• Title/Summary/Keyword: 중량변화법

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Batch Scale Storage of Garlic by Irradiation Combined with Natural Low Temperature (방사선(放射線) 조사(照射)와 자연저온(自然低溫)에 의한 마늘의 저장)

  • Cho, Han-Ok;Kwon, Joong-Ho;Byun, Myung-Woo;Yoon, Hyung-Sik
    • Korean Journal of Food Science and Technology
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    • v.16 no.1
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    • pp.66-70
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    • 1984
  • An attempt was made on the development of a commercial scale storage method of garlic by irradiation. Irradiated garlics with 50, 100 and 150 Gy were stored at natural low temperature storage room $(12{\pm}6^{\circ}C,{\;}75-85%{\;}RH)$ and the physicochemical properties during the 10 months storage were investigated. The unirradiated garlic was mostly sprouted after 8 months storage, whereas the sprouting of all irradiated groups was completely inhibited until 10 months storage, The rotting rate and weigh loss of garlic after 10 months storage were reduced by 25 to 54% at 100 Gy irradiation compared with those of an unirradiated group. The moisture content remained relatively constant during the whole storage period. The total sugar content was increased with storage period. Ascorbic acid content was also decreased until 8 months storage but its content was rapidly increased along with sprouting. Garlic was marketable after 10 months storage by 100 Gy irradiation combined with natural low temperature.

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Air-tightness Test by Silicagel on Museum Cases (조습제(燥濕濟)(Art-Sorb)를 이용한 벽부형진열장(壁附形陳列欌) 밀폐도(密閉度) 간접측정(間接測淀))

  • Yu, Hei-sun;Kim, Myoung-nam;Lee, Sung-eun
    • Conservation Science in Museum
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    • v.3
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    • pp.71-78
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    • 2001
  • The airtightness of museum cases in museums was measured by using CO2 tracing gas, but it has been pointed that it has a problem with measuring the airtightness of a museum case which has a hole inside before it is used or while is being used. So studies tried to come up with alternatives which make it possible to measure the airtightness of a museum case before it is used or while it is being used if necessary by indirectly measuring the airtightness of the museum case without changing its form. Indirect measuring is done by measuring the change of Art-sorb weight and the change of temperature and humidity inside the museum case. Experiments were made for 12 days with three builtin wall case installed at the same place without turning on the lights but with Art-sorb and the data logger of temperature and humidity put into museum case. The change rate was produced with the change of temperature and humidity inside the museum case divided by that of those around museum case. As a result, the temperature change rate of museum case A(0.67) was lower than that of museum case B(0.69) or museum case C(0.79). The humidity change rate of museum case A(0.12) was lower than that of museum case B(0.19) or museum case C(0.72) showing that its airtightness was the best. Also in the direct airtightness measurement by CO2 tracing gas, the air exchange rate was compared with the humidity change rate by Art-sorb in the indirect measurement.

Addition Polymerization of 5-Norbornene-2-carboxylic Acid Esters Using Palladium Catalyst System: Synthesis of Monomers, Effect of Their Stereochemistry on Polymerization Behavior (Palladium 촉매를 이용한 5-Norbornene-2-carboxylic Acid Esters의 부가 중합: 단량체의 합성, 단량체의 Stereochemistry(Endo-, Exo-이성질체)가 고분자의 중합 거동에 미치는 영향)

  • Chung, Hae-Kang;Shim, Hyoug-Sub;Jeon, Seung-Ho;Kim, Ji-Heung;Nam, Sung Woo;Jeon, Boong Soo;Kim, Young Jun
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.487-492
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    • 2015
  • The effects of chemical structure of alkyl groups of norbornene carboxylic alkyl esters(methyl, octyl, 4-chlorobenzyl) and endo/exo ratios of norbornene monomers on activity of palladium catalyst and polymerization behavior were investigated. Norbornene ester monomers were synthesized from the reaction of 5-norborene-2-carboxylic acid and various alcohols. Polymerization catalyst, di-${\mu}$-chloro-bis(-methoxybicyclo[2,2,1]-hept-2-ene)palladium(II) (DCBMP), was synthesized according to the literature procedure and silver hexafluoroantimonate ($AgSbF_6$) was used as a conjugate anion source. Gel permeation chromatography (GPC), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) were the principal techniques for polymer characterization and $^1H$ NMR spectroscopy was used for chemical structures determination of monomers and polymers. For all of the norbonene alkyl esters GPC data showed that when the amounts of endo isomers exceeded those of exo isomers decreased molecular weight polymers were obtained probably due to the decreased catalyst activity. Polymerizations were conducted by varying the monomer/catalyst mole ratios (100:1, 200:1, 300:1). When 300:1 monomer/catalyst ratio was employed it was possible to synthesize high molecular weight ($M_n=27500g/mol$), film forming polymer from exo-norbornene carboxylic acid octyl ester.

Property Studies of PAN/PVdF Composite Nanofiber Manufactured from Electrospinning (전기방사법으로 제조된 PAN/PVdF 복합나노섬유의 특성연구)

  • Yun, Jung-Hyun;Choi, Dong-You
    • 전자공학회논문지 IE
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    • v.46 no.3
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    • pp.6-11
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    • 2009
  • In this paper, manufactured composite nanofiber by electrospinning that make spinning solvent according to weight of PAN/PVdF. PVdF content of composite nanofiber decreases, diameter of fiber decreased. Result that measure contact angle to confirm hydrophile property of PAN/PVdF composite nanofiber, PVdF content increases, could confirm that contact angle with water increases. After leave filter measurement sample for 25 hours in temperature of $40^{\circ}C$, humidity of 85%, result PAN/PVdF composite nanofiber that estimate efficiency could confirm that display performance of HEPA more than 99.95% and ULPA more than 99.999%. And fiber diameter is small, could confirm that filter performance increases. Tensile strength of bulk of PAN/PVdF composite nanofiber was 5-8MPa, expansion 100-300%. And strength and expansion could know that increase according as PVdF's content increases. Tensile strength was 3-8MPa degree after annealing PAN/PVdF composite nanofiber during 2 hours in 120t. Tensile strength was no change almost by annealing, and expansion could know that decrease.

Synthesis of Multi-Terminalized Magnetic-Cored Dendrimer for Adsorption of Chromium and Enhancement of Magnetic Recovery (크롬 흡착 및 자성회수율 향상을 위한 멀티터미널 자성코어 덴드리머의 합성)

  • Yeo, In-Hwan;Jang, Jun-Won;Kim, Lyung-Joo;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.9
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    • pp.613-622
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    • 2012
  • A chrome absorbent that is useful in rapid magnetic recovery and recycling was developed though a synthesis of Multi-Terminalized Magnetic-core Dendrimer (MTMD). Divergence through coprecipitation and rotation growth was used for synthesis. The dendrimer was multi-terminilized through methyl propionate and glutaric acid. The property analysis of the synthesized sample was performed through XRD, FT-IR, TEM, EDS, TGA and zeta potential analyzer. A magnetic-core of MTMD had a magnetite crystal and the size of 4th generation dendrimer was identified to be from 15 nm to 20 nm. Through the analysis of the TGA, the rate of the dendrimer branch for the first generation dendrimer was about 7% and 3% of diminished weight occurred as the generation grows. Also, the potential of the dendrimer when multi-terminalized, had variation from 25.26 mV to -6.53 mV. As a result of MTMD adsorption experiment, it absorbed more than 80% within 5 minutes and indicated absorptivity of 6.308 mg/g. When it was compared with COOH Dendrimer (COOH-D) after magnetic recovery, the recovery time was rapidly reduced by more than half and it could recover 100% within 30 minutes. In case of the regeneration experiment that used chrome, it was identified to maintain the same adsorptivity for four runs.

A Study on the Behavior of Blasting Demolition for a Reinforced Concrete Structure Using Sealed Model Test and Particle Flow Analysis (축소모형실험과 입자결합모델 해석을 통한 철근 콘크리트 구조물의 발파해체 거동에 관한 비교 분석)

  • 채희문;전석원
    • Explosives and Blasting
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    • v.22 no.1
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    • pp.33-43
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    • 2004
  • In this study, a comparison was made between the resulting behaviors of scaled model test and particle flow analysis for blasting demolition of a reinforced concrete structure. For the test and analysis, a progressive failure of a five-story structure was considered. The dimension analysis was carried out to properly scale down the real structure into the laboratory size. The test model was made of the mixture of gypsum, sand and water along with soldering lead to analogy reinforcing steel bars. The ratio of mixing components was chosen to best represent the scaled down strength and deformation modulus. The columns and girders of the structure were precasted in the laboratory and assembled right before the blasting test. The numerical analysis of the blasting demolition was carried out using PFC2D (Particle Flow Analysis 2-Dimension by Itasca). The results of the blasting of concrete lahmen structure showed roughly identical demolition behavior between scaled model test and numerical test. For the blasting of the reinforced concrete structure, the results were more identical and closer to the real demolition behavior, since the demolition behavior was better represented in this case due to the increased tensile strength of the component.

Effect of the Application of Residual Food Compost on Growth of Red Pepper(Capsicum annuum L.) and Physicochemical Properties of soil (남은 음식물 퇴비 시용에 따른 토양의 이화학성 변화와 고추생육에 미치는 영향)

  • Yu, Young-Seok;Chang, Ki-Woon;Lee, Ji-Whan
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.4
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    • pp.81-88
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    • 2001
  • This experiment was carried out to evaluate the effect of residual food compost application on plant growth and physicochemical properties of soil when residual food compost made from the composting process as part of organic waste recycling was applied in soil as variable rate. The treatments were composed non-fertilizer treatment, control treatment applied with pig compost $20Mg(D.W.)ha^{-1}$, and residual food compost treatments each of applied with 20, 40, 60, $80Mg(D.W.)ha^{-1}$ and were randomized complete block design with three replication. Soil pH after experiment was more increased as more increase application of residual food compost. Other chemical properties of soil including EC were also showed the similar results. The plant growth in treatments applied much of residual food compost at the early growth stage was very damaged and these results were proved at the first growth measurement. Production of the red pepper especially reduced in treatments taken growth demage at the early stage and that of $20Mgha^{-1}$ treatment almost same as control treatment. Bulk density was reduced but porosity was increased according to increase of residual food compost application. Considering the reduction of red pepper production and the demage of growth at the early stage by plenty of salt and water soluble application volume of residual food compost was not permitted over of $30Mgha^{-1}$. Additively, to settle the application volume of residual food compost and to evaluate the plant growth and changes of physicochemical properties of soil, the results taken from continual applying is concluded more important than single application.

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Selective Removal of Arsenic Compounds from the Contaminated Paddy Soil in China Using Froth Flotation Technique (포말부선 기술을 이용한 중국 오염농경지내 비소화합물의 선택적 제거)

  • Lee, Seungwoo;Jeon, Chilsung;Lee, Eunseong;Yoo, Kyungmin;Choi, Junhyun;Kim, Hyunjung
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.7
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    • pp.343-352
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    • 2016
  • Effects of grinding time and chemicals dosage in arsenic removal from contaminated paddy soil in China were investigated using lab scale attrition and froth flotation combining process. Arsenic concentration in the field soil was 76.51 mg/kg, exceeding Korean and Chinese standards, and predominant arsenic compounds fraction in sequential extraction was "residual" (over 80%). After wet sieving, soil with >2 mm and < 0.038 mm showed concentration lower than 'Warning Level' in Korea. Soil with 0.038-0.075 mm, showing the highest concentration, was discarded since it occupied minor weight fraction (10.1%). Thus soil between 0.075 and 2 mm was only used in the combining process. The highest Arsenic concentration in progeny fragments smaller than 0.038 mm reached up to 981.66 mg/kg after 5 min of attrition. Optimal dosage of collector ($C_5H_{11}OCS_2K$) and modifier ($Na_2S$ and $CuSO_4$) in froth flotation process for the selective separation of the chipped progeny particles from the parent fragments were determined both as 200 g/ton. Arsenic removal efficiency in froth flotation process was 38.47% and it was increased to 72.74% in additional flotation process, scavenging. Average arsenic concentration after overall process - wet sieving, attrition and froth flotation - was estimated to 16.45 mg/kg.

Coupled Finite Element Analysis of Partially Saturated Soil Slope Stability (유한요소 연계해석을 이용한 불포화 토사사면 안전성 평가)

  • Kim, Jae-Hong;Lim, Jae-Seong;Park, Seong-Wan
    • Journal of the Korean Geotechnical Society
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    • v.30 no.4
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    • pp.35-45
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    • 2014
  • Limit equilibrium methods of slope stability analysis have been widely adopted mainly due to their simplicity and applicability. However, the conventional methods may not give reliable and convincing results for various geological conditions such as nonhomogeneous and anisotropic soils. Also, they do not take into account soil slope history nor the initial state of stress, for example excavation or fill placement. In contrast to the limit equilibrium analysis, the analysis of deformation and stress distribution by finite element method can deal with the complex loading sequence and the growth of inelastic zone with time. This paper proposes a technique to determine the critical slip surface as well as to calculate the factor of safety for shallow failure on partially saturated soil slope. Based on the effective stress field in finite element analysis, all stresses are estimated at each Gaussian point of elements. The search strategy for a noncircular critical slip surface along weak points is appropriate for rainfall-induced shallow slope failure. The change of unit weight by seepage force has an effect on the horizontal and vertical displacements on the soil slope. The Drucker-Prager failure criterion was adopted for stress-strain relation to calculate coupling hydraulic and mechanical behavior of the partially saturated soil slope.

A Study of Blasting Demolition by Scaled Model Test and PEC2D Analysis (축소모형실험 및 PFC2D해석에 따른 발파해체 거동분석)

  • 채희문;전석원
    • Tunnel and Underground Space
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    • v.14 no.1
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    • pp.54-68
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    • 2004
  • In this study, scaled model tests were performed on blasting demolition of reinforced concrete structures and the experimental results were analyzed in comparison with the results of numerical analysis. The tests were designed to induce a progressive collapse, and physical properties of the scaled model were determined using scale factors obtained ken dimension analysis. The scaled model structure was made of a mixture of plaster, sand and water at the ratio determined to yield the best scaled-down strength. Lead wire was used as a substitute for reinforcing bars. The scaled length was at the ratio of 1/10. Selecting the material and scaled factors was aimed at obtaining appropriately scaled-down strength. PFC2D (Particle Flow Code 2-Dimension) employing DEM (Distinct Element Method) was used for the numerical analysis. Blasting demolition of scaled 3-D plain concrete laymen structure was filmed and compared to results of numerical simulation. Despite the limits of 2-D simulation the resulting demolition behaviors were similar to each other. Based on the above experimental results in combination with bending test results of RC beam, numerical analysis was carried out to determine the blasting sequence and delay times. Scaled model test of RC structure resulted in remarkably similar collapse with the numerical results up to 900㎳ (mili-second).