• Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
• /
• 2000.09a
• /
• pp.133-139
• /
• 2000

일방향흐름의 해류나 천해파에 의한 파운동이나 해저면 가까이 경계층흐름은 주로 난류특성을 갖고 있으며, 난류특성은 완난류, 천이난류, 전난류 등 세 가지 증류로 대별된다. 그 중 완난류와 전난류로 대별하여 합성류 조건은 두 가지로 분류할 수 있다. 즉, 천해파와 해류가 합성될 때 해저면 가까이 난류특성 조건은 Table 1에 제시된 바와 같다. (중략)

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.1 no.1
• /
• pp.8-14
• /
• 1989

A mathematical model for computing the bed friction of combined wave-current flow has been developed based on the Prandtl's mixing length theory. Using various approximate expressions, solutions are obtained explicitly. The computational results are compared and found in reasonable agreements with the data of field measurements.

• Journal of the Korean Chemical Society
• /
• v.48 no.4
• /
• pp.385-393
• /
• 2004

2-Ethoxycarbonyl-3-methylquinoxaline 1,4-dioxide (8) was synthesized from benzofuroxan and ethyl acetoacetate. The reaction of compound 8 with hydrazine hydrate or selenium dioxide gave 2-hydrazinocarbonyl-3-methylquinoxaline 1,4-dioxide (9) or 2-ethoxycarbonyl-3-formylquinoxaline 1,4-dioxide (10), respectively. The reaction of compound 9 with alkanoyl chlorides, benzoyl chlorides, heteroacyl chlorides, and benzenesulfonyl chlorides afforded 3-methyl-2-(substituted hydrazinocarbonyl)quinoxaline 1,4-dioxides (11-14), respectively. The reaction of compound 9 with sodium azide gave 2-azidocarbonyl-3-methylquinoxaline 1,4-dioxide (15), and then its refluxing in dioxane/alcohols resulted in the Curtius rearrangement to give N-(3-methyl-1,4-dioxoquinoxalin-2-yl)-alkyl carbamates (16). The reaction of compound 15 with substituted anilines afforded 2-(3-substituted phenylureido)-3-methylquinoxaline 1,4-dioxides (17). The reaction of compound 10 with benzoic hydrazide or substituted anilines provided quinoxaline 1,4-di-oxides (18, 19), respectively. The herbicidal and fungicidal activities of the synthesized compounds were investigated.

• Journal of Korea Water Resources Association
• /
• v.45 no.5
• /
• pp.455-464
• /
• 2012

In this study, a combined unsteady friction model has been developed to simulate the waterhammer phenomenon for the pipeline system. The method of characteristics has been employed as the modeling platform for the integration of the acceleration based model and the frequency dependant model for unsteady friction. Both Zielke's model and Ramos model were also compared with pressure measurements of a pilot plant pipeline system. In order to validate the modeling approach, a pipeline system equipped with the high frequency pressure data acquisition system was fabricated. The time series of pressure, introduced by a sudden valve closure, were obtained for two Reynolds numbers. A trial and error method was used to calibrate parameters for unsteady friction model. The comparison between different unsteady friction contributions in pressure variation provided the comprehensive understanding in the pressure damping mechanism of waterhammer. The proper evaluation of unsteady friction impact is a critical factor for accurate simulation of hydraulic transient.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.12 no.3
• /
• pp.130-138
• /
• 2000

The friction factor equation of open channel flow is developed by using Prandtl's mixing length theory and considering the flow characteristics of smooth or rough turbulent flow. BYO model considers vertical velocity profile for the (:omputation of bottom friction of surface waves and current flow. The model computes the mean bottom friction of combined wave-current flow by the vectorial summation of wave velocity and current velocity at Bijker point. The near bottom flow is discriminated by three flow regimes; smooth, transitional and rough turbulent flow. The model, BYO, has been further refined considering the combination of smooth turbulent flow and rough turbulent flow.

• Journal of the Korean Chemical Society
• /
• v.44 no.3
• /
• pp.229-236
• /
• 2000

The reaction of 6-chloro-2-hydrazinoquinoxaline 4.oxide(10) with acetylacetone or dibenzoylmethane gave 6-chloro-2-(3,5-disubstituted pyrazol-1-yl)quinoxaline 4-oxides (11) through the intramolecular·cyclization.The chlorination of compound 11 with phosphoryl chloride afforded 3,6-dichloro-2-(3,5-disubstituted pyrazol-1-yl)quinoxalines (12), whose reaction with hydrazine hydrate provided 6-chloro-3-hydrazinodehydes, benzenesulfonyl chloride, substituted benzoyl chlohdes or acyl chlorides gave novel pyrazolylquinoxalines (14-17).

• Proceedings of the Korean Society of Applied Pharmacology
• /
• 1993.04a
• /
• pp.121-121
• /
• 1993

Angiotensin Converting Enzyme (ACE)의 효과적인 억제제를 합성하기 위하여 ketomethylene dipeptide isoster와 2-isoxazoline dipeptide isoster를 얻는 방법을 확립하였다. 상기 등입체성 분자들은 아미노산으로부터 유도된 아미노 니트릴 옥사이드의 고리더함반응을 이용하여 효율적으로 합성하였다. 얻어진 이 화합물로부터 ACE 억제제 후보물질 (1, 2)의 합성이 연구되고 있다.

• Journal of Korean Society of Environmental Engineers
• /
• v.36 no.12
• /
• pp.858-864
• /
• 2014

In this study, The effects of empty bed contact time (EBCT) and water temperature on the biodegradation of 8 synthetic fragrances (SFs) in biological activated carbon (BAC) process were investigated. Experiments were conducted at two water temperatures (7 and $18^{\circ}C$) and three EBCTs (5, 10 and 15 min). Increasing EBCT and water temperature increased the biodegradation efficiency of SFs in BAC column. Pentalide and ambrettolide were the highest biodegradation efficiency, but DPMI and ADBI were the lowest. The kinetic analysis suggested a pseudo-first-order reaction model for biodegradation of 8 SFs at various water temperatures and EBCTs. The pseudo-first-order biodegradation rate constants ($k_{bio}$) of 8 SFs ranging from $0.1184{\sim}0.6545min^{-1}$ at $7^{\circ}C$ to $0.3087{\sim}0.9173min^{-1}$ at $18^{\circ}C$. By increasing the water temperature from $7^{\circ}C$ to $18^{\circ}C$, the biodegradation rate constants ($k_{bio}$) were increased 1.4~2.6 times.

• Proceedings of the KIPE Conference
• /
• 2013.07a
• /
• pp.518-519
• /
• 2013

신재생 에너지의 용량이 증대하고, 수요가 늘어 남에 따라, 국가 간, 도시 간의 송전이 중요한 이슈로 대두 되고 있으며, 해당 요구 조건을 만족시키기 위해서 초고압 직류 송전 개발이 요구 되고 있다. 이 초고압 직류송전(HVDC)에는 전류형과 전압형으로 나뉘게 되는데, 각 HVDC 에서 사용되는 Valve는 실제 운전 전에 여러 가지 방법으로 검증이 되어야 한다. 합성 시험회로(Synthetic Test Circuit = 이하 STC) 는 전류형 HVDC에서 사용되는 주요 전력변환 장치 인, Thyristor Valve의 동작을 실제 동작 조건에 맞추어 동작을 시켜, 동작의 신뢰성을 검증하는 시험 설비 이다. 기존 STC는 고전압 대전류 회로와 고전압 저전류 회로의 합성 동작으로 Thyristor Valve의 동작을 검증한다. 하지만 제안된 Topology를 이용하면, 고전압 대전류 회로를 저전압 대전류 회로로 사용할 수 있으며, 제작 비용 및 설치 면적 등을 감소 시킬 수 있어 경제적이다.

• Journal of the Korean Chemical Society
• /
• v.47 no.4
• /
• pp.345-353
• /
• 2003

The reaction of 6-chloro-3-methoxycarbonylmethylene-2-oxo-1,2,3,4-tetrahydroquinoxaline(5) or 3-methoxycarbonylmethylene-6-nitro-2-oxo-1,2,3,4-tetrahydroquinoxaline(6) with hydrazine hydrate gave 3-hydrazinocarbonylmethylene-2-oxo-1,2,3,4-tetrahydroquinoxalines(7, 8). The reaction of compound 7 or 8 with substituted benzaldehydes or heteroaromatic aldehydes afforded quinoxalines(9-14). Compounds showed the tautomerism between the enamine and methylene imine forms, and between the enamine, methylene imine and enaminol forms in dimethyl sulfoxide solution. The tautomer ratios were determined by the 1H NMR.