• Title/Summary/Keyword: 중량변화법

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Effect of Chemical Composition, Molecular Weight, Carbon Black Concentration and Temperature on the Flow Behavior of Styrene/Butyl Methacrylate Homo- and Co-polymer Particles (화학적 구성, 분자량, 카본블랙의 농도 및 온도에 따른 스티렌/부틸메타크릴레이트 단일중합체 및 공중합체 입자의 유동성)

  • Park, Moon-Soo;Moon, Ji-Yeon
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.23-29
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    • 2011
  • We measured shear viscosity of polymeric particles, prepared by suspension polymerization with hydrophobic silica as a stabilizer at $75^{\circ}C$, by a capillary rheometer. Shear viscosity displayed a non-Newtonian behavior with an increase in weight average molecular weight. Measurement of shear viscosity at 170 and $190^{\circ}C$ with copoly(styrene/butyl methacrylate) (co-PSB) particles by varying the ratio between styrene (St) and butyl methacrylate (BMA) showed that shear viscosity was a function of molecular weight, temperature and compositional ratio. When the ratio was 7/3, 5/5 and 3/7, shear viscosity slightly reduced with an increase in BMA concentration despite similar weight average molecular weights. We found that shear viscosity of copolymers with BMA concentrations exceeding 70% displayed a sharp reduction at high shear rates. It is speculated that increased PBMA chain length contributes to enhanced flowability of copolymers. When carbon black was incorporated into co-PSB, shear viscosity progressively increased with increasing carbon black concentration. The increase in shear viscosity, however, was less pronounced compared to the cases of molecular weight increase.

Improvement of Water Quality by Corona Discharge Plasma-activated Water in a Tilapia Recirculating Aquaculture System (코로나 방전-플라즈마 처리수의 틸라피아 순환여과양식시스템 수질 개선 효과)

  • You, Jin Ho;Mun, Seong Hee;Oh, Hyeon Ji;Park, Tae Sup;Kwon, Joon Yeong
    • Journal of Marine Life Science
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    • v.5 no.2
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    • pp.51-57
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    • 2020
  • Disinfection and maintenance of rearing water in aquaculture is an essential element for the prevention of fish diseases. This is especially important in recirculating aquaculture systems (RAS) in which fish are reared at high density using recycled water. In this study, tilapia was reared in two different RAS (one with plasma generator - PW system, another without plasma generator - No PW system). In plasma treated group, UVT% of water was improved clearly, and the number of heterotrophic bacteria decreased significantly after 40 days. Total weight gain of tilapia in PW system was significantly higher, and other growth indicators were also relatively higher although not statistically significant. In addition, the fish in PW system had a 100% survival rate, and there were no histological differences between fish from both systems. Fish did not seem to be affected by the toxicity of ROS. In conclusion, it is expected that plasma water can effectively deactivate fish pathogens and improve the quality of rearing water.

Analgesic Effects of Gyejibokryeong-hwan Aqueous Extracts on the Rat Model of Primary Dysmenorrhea (원발성 월경통에 대한 계지복령환(桂枝茯苓丸) 열수 추출물의 진통 효과)

  • Cho, Su-Yun;Kim, Dong-Chul
    • The Journal of Korean Obstetrics and Gynecology
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    • v.33 no.3
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    • pp.95-118
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    • 2020
  • Objectives: The objective of this in vivo study is to observe the analgesic effects or improvements of Gyejibokryeong-hwan aqueous extracts (GJBRHe) on the Primary dysmenorrhea (PD) in rats as compared to those of Indomethacin (IND). Methods: The rats were administered with estradiol benzoate for 10 days and oxytocin 1 hour after the last 10th administration of estradiol benzoate to make the primary dysmenorrhea rat model. Gyejibokryeong-hwan aqueous extracts 500, 250 and 125 mg/kg were orally administrated, for 10 days once a day. Then the changes on the body weights and gains during experimental periods, uterine weights and gross inspections, abdominal writhing response for analgesic activities, uterus lipid peroxidation (malondialdehyde (MDA) levels), antioxidant defense system - glutathione (GSH) contents, activities of superoxide dismutase (SOD) and catalase (CAT), Nuclear factor-κB (NF-κB) and Cyclooxygenase (COX)-2 mRNA expressions, were monitored with uterus histopathology and immunohistochemistry for tumor necrosis factor (TNF)-α and inducible nitric oxide synthase (iNOS). The results of Gyejibokryeong-hwan aqueous extracts were compared to those of Indomethacin adminstered rats. Results: As results of estradiol benzoate and oxytocin treatment, noticeable decreases of body weights and gains, uterus GSH contents, SOD and CAT activities, increases of abdominal writhing responses, uterus lipid peroxidation (MDA level), uterus weights, NF-κB and COX-2 mRNA expressions were observed with increases of TNF-α and iNOS immunolabeled cells, inflammatory cell infiltrations, congestion and enlargement of the uterus at gross and histopathological inspections. These means classic inflammatory and oxidative stress mediated primary dysmenorrhea are relatively well induced. However, these signs were favorably and dose-dependently inhibited by administration of three different dosages of Gyejibokryeong-hwan aqueous extracts, but lesser than those of Indomethacin. Conclusions: The results obtained in this study suggest that Gyejibokryeong-hwan aqueous extracts has favorable analgesic and refinement activities dose-dependently on the estradiol benzoate and oxytocin treatment-induced primary dysmenorrhea signs.

Anti-osteoporotic Activity of Gojineumja Aqueous Extracts on the Ovariectomized Mice (난소적출 마우스에서 고진음자(固眞飮子) 물 추출물의 골다공증 개선 효과)

  • Cho, Su-Yun;Kim, Dong-Chul
    • The Journal of Korean Obstetrics and Gynecology
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    • v.31 no.4
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    • pp.16-38
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    • 2018
  • Objectives: The objective of this in vivo study is to observe the anti-osteoporotic activities of Gojineumja aqueous extracts (GJEJ) on the ovariectomized (OVX) mice as compared to those of risedronate sodium (RES). Methods: Thirty five days after bilateral OVX, GJEJ was orally administered, for 35 days once a day and then the changes on the body weight and gain during experimental periods, femur weights, bone mineral density (BMD), bone strength (failure load), mineral contents - calcium (Ca) and inorganic phosphorus (IP), histological profiles and histomorphometrical analyses at sacrifice were conducted with serum biochemistry - osteocalcin contents and bone specific alkaline phosphatase (BALP) activities. And the results of GJEJ were compared with RES orally administered OVX mice. Results: As a result of OVX, noticeable increase of body weight and gains and serum osteocalcin levels, decrease of serum BALP activities, femur weights, femur Ca and IP contents, BMD and strength were observed as compared to those of sham control mice, respectively. Also, the decrease of all histomorphometrical indices indicating the bone mass and structure, and the increase of indices about resorption were also detected in the femur of OVX control. However, these estrogen-deficient osteoporotic signs were significantly and dose-dependently inhibited by 35 days of continuous oral treatment of GJEJ, at dose levels of 500, 250 and 125 mg/kg, respectively. Especially, GJEJ 500 mg/kg showed favorable inhibitory activities against estrogen-deficient osteoporosis symptoms induced by OVX as comparable to those of RES 2.5 mg/kg. Conclusions: The results in this study suggest that oral administrations of GJEJ have clear dose-dependent favorable anti-osteoporotic activities in OVX mice.

Preventive Measures on Alkali-Silica Reaction of Crushed Stones (쇄석 골재의 알칼리-실리카 반응 방지 대책)

  • Jun Ssang-Sun;Lee Hyo-Min;Seo Ki-Young;Hwang Jin-Yeon;Jin Chi-Sub
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.129-137
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    • 2005
  • In Korea, due to the insufficiency of natural aggregates and increasing needs of crushed stones, it is necessary to examine the alkali-silica reaction of the crushed stones. The reaction produces an alkali-silica reaction gel which can imbibe pore solution and swell to generate cracks that are visible In affected concrete. In general, crushed stones are tested by petrograptuc examination, chemical method and mortar-bar method, but the most reliable method Is mortar-bar test. This study tested alkali-silica reactivity of crushed stones of various rock types using ASTM C 227 and C 1260, and compared the results of two test methods. This study also analyzed effects of particle size and grading of reactive aggregate on alkali-silica reaction expansion of mortar-bar. The effectiveness of mineral admixtures to reduce detrimental expansion caused by alkali-silica reaction was investigated through the ASTM C 1260 method. The mineral admixtures used were nv ash, silica fume, metakaolin and ground granulated blast furnace slag. The replacement ratios of 0, 5, 10, 15, 25 and $35\%$ were commonly applied for all the mineral admixtures and the replacement ratios of 45 and $55\%$ were additional applied for the admixtures that could maintain workability. The results indicate that replacement ratios of $25\%$ for ay ash, $10\%$ for silica fume, $25\%$ for metakaolin or $35\%$ for ground granulated blast furnace slag were most effective to reduce alkali-silica reaction expansion under the experimental conditions.

Depth Control and Sweeping Depth Stability of the Midwater Trawl (중층트롤의 깊이바꿈과 소해심도의 안정성)

  • 장지원
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.9 no.1
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    • pp.1-18
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    • 1973
  • For regulating the depth of midwater trawl nets towed at the optimum constant speed, the changes in the shape of warps caused by adding a weight on an arbitrary point of the warp of catenary shape is studied. The shape of a warp may be approximated by a catenary. The resultant inferences under this assumption were experimented. Accordingly feasibilities for the application of the result of this study to the midwater trawl nets were also discussed. A series of experiments for basic midwater trawl gear models in water tank and a couple of experiments of a commercial scale gears at sea which involve the properly designed depth control devices having a variable attitude horizontal wing were carried out. The results are summarized as follows: 1. According to the dimension analysis the depth y of a midwater trawl net is introduced by $$y=kLf(\frac{W_r}{R_r},\;\frac{W_o}{R_o},\;\frac{W_n}{R_n})$$) where k is a constant, L the warp length, f the function, and $W_r,\;W_o$ and $W_n$ the apparent weights of warp, otter board and the net, respectively, 2. When a boat is towing a body of apparent weight $W_n$ and its drag $D_n$ by means of a warp whose length L and apparent weight $W_r$ per unit length, the depth y of the body is given by the following equation, provided that the shape of a warp is a catenary and drag of the warp is neglected in comparison with the drag of the body: $$y=\frac{1}{W_r}\{\sqrt{{D_n^2}+{(W_n+W_rL)^2}}-\sqrt{{D_n^2+W_n}^2\}$$ 3. The changes ${\Delta}y$ of the depth of the midwater trawl net caused by changing the warp length or adding a weight ${\Delta}W_n$_n to the net, are given by the following equations: $${\Delta}y{\approx}\frac{W_n+W_{r}L}{\sqrt{D_n^2+(W_n+W_{r}L)^2}}{\Delta}L$$ $${\Delta}y{\approx}\frac{1}{W_r}\{\frac{W_n+W_rL}{\sqrt{D_n^2+(W_n+W_{r}L)^2}}-{\frac{W_n}{\sqrt{D_n^2+W_n^2}}\}{\Delta}W_n$$ 4. A change ${\Delta}y$ of the depth of the midwater trawl net by adding a weight $W_s$ to an arbitrary point of the warp takes an equation of the form $${\Delta}y=\frac{1}{W_r}\{(T_{ur}'-T_{ur})-T_u'-T_u)\}$$ Where $$T_{ur}^l=\sqrt{T_u^2+(W_s+W_{r}L)^2+2T_u(W_s+W_{r}L)sin{\theta}_u$$ $$T_{ur}=\sqrt{T_u^2+(W_{r}L)^2+2T_uW_{r}L\;sin{\theta}_u$$ $$T_{u}^l=\sqrt{T_u^2+W_s^2+2T_uW_{s}\;sin{\theta}_u$$ and $T_u$ represents the tension at the point on the warp, ${\theta}_u$ the angle between the direction of $T_u$ and horizontal axis, $T_u^2$ the tension at that point when a weights $W_s$ adds to the point where $T_u$ is acted on. 5. If otter boards were constructed lighter and adequate weights were added at their bottom to stabilize them, even they were the same shapes as those of bottom trawls, they were definitely applicable to the midwater trawl gears as the result of the experiments. 6. As the results of water tank tests the relationship between net height of H cm velocity of v m/sec, and that between hydrodynamic resistance of R kg and the velocity of a model net as shown in figure 6 are respectively given by $$H=8+\frac{10}{0.4+v}$$ $$R=3+9v^2$$ 7. It was found that the cross-wing type depth control devices were more stable in operation than that of the H-wing type as the results of the experiments at sea. 8. The hydrodynamic resistance of the net gear in midwater trawling is so large, and regarded as nearly the drag, that sweeping depth of the gear was very stable in spite of types of the depth control devices. 9. An area of the horizontal wing of the H-wing type depth control device was $1.2{\times}2.4m^2$. A midwater trawl net of 2 ton hydrodynamic resistance was connected to the devices and towed with the velocity of 2.3 kts. Under these conditions the depth change of about 20m of the trawl net was obtained by controlling an angle or attack of $30^{\circ}$.

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Optimum Digestible Energy to Protein Ratio in Diets for the Korean Rockfish Sebastes schlegeli (조피볼락 Sebastes schlegeli 사료의 적정 에너지/단백질 비)

  • LEE Jong Yun;KANG Yong Jin;LEE Sang-Min;KIM In-Bae
    • Journal of Aquaculture
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    • v.6 no.1
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    • pp.29-46
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    • 1993
  • In order to determine the optimum digestible energy to protein (DE/P) ratio in diets for Korean rockfish, Sebastes schlegeli, $45\%$ and $40\%$ protein diets with graded levels of DE/P ratio were fed to average 36g and 80g fish, respectively. The DE/P ratios in the $45\%$ protein diets ranged from 7.4 to 10.0 kcal/g protein, while those in the $40\%$ protein diets varied between 7.5 and 8.9 kcal/g protein. Both in the $45\%$ and $40\%$ protein diets, the changes in the DE/P ratios did not affect either the daily weight gain or the feed efficiency. However daily protein retention, daily energy retention, nutrient utilization and chemical composition in carcass varied depending on the DE/P ratios. Thus based on these parameters as criteria, the optimum DE/P ratio for both the $40\%$ and $45\%$ protein diets, estimated to be about 8 kcal/g protein. DE/P ratios more than 8 kcal/g protein, led to the deposition of a large amount of body fat, especially in the viscera. Any protein-sparing effect was not observed with the increase of the energy content in the diets. Apparent digestibility coefficients determined by the indirect method, using $Cr_2O_3$ as an indicator, were around $90,\;98\%\;and\;70\%$, for protein, lipid and digestible carbohydrate respectively, without any distinct differences between the diets.

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Quality improvement of retorted frozen seafood by adding sorbitol (솔비톨 첨가에 의한 냉동 해산물의 레토르트 후 품질 향상)

  • Cho, Won-Il;Song, Sang-Hoon
    • Korean Journal of Food Science and Technology
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    • v.49 no.1
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    • pp.85-89
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    • 2017
  • This study was conducted to prevent hardened texture in retorted frozen seafoods such as small octopus, squid, and top shell by adding sorbitol; the strength of mechanical hardness and other qualities were measured. The hardness of the 3 kinds of seafood pretreated with 2-4% (w/w) sorbitol solution decreased by 9-36% compared to the control. The hardness of retorted frozen octopus, squid, and top shell treated with sorbitol solution upon freezing significantly decreased to 1670, 1015, and $521g_f/cm^2$ compared to levels in untreated food of 1841, 1291, and $815g_f/cm^2$ (p<0.05), respectively. Yields based on weight in retorted seafood treated with sorbitol were increased by 2-5% compared to untreated samples. Additionally, the overall preference of texture was 0.4 points higher than that of control samples in descriptive sensory evaluation (p<0.05). The tissue softening of pretreated seafood was based on decreased dewatering due to the formation of small ice crystals during freezing as a result of sorbitol treatment.

휴대형 당도판정센서를 이용한 배의 당도 판정

  • 이강진;최규홍;강석원;최완규;손재룡
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.120-121
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    • 2003
  • 과수원에서 재배되는 배는 과수원 내의 위치, 시비, 토양 등의 요인에 따라 다양한 품질을 나타내며, 당도와 숙도의 편차가 크기 때문에 과수농가에서는 경험에 의존하여 적정 숙기로 판단되는 배를 수확하고 있다. 그러나 과학적이지 못한 사실에 기초한 수확 관행은 시장유통되는 배에 대하여 소비자들의 신뢰성 저하를 초래하게 되고 소비 감소와 더불어 농가 소득 감소로 이어지게 된다. 최근, 전국의 청과물 산지유통센터에는 근적외선을 이용하여 과일 내부의 당도, 산도, 결함 등을 실시간으로 판정할 수 있는 비파괴 선별기가 보급되고 있으나 이는 수확이후의 선별.규격화 유통을 위한 것이다. 본 연구에서는 이와는 달리, 수확 이전, 즉 재배 단계에서 배의 당도와 숙도를 판정하여 수확적기를 판단할 수 있도록 나무에 매달린 배에 대하여 가시광선과 근적외선 반사스펙트럼을 측정할 수 있고 이를 이용하여 당도와 숙도가 판정가능한 휴대형 센서를 개발하였으며, 개발된 시작기를 이용하여 당도판정의 가능성을 시험하였다. 휴대형 당도판정센서는 광원과 광섬유프로브, 광검출부, 당도판정부, 전원공급부로 구성된다. 광원은 할로겐램프(6V)를 이용하였고, 광섬유프로브는 동심원 형태로서 외부의 광섬유를 통하여 광원에서 시료로 빛이 조사되게 하고, 내부의 광섬유를 통하여 광검출기로 확산반사되는 광이 전달될 수 있도록 하였다. 전원공급부는 휴대와 충전이 가능한 배터리(12V, 2AH)와 이 배터리에서 정전류가 광원으로 보내어 질 수 있도록 제작된 회로로 구성하였다. 당도 판정을 위하여 518nm에서 1046nm의 파장대역에서의 반사스펙트럼을 이용하였고, 레퍼런스로써 백색 테플론 구를 제작하여 사용하였다. 수원 농산물 도매시장에서 판매중인 2002년산 신고 배를 구매하고, 시작기를 이용하여 총 113개의 배에 대한 반사스펙트럼을 측정하였다. 다음으로 굴절당도계로 당도값을 측정하고 반사스펙트림을 이용하여 당도값을 예측하기 위한 부분최소제곱회귀(PLSR)모델을 개발하였다. 여기서 모델의 정밀도는 교차검정법을 이용하여 검증하였다. 시료 표면과 광섬유프로브와의 접촉상태 불균일, 광원의 시간에 따른 경시 변화, 과일 형상의 차이 등에 의하여 측정된 반사스펙트럼은 상당한 변이를 나타내었으므로 이를 보정하기 위하여 반사 스펙트럼은 다분산보정처리하여 이용하였다. 당도 예측용 PLSR모델 개발의 결과, 모델의 결정계수($R^2$)는 0.67, SEC는 $\pm$0.4brix.로 나타났으며, 교차검정에 의한 미지 시료의 예측에서 총 113개의 미지 시료에 대한 결정계수는 0.57, SEP는 $\pm$ 0.46brix.로 나타났으며, 이는 현장에서 충분히 활용가능할 것으로 판단되었다. 금후, 전체 시스템의 부피와 중량을 줄이고 각 부분품들의 전력소모의 최소화할 수 있도록 개선할 계획이다.

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Influence of Activation Temperature on Surface and Adsorption Properties of PAN-based Activated Carbon Fibers/Phenolic Resin Matrix Composites (활성화 온도에 의한 PAN계 활성탄소섬유/페놀수지 복합재료의 표면 및 흡착특성)

  • 박수진;김기동;이재락
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.97-104
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    • 2000
  • PAN-based activated carbon fibers/phenolic resin matrix composites (ACFCs) were manufactured via molding process with oxidized carbon fabrics (plain-type) and phenolic resin (resole-type) compounded by 70 : 30 wt%. The green body (as molded) was submitted to carbonization (at 100$0^{\circ}C$) in an inert environment and activation (at 700, 800, 900 and 100$0^{\circ}C$) in a $CO_2$ environment. In this work, the influence of activation temperatures was investigated in surface properties, such as pH, acid- and base-values by titration method, and in adsorption properties, i.e., specific surface area and pore structures by BET-method of the composites. Also, the pressure drops of the specimens were calibrated by ASTM. As a result, the activation temperature influenced the surface property of ACFCs. When the activation temperature was higher than 90$0^{\circ}C$, the surface was gradually developed in basic nature. And, the evolutions of specific surface area, total pore volume and pore size distribution of ACFCs could be easily confirmed the dependence on the activation temperature. Among them, well-developed pore structure from adsorption characteristics was changed of the ACFCs activated at 90$0^{\circ}C$. Also, the pressure drop was slightly decreased with increasing the temperature due to increasing the burn-off with heat treatment temperature of ACFCs.

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