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Determination of fatty acid methyl esters (FAME) content in aviation turbine fuel using multi-dimensional GC-MS (Multi-dimensional GC-MS를 이용한 항공터빈유의 FAME 함량 분석)

  • Youn, Ju Min;Doh, Jin Woo;Hwang, In Ha;Kim, Seong Lyong;Kang, Yong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.717-726
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    • 2017
  • The current allowable cross-contamination level of fatty acid methyl esters (FAME) in aviation turbine fuel (AVTUR) is 50 mg/kg, due to that the presence of FAME in AVTUR can significantly impact the fuel supply system and jet engine. It has been difficult to analyze the level of FAME in AVTUR, since it is consisted of a lot of hydrocarbons. In this study, thus, a new method using multi-dimensional GC-MS (MDGC-MS) was proposed in order to determine the FAME level in AVTUR effectively. Applying to MDGC-MS with Deans switching system enabled us to detect and quantify the FAME with low carbon numbers such as those derived from coconut oil and palm kernel oil. The matrix effect of MDGC-MS method, which could shift the FAME peaks to slightly longer retention times, was reduced by 20 times compared with that of 1-dimensional GC-MS reference method. This developed method could be suitable for qualitative and quantitative analyses to determine the contamination level of trace FAME in AVTUR.

Study on Characteristics of Change of Physical/Chemical property of Refined Fuel Oil(Reduced-pressure) by Mixing with By-product Fuel Oil(No. 2) (부생연료유(2호) 혼합에 따른 정제연료유(감압)의 물성 변화 특성 연구)

  • Doe, Jin-woo;Lim, Tae-yun;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1349-1358
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    • 2018
  • In addition to responding to the environmental pollution caused by fossil fuels, the enforcement of Renewable Fuel Standard(RFS) system has increased the utilization of renewable energy such as refined fuels oil. The by-product fuel oil(No. 2) and the refined fuel oil(reduced-pressure) are strictly regulated by the domestic legislation and the chemical property changes of the refined fuel oil(reduced-pressure) mixed with the by-product fuel oil(No. 2) were analyzed. As a result of analyzing the physical properties of refined fuel oil(reduced pressure) obtained by mixing 1 : 1 of by-product fuel oil(No. 2), it satisfied the quality standards stipulated by the domestic Enforcement Decree of the Wastes Control Act. However, the results of the additional tests related to the fuel showed a high aromatic content. The high content of aromatic in a fuel is likely to cause the soot and ehaust emission gas during the combustion of the used equipment.

A Prediction Model for Agricultural Products Price with LSTM Network (LSTM 네트워크를 활용한 농산물 가격 예측 모델)

  • Shin, Sungho;Lee, Mikyoung;Song, Sa-kwang
    • The Journal of the Korea Contents Association
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    • v.18 no.11
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    • pp.416-429
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    • 2018
  • Typhoons and floods are natural disasters that occur frequently, and the damage resulting from these disasters must be in advance predicted to establish appropriate responses. Direct damages such as building collapse, human casualties, and loss of farms and fields have more attention from people than indirect damages such as increase of consumer prices. But indirect damages also need to be considered for living. The agricultural products are typical consumer items affected by typhoons and floods. Sudden, powerful typhoons are mostly accompanied by heavy rains and damage agricultural products; this increases the retail price of such products. This study analyzes the influence of natural disasters on the price of agricultural products by using a deep learning algorithm. We decided rice, onion, green onion, spinach, and zucchini as target agricultural products, and used data on variables that influence the price of agricultural products to create a model that predicts the price of agricultural products. The result shows that the model's accuracy was about 0.069 measured by RMSE, which means that it could explain the changes in agricultural product prices. The accurate prediction on the price of agricultural products can be utilized by the government to respond natural disasters by controling amount of supplying agricultural products.

Evaluation of Ozone Resistance and Anti-Corrosion Performance of Water Treatment Concrete according to Types of Metal Spray Coating (수처리시설용 콘크리트의 금속용사 피막 종류에 따른 내오존성 및 전기화학적 방식 성능 평가)

  • Park, Jin-Ho;Choi, Hyun-Jun;Lee, Han-Seung;Kim, Sang-yeol;Jang, Hyun-O
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.61-68
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    • 2019
  • As the pollution of water resources deteriorates due to industrialization and urbanization, it is difficult to supply clean water through a water treatment method using chlorine. Therefore, the introduction of advanced water treatment facilities using ozone is on the increase. However, epoxy which is used as waterproofing and anticorrosives and stainless steel used in conventional waterproofing and anti-corrosive methods have deteriorated because of the strong oxidizing power of ozone, causing problems such as leaking. Moreover, it even causes the durability degradation of a concrete. Therefore, in this study, metal spraying system was used as the means of constructing a metal panel with excellent ozone resistance and chemical resistance which is an easier method than an existing construction method. Ozone resistance was evaluated in accordance with the type of metal sprayed coatings to develop a finishing method which can prevent the concrete structure of water treatment facilities from deterioration. Furthermore, electrochemical stability in actual sewage treatment plant environment was evaluated. Experimental results showed that Ti has superior ozone resistance after spraying and the electrochemical stability in the sewage treatment plant environment showed that Ti has the highest polarization resistance of $403.83k{\cdot}{\Omega}{\cdot}cm^2$, which ensures high levels of durability.

The Installation of Royal Kilns in Joseon Dynasty and Its Impact on Local Kilns (음각운문청자의 제작현황으로 본 조선시대 관요의 설치와 지방 가마)

  • Oh, Young-In
    • Korean Journal of Heritage: History & Science
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    • v.50 no.4
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    • pp.38-63
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    • 2017
  • This study sets out to investigate the installation of royal kilns and its impact on local kilns, taking note of celadon vase with inlaid cloud pattern in Joseon Dynasty. For that purpose, it determined the kilns and period to produce celadon vases with inlaid cloud pattern, and compared them with the pattern, design, and deformity of the celadon vases produced in the royal kilns in the 15th centuries. The celadon vase with inlaid cloud pattern was superior in quality than the porcelain for tribute ware manufactured together in Jeolla Province before the installation of royal kilns. And then a majority of sagijangs at local kiln had difficult time securing enough supply of manpower and resources, and discontinued manufacturing the celadon vase with inlaid cloud pattern. En revanche, celadon vases with inlaid cloud pattern produced from specially fixed royal kilns reflected the local sagijang's skill. Local kilns were strongly influenced by the installation of royal kilns. Those could not freely use high-quality white clay, limited to the market. Besides, most of the skillful sagijangs were assigned to royal kilns. Celadon vases with inlaid cloud pattern can be used as evidence to show that the manufacturing technique was transferred from local kilns to the royal kilns as well as to show that their production in royal kilns soon became stabilized.

Threshold Condition for Exclusion of Riprap into Bypass Pipe (저층수 배출관에 유입된 사석의 배제 한계조건)

  • Jeong, Seokil;Lee, Seung Oh
    • Journal of Korean Society of Disaster and Security
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    • v.12 no.1
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    • pp.57-66
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    • 2019
  • One of the most serious problems with concrete small dams or barriers installed in small/median rivers is the deposit of sediments, especially, in Korea. An effective way to discharge such sediments to downstream is to construct a bypass pipe under the river bed. However, efficiency may become lowered if ripraps are entered into the bypass pipe. Therefore, in this study, we derived the threshold condition for the exclusion of ripraps from the bypass pipe using 3D numerical analysis. Upstream flow of the small dam was assumed to be stationary, and the energy concept was applied to the control volume containing the bypass pipe and its periphery. As a result, when the ratio of the water level difference between upstream and downstream to the diameter of the riprap was approximately equal to 1.2, the threshold condition for exclusion of the stones or riprap from the bypass pipe was affirmatively determined. If the characteristics of the adsorptive sediment adversely affecting the river environment in the future would be taken into account, results from this study are expected to put to practical use in the management of concrete small dam with bypass pipe system.

Changes in the Number of Urban Park Users Due to the Spread of COVID-19: Time Series Big Data Analysis (COVID-19 확산에 따른 도시공원 이용자 수의 변화 - 시계열 빅데이터 분석 -)

  • Park, In Kwon;Chung, I Re;Oh, Dawon;Jung, Yeerim
    • Journal of the Korean Regional Science Association
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    • v.37 no.2
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    • pp.17-33
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    • 2021
  • This study empirically analyzes the effect of the spread of COVID-19 and the implementation of social distancing on the number of park users. To this end, we analyzed the time series data on the number of users and the COVID-19 outbreak at Olympic Park, a large-scale comprehensive urban park located in Songpa-gu, Seoul, and four neighborhood parks in the same municipality. And this was compared with the effect on the change in the number of users around Jamsil Lotte World, a representative indoor complex leisure space in Seoul. The analysis results are as follows: First, in small neighborhood parks located in residential areas, the number of users increased by 3 to 6% on average due to the implementation of the social distancing measures and the increase in the number of confirmed COVID-19 cases. In particular, it was found that changes in park use were sensitive to the increase in the intensity of social distancing. On the other hand, the number of users around Jamsil Lotte World decreased by 38% on average, and in the case of Olympic Park, the number of users decreased by 1.9% on average due to the spread of COVID-19. Considering that the number of the vehicle users representing remote users of Olympic Park has decreased by 23% on average, it is estimated that there is little change in the number of users in the surrounding areas. This suggests that urban parks, especially neighborhood parks in residential areas, play a role as a major refuge and leisure space for urban people in the event of a pandemic disaster such as COVID-19, and therefore need to be properly supplied and maintained.

Degradation Evaluation of PEM Water Electrolysis by Method of Degradation Analysis Used in PEMFC (고분자전해질 연료전지 열화 분석방법에 의한 PEM 수전해 열화 평가)

  • Oh, Sohyeong;Yang, Jinwon;Chu, Cheun-Ho;Na, Il-Chai;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.1-5
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    • 2021
  • The PEM(Proton Exchange Membrane)water electrolysis uses the same PEM electrolyte membrane as the PEM fuel cell and proceeds by the same reaction but the opposite direction. The PEM fuel cell has many methods of degradation analysis since many studies have been conducted on the degradation and durability of the membrane and catalyst. We examined whether PEM fuel cell durability evaluation method can be applied to PEM electrolytic durability evaluation. During the PEM electrolytic degradation process, LSV(Linear sweep voltammetry), CV(Cyclic voltammetry), Impedance, SEM(Scanning Electron Microscope) and FT-IR(Fourier Transform Infrared spectroscopy) were analyzed and compared under the same conditions as the PEM fuel cell. As the PEM fuel cell, hydrogen passing through the membrane was oxidized at the Pt/C electrode, and the hydrogen permeation current density was measured to analyze the degree of degradation of the PEM membrane. Electrode degradation could be analyzed by measuring the electrode active area (ECSA) by CV under hydrogen/nitrogen flowing conditions. While supplying hydrogen and air to the Pt/C electrode and the IrO2 electrode, the impedance of each electrode was measured to evaluate the durability of the electrode and membrane.

Development of a Data-Driven Model for Forecasting Outflow to Establish a Reasonable River Water Management System (합리적인 하천수 관리체계 구축을 위한 자료기반 방류량 예측모형 개발)

  • Yoo, Hyung Ju;Lee, Seung Oh;Choi, Seo Hye;Park, Moon Hyung
    • Journal of Korean Society of Disaster and Security
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    • v.13 no.4
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    • pp.75-92
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    • 2020
  • In most cases of the water balance analysis, the return flow ratio for each water supply was uniformly determined and applied, so it has been contained a problem that the volume of available water would be incorrectly calculated. Therefore, sewage and wastewater among the return water were focused in this study and the data-driven model was developed to forecast the outflow from the sewage treatment plant. The forecasting results of LSTM (Long Short-Term Memory), GRU (Gated Recurrent Units), and SVR (Support Vector Regression) models, which are mainly used for forecasting the time series data in most fields, were compared with the observed data to determine the optimal model parameters for forecasting outflow. As a result of applying the model, the root mean square error (RMSE) of the GRU model was smaller than those of the LSTM and SVR models, and the Nash-Sutcliffe coefficient (NSE) was higher than those of others. Thus, it was judged that the GRU model could be the optimal model for forecasting the outflow in sewage treatment plants. However, the forecasting outflow tends to be underestimated and overestimated in extreme sections. Therefore, the additional data for extreme events and reducing the minimum time unit of input data were necessary to enhance the accuracy of forecasting. If the water use of the target site was reviewed and the additional parameters that could reflect seasonal effects were considered, more accurate outflow could be forecasted to be ready for climate variability in near future. And it is expected to use as fundamental resources for establishing a reasonable river water management system based on the forecasting results.

A study of the space sterilization device using atmospheric-pressure DBDs plasma (대기압 유전체장벽방전을 적용한 플라즈마오존 공간살균장치에 관한 연구)

  • Oh, Hee-Su;Lee, Kang-yeon;Park, Ju-Hoon;Jeong, Byeong-Ho
    • Journal of the Korea Convergence Society
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    • v.13 no.3
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    • pp.281-289
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    • 2022
  • Plasma ozone is utilized in a variety of applications in the field of sterilization due to its high sterilization performance. Dielectric materials used in DBD(dielectric barrier discharges) are mainly polymer, quartz and ceramics. These dielectric layers have the advantage of limiting the amount of supplied electron charge and allowing plasma to occur evenly on the surface of dielectric. Actually, the target or environment for sterilization is often a complex structure, so research and academic study are needed by utilizing the concept of space sterilization. In this study, the device is applied to generate DBD plasma at atmospheric pressure for disinfection due to the effectiveness in producing radicals and ozone. The generator of plasma ozone is a basic structure of dielectric barrier discharge by placing ceramic tube dielectrics and stainless steel electrical conductors at regular intervals. Various applications can be developed based on the proposed design method. Plasma ozone generation for space sterilization device is recognized as an excellent sterilization device. Through the design and verification of the device, we intend to establish an optimal design of the spatial sterilization device and provide the basis data for sterilization applications.