• Journal of Adhesion and Interface
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• v.23 no.2
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• pp.25-32
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• 2022

There has been a growing demand for water based-type PSA due to environmental regulations for solvent-type PSA. And accordingly, there is a growing expectation as well for tackifiers used to compensate for the problem of deterioration of physical properties. Therefore, In this study, water-based tackifiers were synthesized by changing the contents of hard and functional acrylic monomers CHMA, IBOA, and AA. And these were added to the pressure-sensitive adhesive at 10 phr and their physical properties were compared. Tackiness slightly decreased as CHMA increased and IBOA decreased. Since the intermolecular bonding force increased due to the increase in AA content, the lower the AA content showed better results. Peel strength increased as the tackifiers were added because the fluidity of the polymer chain increased. And higher AA content showed better results because more hydrogen bonds were formed. The holding power tended to decrease as CHMA increased because the content of IBOA relatively decreased which has a large influence on the holding power. And higher AA content showed better results.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.25-25
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• 2021

점착성 유사는 비점착성 유사에 비해 1차입자의 크기가 작아 1차입자간의 점착력이 중요한 역할을 하는 유사를 말한다. 점착성 유사는 비점착성 유사에 비해 크기가 작아 입자의 전자기적 점착력의 영향을 무시할 수 없으므로 점착력으로 인해 입자들은 서로 응집하는 동시에 입자들 간의 충돌에 의하여 파괴되는 과정을 거친다. 이러한 응집과 파괴가 지속되는 일련의 과정을 응집현상이라 한다. 점착성 유사는 응집과정을 통해 일차입자보다 크기가 크며 수십 개에서 수천 개의 일차입자와 물의 덩어리인 플럭을 형성하게 된다. 흐름 내 존재하는 플럭의 응집현상에 가장 지배적인 영향을 미치는 인자로 난류 거동이 알려진 바 있다. 본 연구에서는 난류 거동에 따른 점착성 플럭의 입도분포 변화를 살펴보고자 하였으며, 점착성 유사 입도분포 모형을 개발하였다. 수치모형의 개발은 확률과정(또는 추계과정)의 개념을 바탕으로 한다. 점착성 유사의 응집현상을 구성하는 응집과정은 다양한 연구를 통해 메커니즘들이 규명된 것과 달리 파괴과정은 난류로 인해 발생하며 무작위한 것으로 여겨진다. 무작위한 플럭의 파괴과정을 확률과정으로 가정하고 매개변수 중 하나를 대수정규분포를 따르는 난수로 고려하였다. 개발된 모형의 검증은 연안지역에서 점착성 플럭의 거동을 측정한 연구결과와의 비교를 통해 수행하였으며, 흐름 유속의 연직분포와 유사 농도의 연직분포, 응집현상 이후 플럭의 평형크기와 입도분포가 모두 합리적으로 계산되는 것이 확인되었다. 더불어 모의 결과에서는 대수정규분포를 따르는 동일한 난수를 적용하였음에도 불구하고 하상으로부터 거리가 가까워짐에 따라 플럭입도분포가 단봉분포(Unimodal Distribution)와 이봉분포(Bimodal Distribution)가 모두 계산되는 것으로 나타났다. 이는 모형의 개발과정에서 플럭의 가능 최대 크기를 콜모고로브 길이규모로 제한한 것과 관련이 있다. 난류 흐름 내 존재하는 플럭의 크기가 응집현상을 통해 난류의 콜모고로브 길이규모까지 성장하는 경우, 난류의 전단응력이 급격하게 증가하여 파괴과정이 활발해지고 응집과정이 저하된다는 것은 널리 알려진 사실이다. 이러한 사실을 바탕으로 플럭의 가능최대 크기를 콜모고로브 길이규모로 제한하였으며, 하상으로부터의 거리에 따라 콜모고로브 길이규모의 변화로 인해 콜모고로브 길이규모 부근에서 하나의 최빈값이 추가로 나타나는 것으로 이해된다. 수치모의 결과로부터 얻어진 콜모고로브 길이규모와 입도분포 형태의 상관관계를 보다 정확하게 이해하기 위해 실측 자료들을 검토해 본 결과, 균질한 재료를 이용한 실험실 실험결과에서 플럭 이봉분포의 최빈값이 콜모고로브 길이규모와 일치하는 것이 확인되었다. 연안지역에서 측정을 수행한 자료들에서도 이봉분포 또는 다봉분포와 콜모고로브 길이 규모와의 상관성을 찾아볼 수 있었다.

• Applied Chemistry for Engineering
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• v.3 no.4
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• pp.678-685
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• 1992

The effects of functional monomers on the pressure sensitive adhesive proporties were studied. Acrylic acid and other monomers were copolymerized by radical solution polymerization and their properties were measured. The desirability function methodology was applied to obtain optimum pressure sensitive adhesive properties. Acrylic acid showed more effective than acrylamide on peel strength increase. On the other hand acrylamide showed more effective than acrylic acid on tack decrease. The optimum monomer ratio of the acrylic pressure sensitive adhesive recipe containing n-butylacrylate 81.7 mole%, acrylic acid 8.0 mole%, acrylamide 2.1 mole% and vinylacetate 8.2 mole% was obtained to result from the statistical analysis with the desirability function methodology. The estimated regression equation of desirability function(D) is as follows: $D=.857+.072X_1-.114X_2-.027X_3-.126X_1{^2}-.046X_1{\cdot}X_2-.063X_1{\cdot}X_3-.152X_2{^2}+.027X2{\cdot}X_3-.120X_3{^2}$ $X_1$:coded acylic acid, $X_2$:coded acylamide, $X_3$:coded vinylacetate

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.25 no.6
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• pp.405-411
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• 2013

A sediment transport calculation considering cohesive force is proposed to deal with the transport phenomena of cohesive sediment. In the proposed calculation, each sand particle is assumed to be surrounded by a thin layer of mud. The critical Shields parameter and bed-load sediment transport rate are modified to include the cohesive force acting on the sand particle. The proposed calculation is incorporated into a two-way coupled fluid-structure-sediment interaction model, and applied to wave-induced topographic change of artificial shallows. Numerical results show that an increase in the content ratio of the mud, cohesive resistance force per unit surface area and water content cause increases in the critical Shields parameter and decreases in the bed-load sediment transport rate, reducing the topographic change of the shallow without changing its trend. This suggests that mixing mud in the pores of the sand particles can reduce the topographic change of shallows.

• Journal of Adhesion and Interface
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• v.13 no.4
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• pp.182-187
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• 2012

In making emulsion-type pressure sensitive adhesive (PSA), environmentally friendly sorbitan nonionic surfactants having various chemical structures were prepared and used to find out the possibility of substituting the traditional nonyl-phenyl nonionic surfactant (NPE40) by comparing their adhesive properties. Results exhibited that the PSA used NSR10-series and Tween 60 showed better adhesive properties in initial ball tack, peel strength and holding power than those of NPE40. The reason for this is their particular chemical structure and the proper ratio of hydrophobic groups to the ethylene oxide groups.

• Tunnel and Underground Space
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• v.23 no.3
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• pp.219-227
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• 2013

Although Mohr-Coulomb failure criterion has limitations in that it is a linear criterion and the effect of the intermediate principal stress on failure is ignored, this criterion has been widely accepted in rock mechanics design. In order to overcome these shortcomings, the Hoek-Brown failure criterion was introduced and recently a number of 3-D failure criteria incorporating the effect of the intermediate principal stress on failure have been proposed. However, in many rock mechanics designs, the possible failure of rock mass is still evaluated based on Mohr-Coulomb criterion and most of practitioners are accustomed to understanding the strength of rock mass in terms of the internal friction angle and cohesion. Therefore, if the equivalent Mohr-Coulomb strength parameters of the advanced failure criteria are calculated, it is possible to take advantage of the advanced failure criteria in the framework of the Mohr-Coulomb criterion. In this study, a method expressing the tangential Mohr-Coulomb strength parameters in terms of the stress invariant is proposed and it is applied to the generalized Hoek-Brown criterion and the HB-WW criterion. In addition, a new approach describing the geometric meaning of the ${\sigma}_2$-dependency of failure criteria in 3-D principal stress space is proposed. Implementation examples of the proposed method show that the influence of the intermediate principal stress on the tangential friction angle and cohesion of the HB-WW criterion is considerable, which is not the case for the 2-D failure criterion.

• Journal of the Korean Geotechnical Society
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• v.32 no.3
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• pp.15-27
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• 2016

In this study, a series of triaxial compressive strength tests were conducted for basaltic intact rocks sampled in the northeastern onshore and offshore, southeastern offshore and northwestern offshore of Jeju Island. Hoek-Brown constants $m_i$ were estimated from the results of the triaxial compression tests, and the properties of the Hoek-Brown constants $m_i$ were investigated. In addition, the cohesion and internal friction angle, strength parameters of Mohr-Coulomb failure criterion, obtained from the results of the triaxial compression tests were compared and analyzed with those estimated from Hoek-Brown failure criterion, respectively. As results, it was found that the Hoek-Brown constant $m_i$ is deeply related to the internal friction angle. As the internal friction grows, the Hoek-Brown constant $m_i$ increases exponentially. The cohesions estimated from the Hoek-Brown failure criterion, on average, are approximately 24% higher than those obtained from the Mohr-Coulomb failure criterion. The internal friction angles estimated from the Hoek-Brown failure criterion are similar to those obtained from the Mohr-Coulomb failure criterion.

• Journal of the Mineralogical Society of Korea
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• v.28 no.2
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• pp.109-126
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• 2015

Because fault gouge developed at the center of fault is recognized as one of the most important weak sites, it is evident that clay mineralogy and physical properties greatly affect the rock stability. The purpose of this study is to establish the relationship of mineralogy and physical factors that control rock stability in fault zones. We analyzed a total of 51 samples from 16 main faults which were selected from a Korea fracture map, using XRD, SEM, and physical analyses like unit weight, friction and cohesion properties. Though it is considered that the most common clay minerals comprising fault gouge are kaolinite, illite and smectite, clay mineralogy slightly varies depending on lithology: illite > smectite > kaolinite and chlorite in volcanic rocks, kaolinite and chlorite > illite > smectite in sedimentary rocks, and illite > smectite > kaolinite and chlorite in abundance, respectively. Friction angle decreases with increasing clay content. Cohesion increases with increasing clay content below the 45 % region while it decreases with increasing clay content at the region higher than 45%, with some scatters in the data. It is likely that these results are ascribed to the physical heterogeneity of fault gouges with varying content of different clay minerals.

• Tunnel and Underground Space
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• v.28 no.6
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• pp.584-595
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• 2018

This study conducted direct shear test on about 290 sorts of materials such as sandy soil, clayey soil and gravely soil to present proper standard on shear strength of soil. Shear strength of soil in large scale tends to show that angle of internal friction increases as sand contents grow and it ranges $23.5^{\circ}{\sim}34.9^{\circ}C$ with cohesion of 2.0 kPa~15.7 kPa. Elastic modulus was visibly distinct by load, and which increased approximately 80% as vertical load grows. Angle of internal friction arranging $15.0^{\circ}{\sim}28.6^{\circ}$ on clayey soil decreased as clay contents rises and cohesion increase in regular scale. Elastic modulus tends to increase initial elastic modulus with almost same growing rate. While angle of internal friction on gravely soil indicates $29.9^{\circ}{\sim}36.7^{\circ}$ which hardly shows distinctive features. According to test in detail, cohesion of SW (well-graded sand), SP (poorly-graded sand), SC (clayey sand) and SM (silty sand) indicates value by 94%, 78% and 59% comparing to SC, SW and SP respectively. Angle of internal friction of ML (low-liquid limit silt) and CL (low-liquid limit clay) appears almost same features, and MH (high-liquid limit silt) despite of 88% value of ML. Cohesion among them varies with similar growing rate.

• Journal of the Korean Geotechnical Society
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• v.23 no.12
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• pp.75-82
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• 2007

The effects of sitting pressure(${\sigma_{sit}}'$) during cementation, relative density and particle characteristics on the cohesion intercept due to cementation bonds and the confining stress inducing the breakage of cementation bonds ${p_i}'_{(BP)}$ are investigated from drained shear tests on the cemented sands confined under the isotropic stress up to 400 kPa. It was observed from the experimental results that the cemented sands, with the same density and gypsum content, show similar values of cohesion intercept and ${p_i}'_{(BP)}$, regardless of ${\sigma_{sit}}'$. Although the cohesion intercept and ${p_i}'_{(BP)}$ of cemented sands are observed to increase with increasing relative density and cementation level, the relative density appears to have more significant effect on ${p_i}'_{(BP)}$ than the cohesion intercept does. From analysing the test results of three different sands, it is shown that the smaller the particle size the larger the cohesion intercept and ${p_i}'_{(BP)}$, due to the increased number of contact points between the particles.