• Title/Summary/Keyword: 팽창 구조

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Thermophysical Properties of 4D Carbon/Carbon Composites with Preform Architectures (프리폼 구조에 따른 4방향성 탄소/탄소 복합재의 열물리적 특성)

  • Kim, Zeong-Baek;Lee, Ki-Woong;Park, Jong-Min;Joo, Hyeok-Jong
    • Applied Chemistry for Engineering
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    • v.18 no.6
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    • pp.580-586
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    • 2007
  • In this study, 4 directional carbon/carbon composites with different preform architectures were manufactured and their thermophysical properties are studied. Carbon fiber preforms are fabricated with fiber bundles using four different spaces. The density of the fabricated preforms were increased through pressure impregnation and carbonizing process. The increased density of the composites was graphitized at $2300^{\circ}C$. Microstructures of these composite were observed under scanning electron microscope. This was to understand the effect the preform architectures has on the thermophysical properties of carbon/carbon composites. Also, the behavior of thermal conduction and heat expansion was investigated and studied in association with the factors of the reinforced direction of fibers and unit cell of preforms.

Design of a Transformable Spherical Robot Based on Multi-Linkage Structure (복합 링크 구조 기반의 가변형 구형로봇 설계)

  • Kang, Hyeongseok;Joe, Seonggun;Lee, Dongkyu;Kim, Byungkyu
    • Journal of Aerospace System Engineering
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    • v.11 no.6
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    • pp.26-33
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    • 2017
  • We propose a variable frame structure connected with telescopic mast-shaped shaft for a robot displaying outstanding ability to cross obstacles, and for effective traction control. The wireless control system was built to extend and contract a deployable mechanism, which is shaped into a hoberman sphere assembled with frame structures. In order to develop important parameters for efficient locomotion, we derived an Euler-Lagrange equation for the spherical robot. According to the equation, the DC motor was selected. A prototype mechanism was tested and a Finite-Element Analysis (FEA) was conducted in parallel. Using these data, we constructed a deployable spherical robot with structural stability. The deployable robot moved at a speed of 0.85 m/s from 520 mm to 650 mm.

Electrochemical Performance of Micro Sized Silicon/CNT/Carbon Composite as Anode Material for Lithium Ion Batteries (리튬이차전지용 음극활물질로서 Micro sized Silicon/CNT/Carbon 복합입자의 전기화학적 특성)

  • Shin, Min-Seon;Lee, Tae-Min;Lee, Sung-Man
    • Journal of the Korean Electrochemical Society
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    • v.22 no.3
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    • pp.112-121
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    • 2019
  • In this study, silicon / carbon nanotube / carbon composite particles with high capacity were fabricated by using micro-sized silicon particles and carbon nanotubes as an anode material for lithium ion batteries. The silicon / carbon nanotube / carbon composite particles were prepared by spray drying method to prepare spherical composite particles. The composite particles have the network structure of the carbon nanotubes around the silicon particles, in which the silicon particles and the carbon nanotubes are bonded by amorphous carbon. It appears that the volume expansion of silicon is effectively buffered and the electrical contact is maintained in the network structure of the composite particles during charge-discharge cycles.

A Study on the Characteristics of the Adiabatically Expanded Polyolefin Structured Foams (단열 발포 폴리올레핀계 구조체의 특성에 관한 연구)

  • Hwang Jun-Ho;Kim Woo-nyon;Jun Jae-Ho;Kwak Soon-Jong;Hwang Seung-Sang;Hong Soon-Man
    • Polymer(Korea)
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    • v.29 no.6
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    • pp.605-612
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    • 2005
  • This study investigates the isothermal crystallization behaviors of polypropylene-polyethylene-(1-butene) terpolymer and the adiabatically expanded polyolefin structured foams. For this purpose, butane gas was used as a physical blowing agent. Avrami equation has been used to interpret theoretically the experimental results obtained by either DSC or polarized optical microscope. It is believed that elongation induced crystallization occurring during the adiabatic expansion process has resulted in an increase in crystallization rate, eventually leading to a faster growth rate of spherulites and an increase in the nucleation density. An analysis of the foam by SEM images showed that the structure of foam is uniform (below diameter 30 $\mu$m closed cell) In addition, the thermal conductivity and the compressive strength of the polyolefin structured foams was measured. The thermal conductivity of foamed resin with excellent insulation characteristics is reduced compared with unfoamed resin. The compressive strength is decreased with increase in the expansion ratio.

Template Synthesis of Ordered-Mesoporous Tin Oxide for Lithium-ion Battery Anode Materials (주형 합성법을 통해 합성된 다공성 주석 산화물을 적용한 리튬이차전지용 음극재 연구)

  • Seo, Gyeongju;Choi, Jaecheol;Lee, Yong Min;Ko, Chang Hyun
    • Journal of the Korean Electrochemical Society
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    • v.17 no.2
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    • pp.86-93
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    • 2014
  • Mesoporous tin oxide (meso-$SnO_2$) with 5 nm mesopore and well-aligned $SnO_2$ nanowire-bundles with 5~7 nm diameters were prepared by template synthesis method. In addition to meso-$SnO_2$, meso-$SnO_2$/$SiO_2$, which has almost the same structure as meso-$SnO_2$ including $SiO_2$ used as the template were prepared by the modification of template synthesis. X-ray diffraction, N2 adsorption-desorption isotherms, transmission electron microscopy observed structures of meso-$SnO_2$ and meso-$SnO_2$/$SiO_2$. Although the meso-$SnO_2$/$SiO_2$ showed some positive evidences to suppress the volume change of meso-$SnO_2$ through cyclic voltammogram, electrochemical impedance spectroscopy, and voltage profiles during cycling, its cycle life was not improved highly to address modified structural effects. Thus, further study might be done to control the nanostructure of meso-$SnO_2$/$SiO_2$ for enhanced cycle performance.

Solid solubility of carbon in TiZrN coating by paste deposition methods for laser carburization (레이저 침탄에서 페이스트 증착방식에 따른 TiZrN 코팅의 carbon solid solubility)

  • Lee, Sungchul;Kim, Seonghoon;Kim, Jaeyoung;Kim, Bae-Yeon;Lee, Heesoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.1
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    • pp.7-11
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    • 2020
  • Carbon solubility on the paste deposition methods in the carbon-doped TiZrN coating was investigated in terms of lattice distortion and atomic concentration. After depositing the carbon paste by the dip coating, spin coating and screen printing, the laser was ablated to form the carbon gradient layer. Thickness and the concentration of doped carbon depended on the paste deposition method. Crystal structure analysis indicated that more lattice distortion occurred when coating layers were doped with spin coating and screen printing than when coating layers were doped with dip coating. The XPS depth profile showed that the thickness of carbon gradient layer by dip coating was about 30 nm, spin coating and screen printing are approximately 100 nm, formed more gradient layer. The hardness before laser carburization was about 30 GPa, and the hardness of 31 GPa with dip coating and 37 GPa with spin coating and screen printing. It was indicated that paste deposition methods for laser carburization contributed to lattice distortion and gradient layer.

Experimental Study on Evaluation on Volume Stability of the Electric Arc Furnace Oxidizing Slag Aggregate (전기로 산화슬래그 골재의 체적안정성 평가에 관한 실험적 연구)

  • Lim, Hee Seob;Lee, Han Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.2
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    • pp.78-86
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    • 2017
  • As the amount of slag generated annually increases, attempts to recycle slag as high value products are underway in order to develop an efficient resource recycling industry based on slag and derive economic benefits as well. However, the application of electric arc furnace (EOS) slag as construction material is practically limited because of the unstable substances included in it, such as free CaO.(EOS contains a small amount of free CaO, but several limitations still exist. Slag is stored for more than 3 months depending on the quantity of slag, which leads to additional economic loss. In this study, the amount of free CaO present in EOS is quantitatively evaluated to examine its qualities as a potential construction material and verify its application as concrete material. The quantitative analysis of free CaO present in EOS is performed using ethylene glycol. The free CaO contents of EOS samples were found to be below 0.5%. This satisfies the criteria specified in KS F 4571, which states that the CaO content should be below 40% and $CaO/SiO_2$ ratio should be below 2.0. In addition, it was confirmed that free CaO content difference appears to be dependent on the aging period and storage position.

Morphological Studies on the Digestive Tracts of the Larvae and Juveniles of the Flounder, Paralichthys olivaceus (넙치(Paralichthys olivaceus) 자치어의 소화기관 형태 발달)

  • Han, Kyeong-Ho;Kim, Kwan-Seok;Lee, Sung-Hoon
    • Development and Reproduction
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    • v.11 no.2
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    • pp.121-125
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    • 2007
  • Morphological changes on digestive tract were observed using Flounder, Paralichthys olivaceus to elucidate the early developmental processes. Hatched larvae, ($2.50{\pm}0.14\;mm$ in total length: TL) has not opened its mouth and anus. The digestive tract showed linear tubular form from mouth to anus extending along with yolk. On $7{\sim}8$ days from hatching, the post-larvae, ($5.05{\pm}0.40\;mm$ TL) has developed digestive tract and activated for feeding. The digestive tract expanded into dorsal side, joined to intestine, and the stomach began to develop. The digestive tract was divided into an anterior and posterior region, and began to differentiate. In the post-larvae($6.50{\pm}0.25\;mm$ TL) on $13{\sim}14$ days from hatching, the digestive tract twisted one cycle in the anterior region, the area was expanded. The digestive tract was completely differentiated into oesophagus, anterior intestine, middle intestine, posterior intestine and arranges fundamental structure. In the embryo($12.40{\pm}0.55\;mm$ TL) after 30 days from hatching, stomach became large and could be distinguished from cardia and pyloric parts apparently. The digestive tract developed similar with that of adult flounder showing clear division of stomach, anterior intestine, middle intestine, posterior intestine and rectum. In the embryo($16.15{\pm}0.85\;mm$ TL) after 40 days from hatching, esophagus, pyloric part, anterior intestine, middle intestine, and rectum have largely expanded, and thus the morphological features are somewhot different with those of post-larvae flounder.

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Heat Transfer on Supersonic Nozzle using Combined Boundary Layer Integral Method (수치해석 통합기법을 이용한 노즐 내열재 표면의 열전달 해석)

  • Bae, Ji-Yeul;Bae, Hyung Mo;Ryu, Jin;Ham, Heecheol;Cho, Hyung Hee
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.1
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    • pp.47-53
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    • 2017
  • A boundary layer integral combined with a 1-D isentropic core flow model has been successfully used to determine heat transfer rate on the surface of a supersonic nozzle. However its accuracy is affected by the core flow condition which is used as a boundary condition for the integral calculation. Because flow behavior near a nozzle throat deviates from 1-D isentropic condition due to 2-D flow turning and interaction between core flow and boundary layer, accuracy of heat transfer calculation decreases at a nozzle throat. Therefore, CFD is adopted to deduce improved core flow condition and increase accuracy of boundary layer integral at nozzle throat in this research. Euler model and SST $k-{\omega}$ model is solved by CFD code and used as a boundary condition for boundary layer integral. Developed code is tested in the supersonic nozzle from the previous research and improvement in accuracy is observed, especially at nozzle throat and diverging section of the nozzle. Error between experimental result and calculation result reduced by 16% when a calculation is made based on the SST $k-{\omega}$ model. Method developed in this research is expected to be used in thermal design of the rocket nozzle.

Evaluation of Fundamental Properties and Chloride Penetration Resistance of Concrete using Superabsorbent Polymers (고 흡수성 폴리머를 혼입한 콘크리트의 기초 물성 및 염화물 침투 저항성 평가)

  • Lee, Chan-Kyu;Kim, Il-Sun;Choi, So-Yeong;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.2
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    • pp.50-59
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    • 2020
  • Superabsorbent Polymer (SAP) expands inside concrete by absorbing water and contracts as it discharges water. Through this process, concrete can achieve the internal curing effect, but the space occupied by the expanded SAP remains as a void. In this study, the effects of SAP internal curing and voids were evaluated by evaluating the fundamental properties and chloride penetration resistance of SAP mixed concrete. Also, to evaluate the internal curing effect by SAP, the tests were carried out under water and sealed curing conditions, respectively. From the result, the compressive strength of water curing did not differ significantly according to the mixing ratio of SAP. In the case of sealed curing, however, the compressive strength tended to increase as the mixing ratio of SAP increased. The internal curing effect of sealed curing was considered to have influenced the increase in compressive strength. In the case of the chloride diffusion coefficient, the diffusion coefficient tended to decrease as the mixing ratio of SAP increased. In particular, as the sealed curing is applied, the chloride penetration resistance is further improved due to internal curing effect. If the curing conditions are different, it is considered inappropriate to estimate the chloride penetration resistance by the surface electrical resistivity.