• Title/Summary/Keyword: 화학제품

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Copper Recovery from Waste Water of Electronic Industry in a Fluidized Bed Reactor (유동층 반응기에서 전자 공장폐수로부터 동의 회수)

  • Lim, Wan-Mook;Woo, Kwang-Jae;Cho, Yong-Jun;Kang, Yong;Won, Chang-Whan;Kim, Sang-Done
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.482-488
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    • 1997
  • Copper recovery from waste water of electronic industry has been conducted effectively in a fluidized bed reactor. Initial concentration of copper in the waste water, liquid flow rate in the reactor, reaction temperature and time and current density between the cathode and anode in the reactor have been selected as operating variables. The effects of operating variables on the recovery of copper have been studied. It has found that the copper resolved in the waste water can be recovered continuously by means of a fluidized bed reactor The recovery of copper decreased with an increase in the initial concentration of copper in the waste water, while it increased with increasing reaction time and current density, however, it exhibited its maximum value with the variations of liquid flow rate and reaction temperature. The optimum reaction condition to maintain the copper recovery around 85% is as follows ; $X_o=3wt%$, $U_L=0.5cm/s$, $T=25^{\circ}C$, $I=7A/dm^2$ and t=2hrs within this experimental condition.

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Ship Sewage Treatment Using Fixed Media Method (고정식 메디아법을 이용한 선박의 오폐수 처리)

  • Han, Sang-Hwa;Lee, Dea-Ho;Nyung, Bu-Nyung;Bae, Sang-Bum;Yoon, Jong-Mun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.2
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    • pp.99-104
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    • 2010
  • The purpose of this study is to develop Sewage Treatment Plant that treat sewage which occurred in ship using fixed media method and to consider applicable to the Pilot Scale device of the STP regulations in MLTM(Ministry of Land, Transport and Maritime Affairs) and MEPC(Marine Environment Protection Committee). In test results, pH geometric mean was 7.68, $BOD_5$(Biochemical Oxygen Demand) geometric mean was 7.28 mg/l, $COD_{cr}$(Chemical Oxygen Demand) geometric mean was 48.39 mg/l, TSS(Total Suspended Solid) geometric mean was 18.00/l, Residual chlorine geometric mean was 0.19 mg/l, and E. coli geometric mean was 1CFU/100 ml. In addition, about 97.4% of $BOD_5$ was reduced, the $COD_{cr}$ reduction averaged 96.4%and the TSS reduction averaged 97.6%. STP have been determined by the MLTM and MEPC regulation of the marine pollution prevention equipment for performance testing product.

A Comparative Study on the Manufacturing Processes of Red Wine (포도주(葡萄酒) 제조방법(製造方法)에 관(關)한 비교연구(比較硏究))

  • Byun, Sang-Sook
    • Journal of Nutrition and Health
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    • v.13 no.3
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    • pp.139-144
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    • 1980
  • A study was conducted to examine the physical and chemical changes of wines fermented from three different varieties by three different methods. The products were evaluated by twenty subjects on color, aroma, and taste. The results were as follows; 1) The moisture contents of those varieties were ranged from 90. 70 to 90.82% The Brix sugar and sugar contents were in order of Muscat Bailey A>Alden>Cambell Early. The titratable acidity was higher in Muscat Bailey A and Alden than in Cambell Early while PH of Cambell Early was higher than those of the two others. 2) The specific gravities of the products were slightly decreased as the fermentation progressed. 3) The yeast-fermentation showed the higher degree of alcoholic contents compared to the natural fermentations. of the natural fermentations, the washed-natural fermentation resulted in the lower alcoholic contents than unwashed one. 4) The PH's were also higher in the yeast-fermentation products than in the natural fermentation groups. The difference, however, was smaller as the fermentation progressed further. 5) The total ester coutents of the yeast fermentation group were slightly higher at the beginning of the fermentation than those of the natural fermentation products and the contents were increased during the fermentation in overall. 6) Twenty panel mentors judged the ripe wine products and the order of preference was Alden>Muscat Baliey A>Cabell Early. They preferred the yeast-fermentation wine to the natural fermentation products.

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Benzo(a)pyrene Reduction in Sesame Oil Using Microwaving Method (Microwaving을 이용한 참기름의 Benzo(a)pyrene 저감화)

  • Oh, Sung-Cheon
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.323-329
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    • 2012
  • Sesame oil has superior oxidation stability and unique roasting flavor. Accordingly, this has been used for edible oil as well as a seasoning material for a long time in Korea. But sesame oil is a simple pressed oil, unrefined. During manufacturing process of roasting-expression, benzo(a)pyrene[B(a)P] formed as a strong carcinogenic substance causes a social problem. Detection of B(a)P in sesame oil was due to residual content in raw-sesame seeds and formation in roasting-expressing process. Especially, maximal forming process was roasting. Accordingly, in this study applied the traditional roasting method by roaster and microwaving method as a new type. Best roasting time by microwaving was for 5~10 min, B(a)P content in sesame oil was 0.53~0.79 ${\mu}g/kg$. These B(a)P contents showed 1/2 level than direct roasting method by roaster. As a result, B(a)P contents in sesame oil appeared the difference of more than 2 times according to roasting condition of sesame seed. For minimizing of B(a)P content in sesame oil is demanded roasting of sesame by microwaving than direct roasting by roaster.

Experimental Research on the Effect of the Number of Layers by Overlay Welding of Monel-Clad Pipe on Weldability (모넬(Monel)-Clad 파이프의 오버레이 용접 적층수가 용접성에 미치는 영향에 관한 실험적 연구)

  • Choi, Hyeok;Park, Joon-Hong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.11
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    • pp.42-50
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    • 2016
  • Overlay welding affects the chemical components and weld hardness by dilution of the lamination layer thickness, which determines the surface properties. This study experimentally investigates different numbers of layers for overlay welding monel materials, which are anti-corrosion materials. The Fe content, weldability of the base metal and monel materials, hardness, and surface flatness were examined. Each evaluation was carried out after overlay welding with three layers on the base material and pipe base material of the plate. The Fe content was evaluated by analyzing the constituents of each layer. The Fe content was satisfactory in the three layers. The weldability of the laminate specimens was evaluated by a bending test. The hardness and bead flatness of the laminate specimens were evaluated by micro Vickers and 3D measurements. The hardness was highest in the heat-affected zone with one layer, and it decreased with increasing lamination. In the case of bead flatness, there is a sharp difference in the deviation with increasing numbers of laminations, which should be considered carefully.

친환경 평판 디스플레이 세정을 위한 $CO_2$ Snow Jet 세정공정 개발에 관한 연구

  • Jeong, Ji-Hyeon;Gang, Bong-Gyun;Kim, Min-Su;Lee, Jong-Myeong;Lee, Gyu-Pil;Park, Jin-Gu
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.66.1-66.1
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    • 2011
  • 반도체를 비롯하여 LCD, OLED와 같은 디스플레이 (FPD: Flat Panel Display) 분야는 국가 선도 사업으로써 발전을 거듭해오고 있다. 하지만 기술의 성숙도가 높아짐에 따라 최근 중국과 대만 업체와의 경쟁이 심화되고 있으며, 더불어 환경문제가 큰 이슈로 떠오르고 있어 신기술 개발을 통한 생산 수율 향상 및 친환경 공정 개발의 중요성이 커지고 있다. 반도체, 디스플레이 공정에서 생산 수율 저하의 주요 원인으로써 공정 중 발생하는 미세 오염 입자를 들수 있다. 반도체 및 디스플레이 공정에서 세정 기술은 전체 기술의 30% 이상을 차지하며 생산 수율 및 제품의 품질에도 큰 영향을 주는 공정이다. 세정 공정은 일반적으로 습식 세정 공정이 낮은 공정비용을 바탕으로 널리 적용되어 왔으나, 기판의 대형화와 패턴의 미세화에 따라 정밀한 세정 스펙이 요구되며 더불어 막대한 양의 초순수와 화학액의 사용으로 인한 공정비용 증가와 환경 규제 강화에 따른 폐수 처리의 문제에 직면하고 있다. 이에 따라 폐수의 양을 줄이며 건조공정을 필요로 하지 않아 공정비용을 줄일 수 있는 건식 세정 공정에 대한 연구가 활발히 진행 되고 있다. $CO_2$ snow jet 세정 기술은 건식 공정으로써 $CO_2$ 가스를 특수하게 제작된 분사 노즐에서 고압으로 가스를 분사하여 이 때 발생되는 순간적인 감압에 의한 단열 팽창으로 생성된 $CO_2$ snow 입자가 기판 표면의 오염물과 물리적 충돌을 하어 세정이 이루어지는 기술이다. 특히 $CO_2$ 세정은 환경과 인체에 무해하며 공정 후 바로 승화하기 때문에 추가적인 폐수처리 공정 등이 필요하지 않고, 건식 공정으로써 수세(Rinse) 공정을 필요로 하지 않기 때문에, 공정비용을 크게 줄일 수 있으며 물반점 발생을 방지 할 수 있는 친환경 건식 공정으로써의 장점을 가지고 있다. 본 연구에서는 자체적으로 개발한 $CO_2$ snow jet을 바탕으로 하여 다양한 공정조건을 변화시켜 세정효율을 측정하는 한편, 최적화 하기 위한 연구를 진행하였으며 더불어 $CO_2$ snow의 세정력을 정량적으로 평가하기 위한 연구를 진행하였다. 실험을 통해 가장 효과적으로 $CO_2$ snow 입자를 배출 할 수 있는 공정 조건으로써 5 bar의 캐리어 가스 압력을 사용하여, 세정력에 가장 큰 영향을 줄 수 있는 분사 노즐과 기판 사이의 거리 및 분사 노즐의 각도 등을 변화시켜 각 조건에 따른 세정효율을 평가하였다. 세정 오염물은 Silica, PSL 표준 입자(Duke scientific, USA)를 정량적으로 웨이퍼에 오염 시킨 후, 파티클 스캐너(Surfscan 6500, KLA-Tencor, USA)를 이용하여 세정 전 후의 오염입자 개수 변화를 통해 정량적으로 세정효율을 평가하였다. 본 연구를 통하여 $CO_2$ snow jet를 이용한 친환경 고효율 건식 세정 공정 메커니즘을 분석하였으며, 노즐과 기판 사이의 간격 및 분사 노즐의 각도 등을 최적화 한 세정 공정을 얻을 수 있었다.

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Preparation and characterization of CoAl2O4 blue ceramic nano pigments by attrition milling (어트리션밀을 이용한 CoAl2O4 나노 무기 안료의 제조 및 특성 평가)

  • Lee, Ki-Chan;Yoon, Jong-Won;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.5
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    • pp.255-264
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    • 2013
  • Cobalt aluminate ($CoAl_2O_4$) is a highly stable pigment with excellent resistance to light, weather, etc., which has resulted in widespread use as a ceramic pigment. Due to the unique optical characteristics, $CoAl_2O_4$ is generally used as a coloring agent to decorate porcelain products, glass, paints and plastics. Here, $CoAl_2O_4$ pigments were synthesized by polymerized complex method and solid state reaction. Then $CoAl_2O_4$ pigment were grinded using the attrition milling with 1 mm size zirconia ball for 3 hours. The attrition milling process was performed at the constant speed of 800 rpm and ball to powder weight ratio (BPR) was 100 : 1. The characteristics of synthesized pigment were analyzed by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), particle size analyser (PSA) and CIE $L^*a^*b^*$. The XRD patterns of $CoAl_2O_4$ show single phase spinel structure. The particle size of $CoAl_2O_4$ measured by FE-SEM, TEM and PSA analysis was in the range of 100~200 nm. The blue color of obtained $CoAl_2O_4$ pigments could be confirmed through CIE $L^*a^*b^*$ measurement.

Measurement of Mechanical Properties of Thin Film Materials for Flexible Displays (플렉서블 디스플레이용 박막 소재 물성 평가)

  • Oh, Seung Jin;Ma, Boo Soo;Kim, Hyeong Jun;Yang, Chanhee;Kim, Taek-Soo
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.3
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    • pp.77-81
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    • 2020
  • Commercialization of flexible OLED displays, such as rollable and foldable displays, has attracted tremendous interest in next-generation display markets. However, during bending deformation, cracking and delamination of thin films in the flexible display panels are the critical bottleneck for the commercialization. Therefore, measuring mechanical properties of the fragile thin films in the flexible display panels is essential to prevent mechanical failures of the devices. In this study, tensile properties of the metal and ceramic nano-thin films were quantitatively measured by using a direct tensile testing method on the water surface. Elastic modulus, tensile strength, and elongation of the sputtered Mo, MoTi thin films, and PECVD deposited SiNx thin films were successfully measured. As a result, the tensile properties were varied depending on the deposition conditions and the film thickness. The measured tensile property values can be applied to stress analysis modeling for mechanically robust flexible displays.

Synergistic Cytotoxic Effects by Combination Treatment of Genistein and Daidzein in Human Colorectal Cancer Cell (대장암 세포주에서 genistein과 daidzein의 병합처리에 의한 상승적인 세포독성 효과)

  • Son, Seong-Min;Lim, Seung-Hyun;Kim, Hyo-Rim;Kim, Min-Jeong;Kim, Tae-Wan;Lee, Jong-Hwa;Kim, Jong-Sik
    • Journal of Life Science
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    • v.19 no.9
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    • pp.1294-1298
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    • 2009
  • To investigate whether isoflavone genistein and daidzein could affect cancer cell viability, human colorectal HCT116 cells were incubated with genistein or daidzein in a dose-dependent manner. Genistein decreased cancer cell viability in a dose-dependent manner, whereas daidzein did not show dramatic cytotoxic effects. We also found that 71 genes were up-regulated more than 2-fold, whereas 64 genes were down-regulated more than 2-fold with 24 hr of $50{\mu}M$ genistein treatment by our previous microarray data. Among the up-regulated genes, we selected 3 genes (DKK1, ATF3 and NAG-1) and performed RT-PCR to confirm microarray data. The results of RT-PCR were highly correlated with those of the microarray experiment. In addition, we investigated whether a combination treatment of genistein and daidzein could affect cancer cell viability. Surprisingly, the combination treatment did show synergistic cytotoxic effects detected by MTS assay. The results of RT-PCR and real-time PCR indicate that a combination of genistein and daidzein can synergistically induce NAG-1 expression in HCT116 cells. This result implies that NAG-1 induction is highly associated with synergistic cytotoxic effects induced by a combination treatment of genistein and daidzein. Overall, these results may provide a clue in explaining the anti-cancer activity of soy bean in human colorectal cancer.

The Experimental Study on The Compressive Strength of Concrete Using High Quality Recycled Fine Aggregate Produced by Sulphuric Water and Low Speed Wet Abrasional (황산수와 저속습식마쇄기로 생산된 고품질 순환 잔골재의 콘크리트 압축강도에 관한 실험적 연구)

  • Choi, Duck-Jin;Lee, Dae-Guen;Kim, Ha-Suk;Kawk, Eun-Gu;Kang, Chul;Kim, Jin-Man
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.385-388
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    • 2008
  • Recycled fine aggregate has low quality because it contains large amount of old mortar. So, its usage is limited to a lower value-add, such as the roadbed material etc. Also, alkaline water occurred from treatment process of the waste concrete is becoming the cause of environmental problem. Accordingly, this study is to develop on the high quality recycled fine aggregate produced by low speed wet abraser using sulphuric. We investigated the properties of compressive strength of the mortar which was manufactured using recycled fine aggregate containing calcined gypsum produced by earlier mentioned process. Test results indicate that concrete using recycled fine aggregate containing calcined gypsum is higher compressive strength than concrete using other sands.

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