• Journal of the Microelectronics and Packaging Society
• /
• v.30 no.4
• /
• pp.1-7
• /
• 2023

The ability of 3D/4D printing technology to create arbitrary 3D structures provides a greater degree of freedom in the design of printed structures. This capability has influenced the field of electronics and biomedical applications by enabling the trends of device miniaturization, customization, and personalization. Here, the current state-of-the-art knowledge of 3D printed electronics and biomedical applications with the unique and unusual properties enabled by 3D/4D printing is reviewed. Specifically, the review encompasses emerging areas involving recyclable and degradable electronics, metamaterial-based pressure sensor, fully printed portable photodetector, biocompatible and high-strength teeth, bioinspired microneedle, and transformable tube array for 3D cell culture and histology.

• Korean Journal of Microbiology
• /
• v.51 no.4
• /
• pp.374-381
• /
• 2015

Occurrences of coastal dredged materials are ever increasing due to port construction, navigational course maintenance and dredging of polluted coastal sediments. Ocean dumping of the coastal dredged materials has become virtually prohibited as London Treaty will be enacted as of the year 2012. It will be necessary to treat and recycle the dredged materials that may carry organic pollutants and heavy metals in a reasonable and effective process: collection of the dredged materials, liquid and solid separation, and treatment of organic compounds and heavy metals. In this study we have developed a continuous bioreactor system that can treat a mixture of silt and particulate organic matter using a microbial consortium (BM-S-1). The steady-state operation conditions were: pH (7.4-7.5), temperature ($16^{\circ}C$), DO (7.5-7.9), and salt concentration (3.4-3.7%). The treatment efficiencies of SCOD, T-N and T-P of the mixture were 95-96%, 92-99%, and 79-97%. The system was also effective in removal of heavy metals such as Zn, Ni, and Cr. Levels of MLSS during three months operation period were 11,000-19,000 mg/L. Interestingly, there was little sludge generated during this period of operation. The augmented microbial consortium seemed to be quite active in the removal of the organic component (30%) present in the dredged material in association with indigenous bacteria. The dominant phyla in the treatment processes were Proteobacteria and Bacteroidetes while dominant genii were Marinobacterium, Flaviramulus, Formosa, Alteromonadaceae_uc, Flavobacteriaceae_uc. These results will contribute to a development of a successful bioremediation technology for various coastal and river sediments with a high content of organic matter, inorganic nutrients and heavy metals, leading to a successful reuse of the polluted dredged sediments.

• Economic and Environmental Geology
• /
• v.50 no.4
• /
• pp.257-266
• /
• 2017

Batch experiments were performed to develop the method for the pH reduction of recycled aggregate by using $scCO_2$ (supercritical $CO_2$), maintaining the pH of extraction water below 9.8. Three different aggregate types from a domestic company were used for the $scCO_2$-water-recycled aggregate reaction to investigate the low pH maintenance of aggregate during the reaction. Thirty five gram of recycled aggregate sample was mixed with 70 mL of distilled water in a Teflon beaker, which was fixed in a high pressurized stainless steel cell (150 mL of capacity). The inside of the cell was pressurized to 100 bar and each cell was located in an oven at $50^{\circ}C$ for 50 days and the pH and ion concentrations of water in the cell were measured at a different reaction time interval. The XRD and SEM-EDS analyses for the aggregate before and after the reaction were performed to identify the mineralogical change during the reaction. The extraction experiment for the aggregate was also conducted to investigate the pH change of extracted water by the $scCO_2$ treatment. The pH of the recycled aggregate without the $scCO_2$ treatment maintained over 12, but its pH dramatically decreased to below 7 after 1 hour reaction and maintained below 8 for 50 day reaction. Concentration of $Ca^{2+}$, $Si^{4+}$, $Mg^{2+}$ and $Na^+$ increased in water due to the $scCO_2$-water-recycled aggregate reaction and lots of secondary precipitates such as calcite, amorphous silicate, and hydroxide minerals were found by XRD and SEM-EDS analyses. The pH of extracted water from the recycled aggregates without the $scCO_2$ treatment maintained over 12, but the pH of extracted water with the $scCO_2$ treatment kept below 9 of pH for both of 50 day and 1 day treatment, suggesting that the recycled aggregate with the $scCO_2$ treatment can be reused in real construction sites.

• Journal of the Microelectronics and Packaging Society
• /
• v.27 no.4
• /
• pp.83-89
• /
• 2020

For the past few decades, as part of efforts to protect the environment where fossil fuels, which have been a key energy resource for mankind, are becoming increasingly depleted and pollution due to industrial development, ecofriendly secondary batteries, hydrogen generating energy devices, energy storage systems, and many other new energy technologies are being developed. Among them, the lithium-ion battery (LIB) is considered to be a next-generation energy device suitable for application as a large-capacity battery and capable of industrial application due to its high energy density and long lifespan. However, considering the growing battery market such as eco-friendly electric vehicles and drones, it is expected that a large amount of battery waste will spill out from some point due to the end of life. In order to prepare for this situation, development of a process for recovering lithium and various valuable metals from waste batteries is required, and at the same time, a plan to recycle them is socially required. In this study, we introduce a nanoscale pattern transfer printing (NTP) process of Li2CO3, a representative anode material for lithium ion batteries, one of the strategic materials for recycling waste batteries. First, Li2CO3 powder was formed by pressing in a vacuum, and a 3-inch sputter target for very pure Li2CO3 thin film deposition was successfully produced through high-temperature sintering. The target was mounted on a sputtering device, and a well-ordered Li2CO3 line pattern with a width of 250 nm was successfully obtained on the Si substrate using the NTP process. In addition, based on the nTP method, the periodic Li2CO3 line patterns were formed on the surfaces of metal, glass, flexible polymer substrates, and even curved goggles. These results are expected to be applied to the thin films of various functional materials used in battery devices in the future, and is also expected to be particularly helpful in improving the performance of lithium-ion battery devices on various substrates.

• Journal of the Korean Electrochemical Society
• /
• v.18 no.4
• /
• pp.156-160
• /
• 2015

Experiments using a metal oxide of a non-nuclear material as a fuel are very useful to develop a new electrolytic reducer for pyroprocessing. In this study, the titanium oxides (TiO and $TiO_2$) were selected and investigated as the non-nuclear fuel for the electrolytic reduction. The immersion tests of TiO and $TiO_2$ in a molten 1.0 wt.% $Li_2O$-LiCl salt revealed that they have solubility of 156 and 2100 ppm, respectively. Then, the Ti metals were successfully produced after the separate electrolytic reduction of TiO and $TiO_2$ in a molten 1.0 wt.% $Li_2O$-LiCl salt. However, Ti was detected on the platinum anode used for the electrolytic reduction of $TiO_2$ unlike TiO due to the dissolution of $TiO_2$ into the salt.

• Applied Chemistry for Engineering
• /
• v.20 no.3
• /
• pp.241-250
• /
• 2009

During the past few years, titanium salts were investigated as alternative coagulants for the removal of organic matter of different molecular sizes in contaminated water. The flocculation efficiency of Ti-salt was comparable to those of $FeCl_3$ and $Al_2(SO_4)_3$ salts, commonly used coagulants. Incinerated sludge-$TiO_2$ showed higher surface area and photocatalytic activity than commercially available $TiO_2$. Metal-doped forms were produced by adding coagulant aids such as iron (Fe-), aluminium (Al-) and (Ca-) calcium salts during Ti-salt flocculation to increase pH. Ca- and Al- doped $TiO_2$ showed very high photocatalytic activity compared to Fe-doped $TiO_2$. When tested in a pilot scale plant for treatment of dye wastewater to check practical feasibility of the novel process, the removal ratio of the chemical oxygen demand was comparable to those of commonly used coagulants but the settling of sludge was faster. The $TiO_2$ generated after sludge incineration showed a high photocatalytic activity for degradation of volatile organic compounds and increased the rate of hydrogen production by water photosplitting. $TiCl_4$ coagulant and $TiO_2$ produced from different water sources with different concentrations had low acute toxicity compared to heavy metals and commercial $TiO_2$ when examined based on D. Magna mortality. This paper presents the production, characterisation and the photoactivity of $TiO_2$ produced from Ti-salt flocculated sludge. Different case studies are discussed to highlighted recent advances in this field.

• International Journal of Highway Engineering
• /
• v.10 no.1
• /
• pp.87-95
• /
• 2008

One way to shield an atypical structure to secure the occupant safety of an impact vehicle is to stack energy absorbing material modules around the structure. To be applicable to a cushion module, material must have enough energy absorbing capabilities while satisfying the safety requirements of the vehicle occupant. Static compression test of the potential materials gives a good indication which material is good for a slacking module. This paper presents the mechanical properties that a cushion material must have to satisfy the safety requirements. Static tests are performed for Quard-Guard system module, sand bag, recycled tires, Geo-Container, Geo-Cell and Expanded Polystyren (EPS) Blocks. Static test results are discussed and EPS block of $30kg/m^{3}$ density showed good potential for a cushion module. To check the dynamic effect of EPS block, drop tests have been made up to 35.6km/h impact speed. Drop test results are compared with static test results and no appreciable difference was found. To improve the EPS module property, making holes to the block is suggested and drop test are performed for the modified blocks. From the drop test results, design values are suggested.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.13 no.1
• /
• pp.71-78
• /
• 2005

This study was performed to obtain the basic data on current situations and challengeable aspects of vermicomposting industries in Korea and to develope foodwaste treatment technology using earthworm. Pre-treatment process of food waste consists of cleaning, grinding, mixing and others, and salinity of food waste was 0.7% on average, thus not suitable for feed of worms. When applying wash water and going through the cleaning process, however, salinity was dropped to 0.38%, indicating that cleaning process applying wash water is necessary to control the proper salinity for growth of worms. In the food waste processing experiment applying worms, it has been presented that smaller particles induce higher processing efficiency. As a result, food waste processing by worms is possible through maintaining the suitable environment for survival of worms from input process to generation of cast. Cast generated after processing food waste was proved to be most suitable for product standard of compost thus cast is presented to be recycled after processing the food waste applying the worms.

• Fire Science and Engineering
• /
• v.16 no.3
• /
• pp.32-38
• /
• 2002

The synthesis of $CF_3$I and $C_2F_5I from $CF_3Br$ was studied for the reuse of $CF_3Br$ which is abolished to save the ozone layer of the earth. Reaction experiments were carried out in experimental scale synthesis equipment with catalysts, such as CuI, Kl, $K_2$$CO_3$, KF metal salt/active carbon and alumina support at $400~600^{\circ}C$. Main products of reaction were $CF_3i$ and $C_2F_5I$ with small amounts of $C_2F_5I$, $CF_4$, $CF_2Br_2$ by-products. 7.5wt% KI and $K_2CO_3$over activated carbon catalysts show the highest yield of $CF_3$I and 7.5wt% CuI over alumina catalysts show the highest yield of $C_2F_5i$. And optimal reaction temperature was about $500^{\circ}C$.

• Journal of Advanced Marine Engineering and Technology
• /
• v.40 no.6
• /
• pp.453-457
• /
• 2016

In various industrial plants such as power generation plants, petrochemical plants, and unit factories, there is an increasing demand for a system that generates hot water using waste or surplus steam. Compact steam unit (CSU), which produces hot water by using steam, is a good solution considering energy reuse. In this study, as a basic study to develop a high-pressure CSU, heat transfer characteristics of a hybrid heat exchanger were investigated through experiments, in order to use the hybrid heat exchanger instead of a conventional plate heat exchanger as the core component of CSU. The experimental results are the followings. Heat balance between the hot side and cold side was satisfied within ${\pm}5%$. Overall heat transfer coefficient increased linearly as the Reynolds number increased and exceeded $5,524W/m^2K$ when the flow velocity was above 0.5 m/s. In addition, pressure drop also increased as the Reynolds number increased, and pressure drop per unit length was below 50 kPa/m.