• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.05a
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• pp.157-158
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• 2012

최근 연잎의 표면과 같은 자기세정효과의 인공적인 제작을 위한 연구가 다방면으로 진행되고 있다. 이러한 자기세정효과는 초소수성 표면 제작 및 젖음 특성 분석을 통해 형성 및 해석이 가능하다. 본 연구에서는 나노임프린트 리소그래피 공정 및 수열합성법을 이용하여 주기적으로 배열된 계층구조의 $TiO_2$ 패턴을 형성 및 표면 개질을 통한 초소수성 구현하였다. 그 결과, 표면 개질된 계층구조의 $TiO_2$ 패턴은 deionized water에 대해 $160^{\circ}$ 이상의 정적 접촉각을 갖는 초소수성 표면을 형성하였다.

• Journal of the Korean Magnetics Society
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• v.14 no.2
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• pp.83-88
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• 2004

Magnetism of molecular nanomagnet, which attracted a lot of academic attention after the discovery of the macroscopic quantum tunneling of magnetism, is reviewed. Molecular nanomagnet is metal-organic material in which magnetic ions are regularly located in the organic skeleton. Also, the interaction between the molecules is very small and those molecules form macroscopic molecular crystal in which molecules are residing at the element points in the crystal. Molecular nanomagnets show a lot of interesting features, especially, equivalence of macroscopic magnetic properties and molecular magnetic properties. In this paper, research results on molecular nanomagnet with microscopic tool like NMR are reviewed mainly. The new method to observe the quantum tunneling of magnetization discovered in Mnl2-ac with NMR is shown and the research results on the microscopic aspects of the macroscopic quantum tunneling of magnetization using the new method are shown. Also, the physical aspect of the level crossing effect which has been reported originally with NMR in molecular nanomagnet is reviewed with experiment results. The research results on the molecular nanomagnets will reveal the important information about the limit of the miniaturization of magnetic memory units and give us the basic scientific knowledge which is needed for the application for the quantum computation. Moreover, academically, many quantum mechanical theories which have not been checked the validity can be checked with experiments.

• Journal of the Korean Society for Precision Engineering
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• v.27 no.11
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• pp.30-36
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• 2010

Previous researches show that linearly integrated Hall sensor arrays (LIHaS) can detect cracks in the steel structure fast and effectively This paper proposes an algorithm that estimates the size and shape of cracks for the developed LIHaS. In most nondestructive testing (NDT), just crack existence and location are obtained by processing 1-dimensional data from the sensor that scans the object with relative speed in single direction. The proposed method is composed with two steps. The first step is constructing 2-dimensionally mapped data space by combining the converted position data from the time-based scan data with the position information of sensor arrays those are placed in the vertical direction to the scan direction. The second step is applying designed Laplacian filter and smoothing filter to estimate the size and shape of cracks. The experimental results of express train wheels show that the proposed algorithm is not only more reliable and accurate to detecting cracks but also effective to estimate the size and shape of cracks.

• Polymer(Korea)
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• v.29 no.3
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• pp.308-313
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• 2005

The effects of molecular environments on photoisomerization of an azobenzene group were investigated using In-situ UV/Vis spectroscopy and optical anisotropy measurement technique. The reversible and repeatable photoisomeritation reactions of azobenzene were observed by irradiating the film containing 4-hydroxyazobenzene and by measuring absorption intensities of the characteristic bands of trans and cis isomers simultaneously. When the self-assembled monolayer with azobenzene groups was used as an alignment layer for a liquid crystal cell, the homeotropic alignment was induced due to their compact packing structures of azobenfene groups along the vertical direction of the substrate. By irradiating UV light on this cell, the trans-azobenzene groups change to cis-isomers through the photoisonlerieation and then resulting in the planar alignment of liquid crystal molecules.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.1140-1144
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• 2007

모래하천과 자갈하천의 하중도에 성립한 식생을 분석하여 하천복원과 복원된 하천의 사후 관리에서 요구되는 생태정보를 구축하였다. 모래하천의 하중도에는 버드나무군락, 물억새군락, 산조풀군락, 속속이풀군락, 큰개여뀌군락, 밭뚝외풀군락 등이 성립하였다. 이러한 식생자료를 서열법으로 처리한 결과, 식물의 배열은 천이경향을 반영하였고, 하중도의 미지형에 의해 결정된 지하수위 높이가 천이단계를 지배하는 것으로 판단되었다. 모래하천인 용수천의 하중도에서 상류로부터 하류를 향해 식생의 분포는 버드나무군락-물억새군락-산조풀군락-속속이풀군락의 순서를 보였다. 우점종의 생활형에 따라 이들을 구분하면, 이 순서는 목본 식물군락-다년생 식물군락-1년생 식물군락의 순서를 보였다. 이러한 식생의 배열로부터 하중도는 하류 방향으로 새로 생성되고 있음을 알 수 있었다. 자갈하천의 하중도에는 발달단계가 다른 세 개의 소나무군락과 초지가 성립하였다. 소나무군락은 유령림, 성숙목과 유령목이 혼합된 복층림, 그리고 성숙림으로 이루어졌다. 초지는 쑥, 달뿌리풀, 환삼덩굴, 소나무 실생, 황철나무 등이 산재하는 밀도가 낮은 식생으로 이루어졌다. 이러한 식생자료를 서열법으로 처리한 결과 여기에서도 식생의 배열은 천이경향을 반영하였다. 천이단계를 지배하는 요인은 홍수에 밀려온 자갈의 피복율로 나타났다. 상류로부터 하류를 향해 식생의 분포는 초지, 소나무 유령림, 소나무 복층림 및 소나무 성숙림의 순서를 보였다. 이러한 식생의 배열로부터 하중도는 상류방향으로 새로 성립하고 있음을 알 수 있었다.변지역에 거주하는 주민의 역할이 중요하며, 이에 따라 보 철거 선정 체계는 보 철거를 위해서 보 주변 지역 거주민을 설득하며, 하천의 환경 개선을 위한 합리적인 대안 제시를 목적으로 하고 있다. 선정 체계를 바탕으로 주민 협의 및 대안 제시를 통해 결정된 대상 보는 선정 체계 안에서 보 철거 영향 판단 절차에 따라서 보 철거로 인한 수문, 수리, 지형, 수질, 생태 영향을 판단하게 되며, 이와 더불어 사회 경제적인 영향을 평가하게 된다. 평가결과에 따라서 보를 완전히 철거하거나 다른 대안을 고려하여 보를 부분적으로 철거하거나 개량하게 된다.곳으로 1/3의 자기 생산을 담당하고 있었다. $\ulcorner$경상도지리지$\lrcorner$(慶尙道地理志)에는 $\ulcorner$세종실록$\lrcorner$(世宗實錄) $\ulcorner$지리지$\lrcorner$(地理志)와 동년대에 동일한 목적으로 찬술되었음을 알 수 있다. $\ulcorner$경상도실록지리지$\lrcorner$(慶尙道實錄地理志)에는 $\ulcorner$세종실록$\lrcorner$(世宗實錄) $\ulcorner$지리지$\lrcorner$(地理志)와의 비교를 해보면 상 중 하품의 통합 9개소가 삭제되어 있고, $\ulcorner$동국여지승람$

• Journal of the Korean Chemical Society
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• v.40 no.1
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• pp.65-71
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• 1996

The chemical behaviour of the Eu(Ⅲ) complexes with organic ligands(tris[3-(trifluoromethylhydroxymethylene-camphorato)]) and tris[3-heptafluoropropylhydroxymethylene-camphorato)] has been investigated by the UV/vis-spectrophotometric, magnetic, and electrochemcial methods. The two or three energy absorption bands are observed by the spectra of these complexes. The magnitude of crystal field splitting energy, the spin pair energy and strength were obtained from the spectra of the complexes. These complexes are found to be delocalization, low-spin state, and strong bonding strenth of electron configuration. The magnetic dipolemoment are found to be diamagnetic. The redox reaction processes of complexes were investigated by cyclic voltammetry in aprotic solvent. The redox reaction processes of complexes are turned out to be single or double reaction with respect to one electron diffusion current.

• Journal of the Korean Magnetics Society
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• v.18 no.5
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• pp.180-184
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• 2008

The relation of ferromagnet anisotropic magnetization and the antiferromagnet atomic spin configuration has been investigated for variously angles of unidirectional deposition magnetic field of FeMn layer in Corning glas/Ta(5 nm)/NiFe(7 nm)/FeMn(25 nm)/ Ta(5 nm) multilayer prepared by ion beam deposition. Three unidirectional deposition angles of FeMn layer are $0^{\circ},\;45^{\circ}$, and $90^{\circ}$, respectively. The exchange bias field ($H_{ex}$) obtained from the measuring easy axis MR loop was decreased to 40 Oe in deposition angle of $45^{\circ}$, and to 0 Oe in the angle of $90^{\circ}$. One other side hand, $H_{ex}$ obtained from the measuring hard axis MR loop was increased to 35 Oe in deposition angle of $45^{\circ}$, and to 79 Oe in the angle of $90^{\circ}$. Although the difference of uniderectional axis between ferromagnet NiFe and antiferromagnet FeMn was 90o, the strong antiferromagnetic dipole moment of FeMn caused to rotate the weak ferromagnetic dipole moment of NiFe in the interface. This result implies that one of origins for exchange coupling mechanism depends on the effect of magnetic field angle during deposition of antiferromgnet FeMn layer.

• Journal of the Korean Magnetics Society
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• v.22 no.5
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• pp.173-177
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• 2012

The multilayer structure of glass/Ta(5.8 nm)/NiFe(5 nm)/Cu(t nm)/NiFe(3 nm)/FeMn(12 nm)/Ta(5.8 nm) as typical GMR-SV (giant magnetoresistance-spin valve) films is prepared by ion beam sputtering deposition (IBD). The coercivity and magnetoresiatance ratio are increased and decreased for the decrease of Cu thickness when the thickness of nonmagnetic Cu layer from is varied 2.2 nm to 3.0 nm. It means that the decrease of non-magntic layer is effected to the interlayer exchange coupling of pinned layer and the spin configuration array of free layer. For experiment of detecting and dropping of magnetic beads we used the GMR-SV sensor with glass/Ta/NiFe/Cu/NiFe/FeMn/Ta structure. From the comparison of before and after for the dropping status of magnetic bead, the variations of MR ratio, $H_{ex}$, and $H_c$ are showed 0.9 %, 3 Oe, and 2 Oe, respectively. The fabrication of GMR-SV sensor was included in the process of film deposition, photo-lithography, ion milling, and MR measurement. Further, GMR-SV device can be easily integrated so that detecting biosensor on a single chip becomes possible.

• Journal of the Microelectronics and Packaging Society
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• v.13 no.3 s.40
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• pp.13-17
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• 2006

Dense and periodic arrays of holes and tungsten none dots were fabricated on silicon oxide and silicon. The holes were approximately 25 nm wide, 40 nm deep, and 60 nm apart. To obtain nano-size patterns, self-assembling resists were used to produce layer of hexagonally ordered parallel cylinders of polymethylmethacrylate(PMMA) in polystyrene(PS) matrix. The PMMA cylinders were degraded and removed with acetic acid rinse to produce a PS mask for pattern transfer. The silicon oxide was removed by fluorine-based reactive ion etching(RIE). Selectively deposited tungsten nano dots were formed inside nano-sized trench by using a low pressure chemical vapor deposition(LPCVD) method. Tungsten nano dot and trenched silicon sizes were 26 nm and 30 nm, respectively.

• Korean Journal of Materials Research
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• v.3 no.2
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• pp.175-184
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• 1993

Abstract Co-and/or AI-added Nd-Fe-B-based magnetic alloys were fabricated by using vacuum induction melting frunace, and melt-spun ribbons were made of the magnetic alloys with single roll rapid quenching method. The variation of magnetic properties of the melt-spun ribbons as a function of Cuwheel velocity (Vs) were investigated. Bonded magnets were made of the optimally quenched ribbon fragments, and the magnetic properties of the melt-spun ribbons and the bonded magnets were studied, relating to the microstructure and crystalline structure. Cu-wheel surface velocity had a strong effect on the magnetic properties of the melt-spun ribbons, and the maximum properties were obtained around Vs =20m/sec. The optimally quenched ribbon had a cellura-type microstructure, in which fine N$d_2$F$e_14$B grains were surrounded by thin Nd-rich phase. In case of a 2.1at% AI-added melt-spun ribbon, the magnetic properties were as follows: iHc, Br, and (BH)max were 15.5KOe, 7.8KG and 8.5MGOe respectively. And resin bonded magnets were fabricated by mixing optimally quenched ribbon fragments with 2.5wt % polyamide resin, compacting and binding at room temperature. The iHc, Br and (BH)max of bonded magnet were lO.2KOe, 4.4KG and 3.3MGOe respectively. And hot-pressed magnets were made by pressing the overquenched ribbons at high temperature. The magnetic properties of hot-pressed magnets were better than those of bonded magnets, and when the holding time was 8 minutes, the iHc, Br, and (BH)max of the hot-pressed magnet were 1O.8KOe, 7.3KG and 8.0MGOe respectively. Domain structure was mainly maze pattern, which means that the easy magnetization axis could be aligned, and the domain width of the hot-pressed magnets was smaller than that of bonded magnets.