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Effects of Crosslinking Agent and Flame Retardant on the Dielectric Properties of Poly(phenylene ether)-based Polymer Substrate Material (폴리페닐렌에테르계 고분자 기판 소재의 유전특성에 대한 가교제 및 난연제의 영향)

  • Kim, Dong-Kook;Park, Seong-Dae;Yoo, Myong-Jae;Lee, Woo-Sung;Kang, Nam-Kee;Lim, Jin-Kyu;Kyoung, Jin-Bum
    • Polymer(Korea)
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    • v.33 no.1
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    • pp.39-44
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    • 2009
  • Polymer substrates were fabricated by using poly (phenylene ether) as a base resin, N,N'-m-phenylenedimaleimide (PDMI) as a crosslinking agent and decabromodiphenylethane as a flame retardant. The effects of crosslinking agent and flame retardant on physical properties such as dielectric property of the substrate were investigated. Thermal curing feature of PDMI with or without an initiator was analyzed by DSC, and then, PPE-PDMI test compositions were designed based on this result. Composite sheets were cast by film coater, laminated under vacuum and pressure, and then, the changes of dielectric constant, dielectric loss, peel strength, solder heat resistance and inflammability according to increasing amount of PDMI and flame retardant were evaluated, Dielectric constant and dielectric loss showed increasing trend with increasing amount of PDMI and flame retardant, but solder heat resistance and inflammability were improved. Peel strength was obtained higher than 1 kN/m when PDMI above 10 wt% was added, but slightly decreased as the amount of flame retardant increased. From the measured gel contents, the reaction mechanism of PPE-PDMI system was deduced to the formation of network structure by crosslinking PDMI with PPE rather than the formation of semi-IPN structure. In conclusion, the polymer composite substrate materials with dielectric constant of 2.52$\sim$2.65 and dielectric loss below 0.002 at 1 GHz were obtained and they will be proper for high frequency applications.

Effect of Stitching on Mechanical and Impact Properties of Glass Fiber Reinforced Composite (스티칭에 의한 유리섬유강화 복합재료의 물성 및 충격거동 변화)

  • Park, Jae-Yong;Kang, Tae-Jin;Yuk, Jong-Il
    • Korean Journal of Materials Research
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    • v.2 no.5
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    • pp.366-374
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    • 1992
  • Mechanical and impact properties of stitched S2 glass fiber reinforced polyester woven laminates composites have been studied. Laminates were stitched using Kevlar 49 thread with 1/2, 1, and 2 inch stitch spacing. Tensile and 3-point bending tests haute been performed to evaluate the mechanical properties of stitched and unstitched laminates. Impact tests at applied energy of 234.7J were performed to examine the impact behavior and toughness changes of the specimen. The same specimens were also tested repeatedly at low impact energy level of 110.2J for 3 times to evaluate damage tolerance properties. The tensile and 3-point bending test results showed that one inch spacing specimen had the highest tensile and flexural strength. It also showed the highest energy absorption capability and the best damage tolerance property at the repeated impact test. The half inch spacing specimen showed the lowest tensile strength and energy absorption property at the impact energy level of 234.7J, even though it had the highest frequency of stitching thread.

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Optimization of Crack-Free Polytypoidally Joined Dissimilar Ceramics of Functionally Graded Material (FGM) Using 3-Dimensional Modeling (폴리타이포이드 경사 방식으로 접합 된 이종 세라믹간의 적층 수의 최적화 및 잔류응력 해석에 대한 연구)

  • Ryu, Sae-Hee;Park, Jong-Ha;Lee, Sun-Yong;Lee, Jae-Sung;Lee, Jae-Chul;Ahn, Sung-Hoon;Kim, Dae-Keun;Chae, Jae-Hong;Riu, Do-Hyung
    • Korean Journal of Materials Research
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    • v.18 no.10
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    • pp.547-551
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    • 2008
  • Crack-free joining of $Si_3N_4\;and\;Al_2O_3$ using 15 layers has been achieved by a unique approach introducing Sialon polytypoids as a functionally graded materials (FGMs) bonding layer. In the past, hot press sintering of multilayered FGMs with 20 layers of thickness $500{\mu}m$ each has been fabricated successfully. In this study, the number of layers for FGM was reduced to 15 layers from 20 layers for optimization. For fabrication, model was hot pressed at 38 MPa while heating up to $1700^{\circ}$, and it was cooled at $2^{\circ}$/min to minimize residual stress during sintering. Initially, FGM with 15 layers had cracks near 90 wt.% 12H / 10 wt.% $Al_2O_3$ and 90 wt.% 12H/10 wt.% $Si_3N_4$ layers. To solve this problem, FEM (finite element method) program based on the maximum tensile stress theory was applied to design optimized FGM layers of crack free joint. The sample is 3-dimensional cylindrical shape where this has been transformed to 2-dimensional axisymmetric mode. Based on the simulation, crack-free FGM sample was obtained by designing axial, hoop and radial stresses less than tensile strength values across all the layers of FGM. Therefore, we were able to predict and prevent the damage by calculating its thermal stress using its elastic modulus and coefficient of thermal expansion. Such analyses are especially useful for FGM samples where the residual stresses are very difficult to measure experimentally.

The Changes of Solid, Nitrogen and Phosphorus Concentrations in Pig Slurry Stored at Various Depth of Slurry Storage Tank (돼지분뇨슬러리의 액비조내 저장깊이별 고형물 및 질소, 인의 함량분포에 관한 연구)

  • Jeong, Kwang-Hwa;Chung, Eui-Soo;Park, Chi-Ho;Kwag, Jung-Hoon;Choi, Dong-Yoon;Yoo, Yong-Hee
    • Journal of Animal Environmental Science
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    • v.12 no.3
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    • pp.161-168
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    • 2006
  • This paper describes the changes of characteristics of pig slurry according to storing depth. Most of the substances containing pollutants, such as were Management of manure and wastewater from animal confinement facilities is a critical factor for pollution control. With proper treatment processing method in both solid and liquid forms, it can be used as a fertilizer and soil conditioner. In Korea, liquid-manure handling system is very popular because its treatment and application is easy and labor saving. In the storage tank treatment, the period of fermentation process and solids-liquid separation averages six months and the supernatant liquid is being used as a fertilizer. In this study, the changes in chemical characteristics of pig slurry at varying depths of the storage tank were investigated. Results showed that the pH value of the fermented pig slurry was > 7, while the major pollutants such as BOD, SS, N and P were highest in the bottom of the tank. Therefore, the above findings proved that varying depths in the storage tank can influence the concentration of pollutants of the fermented pig slurry.

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Thickness Effect of SiOx Layer Inserted between Anti-Reflection Coating and p-n Junction on Potential-Induced Degradation (PID) of PERC Solar Cells (PERC 태양전지에서 반사방지막과 p-n 접합 사이에 삽입된 SiOx 층의 두께가 Potential-Induced Degradation (PID) 저감에 미치는 영향)

  • Jung, Dongwook;Oh, Kyoung-suk;Jang, Eunjin;Chan, Sung-il;Ryu, Sangwoo
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.3
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    • pp.75-80
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    • 2019
  • Silicon solar cells have been widely used as a most promising renewable energy source due to eco-friendliness and high efficiency. As modules of silicon solar cells are connected in series for a practical electricity generation, a large voltage of 500-1,500 V is applied to the modules inevitably. Potential-induced degradation (PID), a deterioration of the efficiency and maximum power output by the continuously applied high voltage between the module frames and solar cells, has been regarded as the major cause that reduces the lifetime of silicon solar cells. In particular, the migration of the $Na^+$ ions from the front glass into Si through the anti-reflection coating and the accumulation of $Na^+$ ions at stacking faults inside Si have been reported as the reason of PID. In this research, the thickness effect of $SiO_x$ layer that can block the migration of $Na^+$ ions on the reduction of PID is investigated as it is incorporated between anti-reflection coating and p-n junction in p-type PERC solar cells. From the measurement of shunt resistance, efficiency, and maximum power output after the continuous application of 1,000 V for 96 hours, it is revealed that the thickness of $SiO_x$ layer should be larger than 7-8 nm to reduce PID effectively.

Distribution of Magnetic Field Depending on the Current in the μ-turn Coil to Capture Red Blood Cells (적혈구 포획용 미크론 크기 코일에 흐르는 전류의 크기에 따른 자기장 분포 특성)

  • Lee, Won-Hyung;Chung, Hyun-Jun;Kim, Nu-Ri;Park, Ji-Soo;Lee, Sang-Suk;Rhee, Jang-Roh
    • Journal of the Korean Magnetics Society
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    • v.25 no.5
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    • pp.162-168
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    • 2015
  • The ${\mu}$-turn coil having a width of ${\mu}m$ on the GMR-SV (giant magnetoresistance-spin valve) device based on the antiferromagnetic IrMn layer was fabricated by using the optical lithography process. In the case of GMR-SV film and GMR-SV device, the magnetoresistance ratios and the magnetic sensitivities are 4.4%, 2.0%/Oe and 1.6 %, 0.1%/Oe, respectively. In the y-z plane the distribution of magnetic field of GMR-SV device and $10{\mu}$-turns coil which put under the several magnetic bead(MB)s with a diameter of $1{\mu}m$ attached to RBC (red blood cell) was analyzed by the computer simulation using the finite element method. When the AC currents of 20 kHz from 0.1 mA to 10.0 mA flow to the 10 turns ${\mu}$-coil, the magnetic field at the position of $z=0{\mu}m$ at the center of coil was calculated from $30.1{\mu}T$ to $3060{\mu}T$ in proportion to the current. The magnetic field at the position of $z=10{\mu}m$ was decreased to one-sixth of that of $z=0{\mu}m$. It was confirmed that the $10{\mu}$-turn coil having enough magnitude of magnetic field for the capture of RBC is possible to use as a biosensor for the detection of magnetic beads attached to RBC.

Marine Terraces and Quaternary Faults in the Homigot and the Guryongpo, SE Korea (호미곶과 구룡포지역 해안단구와 신기지구조운동)

  • Choi, Sung-Ja
    • The Journal of the Petrological Society of Korea
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    • v.25 no.3
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    • pp.231-240
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    • 2016
  • Three Quaternary faults have been revealed in marine terraces nearby the Homigot and the Gurongpo in the southeastern offshore of Korean Peninsula. The Hajung fault cuts the $4^{th}$ marine terraces and the Guman fault the $2^{nd}$, respectively. The Hajung fault strikes $N55^{\circ}$ to $45^{\circ}W$ and dips $40^{\circ}$ to $45^{\circ}NE$ with reverse-displacement of 180cm vertically. There are four sets of colluvial sediment strata that would be produced by faulting and indicate four times of fault movements during MIS 7 and MIS 5c. The Guman fault site consists of three sets of reverse faults that strike $N80^{\circ}E$ to $N70^{\circ}W$ and dip $25^{\circ}{\sim}35^{\circ}SE$ to $30^{\circ}SW$ with vertical displacement of 9~18 cm. The Guman faulting occurred during 80 ka (MIS 5a) to 71 ka (MIS 4) but it extends only to the lowest bed, the pebble sand bed, lay just on the unconformity, and not to the upper. Considering the attitude of the faults, we inferred that the Hajung fault was activated under the ENE-WSW compression during MIS 7 to MIS 5c and the Guman under N-S trending compression during MIS 5a. Using the OSL age dating results, we reconfirmed that the $2^{nd}$ terrace is correlated to MIS 5a and the $4^{th}$ terraces to MIS 7.

Optimization of Elastic Modulus and Cure Characteristics of Composition for Die Attach Film (다이접착필름용 조성물의 탄성 계수 및 경화 특성 최적화)

  • Sung, Choonghyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.503-509
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    • 2019
  • The demand for smaller, faster, and multi-functional mobile devices in increasing at a rapidly increasing rate. In response to these trends, Stacked Chip Scale Package (SCSP) is used widely in the assembly industry. A film type adhesive called die attach film (DAF) is used widely for bonding chips in SCSP. The DAF requires high flowability at high die attachment temperatures for bonding chips on organic substrates, where the DAF needs to feel the gap depth, or for bonding the same sized dies, where the DAF needs to penetrate bonding wires. In this study, the mixture design of experiment (DOE) was performed for three raw materials to obtain the optimized DAF recipe for low elastic modulus at high temperature. Three components are acrylic polymer (SG-P3) and two solid epoxy resins (YD011 and YDCN500-1P) with different softening points. According to the DOE results, the elastic modulus at high temperature was influenced greatly by SG-P3. The elastic modulus at $100^{\circ}C$ decreased from 1.0 MPa to 0.2 MPa as the amount of SG-P3 was decreased by 20%. In contrast, the elastic modulus at room temperature was dominated by YD011, an epoxy with a higher softening point. The optimized DAF recipe showed approximately 98.4% pickup performance when a UV dicing tape was used. A DAF crack that occurred in curing was effectively suppressed through optimization of the cure accelerator amount and two-step cure schedule. The imizadole type accelerator showed better performance than the amine type accelerator.

Modern transformation phrase of (<공무도하가>의 현대적 변용 양상)

  • Ha, Gyoung Sook
    • (The)Study of the Eastern Classic
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    • no.43
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    • pp.93-123
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    • 2011
  • is a work of art that was composed through fluid and laminating by being passed down orally for a long time like other ancient songs. As well as, it is given a history of literature's value in the point that it is a Korea's first poetry work, it is considered it casts a long shadow to establishing traditionality of our country's poetry. Even today, has been transformed and recreated into a variety of genres because its literary subject carry the universal emotions and win the sympathy. This manuscript examines modern poetry, modern novel and modern songs that consist of changed ancient song and looks modern writers' perspective about through characteristic that each of works has and then aims checking special situation and meaning that is implicit and recognizing the value of the original. As the has been recreated as modern poetry, it shows the current chaotic situation specifically by embodying it and actively seeks expressing human character, agony and longing, etc, by excluding factor of the original mythical interpretation. Also it rouses situation of reality as detained and repressed. , recreated as modern novel, expands narrative structure and shows portrait of various characters and speaks diverse human condition about reality and suggests plan for dealing with that. Basic emotions of the original is strongly passed to modern popular song . It makes us know that universal emotions which human has across generations can touch people transcending time and space and it is a fresh discovery and possibility that reaffirms the emotion of our people. Ancient song has been studied with emphasis on resignation and grief by focusing on the subject, simply parting and death. But recently, through transformation between a wide range of genres. it carries the spirit of the times that author toward, showing realistic and specific situations. Flexibility of ancient song is expected to continue its vitality transcending generations. Ancient song is assured that it can lead various aspects through active groping in era of change with a various possibility, that the original has, through communication between genres.

A Study on the Analysis of the Trend of installations Using 3D Printing Technique (3D프린팅 조형설치물 경향분석에 관한 연구)

  • Kim, Ji Min;Lee, Tae Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.52-60
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    • 2021
  • The aim of this study was to derive a new trend by analyzing installations using 3D printing that are out of the limits of size and design according to the trends of developing 3D printing technology. This paper classified the types of installations using 3D printing and analyzed them with two trends: the trend of design and the trend of output. The trends of installations using 3D printing derived from this study are as follows. First, as the implementation of design through an algorithm is accomplished, the transformation appears with the atypical design that is prominent in complex expression. Second, Robotics and FDM 3D Printing is fused, which is changing the existing paradigm. Therefore, the production and utilization of installations using 3D printing proceeded at a faster pace through the interaction between the algorithm design method and freeform 3D printing technology. This study was conducted on installations using 3D printing around the world and played a basic role in the research on the production of installations using 3D printing along with domestic 3D printing technology to be developed in the future. Follow-up studies in various aspects, such as materials and combination methods, will be needed.