• Title/Summary/Keyword: 침출법

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A Study on the Removal of Fluorine from Leachate of Reclaimed Mine Waste Dump Site Using Alum Coagulation (알럼 응집을 이용한 광산폐기물 적치장 침출수 내 불소 제거 연구)

  • Sang-Woo Lee;Woo-Chun Lee;Seong Hee Kim;Sang Heon Jeong;Bo Young Lee;Sang-Hwan Lee;Soon-Oh Kim
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.1
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    • pp.19-32
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    • 2023
  • This study was conducted to remove fluorine (F) (initial concentration of 9.5 mg/L) from leachate of reclaimed mine waste dump site via different methods: (1) co-precipitation using Ca-based materials; (2) adsorption using activated carbon and fly ash; and (3) coagulation and sedimentation using alum. The F removal efficiencies of each case were estimated as 65.6% (Ca co-precipitation), 27.9% (adsorption of activated carbon), 71.5% (adsorption of fly ash), and 96.6% (alum coagulation and sedimentation). In addition, the applicability of the continuous treatment process using alum coagulation was evaluated by lab-scale experiments using simulated mine drainage containing F of lower (6.4 mg/L) and higher (15.7 mg/L) concentrations, and it was confirmed that the treatment of both cases met the domestic standard (below 3 mg/L) for discharged water in clean areas. Furthermore, the results of bench-scale field tests indicated that the water quality standard of discharged water could be satisfied with the proper operation and management of the process.

Comparative Evaluation of Various Standard Methods in Leaching Test of Radioactive Waste Form (방사성고화체로부터의 $^{60}$ Co, $^{137}$ Cs 침출에 대한 표준시험법의 상호비교)

  • Kim, Ki-Hong;Ryu, Young-Gerl;Chung, Kyung-Ki;Hong, Kwon-Pyo;Lee, Nak-Hee;Jeong, Yi-Yeong;Koh, Duck-Joon;Kim, Heon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.93-103
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    • 2003
  • IAEA, FT-04-020, and ANS 16.1, standard leaching test methods, were evaluated comparatively with their test results. Leaching index of $^{60}$ Co and $^{137}$ Cs by ANS 16.1 method for waste forms of paraffin and cement were above 6.0. Their leaching behavior were depending on the type of matrix and leachant. Leachability of $^{60}$ Co for cement waste form was higher in simulated seawater than do-mineralized water, and was higher in de-mineralized water for paraffin waste form. leachability of $^{60}$ Co was contrary to $^{137}$ Cs. Cumulative fraction leached of $^{60}$ Co was higher in order or IAEA > ANS > FT in a cement waste form.

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NaOH Decomposition and Hydrochloric Acid Leaching of Monazite by Hot Digestion Method (Hot digestion법(去)에 의(依)한 모나자이트정광(精鑛)의 알카리분해(分解) 및 염산침출(鹽酸浸出) 거동(擧動))

  • Kim, Sung-Don;Lee, Jin-Young;Kim, Chul-Joo;Yoon, Ho-Sung;Kim, Joon-Soo
    • Resources Recycling
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    • v.19 no.6
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    • pp.70-76
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    • 2010
  • It was to investigate the optimum leaching conditions for the NaOH hot digestion and hydrochloric acid leaching of Monazite. The optimum condition for NaOH hot digestion was that the concentration of NaOH/TREO mole ratio was 15, the temperature of decomposition $140^{\circ}C$, and reaction time 2 hrs. And the optimum condition for the hydrochloric acid leaching of NaOH hot digestion product was that the concentration of hydrochloric acid was 6N, leaching time 2 hrs and pulp density about 15%. The yield of rare earth oxide was above 90% on the above experimental condition.

Monitoring of Leaching Conditions for Functional Components of Black Tea Using Response Surface Methodology (반응표면분석에 의한 홍차로부터 기능성 성분의 침출조건 모니터링)

  • Shin, Gyoung-Ah;Lee, Go-Eun;Oh, Young-Hwan;Noh, Jung-Eun;Yoon, Sung-Ran;Lee, Jeong-Eun;Kim, Gui-Ran;Jeon, Eun-Ju;Chung, Hun-Sik;Kim, Jeong-Sook;Kwon, Joong-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.1
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    • pp.66-71
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    • 2008
  • This study was conducted to predict optimum leaching conditions for functional components of black tea. Two variables were used to determine the optimum leaching temperature and leaching time with a five-level central composite design and response surface methodology. Soluble solid, reducing sugar, total phenolics, and total flavonoid contents increased as leaching temperature and time increased. The ranges of maximum leaching conditions for these components were $78.28{\sim}87.08^{\circ}C$ and $3.97{\sim}4.27min$. Vitamin C level was maximal at $61.29^{\circ}C$ and 2.68 min. Electron donating ability showed the highest values at $68.30^{\circ}C$ and 0.54 min. Based upon the superimposed results, it was predicted that the optimal ranges of leaching conditions for some functional components from black tea were $63{\sim}79^{\circ}C$ for $1.5{\sim}2.1$ min.

The Mineral Contents of Green Tea Made with Different Drawing Conditions (전차법(煎茶法)에 따른 녹차중(綠茶中) 무기물(無機物) 함량(含量))

  • Kim, Youn-Hee;Koh, Jin-Bog
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.3
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    • pp.289-295
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    • 1985
  • This experiment aimed to find out the most effective condition of drawing method when making tea by determination of the contents of minerals infused from four kinds of green tea samples of market with its different drawing time and temperature. The mineral contents in 100 grams of raw green tea leaves revealed $1737{\sim}3000\;mg$ potassium, $178{\sim}205\;mg$ magnesium, $171{\sim}201\;mg$ calcium, $54{\sim}71\;mg$ manganese, $24{\sim}50\;mg$ sodium, $11.6{\sim}12.3\;mg$ iron, $3.4{\sim}5.3\;mg$ copper and $4.6{\sim}5.9\;mg$ zinc. The values showed some variation in their contents according to the kinds of raw green tea samples. The decreasing order of the amounts of minerals infused from the green tea samples was K, Zn, Mg, Mn, Fe, Na, Cu and Ca. The amount of minerals infused from the green tea leaves increased with increase in the drawing time and temperature. The total infusion amount of minerals was remarkably larger when drawing time was three minutes with three times repetition than when it was eight minutes without repetition at the same temperature.

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A Study on the Separation of Membrane and Leaching of Platinum and Ruthenium by Hydrochloric Acid from MEA of Fuel Cell (연료전지용(燃料電池用) 막전극접합체(膜電極接合體)의 막분리(膜分離) 및 염산(鹽酸)에 의한 백금(白金)과 루테늄의 침출(浸出)에 관(關)한 연구(硏究))

  • Lee, Jin-A;Kang, Hong-Yoon;Ryu, Ho-Jin
    • Resources Recycling
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    • v.21 no.3
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    • pp.15-20
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    • 2012
  • In this paper, we carried out separation of membrane and leaching of Pt and Ru using hydrochloric acid from MEA(membrane-electrode assembly) of fuel cell. In this method, these were separated from MEA of fuel cell using the distilled water, 10 vol.% butanol solution and 15 vol.% cationic surfactant(Koremul-LN-7) by dipping method without the dispersion of catalyst particles. And the leaching of Pt and Ru containing in the separated carbon paper catalysts has been studied by hydrochloric acid using $HNO_3$ or $H_2O_2$ as a oxidant. The leaching ratio of Pt and Ru were higher when $H_2O_2$ was used as a oxidant and the optimum conditions were obtained in 8M HCl, the amount of $H_2O_2$ 5M and 6 hours of leaching time at $90^{\circ}C$. In this condition, extraction of Pt and Ru were 98% and 71.5%, respectively.

Studies on Antioxidative Activity of Green Tea Extracts in Medilite-Extraction Water (Medilite 침출수에 의한 녹차 추출물의 항산화 활성연구)

  • 차재영;조영수
    • Journal of Life Science
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    • v.13 no.2
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    • pp.168-174
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    • 2003
  • The chemical compositions and antioxidant activity of green tea extracts in medilite-extraction water were compared to that of distilled water(DW). Antioxidant activity was fetermined by the formation of thiobarbituric acid reactive substances (TBARS) in rat liver homogenates and microsomes and the scavenging activity of free radicals by DPPH ($\alpha$, $\alpha$'-diphenyl-$\beta$-picrylhydrazyl). The order of total polyphenolic compounds and extracted yield by extracts was medilite 325 mesh-extraction water, medilite 600 mesh-extraction water and distilled water(DW). The ranges of scavenging activity of green tea extracts in DPPH method were 60.95% - 64.51%. The inhibition ratios of TBARS formation in the rat liver homogenates and microsomal fractions were significantly lower with green tea extracts by DW-extraction than with both medilite 325 mesh and 600 mesh-extraction water. The concentration of iron ion of water containing medilite 325 mesh and green tea extracts and of water containing medilite 600 mesh and green tea extracts were significantly higher compared to DW. Therefore, this result suggested that enhanced concentration of iron ion in green tea extracts by medilite-extraction water containing high iron ion content was associated with enhanced peroxidation of the rat liver microsomal fractions. These results showed that total polyphenolic compounds, the % of yield and mineral compounds of green tea extracts were increased using medilite 325 mesh and 600 mesh-extraction water.

Determination of $^{226}Ra$ Isotope in the Leachate around Phosphogypsum Stack Using Ethylenediaminetetraacetic Acid (EDTA) (Ethylenediaminetetraacetic acid (EDTA)를 이용한 인산석고 야적장 침출수 중의 $^{226}Ra$ 분석법 개발)

  • Kim, Geun-Ho;Kim, Yong-Jae;Chang, Byung-Uck
    • Journal of Radiation Protection and Research
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    • v.36 no.4
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    • pp.223-229
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    • 2011
  • Ba is the most useful element to get the $Ba(Ra)SO_4$ precipitate. However, when the high concentrations of ions such as sulfate, calcium are existed in the leachate of phosphogypsum stack, it is difficult to get the $Ba(Ra)SO_4$ precipitate. Since this reason, the developed method for the Ba coprecipitate using EDTA was performed to determine the $^{226}Ra$ concentration in the high sulfate sample. The average concentration of $^{226}Ra$ in a leachate of phosphogypsum using this method was 0.102 $Bq{\cdot}kg^{-1}$ and the minimal detectable activity is 3.4 $mBq{\cdot}kg^{-1}$. The $mBq{\cdot}kg^{-1}$ method was 0.102 $Bq{\cdot}kg^{-1}$ and the minimal detectable activity is 3.4 $mBq{\cdot}kg^{-1}$. The $^{226}Ra$ stock solution and the CRM (Certified Reference Material) were analyzed to verify this method. In analyzed $^{226}Ra$ stock solution, bias with added concentration was approximately 1% and the correlation curve between $^{226}Ra$ concentration in simulated standard sample and measured $^{226}Ra$ concentration showed good agreement with a correlation coefficient ($R^2$) of 0.99. In analyzed CRM, maximum bias with reference value was 5.8% (k=1) and the analytical results were in good agreement with the reference value.

Application of Electrical and Small-Loop EM survey to the Identification of the Leachate at a Waste Landfill in Jeiu Island (제주도 쓰레기매립장 침출수 조사를 위한 전기 및 소형루프 전자탐사의 적용)

  • Song Sung-Ho;Yong Hwan-Ho;An Jung-Gi;Kim Gee-Pyo
    • Geophysics and Geophysical Exploration
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    • v.6 no.3
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    • pp.143-152
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    • 2003
  • Among the various geophysical approaches to identify the leakage of leachate with conductivity variation, conventional electrical resistivity survey has been mainly used at waste landfill. We adopted small-loop electromagnetic (EM) survey using multi-frequencies in parallel with electrical resistivity survey to delineate the leakage of leachate through the shallow soil layer at a waste landfill in Jeju Island, and also with self-potential monitoring to detect the streaming potential produced by the movement of leachate. There were no evidences of leakage from waste landfill according to the results of the electrical resistivity survey and SP monitoring, and it was also true from the results of water quality analysis at stream around waste landfill periodically. On the other hand, the results of one-dimensional inversion of spatially-filtered small-loop EM survey data showed the anomalous zone of low resistivity with depth both around and inner waste landfill.

The Effect of Deodeok Contents on the Quality of Deodeok Wine (더덕 함량이 더덕 침출주의 품질에 미치는 영향)

  • Kwon, Dong-Jin;Choi, Shin-Yang
    • Food Science and Preservation
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    • v.14 no.4
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    • pp.414-418
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    • 2007
  • The physicochemical characteristics and sensory properties of Deodeok wine, formed by leaching of Deodeok at room temperature for 180 days, were investigated over the following range of Deodeok levels: 10, 15 and 20% (all w/v). The higher the level of Deodeok, the greater were the final values of total sugars, reducing sugars, total polyphenols, and crude saponins. The Hunter's b-value (yellowness) of Deodeok wine varied markedly with Deodeok levels, and yellowness was highest in Deodeok wine containing 20% (w/v) Deodeok. Non-volatile compounds, that form the basis of the liquor tax law, were 0.64, 1.38 and 2.11% (all w/v), respectively, at day 160. Of these values, that of 2.11% (w/v), the level of non-volatile compounds in Deodeok wine containing 20% (w/v) Deodeok, was in accord with the liquor tax law (that requires this figure to be 2.0%). Sensory evaluation showed that Deodeok wine containing 20% (w/v) Deodeok was superior to the other wines tested.