• Applied Chemistry for Engineering
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• v.32 no.5
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• pp.509-515
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• 2021

In this study, poly lactic-co-glycolic acid (PLGA) nanoparticles (PNP) were prepared through double (w/o/w) emlusion and emulsifying solvent-evaporation technique using PLGA, which has biocompatibility and biodegradability. To maximize stability and bioavailability of the particles, chitosan-coated PLGA nanoparticles (CPNP) were prepared by charge interaction between PNP and chitosan. We demonstrated that CPNP can be utilized as a drug carrier of oral administration. The chemical structure of CPNP was analyzed by ¹H-NMR and FT-IR, and all characteristic peaks appeared, confirming that it was successfully prepared. In addition, particle size and zeta potential of CPNP were analyzed using dynamic light scattering (DLS) while morphological images were obtained using transmission electron microscope (TEM). Thermal decomposition behavior of CPNP was observed through thermogravimetric analysis (TGA). In addition, the cytotoxicity of CPNP was confirmed by MTT assay at HEK293 and L929 cell lines, and it was proved that there is no toxicity confirmed by the cell viability of above 70% at all concentrations. These results suggest that the CPNP developed in this study may be used as an oral drug delivery carrier.

• Applied Chemistry for Engineering
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• v.32 no.5
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• pp.524-531
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• 2021

Depending on the type and amount of acid used as a modulator in the manufacturing process, the structural properties of UiO-66 can be modified and the adsorbability of chemical warfare agents can be enhanced. In this study, several acids as a modulator were used to synthesize UiO-66. Their properties were analyzed with FT-IR, XRD, titrator, and adsorption isotherms using chemical warfare agent simulant, DIMP. The UiO-66, structurally damaged by hydrochloric acid as a modulator, showed lower crystallinity and DIMP adsorption capacity and also smaller specific surface area and volume of voids compared to those of UiO-66, which was manufactured using acetic acid, and formic acid as a modulator. Additionally, UiO-66 which was synthesized by adding formic acid and hydrochloric acid as a modulator, showed the highest DIMP adsorption capacity and is likely to be used as an adsorbent for chemical warfare agent in the future.

• Journal of the Korean Institute of Landscape Architecture
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• v.49 no.5
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• pp.46-58
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• 2021

Parks became essential to people after the introduction of modern parks in Korea. Following mayoral elections by popular vote, issues surrounding parks, such as the creation of parks, have arisen and have been publicized by the media, allowing for the formation of discourse. Accordingly, this study conducted a topic analysis by collecting news articles from major media outlets in Korea that addressed issues related to parks since 1995, after the introduction of mayoral elections by popular vote, and analyzed changes over time in the discourse on parks through semantic network analysis. As a result of a Latent Dirichlet allocation topic modeling analysis, the following five topics were classified: urban park expansion (Topic 1), historical and cultural parks (Topic 2), use programs (Topic 3), zoo event (Topic 4), and conflicts in the park creation process (Topic 5). The park-related discourse addressed by the media is as follows. First, the creation process and conflicts regarding the quantitative expansion of parks are treated as the central discourse. Second, the names of parks appear as keywords every time a new park is created, and they are mentioned continuously from then on, thereby playing an important role in the formation of discourse. Third, 'residents' form discourse about the public nature of the park as the principal agent in park-related media. This study has significance in that it examines how parks are interpreted and how discourse is formed and changed by the media. It is expected that discourse on parks will be addressed from various perspectives in further research focusing on other media, such as regional and specialized magazines.

• Korean Journal of Remote Sensing
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• v.37 no.6_1
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• pp.1589-1597
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• 2021

Submarine groundwater discharge (SGD) in coastal areas is gaining importance as a major transport route that bring nutrients and trace metals into the ocean. This paper describes the analysis of the seasonal changes and spatiotemporal characteristicsthrough the modeling monthly SGD for 35 years from 1986 to 2020 for the Nakdong river basin. In this study, we extracted 210 watersheds and SGD estimation points using the SRTM (Shuttle Radar Topography Mission) DEM (Digital Elevation Model). The average annual SGD of the Nakdong River basin was estimated to be 466.7 m²/yr from the FLDAS (Famine Early Warning Systems Network Land Data Assimilation System) recharge data of 10 km which is the highest resolution global model applicable to Korea. There was no significant time-series variation of SGD in the Nakdong river basin, but the concentrated period of SGD was expanded from summer to autumn. In addition, it was confirmed that there is a large amount of SGD regardless of the season in coastal area nearby large rivers, and the trend has slightly increased since the 1980s. The characteristics are considered to be related to the change in the major precipitation period in the study area, and spatially it is due to the high baseflow-groundwater in the vicinity of large rivers. This study is a precedentstudy that presents a modeling technique to explore the characteristics of SGD in Korea, and is expected to be useful as foundational information for coastal management and evaluating the impact of SGD to the ocean.

• Food Engineering Progress
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• v.14 no.2
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• pp.135-145
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• 2010

In order to enhance overall quality of the Backsulki, a sweet potato flour (SPF) which is rich in sugar and dietary fiber was added into the rice flour at 0, 5, 15, and 25% (w/w, db) ratios. Quality changes of the products were evaluated by storing at 5, 15, and 25$^{\circ}C$ for 4 days. Water binding capacity, swelling power, and solubility of the products increased as the SPF increased. Hunter colorimetric a- and b-value increased while L value of the products decreased as the SPF increased. Retarded retrogradation of the flour mixtures containing the SPF was shown from the DSC thermogram as indicated by the decreased $\Delta$H values. Increases in $T_{i}$ and $T_{p}$ values in relation with the starch gelatinization were shown from the DSC thermogram with a temperature margin of 15-20$^{\circ}C$ as the SPF increased. Increases in softness along with decreases in springiness and chewiness of the products were shown as the SPF increased. It was not so much the storage temperature as the added SPF affected the final texture of the products. Retarded growth of the total microbes of the products was noted by the added SPF during storage at 25$^{\circ}C$ for 3 days. Regarding the above and additional sensory preference scores of the products, a 15%(w/w) level of the SPF was suggested as optimum for the best Backsulki with improved qualities.

• Food Engineering Progress
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• v.15 no.4
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• pp.382-387
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• 2011

Physicohemical properties of dual-modified rice starches, cross-linked (with $POCl_{3}$) and hydroxypropylated (with propylene oxide) rice starches, were studied. Rice starch was cross-linked using $POCl_{3}$ (0.005%, 0.02% (v/w)) at 45$^{\circ}C$ for 2 hr and then hydroxypropylated using propylene oxide (2%, 6%, 12% (v/w)) at 45$^{\circ}C$ for 24 hr, respectively. Swelling power, solubility, thermal properties (DSC) and pasting properties (RVA) of cross-linked and hydroxypropylated (CLHP) rice starches were determined. Swelling power of CLHP rice starch increased at relatively lower temperature than native rice starch. Solubility of CLHP rice starch was lower than that of native rice starch. Peak viscosity of CLHP rice starch was lower than that of native starch while holding strength and final viscosity were increased with modification. Breakdown value was lower and setback value was higher than native rice starch. DSC thermal transitions of CLHP rice starch shifted toward lower temperature. Amylopectin-melting enthalpy of CLHP rice starch decreased, whereas it was not affected by the amount of $POCl_{3}$.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.4
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• pp.76-85
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• 2019

Recently, various investigation of vegetable oil which is extracted from natural resources is being progressed because of its low cost and environmental aspect. However, double bonds in vegetable oil should be substituted to other high reactive functional group due to its low reactivity for synthesizing bio-polymeric materials. ${\alpha}$-eleostearic acid, which is consist of conjugated triene, is the main component of tung oil, and the conjugated triene allows tung oil to have higher reactivity than other vegetable oil. In this study, tung oil is copolymerized with styrene and divinylbenzene to make thermoset resin without any substitution of functional group. Thermal and mechanical properties are measured to investigate the effects of the composition of each monomer on the synthesized thermoset resin. The result shows that the products have only one Tg, which means the synthesized thermoset resins are homogeneous in molecular level. Mechanical properties show that tung oil act as soft segment in the copolymer and make more elastic product. On the other hand, divinylbenzene acts as hard segment and makes more brittle product.

• Clean Technology
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• v.25 no.1
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• pp.33-39
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• 2019

A.C (activated carbon) is mainly used to remove VOCs (volatile organic compounds), however, it has many problems such as fire risk due to increasing of adsorbent surface temperature during VOCs ad/desorption, increased cost by frequent replacement cycles requirement and performance degradation when containing moisture. In order to solve these problems, many researches, hydrophobic zeolite adsorbents, have been reported. In this study, $NH_4{^+}Y$-zeolite was synthesized with Y-zeolite through steam treatment and acid treatment, which is one of the hydrophobic modification methods, to secure high surface area, thermal stability and humidity resistance. The Y, Y-550-HN, Y-600-HN and Y-650-HN had adsorption capacities of $23mg\;g^{-1}$, $38mg\;g^{-1}$, $77mg\;g^{-1}$, $61mg\;g^{-1}$. The change of Si/Al ratio, which is an index to confirm the degree of modification, was confirmed by XRF (X-ray fluorescence spectrometer) analysis. As a result, the adsorbtion performance was improved when Y-zeolite modified, and the Si/Al ratio of Y, Y-550-HN, Y-600-HN, Y-650-HN were increased to 3.1765, 6.6706, 7.3079, and 7.4635, respectively. Whereas it was confirmed that structural crystallization due to high heat treatment temperature affected performance degradation. Therefore, there is an optimal heat treatment temperature of Y-zeolite, optimum modification condition study could be a substitute for activated carbon as a condition for producing an adsorbent having high durability and stability.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.652-656
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• 2018

In this study, effects of the reaction pressure were studied for petroleum-based pitch synthesis. A two-stage reaction process was performed based on different reaction pressure conditions. Each stage experiments for the two-stage reaction were consecutively carried out. The first stage was consisted of three different pressure conditions; high (10 bar), normal and low (0.1 bar). And the second stage was carried out at the normal and low (0.1 bar) pressure. The pitch synthesis was realized at $400^{\circ}C$ for 2 h. Thermal properties and molecular weight distributions of each samples were investigated by analyzing the softening point and MALDI-TOF data. Volatilized components during the pith synthesis were measured by GC-SIMDIS. In case of the first-step reaction with the high pressure condition, the low molecular weight component participated to the pitch formation more effectively and the pitch with the low softening point was obtained. However, for the case of the first-step with the low pressure, the low molecular weight component was vent outside and the partial coke formation occurred. Eventually, pitch properties such as the softening point and yield were controlled effectively by changing the pressure in the pitch synthesis reaction.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.22 no.3
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• pp.1-14
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• 2019

With a view to developing a database of death years of Korean firs (Abies koreana) at Yeongsil in Mt. Halla and investigating their abrupt inter-annual growth reduction tree-ring analysis was employed. To this end, 10 living trees (YSL) were selected to establish a master chronology and 20 dead trees were used to date their dead years. To investigate the difference in death years by death types, 10 trees, which remained standing (YSSD) out of the 20 dead trees were selected. The rest 10 dead trees were already fallen (YSFD). Two increment cores per tree at breast height were extracted in contour direction using an increment borer. A 106-year master chronology (1911-2016) was successfully established from the 10 YSLs. Through cross-dating between individual YSSD time series and the master chronology, it was verified that 1 YSSD was dead in summer 1978, 1 YSSD between autumn 1999 and spring 2000, 2 YSSDs in summer 2007, 1 YSSD in summer 2010, 1 YSSD in summer 2012, and 1 YSSD in summer 2013. The youngest tree rings of 2 YSSDs having no bark were in 1977 and 2002. For the YSFDs, it was verified that 1 YSFD was dead between autumn 1997 and spring 1998, 1 YSFD between autumn 2001 and spring 2002, 2 YSFDs between autumn 2009 and spring 2010, 1 YSFD in summer 2010, and 2 YSFDs between autumn 2012 and spring 2013, while the youngest tree rings of 2 YSFDs having no bark were in 1989 and 2004. To note, the death years of two trees, one from each death type (YSSD and YSFD), could not be verified due to poor cross-dating with the master chronology. The inter-annual growth reductions of YSSD and YSFD occurred more frequently and intensively than YSL. Typically, the YSFD showed the most frequent and intensive inter-annual growth reduction. On comparing the inter-annual growth reductions with the corresponding records of typhoons however we could not find any reliable relationship. Finally, from prior reports and results of the current study it can be concluded that the death and abrupt growth reduction of korean fir at Yeongsil in Mt. Halla are not caused by only a certain environmental factor but various factors.