• Title/Summary/Keyword: 유기계

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VOCs Permeation Property of Composite Hollow Fiber Membranes (중공사 복합막을 이용한 다성분계 휘발성 유기 화합물 투과 특성)

  • Choi, Whee Moon;Cho, Soon Haing;Kim, Soon Tae;Lee, Chung Seop;Nam, Sang Yong
    • Membrane Journal
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    • v.23 no.2
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    • pp.176-184
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    • 2013
  • To investigate the performance of VOC separation, composite hollow fiber membrane was prepared which composed of poly (ether imide) support prepared by phase separation method and poly (dimethylsiloxane) coating active layer. The performances of the membranes for the application of recovery process in terms of their morphology, gas permeance test for $N_2$ and $O_2$ gases. Durability against benzene, toluene and xylene was also investigated. And permeation test for multi-component VOCS through the membrane with different feed concentration and stage-cut were investigated. Permeance of PEI supported membrane and the membranes coated with PDMS decreased from 45,000 GPU to 63 GPU and 49,450 to 30 GPU for $N_2$ and $O_2$, respectively. Recovery efficiency and concentration of VOCs in permeate increased with decreasing stage-cut. VOCs concentration in permeate proportionally increased with increasing feed concentration but concentration ratio and recovery efficiency showed any noticeable changes with feed concentration change.

Effects of Dietary Organic Selenium and Vitamin E on Performance, Selenium Retention and Quality of Egg in Laying Hens (유기태 셀레늄과 비타민 E의 복합 급여가 산란계의 생산성, 셀레늄 축적 및 난질에 미치는 영향)

  • Na, J.C.;Kim, J.H.;Yu, D.J.;Jang, B.G.;Kang, G.H.;Kim, S.H.;Kang, B.S.;Choi, C.H.;Suh, O.S.;Lee, W.J.;Lee, J.C.
    • Korean Journal of Poultry Science
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    • v.34 no.3
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    • pp.157-163
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    • 2007
  • To examine the effects of dietary organic selenium and vitamin E supplementation on egg production, egg weight, daily egg mass, feed intake, feed conversion, egg quality, lipid-soluble antioxidative capacity (ACL) in egg yolk, and selenium retention of egg in laying hens, Hy-Line laying hens of 77 wk old were replaced in the individual cage for 12 week. A corn-soybean meal based diet was supplemented with 0 (control), vitamin E 100 IU/kg and the combination of 0.9 ppm Se from selenium yeast (SY) and vitamin E 50, 100 and 150 IU/kg. Egg production and daily egg mass were significantly increased (P<0.05) in supplemental vitamin E 100 IU, and 0.9 ppm SY + vitamin E 50 IU than control for the whole experimental period. However, feed intake and feed conversion were not affected by supplemental vitamin E and SY. Haugh unit was significantly (P<0.05) higher in supplemental vitamin E 100 IU and 0.9 ppm SY + vitamin E 50 IU than control, 0.9 ppm SY + vitamin E 100 and 0.9 ppm SY + 150 IU in week 5. Haugh unit of the eggs during storage decreased significantly(P<0.05) from day 1 to day 11. However, Haugh units of the eggs from 0.9 ppm SY + vitamin E 150 IU treated groups did not decreased significantly until day 5. Yolk color was significantly (P<0.05) higher in 0.9 ppm SY + vitamin E 50 and 0.9 ppm SY + 100 IU than other treatment groups in week 1. Selenium concentrations of egg were significantly increased (P<0.05) in 0.9 ppm SY + vitamin E than control and vitamin E 100 IU groups. Lipid-soluble antioxidative capacity (ACL) in egg yolk was significantly (P<0.05) higher in supplemental combination of 0.9 ppm SY + vitamin E 150 IU when compared to those of other treatment groups.

Preparation and Polarization Properties of Poly(vinyl alcohol) Polarizing Film Using the Mixed System of Supercritical $CO_2$/Organic Solvents/Dichroic Dye (초임계 탄산가스/유기용매/이색성 염료의 혼합계를 이용한 폴리(비닐 알코올) 편광필름의 제조 및 편광특성)

  • Park, Ki-Sang;Choi, E-Joon;Chang, Jin-Ho;Park, Il-Hyun
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.458-466
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    • 2011
  • In the mixed system of supercritical carbon dioxide/organic solvents, poly(vinyl alcohol)(PVA) film of high degree of hydrolysis could be dyed with a dichroic dye of C. I. direct black 22(DB22) and as a result, high durability was obtained. Especially, as a dye dispersant in a supercritical fluid phase, a mixed solvent system of ethylene glycol: dimethyl sulfoxide=4 : 6 weight ratio was investigated. Then the optimum pressure for dyeing could be reduced down to 200 bar. Using this supercritical fluid system, the maximum dyeing appeared as the transmittance of less than 1% and the waste amount was reduced to the level of 1/10. After 500% drawing of this PVA film, both the polarizing efficiency of 94% and the single piece transmittance of 30% were obtained. The limitation of DB22 and further improvements were also discussed.

Evaluation of Carbon Balance for Carbon Sink/Emission with Different Treatments in Paddy Field (벼논에서 양분관리별 탄소의 흡수·배출에 대한 탄소수지 평가)

  • Kim, Gun-Yeob;Lee, Jong-Sik;Lee, Sun-Il;Jeong, Hyun-Cheol;Choi, Eun-Jung;Na, Un-sung
    • Korean Journal of Environmental Biology
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    • v.35 no.4
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    • pp.715-725
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    • 2017
  • Importance of climate change and its impact on agriculture and environment has increased with the rise in the levels of Green House Gases (GHGs) in the atmosphere. To slow down the speed of climate change, numerous efforts have been applied in industrial sectors to reduce GHGs emission and to enhance carbon storage. In the agricultural sector, several types of research have been performed with emphasis on GHGs emission reduction; however, only a few work has been done in understanding the role of carbon sink on reduction in GHGs emission. In this study, we investigated ecosystem carbon balance and soil carbon storage in an agricultural paddy field. The results obtained were as follows: 1) Evaluation of soil C sequestration in paddy field was average $3.88Mg\;CO_2\;ha^{-1}$ following NPK+rice straw compost treatment, average $3.22Mg\;C\;ha^{-1}$ following NPK+hairy vetch treatment, and average $1.97Mg\;CO_2\;ha^{-1}$ following NPK treatment; and 2) Net ecosystem production (NEP) during the paddy growing season was average $14.01Mg\;CO_2\;ha^{-1}$ following NPK+hairy vetch treatment, average $12.60Mg\;CO_2\;ha^{-1}$ following NPK+rice straw compost treatment, and average $11.31Mg\;CO_2\;ha^{-1}$ following NPK treatment. Therefore, it is proposed that organic matter treatment can lead to an increase in soil organic carbon accumulation and carbon sock of crop ecosystem in fields compared to chemical fertilizers.

A Study of Synthesis and Property of $CaCO_3$/Organic Core-Shell Particle (탄산칼슘 /유기계 Core-Shell 입자의 제조와 물성에 관한 연구)

  • Seul, Soo-Duk
    • Polymer(Korea)
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    • v.34 no.1
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    • pp.38-44
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    • 2010
  • Core-shell particles of inorganic/organic pair were synthesized from $CaCO_3$ absorbed sodium dodecyl benzene sulfonate(SDBS) surfactant. Shell components were synthesized by sequential emulsion polymerization. Various monomers were used as shell components such as methyl methacrylate(MMA), ethyl acrylate(EA), butyl acrylate(BA), and styrene(St). Ammonium persulfate(APS) was used as an initiator and 2-ethylhexyl acylate(2-EHA) was used as a functional monomer, In the $CaCO_3$/organic core-shell particle polymerization, $CaCO_3$ absorbed surfactant SDBS of 0.5 wt% was prepared first and then core $CaCO_3$ was encapsulated by emulsion polymerization. 0.1 wt% of APS was added sequentially to minimize the formation of new monomer particle during shell polymerization. The structure of inorganic/organic core-shell particles were characterized by measuring the decomposition degree of $CaCO_3$ using HCl solution, thermogravimetric analyzer, scanning electron microscope, and transmission electron microscope.

Emulsion Viscosity with Oil Polarity and Interpretation by Organic Conceptual Diagram (오일 극성도에 따른 에멀젼의 점도와 유기개념도에 의한 해석)

  • Kim, Jung-Il;Kim, Hyun-Dong
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.623-627
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    • 2014
  • Emulsions are a class of disperse systems consisting of two immiscible liquids. Emulsions are affected by the size of oil drop, the type of continuous and disperse phase, the ratio of continuous and disperse phase, the type of emulsifies and emulsification devices. This study is to observe the viscosity of emulsions with oil polarities and interpret the results by organic conceptual diagram. The emulsions were made with hydrocarbon, ester and silicone oils and then the viscosity of emulsions was measured. As the oil polarity was increased, the viscosity of emulsion was decreased by reducing the amount of emulsifies and emulsion stabilizers arranged at interface. Organic conceptual diagram was used to compare the polarities among oils numerically. The interpretation of organic conceptual diagram and the results of experimental measurement were corresponded except emulsion made with silicone oil.

Characteristics and Effective Usage of Organic Indexes in Water Environments -Lakes in Nakdong River Basin- (물환경에서의 유기물질 지표 특성 및 효율적 이용방안 -낙동강수계 호소수를 대상으로-)

  • Kang, Meea
    • Journal of Wetlands Research
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    • v.16 no.1
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    • pp.153-160
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    • 2014
  • TOC environmental standard was established to understand the pollution level accurately and to improve the water quality. It was found that the relationship between COD and TOC showed a significant coefficient($R^2$=0.639) in four lakes for drinking water located in Nakdong River basin. The relationship between COD and TOC($R^2$=0.774) was higher with respect to the elevated concentration level when the data was added. Resulting in the oxidation(C) was $62{\pm}8%$ regardless of COD concentrations. It was difficult to find a significant difference by lakes. The result showed the similar organic property in study lakes. It was necessary to evaluate the level of organic matters in consideration of characteristics and utilization of lakes to use COD data wisely until TOC data be accumulated sufficiently.

Color-Edge Detection with CIEL*Ch Color Space (컬러영상 경계추출을 위한 CIEL*Ch 색체계 변환의 적용)

  • Yang, Sung-Chul;Kim, Yong-Il;Yu, Ki-Yun
    • 한국공간정보시스템학회:학술대회논문집
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    • 2005.05a
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    • pp.273-278
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    • 2005
  • 전정색영상과 달리 컬러영상에서 개체를 추출할 경우 밴드별 분광특성을 이용하여 특정지물을 효과적으로 인식할 수 일고 밝기값만으로 구별해낼 수 없는 개체를 추출할 수 있는 장점이 있다. 본 연구에서는 컬러영상에서 지형지물을 추출하기 위해 컬러정보를 이용하여 경계를 추출하는 연구를 수행하기 위해 일반적으로 사용하는 RGB 색체계가 아닌 CIEL*Ch 색체계로 변환한 후 L*에서 경계를 추출하고 C, h값으로 특정지물을경계를 추출하는 기법으로 컬러영상의 경계를 추출하였다.

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Electrochemical Preparation of Si-Based Thin Films at Room Temperature (상온 전해 도금을 통한 실리콘계 박막 제조)

  • Kim, Eun-Ji;Sin, Heon-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.68-68
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    • 2012
  • 유기 용매를 사용하여 상온에서 실리콘계 전해 도금층을 형성하였다. 도금층의 몰폴로지는 전류밀도 및 도금 시간에 크게 영향을 받았으며, 다공성 구조에서 치밀한 구조까지 다양하게 나타났다. 조성 및 구조가 잘 정의된 실리콘계 전해 도금 층을 리튬이차전지용 애노드 활물질로써 평가해 본 결과 도금층 내 실리콘은 리튬과 가역적으로 반응하였다.

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A Study on Organic-Inorganic Hybrid Sound Absorbing Materials Using by Recycling Gypsum (재활용 석고 부산물을 이용한 유무기 하이브리드 흡음재 개발 연구)

  • Shin, Hyun-Gyoo;Jeon, Bo-Ram;Ha, Joo-Yeon;Jeon, Chan-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.481-487
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    • 2017
  • The purpose of this study is to develop the hybrid sound-absorbing materials that is made from organic polyurethane sponge impregnated with inorganic binder solutions. The inorganic slurry which is made from ${\alpha}$-hemihydrate gypsum mixed with 60% water, and various additives including plasticizer are used as binder. The test specimens are prepared and tested for sound absorption performance by the impedance tube methods. From the test results, noise reduction coefficient(NRC) of development materials specimen bound by the inorganic binder slurry is 0.41. They are 2 times or more higher than commercial products specimens bound by organic materials only which have NRC values in the range of 0.14 to 0.28. The polyurethane sponge specimens impregnated with inorganic gypsum slurry binder have a good balance between performance and cost, and have proper properties in density, thermal conductivity, non-combustible, and absence of harmful substances as sound-absorbing internal boards for noise barrier wall. It is apparent that the good sound absorption materials can be produced according to the optimum mix design that is recommended from this study.