• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.32 no.10
• /
• pp.93-101
• /
• 2004

A method to calculate stability limits is investigated to predict the characteristics of high-frequency combustion instability in liquid-propellant rocket engine. It is based on the theory of linear stability analysis proposed in previous works and useful to predict combustion stability at the beginning stage of engine development. The system of equations governing reactive flow in combustor has the simplified and linearized forms. The overall equation expressing stability limits is adopted. The procedures to evaluate quantitatively each term included in the equation are proposed. The thermo-chemical properties and flow variables required in the evaluation can be obtained from calculation of thermodynamic equilibrium, CFD results, and experimental test data. Based on the existent data, stability limits are calculated with actual rocket engine (KSR-III rocket engine). The present calculations show the reasonable stability limits in a quantitative manner and the stability characteristics of the engine are discussed. The prediction from linear stability analysis could be serve as the first approximation to the true prediction.

• Resources Recycling
• /
• v.17 no.2
• /
• pp.63-69
• /
• 2008

The adsorption features of $Ni^{2+}$ onto spent alkaline manganese batteries powder have been investigated with the adsorbent dose, initial concentration of adsorbate and temperature as the experimental variables. The adsorption reaction of $Ni^{2+}$ ion followed the pseudo-second order rate model, and the adsorption rate constants($k_2$) decreased with increasing initial concentration of nickel ion. The equilibrium adsorption data were fitted to the Langmuir and Freundlich models. The Freundlich model represents the equilibrium data better than the Langmuir model in this initial adsorbate concentration range. As the temperature increased, the adsorbed amount of nickel ion at equilibrium was also increased, which indicated that the adsorption reaction was endothermic. Based on the experimental results obtained along with temperatures, thermodynamic parameters such as ${\Delta}H^{\circ},\;{\Delta}G^{\circ},\;and\;{\Delta}S^{\circ}$ were calculated.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.16 no.11
• /
• pp.2196-2202
• /
• 1992

The optimum size combination of heat exchangers in a Joule-Thomson(J-T) circuit for small cryogenic systems has been sought analytically, when the circuit is combined with a two-stage Gifford-McMahon(GM) cooler. Full thermodynamic cycle analysis was carried out to predict the performance of the combined refrigeration system. Relevant convective heat transfer coefficients, the computerized properties of helium, and the refrigeration capacity curve of a typical GM cooler have been used in the analysis. The result showed that, by changing the configuration(heat exchanger area ratio) of the system, the performance of the commonly-used GM/J-T refrigerators could be optimized. For the maximum refrigeration performance, the optimum mass flow rate of the refrigerant and the relative size between the heat exchangers have been obtained, when the cooling load was 0.1W at 3.995K with the total heat exchanger area being given.

• Applied Chemistry for Engineering
• /
• v.18 no.2
• /
• pp.136-141
• /
• 2007

The decomposition of chlorinated methanes including $CCl_4$, $CCl_3H$, and $CCl_2H_2$ was carried out using a thermal plasma process and the characteristics of the process were investigated. The thermal equilibrium composition was analyzed with temperature by Fcatsage program. The decomposition rates at various process parameters including the concentration of reactants, flow rate of carrier gas, and quenching rate, were evaluated, where sufficiently high conversion over 92% was achieved. The generation of main products was strongly influenced by the reaction atmosphere; carbon, chlorine, and hydrogen chloride at neutral condition; carbon dioxide, chlorine, and hydrogen chloride at oxidative condition. The decomposition mechanism was speculated considering the results from Factsage and the identification of generated radicals and ionic species. The main decomposition pathways were found to be dissociative electron attachment and oxidative by radicals formed in a plasma state.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.1 no.2
• /
• pp.74-83
• /
• 1997

The definition of burning admittance and conventional n-$\tau$ stability rating technique are combined to investigate the high frequency combustion instabilities inside the cylindrical combustion chamber. Perturbed flow variables are written as the sum of fluctuating and time-averaged mean quantities on the assumption that the terms of the order higher than unity are sufficiently small, hence linearized governing equations could be formulated. Chamber admittances up and downstream of the flame front calculated with appropriate boundary conditions result in the burning admittance and corresponding n-$\tau$ neutral stability curve. Configurational and operational design factors are tested to detect the unstable wave-induced LOX-RP1 combustion instabilities. Operational design factors, e.g. pressure or O/F ratio, appear less influential to drive high frequency instability while the location of the flame front and configurational factors enhance or deteriorate the stabilities strongly. Conclusively, LOX-RP1 combustion inside the cylindrical combustion chamber is apt to be unstable against long residence time and shortened chamber length.

• Nuclear Engineering and Technology
• /
• v.28 no.2
• /
• pp.103-117
• /
• 1996

A mathematical model of vapor explosion propagation is presented. The model predict two-dimensional, transient flow fields and energies of the four fluid phases of melt drop, fragmented debris, liquid coolant and vapor coolant by solving a set of governing equations with the relevant constitutive relations. These relations include melt fragmentation, coolant-phase-change, and heat and momentum exchange models. To allow thermodynamic non-equilibrium between the coolant liquid and vapor, an equation of state for oater is uniquely formulated. A multiphase code, TRACER, has been developed based on this mathematical formulation. A set of base calculations for tin/water explosions show that the model predicts the explosion propagation speed and peak pressure in a reasonable degree although the quantitative agreement relies strongly on the parameters in the constitutive relations. A set of calculations for sensitivity studies on these parameters have identified the important initial conditions and relations. These are melt fragmentation rate, momentum exchange function, heat transfer function and coolant phase change model as well as local vapor fractions and fuel fractions.

• Applied Chemistry for Engineering
• /
• v.29 no.4
• /
• pp.369-375
• /
• 2018

Batch experiments were conducted to investigate the effects of operating parameters such as the temperature, initial concentration, contact time and adsorbent dosage on the adsorption of antibiotics amoxicillin (AMX) by waste citrus peel based activated carbon (WCAC). The kinetics and isotherm experiment data can be well described with the pseudo-second order model and the Langmuir isotherm model, respectively. The maximum adsorption capacity of AMX by WCAC calculated from the Langmuir isotherm model was 125 mg/g. The adsorption of AMX by WCAC shows that the film diffusion (external mass transfer) and the intraparticle diffusion occur simultaneously during the adsorption process. The adsorption rate is more influenced by the intraparticle diffusion than that of the external mass transfer as the particle size of WCAC increases, and the intraparticle diffusion is the rate controlling step. The thermodynamic parameters indicated that the adsorption reaction of AMX by WCAC was an endothermic and spontaneous process.

• Journal of Energy Engineering
• /
• v.25 no.4
• /
• pp.85-92
• /
• 2016

Since the power density of the VHTR(Very High Temperature Reactor) is lower, there is less possibility of core melt. VHTR has no risk of explosion caused by hydrogen generation when the loss of coolant accident occurs, which is another advantage. Along with safety benefit, it can be used as a process heat supplier near demand facilities because coolant temperature is very high enough to be used for industrial purpose. In this paper, we designed the primary system using VHTR and the secondary system providing electricity and process heat. Based on that 350 MW thermal reactor proposed by NGNP(Next Generation Nuclear Part), we developed conceptual model that the IHX(Intermediate Heat Exchanger) loop transports 300 MW thermal energy to the secondary system. In addition, we analyzed thermodynamic behavior and performed the efficiency analysis and optimization study depending on major parameters.

• Korean Chemical Engineering Research
• /
• v.55 no.6
• /
• pp.771-777
• /
• 2017

Adsorption characteristics of Eosin Y dye by carbon nano tubes (CNTs) were examined through batch experiments. CNTs used in the study had specific surface area of $106.9m^2/g$, porosity volume of $1.806cm^3/g$, and porosity diameter of $163.2{\AA}$, respectively. Adsorption experiments were carried out as function of contact time, initial solution pH (2~10), dye concentration (100, 150 and 200 mg/L), adsorbent dose (0.05~1.0 g) and temperature (293, 313 and 333 K). The adsorption was favoured at lower pHs and temperatures. Adsorption data were well described by the Langmuir model. The adsorption process followed the pseudo-second order kinetic model. The adsorption capacity decreased with increase in temperature. The results of the intraparticle diffusion model suggested that film diffusion and particle diffusion were simultaneously occured during the adsorption process. Thermodynamic studies suggested the spontaneous and endothermic nature of adsorption of Eosin Y dye onto CNTs.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2003.05a
• /
• pp.258-261
• /
• 2003

The optimal design and combustion analysis of the gas generator for Liquid Rocket Engine (LRE) were performed. A fuel-rich gas generator in open cycle turbopump system was designed for 101on1 in thrust with RP-1/LOx combination. The optimal design was done for maximizing specific impulse of main combustion chamber with constraints of combustion temperature and power matching in turbopump system. Results of optimal design show the dimension of length, diameter, and contraction ratio of gas generator. The configuration of the gas generator and the condition for performance which can maximize the objective function were determined and found to meet the design constraints. Also, the combustion analysis was conducted to evaluate the performance of designed chamber and injector of gas generator. And the effect of the turbulence ring was investigated on the mixing enhancement in the chamber.