• Journal of Korean Society of Environmental Engineers
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• v.38 no.10
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• pp.543-550
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• 2016

Amine-type PP-g-VBC-EDA adsorbent, which possesses anionic exchangeable function, was prepared through photoinduced graft polymerization of vinylbenzyl chloride (VBC) onto polypropylene non-woven fabric and subsequent amination reaction using ethylenediamine (EDA). Adsorption characteristics of anionic nutrients on the PP-g-VBC-EDA adsorbent have been studied by batch adsorption experiments. The equilibrium data well fitted the Langmuir isotherm model, and the maximum monolayer sorption capacity was found to be 59.9 mg/g for $NO_3-N$ and 111.4 mg/g for $PO_4-P$. The adsorption energies were higher than 8 kJ/mol indicating anion-exchange process as the primary adsorption mechanism. The pseudo-second order kinetic model described well the kinetic data and resulted in the activation energy of 9.8-36.7 kJ/mol suggesting that the overall rates of $NO_3-N$ and $PO_4-P$ adsorption are controlled by the chemical process. Thermodynamic parameters such as ${\Delta}G^o$, ${\Delta}H^o$ and ${\Delta}S^o$ indicated that the adsorption nature of PP-g-VBC-EDA for anionic nutrients is spontaneous and exothermic. The PP-g-VBC-EDA could be regenerated by washing with 0.1 N HCl.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.7
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• pp.426-439
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• 2017

This review summarizes advantage and limitation in infrared spectroscopy and computational chemistry to understand rhizospheric interaction among organic acids, oxyanions and metal oxides. Since organic acids and metal oxides determine dynamics of oxyanions in the soil environment, knowledge of fundamental mechanisms is a prerequisite for understanding the interactions at soil-water interface. Attenuated total reflectance-fourier transform infrared spectroscopy (ATR-FTIR) is a powerful tool to measure the interfacial reactions. However, the ATR-FTIR measurements are abstruse, because the optical characteristics for measurements are variable depending on the experimental setup. In addition, spectral overlapping is a primary obstacle to the analysis of the interfacial reaction; thus, it is essential to detect and to deconvolute bands for signal interpretation. In this review, we expained the fundamental principle for spectrum processing, and four band identification methods, such as derivative spectroscopy, two-dimension correlation spectroscopy, multivariate curve resolution, and computational chemistry with example of aqueous phosphate speciation. As a result, spectrum processing and computational chemistry improved interpretation and spectral deconvolution of overlapped spectra in relatively simple systems, but it was still unsatisfactory for the problems in more complexed system like nature. Nevertheless, we believed that our challenge would contribute practically to develop adequate analytical procedure, signal processing and protocols that could help to improve interpretation and to understand the interfacial interactions of oxyanions in natural systems.

• The Korean Journal of Ecology
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• v.25 no.3 s.107
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• pp.145-152
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• 2002

Saussurea chabyoungsanica was recorded in new species by Lim Hyoung Tak in 1997. In order to understand the entity of new species, we investigated the new distribution sites, vegetation structure and soil environmental factors. Additionally discovered distribution sites of S. chabyoungsanica were Manduckbong, Mt. Sukbyoung, Mt. Duckhang, and Sukgaejae, which were located on ridge of the Taebaek Mountains. Those sites are typical limestone zones of Korea and among them Sukgaejae belongs to lower great limestone area and Manduckbong, Mt. Sukbyoung and Mt. Duckhang belong to upper great limestone area. According to the result of phytosociological study, plant communities of S. chabyoungsanica were classified by 1 Community group, 4 Communities and 2 Subcommunities; Carex humilis var. nana-Saussurea chabyoungsanica Community group in wide sense Quercus mongolica Community group, Lespedeza maximowiczii-Saussurea chabyounsanica Community, Galium kinuta-Saussurea chabyoungsanica Community, Salvia chanryonica-Saussurea chabyoungsanica Community, Zabelia coreana-Saussurea chabyoungsanica Community. Environmental factor analysis of habitat showed that the distribution site of S. chabyoungsanica was ridge of North aspect and displayed pH $7{\sim}8$ typical of limestone. Soil moisture content was high, whereas organic matter content was low. Considering its high occurrence in sites of $1{\sim}10cm$ in soil depth, and of $30{\sim}45%$ in relative light intensity, major distribution sites were outcrops and boundaries between shrubland and forest. After community division by vegetation structure in habitat of S. chabyoungsanica, we investigated characters of soil environment by community. As a result of PCA analysis of soil sample by community, it was possible to divide community by characters of soil environmental factor. The cumulative value of contribution rate represented in second dimension space was 73% and the major factors for that value were soil texture, organic matter content and field capacity.

• Journal of the Korean earth science society
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• v.22 no.6
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• pp.512-527
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• 2001

Separated flows passed complex geometries are modeled by discrete vortex techniques. The flows are assumed to be rotational and inviscid, and a new techlnique is described to determine the stream functions for linear shear profiles. The geometries considered are the snow cornice and the backward-facing step, whose edges allow for the separation of the flow and reattachment downstream of the recirculation regions. A point vortex has been added to the flows in order to constrain the separation points to be located at the edges, while the conformal mappings have been modified in order to smooth the sharp edges and to let the separation points free to oscillate around the points of maximum curvature. Unsteadiness is imposed to the flow by perturbing the vortex location, either by displacing the vortex from the equilibrium, or by imposing a random perturbation with zero mean to the vortex in equilibrium. The trajectories of passive scalars continuously released upwind of the separation point and trapped by the recirculating bubble are numerically integrated, and concentration time series are calculated at fixed locations downwind of the reattachment points. This model proves to be capable of reproducing the trapping and intermittent release of scalars, in agreement with the simulation of the flow passed a snow cornice performed by a discrete multi-vortex model, as well as with direct numerical simulations of the flow passed a backward-facing step. The results of simulation indicate that for flows undergoing separation and reattachment the unsteadiness of the recirculating bubble is the main mechanism responsible for the intense large-scale concentration fluctuations downstream.

• Journal of the Korean earth science society
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• v.34 no.1
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• pp.13-27
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• 2013

Quantitative precipitation estimation (QPE) is one of the most important elements in meteorological and hydrological applications. In this study, we adjusted the QPE from an S-band weather radar based on co-kriging method using the geostatistical structure function of error distribution of radar rainrate. In order to estimate the accurate quantitative precipitation, the error of radar rainrate which is a primary variable of co-kriging was determined by the difference of rain rates from rain gauge and radar. Also, the gauge rainfield, a secondary variable of co-kriging is derived from the ordinary kriging based on raingauge network. The error distribution of radar rain rate was produced by co-kriging with the derived theoretical variogram determined by experimental variogram. The error of radar rain rate was then applied to the radar estimated precipitation field. Locally heavy rainfall case during 6-7 July 2009 is chosen to verify this study. Correlation between adjusted one-hour radar rainfall accumulation and rain gauge rainfall accumulation improved from 0.55 to 0.84 when compared to prior adjustment of radar error with the adjustment of root mean square error from 7.45 to 3.93 mm.

• The Journal of the Petrological Society of Korea
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• v.21 no.1
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• pp.13-30
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• 2012

Phlogopite and kaersutite, showing distinctively different textural characteristics compared to the common phenocrysts, are observed in alkali basalt from Jeju Island. They occur as large crystals (2-10 mm) in host basalts, whereas fine-grained phlogopite and kaersutite occur in ultramafic mantle xenoliths and mafic gabbroic xenoliths, respectively, as an interstitial and microvein phases, or in corona textures (<1 mm). This textural characteristics of fine-grained grains clearly indicates secondary in origin. Phlogopite contains high $TiO_2$(4.1-6.9 wt%) and F(2.8-4.6 wt%) and relatively high mg#[=100Mg/(Mg+$Fe^t$) in mols, where $Fe^t$ is total iron](88-80), whereas kaersutite has high $TiO_2$(5.6-6.11 wt%) and much lower mg#s(68-64). Our textural observations and the geochemical character of these hydrous minerals suggest that they were unrelated to each other and mica formation happened early in the upper mantle before the mantle xenoliths had been trapped. In contrast, kaersutite formation has happened later, probably during the late stage of crystallization as intracrustal processes. The presence of phlogopite and kaersutitic amphibole is a direct evidence for K-, Ti-, F- and $H_2O$-bearing fluid/melt percolation in the lithosphere beneath Jeju Island, indicating that they are product of interaction between host rock/peridotite/fluid-melt. Thus, the upper mantle/lower crust beneath Jeju Island are metasomatized to various extents, characterized by a change in major metasomatic hydrous minerals from phlogopite to amphibole with decreasing depth.

• The Korean Journal of Ecology
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• v.25 no.2
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• pp.75-82
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• 2002

Saussurea chabyoungsanica was recorded in new species by Lim Hyoung Tak in 1997. In order to understand the entity of new species, we investigated the new distribution sites, vegetation structure and soil environmental factors. Additionally discovered distribution sites of S. chabyoungsanica were Manduckbong, Mt. Sukbyoung, Mt. Duckhang, and Sukgaejae, which were located on ridge of the Taebaek mountains. Those sites are typical limestone zones of Korea and among them Sukgaejae belongs to lower great limestone area and Manduckbong, Mt. Sukbyoung and Mt. Duckhang belong to uper great limestone area. According to the result of phytosociological study, plant communities of S. chabyoungsanica were classified by 1 Community group, 4 Communities and 2 Subcommunities; Carex humilis var. nana - Saussurea chabyoungsanica Community group in wide sense Quercus mongolica Community group, Lespedeza maximowiczii- Saussurea chabyoungsanica Community, Galium kinuta - Saussurea chabyongsanica Community, Saliva chanryonica - Saussurea chabyoungsanica Community, Zabelia coreana - Saussurea chabyoungsanica Community. Environmental factor analysis of habitat showed that the distribution site of S. chabyoungsanica was ridge of North aspect and displayed pH 7∼8 typical of limestone. Soil moisture content was high, whereas organic matter content was low. Considering its high occurrence in sites of 1∼10cm in soil depth, and of 30∼45% in relative light intensity, major distribution sites were outcrops and boundaries between shrubland and forest. After community division by vegetation structure in habitat of S. chabyoungsanica, we investigated characters of soil environment by community. As a result of PCA analysis of soil sample by community, it was possible to divide community by characters of soil environmental factor. The cumulative value of contribution rate represented in second dimension space was 73% and the major factors for that value were soil texture, organic matter content and field capacity.

• Journal of the Korean School Mathematics Society
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• v.17 no.3
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• pp.359-384
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• 2014

The purpose of this study is inquire the reaction and adaptability of the mathematically gifted student, in the case of introduce learning materials based on GeoGebra in real class. The study program using GeoGebra consist of 'construction of fundamental figures', 'making animation with using slider tools' (graph of a function, trace of a figure, definite integral, fixed point, and draw a parametric curve), make up the group report after class. In detail, 1st to 15th classes are mainly problem-solving, and topic-exploring classes. To analyze the application effects of developed learning materials, divide students in four groups and lead them to make out their own creative products. In detail, guide students to make out their own report about mathematical themes that based on given learning materials. Concretely, build up the program to make up group report about their own topics in six weeks, after learning on various topics. Expert panel concluded that developed learning materials are successfully stimulate student's creativity in various way, after analyze of the student's activities. Moreover, those learning programs also contributed to the develop of the mathematical ability to thinking that necessary to writing a report. As well, four creative products are assessed as connote mathematically gifted student's creative thinking and meaningful elements in mathematical aspects.

• Korean Journal of Environmental Biology
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• v.26 no.2
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• pp.121-127
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• 2008

As a step toward developing conservation and restoration plans for an endangered species of the Oriental White Stork (Ciconia boyciana), we studied daily foraging behavior and ecology. We released two individuals, male and female, after enclosing study site with a fence and cutting out a part of two or three feathers of primaries. Research was conducted from 16 June to 11 July, 2007 for 25 days at Whawonri, Mewonmyung, Chungbuk province. We investigated diural and daily variation of foraging time budget, diet composition, and habitat selection of the feeding individuals. The storks quadratically invested for foraging time and resting time according to time of day, but no significant variation in the foraging time and resting time appeared daily over 25 days. As a result, the storks mainly used wetland as a foraging site in the center of the study area to that in the edge as well as to other types of habitat. The high usage for wetland in the center did not change over the 25 days while Rice field decreased and Wetland in the edge and Pathway increased. Female invested more time for foraging than male, but the foraging efficiency did not differ between them. We discussed the significance of foraging behavior and habitat selection for management plan.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.9
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• pp.2334-2339
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• 2009

In case of an embedded system having an LCD panel with touch-screen capability, various figures such as rectangles, pentagons, circles, and arrows are frequently used for the delivery of user-input commands. In such a case, it is necessary to have an algorithm that can recognize whether a touched location is within a figure on which a specific user-input command is assigned. Such algorithms, however, impose a considerable amount of overhead for embedded systems with restricted amount of computing resources. This paper first describes a method for initializing and driving a touch-screen LCD and a coordinate-calibration method that converts touch-screen coordinates into LCD panel coordinates. Then it introduces methods that can be used for recognizing touched areas of rectangles, many-sided figures like pentagons, and circles; they are a range checking method for rectangles, a crossing number checking method for many-sided figures, a distance measurement method for circles, and a color comparison method that can be applied to all figures. In order to evaluate the performance of these methods, we implement two-dimensional graphics functions for drawing figures like triangles, rectangles, circles, and images. Then, we draw such figures and measures times spent for the touched-area recognition of these figures. Measurements show that the range checking is the most suitable method for rectangles, the distance measurement for circles, and the color comparison for many-sided figures and images.