• Polymer(Korea)
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• v.32 no.1
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• pp.31-37
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• 2008

The effect of MMT on mechanical properties of CTBN toughened epoxy nanocomposite is studied. In case of CTBN toughened epoxy nanocomposite with modified MMT, it is found that the enhancement of toughness and tensile properties are exhibited in CTBN toughened epoxy nanocomposite with modified MMT From the results of fractured surface morphology of sample, it is clearly shown that the improved mechanical properties can be obtained in CTBN toughened nanocomposite due to the significant energy dissipation mechanism by MMT loading.

• The Journal of the Petrological Society of Korea
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• v.7 no.2
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• pp.132-145
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• 1998

The coal-bearing siliciclastic rocks of the Lower Permian Jangseong Formation, Samcheog coalfield, represent a megacyclothem which shows cyclic repetitions of sandstone, shale, coaly shale, and coals. Petrographic, geochemical, and SEM studies for sandstone samples, and XRD analysis for clay minerals were carried out to understand diagenesis in the sandstones of the Jangseong Formation. The Jangseong sandstones are composed of 60% quartz (mainly monocrystalline quartz) and 36% clay matrix and cement with minor amounts of feldspar, lithic fragments and accessory minerals (less than 4%). Jangseong sandstones are classified mostly as quartzwackes and partly as lithic graywackes according to the scheme of Dott(1964). The textural relationships between authigenic minerals and cements in thin sections and SEM photomicrographs suggest the paragenetic sequence as follows; (1) mechanical compaction, (2) cementation by quartz overgrowth, (3) formation of authigenic clay minerals (illite, kaolinite), (4) dissolution of framework grains and development of secondary porosity, and (5) later-stage pore-filling by pyrophyllite. We propose that these diagenetic processes might be due to organic-inorganic interaction between the dominant framework grains and the formation water. The Al, Si ions and organic acid, derived from dewatering of interbedded organic-rich shale and coals, were transported into the Jangseong sandstones. This caused changes in the chemistry of the formation water of the sandstones, and resulted in overgrowth of quartz and precipitation of authigenic clay minerals of kaolinite and illite. The secondary pores, produced during dissolution of clay and framework grains by organic acid and $CO_2$ gas, were conduit for silica-rich solution into the Jangseong sandstones and the influx of silica-rich solution produced the late-stage pyrophyllite after the expanse of kaolinite. The origin of the solution that formed pyrophyllite is not likely to be the organic-rich formation water based on the observation of fracture-filling pyrophyllite in the Jangseong sandstones, but the process of pyrophyllite pore-filling was indirectly related to organic-inorganic interaction.

• The Korean Journal of Quaternary Research
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• v.16 no.2
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• pp.9-21
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• 2002

In Korea, many open-air upper palaeolithic sites are located at the river valley, particularly exposed in gently rotting terrain along the river course. They are situated at an altitude less trail 30 m above present river bottom, and covered with the blankets of slope deposits of several meters in thickness. The purpose of this research is to eluridate depositional and vegetational environment of the alluvial upper palaeolithic Jangheung-ri sites on the basis of analytical properties of grain size population, chronology, palynology, soil chemistry and clay mineralogy and magnetic susceptibility of the Jangheung-ri Quaternary formations. The lithostratograpy of Jangheung-ri sit is subdivided into 3 layers based on the depositional sequence and radiocarbon ages. From bottom to top, they are composed of slope deposits with lower paleosol layers, young fluvial sand and gravel with backswamp organic muds, and upper paleosol layers. The upper paleosol was formed under rather dry climatic condition between each flooding period. Dessication cracks were prevalent in the soil solum which was filled with secondarily minuted fragments due to pedogenetic process. The soil structure shows typical braided-typed cracks in the root part of cracking texture, and more diversified pattern of crackings downward. The young fluvial sand gravel were formed by rather perennial streams after LGM. The main part of organic muds was particularly formed after 15Ka. Local backswamp were flourished with organic muds and graded suspension materials in the flooding muds were intermittently accumulated in the organic muds until ca. 11Ka. This episode was associated with migration of Nam River toward present course. Organic muds were formed in backswamp or local pond. Abies/Picea-Betula with Ranunculaceae, Compositae, Cyperaceae were prevalent. This period is characterized with B$\Phi$lling, Older Dryas, Allerod, and Younger Dryas (MIS-1). Stone artefacts were found in the lower paleosol layers formed as old as 18Ka-22Ka. Based on the artefacts and landscape settings of the Jangheung-ri site, it is presumed that settlement grounds of old people were buried by frequent floodings of old Nam River, the river-beds of which were heavily fluctuated laterally and river-bed erosions were activated from south to north in Jangheung-ri site until the terminal of LGM9ca 17Ka).

• Journal of the Korean GEO-environmental Society
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• v.4 no.4
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• pp.53-59
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• 2003

Phosphogypsum is a by-product resulting from the phosphoric acid process for manufacturing fertilizers. It consists mainly of $CaSO_4{\cdot}2H_2O$ and contains some impurities such as $P_2O_5$, $F^-$, and organic substances. Recycling research of phosphogypsum is very limited to a field of study, especially, civil engineering. This study describes an application of phosphogypsum as dredged materials. For this purpose, experiments are performed to evaluate the physicochemical properties and environmental characteristics of dredged clay with phosphogypsum ; sedimentation test, pH, and leaching test. The result of this study are as follows : the settling velocity is increased due to the activity of phosphogypsum. And leaching and radioactive test results are far below than those of regulatory requirement of Waste Management Act in Korea. Therefore phosphogypsum can be used as dredged materials in reclamation.

• Elastomers and Composites
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• v.41 no.4
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• pp.252-259
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• 2006

A new route for making rubber/clay nanocomposites was suggested based on skim natural rubber latex (SNRL), which is a protein rich by-product obtained during the centrifugal concentration of natural rubber (NR) latex. NR/acrylonitrile butadiene rubber (NBR) based nanocomposites were prepared from SNRL and NBR latex of 26 % acrylonitrile content by blending of aqueous dispersion of organoclay (OC) followed by coagulation, drying, mill mixing and vulcanization. X-ray diffraction(XRD) studies revealed that NR/NBR blend nanocomposites exhibited a highly intercalated and exfoliated structure, especially for NBR-rich blends. Dynamic mechanical studies showed that more compatible behavior was observed for NBR-rich blends. The 25/75 NR/NBR blend nanocomposite showed the best mechanical properties.

• Journal of the Korean Geotechnical Society
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• v.19 no.6
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• pp.217-225
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• 2003

An experimental study was conducted to evaluate the smeared effect due to mandrel penetration into soft ground for a vertical drain installation. Laboratory tests were performed to investigate the formation of a smear zone, the variations of strength, and the consolidation characteristics in the disturbed zone using two types(CL at Yangsan site and OH at Pohang site) of soft clayey soils. The smear zone effect was evaluated focusing on mandrel shape, mandrel size, penetration speed, and ground condition. Based on laboratory test results, the diameter of the smear zone$(d_s)$ ranged from 3.08 and 3.92 times that of mandrel$(d_m)$. It was also found that the $(d_s/d_m)$ value of the circular shape of the mandrel is smaller than those of square and rectangular shapes. The value of $(d_s/d_m)$ decreased with larger mandrel size, lower penetration speed in the CL soil, and higher penetration speed in the OH soil. However, natural water content was minimally affected by $(d_s/d_m)$. Respectively, the coefficients of horizontal consolidation$(C_{hs})$ and horizontal Permeability$(K_s)$ of smear zone ranged from 0.81 to 0.87 times, and 0.73 to 0.83 times those of the undisturbed zone. Based on this study, the values of $C_{hs}, K_s$ and unconfined compressive strength$(q_{us})$ in the smear zone were the lowest at close vicinity of the mandrel and increased linearly with distance from the mandrel. Further, the $(q_{us})$ varied from 0.5 to 0.9 times that of the undisturbed zone strength.

• Journal of the Korean GEO-environmental Society
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• v.24 no.5
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• pp.13-20
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• 2023

The Gangneung region has an environment suitable for the formation of organic soil, and there is an alluvial layer in which sedimentary sand layers are distributed on the upper and lower parts of the organic soil. In order to evaluate the seismic safety of the railway roadbed passing through the Gangneung area, a railway roadbed and ground model considering the similarity ratio was fabricated, a shaking table test was conducted, and the seismic stability was evaluated by comparing the effective stress analysis results. The applied seismic waves were artificial seismic waves, Gyeongju seismic waves, Borah seismic waves, Nahanni seismic waves, and Tabas seismic waves. It became. Due to the ground reinforcement effect by jet grouting applied to the lower ground of the new roadbed, the displacement of the new roadbed was found to be reduced from a minimum of 33.7% to a maximum of 56.7% compared to the existing roadbed. The shaking table test results were verified by effective stress analysis using the Finn model of the Flac program, and showed a similar trend to the shaking table test values.

• Korean Journal of Soil Science and Fertilizer
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• v.42 no.6
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• pp.478-485
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• 2009

This study was conducted to reclassify Yongheung series based on the second edition of Soil Taxonomy and to discuss the formation of Yongheung series in Jeju Island. Morphological properties of typifying pedon of Yongheung series were investigated and physico-chemical properties were analyzed according to Soil Survey Laboratory Methods Manual. The typifying pedon contains 3.2~3.4% oxalate extractable (Al + 1/2 Fe), less than 85% phosphate retention, and higher bulk density than $0.90Mg\;m^{-3}$. That can not be classified as Andisol. But it has an argillic horizon from a depth of 15 to 150 cm and a base saturation (sum of cations) of less than 35% at 125 cm below the upper boundary of the argillic horizon. That can be classified as Ultisol, not as Andisol or Alfisol. The typifying pedon has 0.9 % or more organic carbon in the upper 15 cm of the argillic horizon and accordingly, can be classified as Humult. It has a clay distribution in which the percentage of clay does not decrese from its maximum amount by 20% or more within a depth of 150 cm from the mineral soil surface, and keys out as Palehumult. Also that meets the requirements of Typic Palehumult. That has 35 % or more clay at the particle-size control section and has mesic soil temperature regime. Yongheung series can be classified as fine, mixed, thermic family of Typic Palehumults, not as fine, mixed, thermic family of Typic Hapludalfs. Most soils distributed in the southern coastal areas in Jeju island which have a humid climate are developed as Andisols. But Yongheung series distributed in this areas and derived from mainly trachyte, trachytic andesite, and volcanic ash are developed as Ultisols.

• Applied Chemistry for Engineering
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• v.24 no.1
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• pp.55-61
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• 2013

Heterogeneous metallocene catalysts supported on montmorillonite (MMT), [$Cp_2ZrCl_2$/MMT, $Cp_2ZrCl_2$/MAO/MMT, and $Cp_2ZrCl_2$ + MAO/MMT], were prepared with three different methods of immobilization and tested for ethylene polymerization. The heterogeneous catalysts immobilized on organo clay (30B-MMT) showed the higher metal loading and polymerization activity than those immobilized on natural clay $Na^+-MMT$. These results suggest that the hydroxyl groups of organo clay interlayers react with the MAO and catalyst through the chemical bond. The metallocene catalyst supported directly on MMT showed lower activity for ethylene polymerization compared to the homogeneous systems, while MMT/MAO/$Cp_2ZrCl_2$, catalysts treated with MAO before impregnation, showed a higher activity. The polymers obtained from MMT-supported catalysts have higher melting point, molecular weight and molecular weight distributions than those of homogeneous catalysts. The polymer particles with increasing significant size. Ethylene polymerization over 30B-MMT/MAO/$Cp_2ZrCl_2$ catalyst was also performed varying the process variables to optimize the process conditions.

• Geotechnical Engineering
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• v.12 no.1
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• pp.21-34
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• 1996

This paper presents the engineering characteristics of the Samcheok organic soil which contains a large portion of organic matter and high natural water content. A series of lab tests shows that the measured liquid limit is quite different depending on preparing methods of specimens. The values tested with natural condition are higher up to 4 times than thole of the oven dry specimen. It is shown that the organic soils fail at large strain and do not show peak stress in the stress strain relationships. Also strength increase ratios, which are measured 0.43 to 0.65 in this tests, are significantly higher than those of the soft clay without organic matter. The consolidation tests indicate that the verti'cal and horizontal Permeabilities are almost the same. For the remolded samples is reduced from 112 to 116 of the vertical permeability An increase of organic matter or water content of the organic soils results in an increase of the coefficient of secondary consolidation. The increase rate is slow below 15 percents of the organic contents while the rate becomes higher above the value.