[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.14478/ace.2021.1061

The Characteristics of Diisopropyl Methylphosphonate Adsorption on Zirconium-based Metal Organic Frameworks Manufactured by using Different Acids as Modulators

Jang, Wonhyeong (Nuclear & WMD Protection Research Center, Korea Military Academy)
Kim, Honghyun (Nuclear & WMD Protection Research Center, Korea Military Academy)
Jeong, Sangjo (Nuclear & WMD Protection Research Center, Korea Military Academy)

Publication Information

Applied Chemistry for Engineering / v.32, no.5, 2021 , pp. 524-531 More about this Journal

Abstract

Depending on the type and amount of acid used as a modulator in the manufacturing process, the structural properties of UiO-66 can be modified and the adsorbability of chemical warfare agents can be enhanced. In this study, several acids as a modulator were used to synthesize UiO-66. Their properties were analyzed with FT-IR, XRD, titrator, and adsorption isotherms using chemical warfare agent simulant, DIMP. The UiO-66, structurally damaged by hydrochloric acid as a modulator, showed lower crystallinity and DIMP adsorption capacity and also smaller specific surface area and volume of voids compared to those of UiO-66, which was manufactured using acetic acid, and formic acid as a modulator. Additionally, UiO-66 which was synthesized by adding formic acid and hydrochloric acid as a modulator, showed the highest DIMP adsorption capacity and is likely to be used as an adsorbent for chemical warfare agent in the future.

Keywords

Metal organic frameworks; UiO-66; Chemical warfare agents; Adsorption; DIMP;

Citations & Related Records

Reference

1	Z. Hasan and S. H. Jhung, Removal of hazardous organics from water using metal-organic frameworks (MOFs): plausible mechanisms for selective adsorptions, J. Hazard. Mater. 283, 329-339 (2015). DOI
2	J. Qiu, Y. Feng, X. Zhang, M. Jia, and J. Yao, Acid-promoted synthesis of UiO-66 for highly selective adsorption of anionic dyes: Adsorption performance and mechanisms, J. Colloid Interface Sci. 499, 151-158 (2017). DOI
3	A. Mott and R. Peter, Calculated infrared spectra of nerve agents and simulants, Spectrochim. Acta A: Mol. Biomol. Spectrosc. 91, 256-260 (2012). DOI
4	R. C. Klet, Y. Liu, T. C. Wang, J. T. Hupp, and O. K. Farha, Evaluation of Bronsted acidity and proton topology in Zr-and Hf-based metal-organic frameworks using potentiometric acidbase titration, J. Mater. Chem. A 4, 1479-1485 (2016). DOI
5	C. G. Piscopo, F. Trapani, A. Polyzoidis, M. Schwarzer, A. Pace, and S. Loebbecke, Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metalorganic frameworks, New J. Chem. 40, 8220-8224 (2016). DOI
6	J. H. Cavka, S. Jakobsen, U. Olsbye, N, Guillou, C, Lamberti, S, Bordiga, and K. P. Lillerud, A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability, J. Am. Chem. Soc. 130, 13850-13851 (2008). DOI
7	T. F. Liu, N. A. Vermeulen, A. J. Howarth, P. Li, A. A. Sarjeant, J. T. Hupp, and O. K. Farha, Adding to the arsenal of zirconium-based metal-organic frameworks: the Topology as a platform for solvent-assisted metal incorporation, Eur. J. Inorg. Chem. 2016, 4349-4352 (2016). DOI
8	M. J. Katz, Z. J. Brown, Y. J. Colon, P. W. Siu, K. A. Scheidt, R. Q. Snurr, J. T. Hupp, and O. K. Farha, A facile synthesis of UiO-66, UiO-67 and their derivatives, Chem. Comm. 49, 9449-9451 (2013). DOI
9	G. Hu, W. Xiong, H. Luo, H. Shi, Z. Li, J. Shen, X. Fang, B. Xu, and J. Zhang, Raman spectroscopic detection for simulants of chemical warfare agents using a spatial heterodyne spectrometer, Appl. Spectrosc. 72, 151-158 (2018). DOI
10	S. Lin, J. K. Bediako, C. Cho, M. Song, Y. Zhao, J. Kim, J. Choi, and Y. Yun, Selective adsorption of Pd(II) over interfering metal ions (Co(II), Ni(II), Pt(IV)) from acidic aqueous phase by metal-organic frameworks, Chem. Eng. J. 345, 337-344 (2018). DOI
11	S. I. Kim, T. U. Yoon, M. B. Kim, S. J. Lee, Y. K. Hwang, J. S. Chang, H. J. Kim, H. N. Lee, U. H. Lee, and Y. S. Bae, Metal-organic frameworks with high working capacities and cyclic hydrothermal stabilities for fresh water production, Chem. Eng. J. 286, 467-475 (2016). DOI
12	H. Ogawa, T. Chihara, S. Teratani, and K. Taya, Infrared spectrum of terephthalic acid adsorbed on alumina surface, Bull. Tokyo Gakugei Univ. Sect IV 40, 51-55 (1988).
13	L. G. Wade, Organic chemistry, 8th ed., Pearson, London, UK (2012).
14	C. H. Lau, R. Babarao, and M. R. Hill, A route to drastic increase of CO₂ uptake in Zr metal organic framework UiO-66, Chem. Comm. 49, 3634-3636 (2013). DOI
15	A. Schaate, P. Roy, A. Godt, J. Lippke, F. Waltz, M. Wiebcke, and P. Behrens, Modulated synthesis of Zr-based metal-organic frameworks: From nano to single crystals, Chem. Eur. J. 17, 6643-6651 (2011). DOI
16	S. R. Ryu, I. Noda, and Y. M. Jung, What is the origin of positional fluctuation of spectral features: true frequency shift or relative intensity changes of two overlapped bands? Appl. Spectrosc. 64, 1017-1021 (2010). DOI
17	X. Cheng, X. Jiang, Y. Zhang, C. H. Lau, Z. Xie, D. Ng, S. J. Smith, M. Hill, and L. Shao, Building additional passageways in polyamide membranes with hydrostable metal organic frameworks to recycle and remove organic solutes from various solvents, ACS Appl. Mater. Interfaces 9, 38877-38886 (2017). DOI
18	J. B. DeCoste and G. W. Peterson, Metal-organic frameworks for air purification of toxic chemicals, Chem. Rev. 114, 5695-5727 (2014). DOI
19	R. C. Gupta, Handbook of Toxicology of Chemical Warfare Agents, 2nd ed., Elsevier, Amsterdam, Netherlands (2015).
20	J. P Ruffley, I. Goodenough, T. Y. Luo, M. Richard, E. Borguet, N. L. Rosi, and J. K. Johnson, Design, synthesis, and characterization of metal-organic frameworks for enhanced sorption of chemical warfare agent stimulants, J. Phys. Chem. C 123, 19748-19758 (2019). DOI
21	G. Lu, C. Cui, W. Zhang, Y. Liu, and F. Huo, Synthesis and self-assembly of monodispersed metal-organic framework microcrystals, Chem. Asian J. 8, 69-72 (2013). DOI
22	A. J. Howarth, Y. Liu, P. Li, Z. Li, T. C. Wang, J. T. Hupp, and O. K. Farha, Chemical, thermal and mechanical stabilities of metal-organic frameworks, Nat. Rev. Mater. 1, 15018 (2016). DOI