• Title/Summary/Keyword: 입자분리

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Separation of Hydrogen-Nitrogen Gas Mixture by PTMSP-Silica-PEI Composite Membranes (PTMSP-Silica-PEI 복합막에 의한 수소-질소 혼합기체 분리)

  • Lee Hyun-Kyung;Choi Youn-Jung
    • Membrane Journal
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    • v.14 no.4
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    • pp.304-311
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    • 2004
  • The poly(1-trimethylsilyl-1-propyne) (PTMSP) and silica-filled PTMSP membranes were prepared by casting from a toluene solution on porous polyetherimide (PEI). FT-IR spectrum, GPC and SEM pictures have been taken to characterize the membranes. The particle size of membrane decreases as silica content of the membrane increases from 23 to 60 wt%, and a uniform distribution of the silica is observed. The separation properties of the gas mixture (32 mol% $H_2$/ 68 mol% $N_2$) through the composite membranes were studies as a function of pressure and percentage of silica. Selectivity values of $H_2$/$N_2$ increased as the pressure of permeation cell and silica content of the membrane increased. The real separation factor($\alpha$), head separation factor($\beta$), and tail separation factor((equation omitted)) of PTMSP-PEI composite membrane were 2.28, 1.58, and 1.44 respectively at $\Delta$P 30 psi and $25^{\circ}C$. $\alpha$, $\beta$, and (equation omitted) of PTMSP-Silica-PEI composite membrane for 60 wt% silica were 3.34, 1.95, 1.72 at $\Delta$P 30 psi and $25^{\circ}C$.

Physicochemical Properties of Starch Granules Isolated from Naked Barley Seeds during Germination (쌀보리의 발아과정중 분리전분의 이화학적 특성)

  • Seog, Ho-Moon;Park, Yong-Kon;Nam, Young-Jung;Kim, Jun-Pyong;Sohn, Tae-Hwa;Yoon, Hyung-Sik
    • Applied Biological Chemistry
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    • v.31 no.4
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    • pp.339-345
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    • 1988
  • Physicochemical properties of starch isolated from the naked barley seeds during germination were investigated, The germinated barley seeds showed an apparent increase in amylose component of the starches, and water binding capacities of the starches decreased initially and then increased with longer germination time. The size frequency distribution of starch granules showed that the granules larger than $20.2{\mu}$ in diameter were preferentially degraded, and moreover the rate of degradation was higher than that of granules of any other size. It was apparent that the mean diameter of granules was $12.7{\sim}20.2{\mu}$ at all stages of germination. The results of differential scanning calorimetry, swelling power, solubility and X-ray diffraction patterns of starch granules isolated at various stages of germination showed little changes during germination. Scanning electron microscopy revealed that the starch granules have been damaged extensively by degradative enzymes during germination, but all the starch granules were not degraded uniformly.

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Physical Property Changes of Wasted Printed Circuit Board by Heat Treatment (열처리에 의한 폐 인쇄회로기판의 물성변화)

  • Kim, Boram;Park, Seungsoo;Kim, Byeongwoo;Park, Jaikoo
    • Resources Recycling
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    • v.27 no.1
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    • pp.55-63
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    • 2018
  • Physical property changes of printed circuit board (PCB) according to heat treatment conditions were investigated. The heat treatment was carried out in air and nitrogen atmosphere at temperature range from $200^{\circ}C$ to $325^{\circ}C$. Thermogravimetric analysis showed that the PCB was pyrolyzed in two steps. The thickness of PCB expanded by 11~28% at about $300^{\circ}C$ in both air and nitrogen atmosphere as layer disintegration occurred. Mechanical strength of PCB decreased from 338.4 MPa to 20.3~40.2 MPa due to the delamination caused by the heat treatment. The heated printed circuit boards were crushed and sieved for analysis of density distribution and liberation degree of copper according to particle size. As a result of the density distribution measurement, non metallic particles and copper particles were concentrated into different size range, respectively. The liberation degree of copper was improved from 9.3% to 100% at size range of $1,400{\sim}2,000{\mu}m$ by heat treatment.

Use of a Combined Photocatalysis/Microfiltration System for Natural Organic Matter Removal (광촉매 반응과 침지형 정밀여과를 이용한 자연산 유기물의 제거)

  • 추광호;박경원;김문현
    • Membrane Journal
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    • v.14 no.2
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    • pp.149-156
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    • 2004
  • This work focused on the degradation of natural organic matter (NOM) present in lake water using a combined pkotocatalysisimicrofiltration (MF) process. The system performances were investigated in terms of organic removal efficiency and membrane permeability. The addition of iron oxide particles (IOP) into the photocatalytic membrane reactor improved initial NOM removal by sorption, but during photocatalysis the removal efficiency was reversed, probably due to the scattering of UV light by IOP. The modification of TiO$_2$ surfaces by IOP deposition was conducted to enhance the photocatalytic NOM removal efficiency. A minimal amount of Impregnation of IOP on TiO$_2$ surfaces was required to prevent the light scattering effect as well. The coating of MF membranes with IOP helped to improve the NOM removal efficiency while sorbing NOM by IOP. Regardless of tile operating conditions and particles addition examined, no significant fouling was occurring at a flux of 15 L/$m^2$-h during entire MF operation.

Evaluation of Sampling and Analytical Methods for the Determination of Polycyclic Aromatic Hydrocarbons in the Ambient Atmosphere (환경대기중 다환방향족탄화수소의 포집과 분석방법에 관한 연구)

  • 백성옥
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.1
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    • pp.1-16
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    • 1991
  • In this study, sampling and analytical procedures were evaluated for the determination of ambient levels of atmospheric PAH, both in gaseous and particulate phase. The method involves low-volume sampling and Soxhlet extraction of the filters and Tenax absorbent, followed by a clean-up stage using a silica column prior to analysis by reversed-phase HPLC with wavelength programmable fluorescence and UV detection. A total of 18 PAH were identified and quantified, all of which have been of environmental concern. In order to validate the methodology and to ensure compatibility of the results, the analytical method used for the determination of PAH was evaluated with respect to the efficiencies of extraction and clean-up procedure, HPLC separation, and lower limits of detection. In addition, substrate dependency of PAH recovery was investigated for the two types of fiters, i.e. glass fiber and PTFE filters.

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Experimental and Numerical Investigation of the Effect of Load and Speed of T-GDI Engine on the Particle Size of Blow-by Gas and Performance of Oil Mist Separator (T-GDI 엔진의 속도 및 하중이 블로우바이 가스의 오일입자 크기와 오일분리기 성능에 미치는 영향에 대한 실험 및 수치적 연구)

  • Jeong, Soo-Jin;Oh, Kwangho
    • Journal of ILASS-Korea
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    • v.25 no.4
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    • pp.162-169
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    • 2020
  • The worldwide focus on reducing the emissions, fuel and lubricant consumption in T-GDI engines is leading engineers to consider the crankcase ventilation and oil mist separation system as an important means of control. In today's passenger cars, the oil mist separation systems mainly use the inertia effect (e.g. labyrinth, cyclone etc.). Therefore, this study has investigated high efficiency cylinder head-integrated oil-mist separator by using a compact multi-impactor type oil mist separator system to ensure adequate oil mist separation performance. For this purpose, engine dynamometer testing with oil particle efficiency measurement equipment and 3D two-phase flow simulation have been performed for various engine operating conditions. Tests with an actual engine on a dynamometer showed oil aerosol particle size distributions varied depending on operating conditions. For instance, high rpm and load increases bot only blow-by gases but the amount of small size oil droplets. Submicron-sized particles (less than 0.5 ㎛) were also observed. It is also found that the impactor type separator is able to separate nearly no droplets of diameter lower than 3 ㎛. CFD results showed that the complex aerodynamics processes that lead to strong impingement and break-up can strip out large droplets and generate more small size droplets.

The Screen Efficiency Improving Effect Analysis by the Screen Motion Characteristic Analysis Applying Blockage Prevention Spring (막힘 방지 스프링 적용 스크린 운동 특성 분석을 통한 스크린 효율 개선 효과 분석)

  • Han-Sol Lee;Myouing-yuol Yu;Hoon Lee
    • Resources Recycling
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    • v.31 no.6
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    • pp.36-43
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    • 2022
  • The general screen used to separate the particle size of recycled aggregate has restrictions when dealing with moisturized materials because of the blockage phenomenon. Therefore, in this study, to improve the separation efficiency of the conventional screen, the excellence of additional vibrating device based on spring was decided by a simulation experiment based on the discrete element method (DEM). The motion characteristic was investigated by analyzing the displacement, amplitude, and strain angle based on the spring design. Further, the particle motion was simulated by applying spring motion. The material flow and separation efficiency of the screen applied spring were confirmed as 9.2 kg/s and 97 %, respectively. Consequently, the improvement in the screen applied with blockage prevention spring was confirmed by comparing with the conventional screen.

Crushing Characteristics of Single Particle of Recycled Aggregate from Waste Concrete (폐콘크리트 순환골재의 단입자 파쇄 특성)

  • Park, Sung-Sik;Kim, Sang-Jung;Moon, Hong-Duk
    • Journal of the Korean Geotechnical Society
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    • v.32 no.12
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    • pp.23-32
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    • 2016
  • A single particle crushing test was carried out for recycled aggregates from waste concrete while demolishing various structures. When the recycled aggregates were used for backfill or road subbase materials, load-displacement and crushing characteristics were analyzed. The recycled aggregates with hydrates and aggregates were sorted into 40 mm size (75-40 mm) and 20 mm size (40-20 mm). At initial loading, their irregular surface was closed to and then crushed by loading plate. Such first crushing stage was called 'Surface crushing'. Further loading, some hydrate was crushed and detached from aggregate, and such process repeated several times. This state is called 'hydrate crushing'. The final state is called 'aggregate crushing' in which aggregate crushed and following load suddenly dropped down. As the load increased, such crushing cycle is repeated several times. The shapes of aggregates are round or square, and triangle or long shaped. Depending on their shapes and surface conditions, they crushed in different ways. The 63% of aggregates showed more than 50% load reduction due to aggregate crushing. The 90% load reduction occurred at 15% of aggregates. The 40 mm aggregate crushed at maximum load between 3.05-4.38 kN and 70% of crushed aggregates were less than 20 mm.

Characterization of Flacherie Virus of the Silkworm, Bombyx mori, isolated in Korea (한국산 연화병 바이러스의 분리 및 성상)

  • 김근영;강숙우
    • Journal of Sericultural and Entomological Science
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    • v.33 no.1
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    • pp.13-20
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    • 1991
  • The flacheric virus(FV) was isolated from the diseased larvae with flaccidity symptoms of the silkworm, Bombyx mori, which were collected in Hyangnam, Kyunggi Province and in Youcheon, Kyungpook Province. The properties of the virus were investigated and compared with the Japanese FV in morphology, size, nucleic acid and structural proteins. The Hyangnam isolate had a diameter of 27$\pm$1, 7nm with speherical shape and contained RNA of which the electrophoretic pattern was same as that of the Japanese FV. The virus had four sturctural proteins and their molecular weight were estimated as 35, 000, 33, 000, 31, 000, and 11, 400 daltons, respectively. The Youcheon isolate had two different sizeds in diameter of 27$\pm$1.7nm and 21$\pm$0.8nm. The antigenicity of the Hyangnam isolate was proved to be identical to that of Japanese FV, whereas the antisera against the Youcheon isolate (mixed with two different sizes) reacted with Japanese FV and densonucleosis virus type 1, respectively. From these characteristic of the isolated viruses, it was concluded that the Hyangnam isolate was identical to the Japanese FV and the Youncheon isolate contained the same viruses as the Japanese FV and DNVI.

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Cellulose Nanocrystals Incorporated Poly(arylene piperidinium) Anion Exchange Mixed Matrix Membranes (셀룰로오스 나노 결정을 도입한 폴리아릴렌 피페리디늄 음이온 교환 복합매질분리막)

  • Da Hye Sim;Young Park;Young-Woo Choi;Jung Tae Park;Jae Hun Lee
    • Membrane Journal
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    • v.34 no.2
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    • pp.154-162
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    • 2024
  • Anion exchange membranes (AEMs) are essential components in water electrolysis systems, serving to physically separate the generated hydrogen and oxygen gases while enabling the selective transport of hydroxide ions between electrodes. Key characteristics sought in AEMs include high ion conductivity and robust chemical and mechanical stability in alkaline. In this study, quaternized Poly(terphenyl piperidinium)/cellulose nanocrystals (qPTP/CNC) mixed matrix membrane was fabricated. The polymer matrix, PTP, was synthesized via super-acid polymerization, known for its excellent ion conductivity and alkaline durability. The qPTP/CNC membrane showed a dense and uniform morphology without significant voids or large aggregates at the polymer-nanoparticle interface. The qPTP/CNC membrane containing 2 wt% CNC demonstrated a high ion exchange capacity of 1.90 mmol/g, coupled with low water uptake (9.09%) and swelling ratio (5.56%). Additionally, the qPTP/CNC membrane showed significantly lower resistance and superior alkaline stability (384 hours at 50℃ in 1 M KOH) compared to the commercial FAA-3-50 membrane. These results highlight the potential of hydrophilic additive CNC in enhancing ion conductivity and alkaline durability of ion exchange membranes.