• Title/Summary/Keyword: 질소산화물 저감

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A Study on the Engine Performance and Emission Characteristics in a LP EGR System with Electronic Throttle Control (ETC를 적용한 저압 EGR시스템의 엔진성능 및 배출가스 특성에 관한 연구)

  • Park, Jun-Heuk;Lim, Jong-Han;Yoon, Jun-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.4
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    • pp.379-387
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    • 2011
  • Research and development of LP EGR system for the performance improvement and emission reduction on diesel engine is proceeding at a good pace. LP EGR system seems to be helpful method to further reduce$NO_x$ emissions while maintaining PM emissions at a low level because the boost pressure is unchanged while varying EGR rate. This study is experimentally conducted on a 2.0L common rail DI engine at the medium load condition (2000 rpm, BMEP 1.0 MPa, boost pressure 181.3 kPa) that difficult to use large amount of EGR gas because of deteriorations of performance and fuel consumption. And we investigated the characteristics of performance and fuel consumption while varying EGR systems. The overall results using LP EGR system equipped with ETC identified benefits on reduction of PM and improvement of fuel consumption and thermal efficiency while keep the $NO_x$ level compared to HP EGR and LP EGR with back pressure valve.

Effect of Reduced Valve Overlap on Emission Characteristics of Hydrogen-Compressed Natural Gas Engine (수소-천연가스엔진에서 밸브오버랩 감소가 배기특성에 미치는 영향)

  • Lee, Sungwon;Lim, Gihun;Park, Cheolwoong;Choi, Young;Kim, Changgi
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.1
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    • pp.21-27
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    • 2015
  • In order to meet the current emission regulations (EURO-6), it is necessary to significantly reduce $CH_4$ and $NO_X$ emissions. This study investigated the effect of a reduction in the valve overlap on the combustion and emission characteristics of a hydrogen-compressed natural gas engine under a part-load operating condition. The combustion and emission characteristics were analyzed for each fuel using the original camshaft and an altered camshaft with reduced valve overlap. The results showed that the thermal efficiency was decreased and the fuel flow was increased when using the altered camshaft. The $CO_2$ and $CH_4$ emissions were increased as a result of the reduced thermal efficiency. Under lean operating conditions, the $NO_X$ emission was decreased compared with one of the conventional camshaft. Thus, under the same fuels and operating conditions, it had a harmful influence on the emission characteristics and thermal efficiency.

Effect of Water on the Kinetics of Nitric Oxides Reduction by Ammonia over V-based Catalyst (바나듐계 촉매상에서 암모니아를 이용한 질소산화물의 환원반응속도에 수분이 미치는 영향에 관한 연구)

  • Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.6
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    • pp.73-82
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    • 2012
  • The main and side reactions of the three selective catalytic reduction (SCR) reactions with ammonia over a vanadium-based catalyst have been investigated using synthetic gas mixtures in the temperature range of $170{\sim}590^{\circ}C$. The three SCR reactions are standard SCR with pure NO, fast SCR with an equimolar mixture of NO and $NO_2$, and $NO_2$ SCR with pure $NO_2$. Vanadium based catalyst has no significant activity in NO oxidation to $NO_2$, while it has high activity for $NO_2$ decomposition at high temperatures. The selective catalytic oxidation of ammonia and the formation of nitrous oxide compete with the SCR reactions at the high temperatures. Water strongly inhibits the selective catalytic oxidation of ammonia and the formation of nitrous oxide, thus increasing the selectivity of the SCR reactions. However, the presence of water inhibits the SCR activity, most pronounced at low temperatures. In this study, the experimental results are analyzed by means of a dynamic one-dimensional isothermal heterogeneous plug-flow reactor (PFR) model according to the Eley-Rideal mechanism.

Experimental Study on Characteristics of Ammonia Conversion Rate of Urea Aqueous Solution in 250℃ Exhaust Pipe (250℃ 이하 배기관에서 우레아 수용액의 암모니아 전환율 특성에 관한 실험적 연구)

  • Ku, Kun Woo;Park, Hong Min;Hong, Jung Goo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.2
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    • pp.177-182
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    • 2015
  • The NOx emissions from diesel engines and industrial boilers are a major cause of environmental pollution. The selective catalytic reduction of urea is an aftertreatment technology that is widely used for the reduction of NOx emissions. The objective of this study was to investigate the characteristics of the thermal decomposition of a urea aqueous solution using laboratory-scale experimental equipment under conditions similar to those of marine diesel engines. A 40 wt. urea aqueous solution was used in this study. It was found that the total conversion rate varied with the inflow gas conditions and flow rates of the urea aqueous solution. In addition, there were conversion rate differences between NH3 and HNCO. At inflow gas temperature conditions of $210^{\circ}C$ and $250^{\circ}C$, the $NH_3$ conversion rate was found to be higher than that of the HNCO, depending on the residence time.

The characteristics of temperature distribution, NOx and CO formation in a MILD combustor with the variation of equivalence ratio (당량비 변화에 따른 MILD 연소로의 온도 분포 및 NOx, CO 생성 특성)

  • Ha, Ji-Soo;Yu, Sang-Yeol;Sim, Sung-Hoon;Kim, Tae-Kwon
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.4
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    • pp.485-490
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    • 2010
  • MILD (Moderate and Intense Low Oxygen Dilution) combustion is a technique which is able to reduce NOx formation and to uniform temperature distribution in the furnace by recirculating the exhaust gas to the fresh air and fuel. This study focuses on finding optimal condition of MILD combustor by changing equivalence ratio with fuel and air flow. The present experiment employs six thermocouple sensors in the furnace, and two concentration probes of NOx and CO at the exhaust exit pipe respectively. The MILD combustion phenomena have been observed at the condition of equivalent ratios of 0.71~0.73, and the temperature uniformity, NOx and CO concentration are also examined at the MILD combustion condition.

Effects of Biodiesel Fuel on Characteristics of Specific Fuel Consumption and Exhaust Emissions in DI Diesel Engine - Using Rape Oil - (직접분사식 디젤기관에서 연료소비율 및 배기배출물 특성에 미치는 바이오디젤유의 영향 - 유채유를 중심으로 -)

  • Lim, Jae-Keun;Choi, Soon-Youl;Kim, Suk-Joon;Cho, Sang-Gon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.14 no.1
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    • pp.83-87
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    • 2008
  • We have a lot of interest in alternative fuels to provide energy independence from oil producing country and to reduce exhaust emissions for air pollution prevention. Biodiesel, which can be generated from natural renewable sources such as new or used vegetable oils or animal fats, may be used as fuel without change of engine structure in diesel engine of compression ignition engine. In this paper, the test results on specific fuel consumption and exhaust emissions of neat diesel oil and biodiesel blends(10 vol.% biodiesel and 20 vol.% biodiesel) were presented using four stroke, direct injection diesel engine. Especially this biodisel was produced from rape oil at our laboratory by ourselves. This study showed that specific fuel consumption and NOx emission were slightly increased, on the other hand CO emission and Soot were tolerably decreased more in the case of biodiesel blends than neat diesel oil.

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Numerical Investigation of Low-pollution Combustion with applying Flue Gas Recirculation in Counterflow Flames: Part II. Analysis of NOx formation mechanism (대향류 화염에서 FGR이 적용된 저공해 연소의 수치적 해석: Part II. NOx 생성기구 분석)

  • Cho, Seo-Hee;Kim, Gyeong-Mo;Lee, Kee-Man
    • Journal of the Korean Institute of Gas
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    • v.24 no.4
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    • pp.39-47
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    • 2020
  • Flue gas recirculation(FGR) is an effective combustion technique for reducing nitrogen oxides(NOx) and is applied in various fields of low-pollution combustion. Continuing the previous study, a numerical analysis was conducted to identify changes of flame characteristics and NOx formation mechanism with applying FGR technique in CH4/air premixed counterflow flames. NOx emitted was divided into four main reaction paths(thermal NO, prompt NO, N2H and N2O), showing relatively the production rate of NO with the recirculation ratio. As a result, thermal NO contributed greatly to the overall NO whereas the effect of N2H was minimal. In addition, emission index of NO was compared as the recirculation ratio increased by modifying the UC San Diego mechanism to examine the contribution of thermal NO.

Optimization of an Ozone-based Advanced Oxidation Process for the Simultaneous Removal of Particulate Matters and Nitrogen Oxides in a Semiconductor Fabrication Process (반도체 제조공정 미세먼지-질소산화물 동시 저감을 위한 오존 고속산화공정 최적화 연구)

  • Uhm, Sunghyun;Lee, Seung Jun;Ko, Eun Ha;Hong, Gi Hoon;Hwang, Sangyeon
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.659-663
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    • 2021
  • 10 m3/min (CMM) multi-pollutants abatement system was successfully developed by effectively integrating ozone oxidation, wet scrubbing, and wet electrostatic precipitation for the simultaneous removal of particulate matters (PMs) and NOx in a semiconductor fabrication process. The sophisticated control and optimization of operating parameters were conducted to maximize the destruction and removal efficiency of NOx. In particular, the stability test of a wet electrostatic precipitator was carried out in parallel for 30 days to validate the reliability of core parts including a power supply. An O3/NO ratio, which is the most important operating parameter, was optimized to be about 1.5 and the optimization of wet scrubbing with a reducing agent made it possible to analyze the contribution of neutralization reaction.

Nitrogen Oxides Removal Characteristics of SNCR-SCR Hybrid System (SNCR-SCR 하이브리드 시스템의 질소산화물 제거 특성)

  • Cha, Jin Sun;Park, Sung Hoon;Jeon, Jong-Ki;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.658-663
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    • 2011
  • The SNCR-SCR (selective non-catalytic reduction-selective catalytic reduction) hybrid system is an economical NOx removal system. In this study, the effect of the operating parameters of the SNCR-SCR hybrid system on NOx removal efficiency was investigated. When the SNCR reactor was operated at a temperature lower than the optimum temperature ($900{\sim}950^{\circ}C$), an additional NO removal is obtained basesd on the utilization of $NH_3$ slip. On the other hand, the SNCR reactor operated above the temperature resulted in no additional NO removal of SCR due to decomposition of $NH_3$. Therefore, the SNCR process should be operated at optimum temperature to obtain high NO removal efficiency and low $NH_3$ slip. Thus, it is important to adjust NSR (normalized stoichiometric ratio) so that $SR_{RES}$ can be maintained at an appropriate level.

An Optimization Study on a Low-temperature De-NOx Catalyst Coated on Metallic Monolith for Steel Plant Applications (제철소 적용을 위한 저온형 금속지지체 탈질 코팅촉매 최적화 연구)

  • Lee, Chul-Ho;Choi, Jae Hyung;Kim, Myeong Soo;Seo, Byeong Han;Kang, Cheul Hui;Lim, Dong-Ha
    • Clean Technology
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    • v.27 no.4
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    • pp.332-340
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    • 2021
  • With the recent reinforcement of emission standards, it is necessary to make efforts to reduce NOx from air pollutant-emitting workplaces. The NOx reduction method mainly used in industrial facilities is selective catalytic reduction (SCR), and the most commercial SCR catalyst is the ceramic honeycomb catalyst. This study was carried out to reduce the NOx emitted from steel plants by applying De-NOx catalyst coated on metallic monolith. The De-NOx catalyst was synthesized through the optimized coating technique, and the coated catalyst was uniformly and strongly adhered onto the surface of the metallic monolith according to the air jet erosion and bending test. Due to the good thermal conductivity of metallic monolith, the De-NOx catalyst coated on metallic monolith showed good De-NOx efficiency at low temperatures (200 ~ 250 ℃). In addition, the optimal amount of catalyst coating on the metallic monolith surface was confirmed for the design of an economical catalyst. Based on these results, the De-NOx catalyst of commercial grade size was tested in a semi-pilot De-NOx performance facility under a simulated gas similar to the exhaust gas emitted from a steel plant. Even at a low temperature (200 ℃), it showed excellent performance satisfying the emission standard (less than 60 ppm). Therefore, the De-NOx catalyst coated metallic monolith has good physical and chemical properties and showed a good De-NOx efficiency even with the minimum amount of catalyst. Additionally, it was possible to compact and downsize the SCR reactor through the application of a high-density cell. Therefore, we suggest that the proposed De-NOx catalyst coated metallic monolith may be a good alternative De-NOx catalyst for industrial uses such as steel plants, thermal power plants, incineration plants ships, and construction machinery.