• Title/Summary/Keyword: 촉매장치

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A study on the electrochemical reduction of carbon dioxide (전기화학환원에 의한 이산화탄소의 수소화 반응연구)

  • Sim, Kyu-Sung;Kim, Jong-Won;Kim, Yeon-Soon;Myeong, Kwang-Sik
    • Journal of Hydrogen and New Energy
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    • v.9 no.1
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    • pp.8-15
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    • 1998
  • The catalytic hydrogenation of carbon dioxide has been studied for the fixation of carbon dioxide to mitigate global warming problems, but it needed hydrogen, which the price is still high. Recently, the electrochemical reduction of carbon dioxide has been drawn attractions because carbon dioxide could be converted to the valuable chemicals such as methane, ethane and alcohols electrochemically in the electrolyte solution using a catalytic electrode. This system is simple because the water electrolysis and hydrogenation take place at the same time using the surplus electricity at midnight. In this work, a continuous electrochemical reduction system was fabricated, which was composed of the reduction electrode (copper or perovskite type, $2{\times}2cm^2$), reference electrode(platinum, $2{\times}6cm^2$), standard electrode(Ag/AgCl), and potassium bicarbonate electrolyte solution saturated with carbon dioxide. The quality and quantity of the products and reduction current were analyzed, according to the electrolyte concentration and electrode type.

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A Study on Reduction of Nitrogen Oxide (NOx) and Stability of Incineration Facility by the Food Wastewater Incineration (음식물류 폐수 소각처리에 따른 질소산화물 저감 및 소각설비의 안정성 평가에 관한 연구)

  • Hwang, Seung-Min;Chung, Jin-Do;Song, Jang-Heon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.10
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    • pp.901-908
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    • 2009
  • We examine the processing method of the food wastewater to direct spray at living waste incinerator. The demoscale stoker system is used as a incineration facility. The results show that it brings effect on the reduction of nitrogen oxide ($NO_x$) concentration as well as the ammonia ($NH_3$) amount in SNCR (selective non-catalytic reduction) by the incineration of food wastewater which is containing a plentiful ammoniac nitrogen ($NH_3$-N). Furthermore, the stability of incineration facility and the extension of operation period is actualized as a improvement of clogging phenomenon on outer wall of water pipe as the 870~$950^{\circ}C$ maintain of exit temperature in a second combustor by spray of the food wastewater. The 26 items of air pollution matter of nitrogen oxide ($NO_x$), sulfur oxide ($SO_x$) and dioxin etc. are measured. The results show that it is under the value of allowable exhaust standard.

Synthesis of Prussian Blue Analogue and Magnetic and Adsorption Characteristics of MnFe2O4 (프러시안 블루 유사체의 합성 및 MnFe2O4의 자성과 흡착 특성)

  • Lee, Hye-In;Kang, Kuk-Hyoun;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.67-74
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    • 2016
  • The Prussian Blue Analogue(PBA) has three dimensional structure and the metal - organic framework material, and it has a variety configurations depending on the type of organic ligands. PBA has been receving an attention in the fields of biosensors, optical, catalytic, and hydrogen storage device. Also, it is an environmental friendly substance with a chemical stability. In addition, PBA is widely used in the filed of adsorption art since we can adjust the size of the fine pores. In this study, we synthesized $Mn_3[Fe(CN)_6]_2$, an organometallic framework chains by using a hydrothermal synthesis method. We used $K_4[Fe(CN)_6]$ and $MnCl_2$ as precursors. We also produced a manganese iron oxide, by baking the synthesized material. The effect of the size and shape of the particles was examined by controling pH of the precursor solution, the molar concentration of the precursor, and reaction time as the experimental variables. Synthesized absorbent was analyzed by XRD, SEM, FT-IR, UV-Vis, and TG / DTA to evaluate the adsorption properties of several dyes.

Water Properties of Electrolytic Machine by Stainless Diaphragm and Effects of Electrolytic Ice Water Storage For Keeping Freshness of Squid, Todarodes pacificus (스테인레스 극판을 이용한 전해수장치의 수질특성과 오징어 선도유지를 위한 전해수 빙장 효과)

  • Lee, Nahme-Gull
    • Journal of Fisheries and Marine Sciences Education
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    • v.18 no.3
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    • pp.293-301
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    • 2006
  • This study was undertaken to prolonging the freshness in Squid(Todarodes pacificus) on the effects of ice storage methods(tap water ice, electrolytic water ice) using stainless diaphragm electrolytic instrument and also test an efficiency of instrument. Basically, stainless diaphragm electrolytic instrument studied for changes of pH on difference water flow and ampere. The lower water flower and higher ampere made low pH on acid part of electrolytic instrument. Squid samples were stored in tap water ice, acid part of electrolytic water and base part of electrolytic water and used in studying the changes of VBN and skin color through storage. Acid water had strong sterilization effects and VBN was lower levels of acid water than the others. Base water had not sterilization effects. Tap water ice storage was more sterilizing effects than base water ice storage but less effects than acid water ice storage. Lightness of Squid skin showed getting decrease at storage of ice water of all storage methods but acid water ice storage showed more retarding than the other two storage. From these results, it could be suggested that acid electric water ice storage is effective in extendance the shelf-life of squid at chilled storage.

Synthesis of Titanium Dioxides by Microemulsion Method and Their Photocatalytic Degradation of p-Nitrophenol (마이크로에멀젼법에 의한 이산화티탄의 합성 및 p-Nitrophenol의 광촉매 분해반응)

  • Jung, Won Young;Han, Yeon Hee;Lee, Gun-Dae;Park, Seong Soo;Hong, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.351-356
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    • 2008
  • Titania nanoparticles were prepared by controlled hydrolysis of titanium tetraisopropoxide (TTIP) in water-in-oil (W/O) and microemulsion stabilized with a nonionic surfactant, N P-10 (Polyoxyethylene Nonylphenol Ether: $C_9H_{19}C_6H_4(OCH_2CH_2)_{10}OH$)). The nanosized particles prepared in W/O microemulsion were characterized by FT-IR, TEM, XRD, TGA, and DTA. In addition, the photocatalytic degradation of p-nitrophenol has been studied by using a batch reactor in the presence of UV light in order to compare the photocatalytic activity of prepared nanosized titania. The nanaosized titania particles calcined at $300{\sim}600^{\circ}C$ showed an anatase structure, but it transformed to a rutile phase above $700^{\circ}C$ of calacination temperature. With an increase of $W_o$ ratio, the crystallite size increased but photocalytic activity decreased. The titania synthesized at $W_o=5$, R = 2, and calcined at $400{\sim}500^{\circ}C$ showed the highest activity on the photocatalytic degradation of p-nitrophenol.

Development of the Protocol of the High-Visibility Smart Safety Vest Applying Optical Fiber and Energy Harvesting (광섬유와 압전 에너지 하베스팅을 적용한 고시인성 스마트 안전조끼의 개발)

  • Park, Soon-Ja;Jung, Jun-Young;Moon, Min-Jung
    • Science of Emotion and Sensibility
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    • v.24 no.2
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    • pp.25-38
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    • 2021
  • The aim of this study is to protect workers and pedestrians from accidents at night or bad weather by attaching optical fiber to existing safety clothing that is made only with fluorescent fabrics and retroreflective materials. A safety vest was designed and manufactured by applying optical fiber, and energy-harvesting technology was developed. The safety vest was designed to emit light using the automatic flashing of optical fibers attached to the film, and an energy harvester was manufactured and attached to drive the light emission of the optical fiber more continuously. As a result, first, the vest wearer' body was recognized from a distance through the optical fiber and retroreflection, which helped prevent accidents. Thus, this concept helps in saving lives by preventing accidents during night-time work on the roadside or activities of rescue crew and sports activities, or by quickly finding the point of an accident with a signal that changes the optical fiber light emission. Second, to use the wasted energy, a piezoelectric-element power generation system was developed and the piezoelectric-harvesting device was mounted. Potentially, energy was efficiently produced by activating the effective charging amount of the battery part and charging it auxiliary. In the existing safety vest, detecting the person wearing the vest is almost impossible in the absence of ambient light. However, in this study, the wearer could be found within 100 m by the light emission from the safety vest even with no ambient light. Therefore, in this study, we will help in preventing and reducing accidents by developing smart safety clothing using optical fiber and energy harvester attached to save lives.

Role of Graphene Derivatives in Anion Exchange Membrane for Fuel Cell: Recent Trends (연료전지용 음이온교환막에서 그래핀 유도체의 역할: 최근 동향)

  • Manoj, Karakoti;Sang Yong, Nam
    • Membrane Journal
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    • v.32 no.6
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    • pp.411-426
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    • 2022
  • Energy plays a significant role in modern lifestyle because of our extensive reliance over energy-operating devices. Therefore, there is a need for alternative and green energy resources that can fulfill the energy demand. For this, fuel cell (FCs) especially anion exchange membrane fuel cells (AEMFCs) have gained tremendous attention over the other (FCs) due to their fast reaction kinetics without using noble catalyst and allow to use of cheaper polymers with high performance. But lack of highly conductive, chemically, and mechanically stable anion exchange membrane (AEM) still main obstacle to the development of high performance AEMFCs. Therefore, graphene-based polymer composite membranes came into the existence as AEMs for the FCs. The exceptional properties of the graphene help to improve the performance of AEMs. Still, there are lot of challenges in the graphene derivatives based AEMs because of their high tendency of agglomeration in polymer matrix which reduced their potential. To overcome this issue surface modification of graphene derivatives is necessary to restrict their agglomeration and conserved their potential features that can help to improve the performance of AEM. Therefore, this review focus on the surface modification of graphene derivatives and their role in the fabrication of AEMs for the FCs.

A Study on the Optimal Operating Conditions for an Unreacted Hydrogen Oxidation-Heat Recovery System for the Safety of the Hydrogen Utilization Process (수소 활용공정 안전성 확보를 위한 미반응 수소 산화-열 회수 시스템의 운전 조건 최적화 연구)

  • Younghee Jang;Sung Su Kim
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.307-312
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    • 2023
  • In this study, a catalytic oxidation-heat recovery system was designed that can remove unreacted with a concentration of about 1% to 6% in the exhaust gas of hydrogen fuel cells and recover heat to ensure safety in the hydrogen economy. The safety system was devised by filling hydrogen oxidation catalysts at room temperature that can remove unreacted hydrogen without any energy source, and an exhaust-heat recovery device was integrated to efficiently recover the heat released from the oxidation reaction. Through CFD analysis, variations in pressure and fluid within the system were shown depending on the filling conditions of the hydrogen oxidation system. In addition, it was found that waste heat could be recovered by optimizing the temperature of the exhaust gas, flow rate, and pressure conditions within the heat recovery system and securing hot water above 40 ℃ by utilizing the exhaust gas oxidation heat source above 300 ℃. Through this study, it was possible to confirm the potential of utilizing hydrogen processes, which are applied in small to medium-sized systems such as hydrogen fuel cells, as a safety system by evaluating them at a pilot scale. Additionally, it could be a safety guideline for responding to unexpected hydrogen safety accidents through further pilot-scale studies.

Zombie, the Subject Ex Nihilo and the Ethics of Infection (좀비, 엑스 니힐로의 주체와 감염의 윤리)

  • Seo, Dong-Soo
    • Journal of Popular Narrative
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    • v.25 no.3
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    • pp.181-209
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    • 2019
  • The purpose of this article is to compare zombie narratives in relation to the Other. In previous research, the view of zombies as post-capitalist soulless consumers or workers has been frequently expressed. But in this article, I wanted to look at zombies as the main cause of the collapse of the world and a new future. First, zombies do not only mean the representation of the consumer in the late capitalist era. Rather, it is an awakening subject desiring the outside of the system. As you can see from the Uncanny's point of view, zombies are something that we should oppress as freaks and monsters that threatened the Other. To be a zombie in this way is to meet one's other self, the "Fundamentals of Humanity," and it is the moment when everything becomes the subject ex nihilo, the new beginning. Second, the concept of infection shows a new ethic. Zombie cannibalism is different from the selfish love of a vampire who sucks a worker's blood. Zombie cannibalism is an infection, which is a model of Christian love for one's neighbor. It is a moment of awakening and the beginning of solidarity. It is on the waiting for the solidarity that the zombie hangs in such a way, and the attack on the human being is an active illusion. Third, the situation of the end of a zombie narrative is another event for newness. The anger of a zombie serves not just to show monsters, but acts as a catalyst that accelerates the world's catastrophes. The anger of zombies is the messianic violence that stops the false world, and presents a new way. The emergence of zombies and the popular response to them embody a desire for the possibility of a new subject and world.

Recent Synthetic Trends of Ti3C2Tx MXene (Ti3C2Tx MXene 합성 최신 연구 동향)

  • Suin Shim;Kwang Se Lee;Chang-Ho Choi
    • Applied Chemistry for Engineering
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    • v.35 no.5
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    • pp.372-378
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    • 2024
  • MXene, a two-dimensional transition metal carbide, nitride, or carbonitride, possesses exceptionally thin and large surface areas while also exhibiting remarkable electrical and chemical properties. These properties have attracted considerable interest in the application of MXene, including energy storage devices, sensors, and catalysts. Since the discovery of MXene in 2011, a number of synthetic methods have been proposed. The synthesis of MXene can be mainly divided into two stages: an etching step and a delamination step. The type of terminations or surface defects are dependent on the synthetic method and have a significant impact on key properties such as electrical conductivity. Therefore, research on synthetic methods is essential for the industrialization of MXene. This review provides an overview of the various etching methods and delamination strategies employed in the synthesis of Ti3C2Tx MXene, including the commonly used hydrofluoric acid etching method and the fluorine-free method, which has recently emerged as an environmentally friendly alternative. We also address the latest research trends, challenges, and perspectives for the industrialization of MXene.trialization of MXene.