HR3C alloy was secured through computer simulation research, and the ingot mold with greater than 85% of sound area was designed and manufactured. Moreover, the optimized coagulation was proposed at design stage through computer simulation and test was performed upon ingot manufactured. After the test, the defect pattern was analyzed through cutting and non-destructive inspection to verify the parameter and ingot mold design. Based on the verification results, shrinkage defect parameters such as Niyama, Feed Efficiency, and Hot Tear Intensity of HR3C Alloys were obtained. In addition, through the secured parameters, a plan for designing ingot mold with a Non-defect area of 85% or more was secured.

Optimization for Hot Water Extraction Process of Cordyceps militaris using Response Surface Methodology (반응표면분석법에 의한 동충하초 열수추출공정의 최적화)

  • 윤광섭;정용진;이기동;신승렬;구재관
    • Food Science and Preservation
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    • v.9 no.2
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    • pp.184-188
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    • 2002
  • This study was conducted to optimize hot water extraction process of cordyceps militaris for development beverage. Optimal condition for hot water extraction was investigated with changes in extraction concentration and temperature by response surface methodology. The content of soluble solid was effected with concentration. The efficiency of extraction for turbidity, total sugar, reducing sugar and protein increased with low concentration. The response variables had significant with concentration and the established polynomial model was suitable (p>0.05) model by lack-of-fit analysis. Optimal extraction conditions as the limited renditions of 2.0∼2.4% extractable solids, 1.5∼2.0% brix, l14∼120 $\mu\textrm{g}$/g total sugar, 10.5∼11.0 $\mu\textrm{g}$/g reducing sugar and 110∼l15 $\mu\textrm{g}$/g protein were 95∼100$\^{C}$ and 4.0∼4.1% of concentration.

Development of a regressive prediction method of solute transport in rivers based on relation between breakthrough curve and travel distance (하천에서 농도곡선-유하거리 상관성 기반 회귀적 물질혼합 예측 기법)

  • Kim, Byunguk;Seo, Il Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.45-45
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    • 2022
  • 산업화에 따른 화학물질 사용량의 증가는 담수로의 유해화학물질 유출사고의 위험을 증가시키며, 이러한 사고는 하천수 수질과 수환경 생태계에 심각한 위해와 손상을 야기한다. 이러한 수질사고 발생시 신속 대응을 위해, 하천에 유입된 물질의 거동을 신속하게 예측하는 것이 필요하며 이 경우 1차원 추적모형이 주로 사용된다. 1차원 물질혼합 모형은 하천을 하나의 유선으로 보며, 복잡한 하천흐름의 시스템을 현상학적으로 해석하고, 오염물질의 이송 및 혼합 메카니즘을 모델 매개변수에 반영하여 모형화한다. 이러한 매개변수들은 직접적으로 측정하기 어려우며, 이론에 기반한 매개변수 산정 기법이 구축되지 않은 실정이다. 따라서 대부분의 연구에서는 추적자 실험을 실시하여 유한한 하천구간에서 추적자의 시간-농도곡선(Breakthrough curve, BTC)을 취득하고, 이를 통하여 대상 구간의 매개변수를 역산하는 최적화 기법에 의존하고 있다. 하지만, 모든 하천구간에 대하여 추적자 실험을 수행하여 데이터를 확보하는 것이 어렵기 때문에 최적화 기법의 적용성에 한계가 있다. 본 연구는 흐름정보가 제공되지 않은 미계측 하천구간에서 BTC를 신속하게 예측할 수 있는 회귀모형을 구축하는 것을 목표로 한다. 국내 하천에서 수행한 4회의 추적자 실험으로부터 취득한 28개 구간 케이스의 데이터에 대하여 농도곡선 전처리를 수행하고 14개의 통계적 특징을 추출하였으며, 계측된 흐름특성과의 상관관계를 분석하였다. 분석 결과, 대상 구간에서의 BTC의 변화가 추적자의 유하거리에 매우 높은 상관관계를 보였으며, 이를 이용하여 회귀모형을 제시하였다. 제안된 회귀모형을 적용하여 하류의 지점에서의 BTC를 예측하였으며, 1차원 이송-분산 방정식과 하천저장대모형을 활용한 예측결과와 비교하여 검증하였다. 그 결과, BTC의 변화특성을 활용한 회귀적 예측이 하천 지형 및 흐름의 변동성이 작은 구간에서 1차원 혼합모형들을 이용한 예측보다 더 높은 정확도를 보였으며, 이러한 장점은 장거리 예측에서 더 분명하게 나타났다.

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Optimization of KOH pretreatment conditions from Miscanthus using high temperature and extrusion system (고온 압출식 반응시스템을 이용한 억새 바이오매스의 KOH 전처리조건 최적화)

  • Cha, Young-Lok;Park, Sung-Min;Moon, Youn-Ho;Kim, Kwang-Soo;Lee, Ji-Eun;Kwon, Da-Eun;Kang, Yong-Gu
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1243-1252
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    • 2019
  • The purpose of this study is to investigate the optimum conditions of biomass pretreatment with potassium hydroxide (KOH) for efficient utilization of cellulose, hemicellulose and lignin from Miscanthus. The optimization of variables was performed by response surface methodology (RSM). The variation ranges of the parameters for the RSM were potassium hydroxide 0.2~0.8 M, reaction temperature 110~190℃ and reaction time 10~90 min. The optimum conditions of alkali pretreatment from Miscanthus were determined as follows: concentration of KOH 0.47 M, reaction temperature 134℃ and reaction time 65 min. At the optimum conditions, the yield of cellulose from the solid fraction after pretreatment was predicted to be 95% by model prediction. Finally, 66.1 ± 1.1% of cellulose were obtained by verification experiment under the optimum conditions. The order contents of solid extraction were hemicellulose 26.4 ± 0.4%, lignin 3.7 ± 0.1% and ash 0.5 ± 0.04%. The yield of ethanol concentration of 96% was obtained using separated saccharification and fermentation.

A Study on Optimization of Manufacturing Condition for LiNi1/3Mn1/3Co1/3O2-based Cathode Electrode (LiNi1/3Mn1/3Co1/3O2계 정극활물질을 적용한 전극 제조조건 최적화 연구)

  • Kim Hyun-Soo;Kim Sung-Il;Lee Chang-Woo;Moon Seong-In;Kim Woo-Seong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.2
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    • pp.139-144
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    • 2006
  • A fabrication condition of the cathode electrode was optimized in a lithium secondary battery. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ powders were used as a cathode material. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$/Li cells were prepared with a certain formulation and their cycleability and rate-capability were evaluated. Optimum electrode composition simulated from the evaluated value was 86.3: 5.6: 8.1 in mass $\%$ of active material: binder: conducting material. Discharge capacity decreased markedly as the press ratio exceeded $30\%$ during preparation of the electrode. Discharge performance at a high current rate deteriorated abruptly as the electrode thickness was over $120{\mu}m$.

Land Use Optimization using Genetic Algorithms - Focused on Yangpyeong-eup - (유전 알고리즘을 적용한 토지이용 최적화 배분 연구 - 양평군 양평읍 일대를 대상으로 -)

  • Park, Yoonsun;Lee, Dongkun;Yoon, Eunjoo;Mo, Yongwon;Leem, Jihun
    • Journal of Environmental Impact Assessment
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    • v.26 no.1
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    • pp.44-56
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    • 2017
  • Sustainable development is important because the ultimate objective is efficient development combining the economic, social, and environmental aspects of urban conservation. Despite Korea's rapid urbanization and economic development, the distribution of resources is inefficient, and land-use is not an exception. Land use distribution is difficult, as it requires considering a variety of purposes, whose solutions lie in a multipurpose optimization process. In this study, Yangpyeong-eup, Yangpyeong, Gyeonggi-do, is selected, as the site has ecological balance, is well-preserved, and has the potential to support population increases. Further, we have used the genetic algorithm method, as it helps to evolve solutions for complex spatial problems such as planning and distribution of land use. This study applies change to the way of mutation. With four goals and restrictions of area, spatial objectives, minimizing land use conversion, ecological conservation, maximizing economic profit, restricting area to a specific land use, and setting a fixed area, we developed an optimal planning map. No urban areas at the site needed preservation and the high urban area growth rate coincided with the optimization of purpose and maximization of economic profit. When the minimum point of the fitness score is the convergence point, we found optimization occurred approximately at 1500 generations. The results of this study can support planning at Yangpyeong-eup.ausative relationship between the perception of improving odor regulation and odor acceptance.