• Journal of the Korean Geotechnical Society
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• v.30 no.1
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• pp.93-101
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• 2014

In this study, a blast furnace slag having latent hydraulic property with an alkaline activator for resource recycling was used to solidify sand without using cement. Existing chemical alkaline activators such as $Ca(OH)_2$ and NaOH were used for cementing soils. An alkaliphilic microorganism, which is active at higher than pH 10, is tested for a new alkaline activator. The alkaliphilic microorganism was added into sand with a blast furnace slag and a chemical alkaline activator. This is called the microorganism alkaline activator. Four different ratios of blast furnace slag (4, 8, 12, 16%) and two different chemical alkaline activators ($Ca(OH)_2$ and NaOH) were used for preparing cemented specimens with or without the alkaliphilic microorganism. The specimens were air-cured for 7 days and then tested for the experiment of unconfined compressive strength (UCS). Experimental results showed that as a blast furnace slag increased, the water content and dry density increased. The UCS of a specimen increased from 178 kPa to 2,435 kPa. The UCS of a specimen mixed with $Ca(OH)_2$ was 5-54% greater than that with NaOH. When the microorganism was added into the specimen, the UCS of a specimen with $Ca(OH)_2$ decreased by 11-60% but one with NaOH increased by 19-121%. The C-S-H hydrates were found in the cemented specimens, and their amounts increased as the amount of blast furnace slag increased through SEM analysis.

• Journal of the Korea Concrete Institute
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• v.24 no.6
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• pp.745-752
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• 2012

This paper studies the effect of the compressive strength for combined alkali-activated slag mortars. The effect of activators such as alkali type and dosage factor on the strength was investigated. The alkalis combinations made using five caustic alkalis (sodium hydroxide (NaOH, A series), calcium hydroxide ($Ca(OH)_2$, B series), magnesium hydroxide ($Mg(OH)_2$, C series), aluminum hydroxide ($Al(OH)_3$, D series), and potassium hydroxide (KOH, E series)) with sodium carbonate ($Na_2CO_3$) were evaluated. The mixtures were combined in different dosage at 1M, 2M, and 3M. The study results showed that the compressive strength of combined alkali-activated slag mortars tended to increase with increasing sodium carbonate. The strength of combined alkali-activated slag mortars was better than that of control cases (without sodium carbonate). The result from scanning electron microscopy (SEM) analysis confirmed that there were reaction products of calcium silicate hydrate (C-S-H) and alumina-silicate gels from combined alkali-activated slag specimens.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.397-398
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• 2009

Recently, the research about alkaline activity concrete is being progressed actively. In this paper, the effect of many kinds of alkaline activation to fly ash based cement zero mortar is examined.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.1
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• pp.29-36
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• 2017

The purpose of this study is to investigate experimentally the effect of types of alkali-activators and curing conditions on the compressive and tensile behavior of fiber-reinforced cementless composites. Two types of alkali-activators and two curing conditions were determined and density test, compressive strength test, and uniaxial tension test were performed. Test results showed that the cementless composite with sodium silicate showed higher performance in terms of strength, tensile strain capacity, and toughness than that with calcium hydroxide and sodium carbonate. The effect of curing conditions depends on the types of alkali-activators.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.6
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• pp.26-33
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• 2012

This paper reported on the effect of blended activator on the physical properties of alkali-activated slag mortar. Five different activators(caustic alkalis) were used: sodium hydroxide(NaOH, A Case), calsium hydroxide($Ca(OH)_2$, B Case), magnesium hydroxide($Mg(OH)_2$, C Case), aluminum hydroxide($Al(OH)_3$, D Case), and potassium hydroxide(KOH, E Case). We blended five caustic alkalis with sodium carbonate($Na_2CO_3$). The dosage of five caustic alkalis was 3M and sodium carbonate was 1M, 2M and 3M. The result of flow and setting time was decrease as the dosage of sodium carbonate increase. But the compressive strength was increase as the dosage of sodium carbonate increase. It was shown that there is a good effect of blended caustic alkalis with sodium carbonate in alkali-activated slag mortar.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.4
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• pp.152-158
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• 2007

This is a fundamental research to utilize alkali activated cement(AAC) in concrete. The compressive strength of AAC concrete were measured for the various mixing ratios of activator/fly ash, and the mixing ratios of water glass, NaOH, and water among the activators. The mixing ratio of fine and coarse aggregates was maintained constantly. The relationships between the compressive strength and mixing ratios were analyzed to find the optimal mixing ratio of AAC concrete. As the results, the optimal mixing ratio of activator/fly ash in AAC concrete was 0.7, and that of water glass, NaOH, water among the activator was 4.0:1.0:2.5 for the maximum compressive strength.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.2
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• pp.159-167
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• 2022

The present study assessed the micro structure and durability characteristics of ternary blended cement with different types of alkali activators. Ground granulated blast furnace slag(GGBS) and ferronickel slag(FNS) was replaced until 50 % of the weight of cement. In addition, potassuim hydroxide and sodium hydroxide were used for comparing the properties of different type of alkali activator. Ternary blended cement with alkali activators showed higher peak portlandite peak than that of OPC(Ordinary Portlande Cement) and non activated ternary blended cement. Also, there was no new hydration products in ternary blended cement or/and alkali activators. Based on the mercury intrustion porosimetry(MIP) test result, ternary blended cement increased macro pore while alkali activated ternary blended cement modified pore structure and increased microp pore as compared to OPC as control. Combination with alkali activators is desirable to enhance the compressive strength and freeze thaw resistance.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.1
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• pp.33-40
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• 2013

The cement industry brought very severe environment problems with massive carbon dioxide during its production. To solve this problem, attempts on Alkali-Activated Slag (AAS) concrete that perfectly substitutes industrial by-products such as ground granulated blast furnace slag (GGBFS) for cement are being actively made. AAS concrete is possible to have high strength development at room temperature, however, it is difficult to ensure the working time due to the fast setting time and the loss of workabillity because of the alkali reaction. In this study, the early age properties of alkali activated slag mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The water-binder ratio (W/B) was fixed at 0.35 and sodium hydroxide and waterglass as alkali activator was used. The compressive strength, the flow and the ultrasonic pulse velocity were measured according to the type of superplasticisers, which were naphthalene(N), lignin(L), melamine(M) and PC(P), up to a maximum of 2 percent by the mass of GGBFS. The results showed that adding melamine type of superplasticizer improved the fluidity of AAS mortar without decreasing the compressive strength, while naphthalene and polycarbonate type of superplasticizer had little effect on the fluidity of AAS mortar.

• Journal of the Korea Concrete Institute
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• v.27 no.3
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• pp.311-317
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• 2015

Cement zero concrete produced by alkali-activators and industrial by-products such as slag instead of cement, enables to solve the environmental pollution problems provoked by the exhaustion of natural resources and energy as well as the discharge of carbon dioxide. However, researches on the cement zero concrete are still limited to material studies and thus, study on the structural behavior of relevant members is essential to use the cement zero concrete as structural materials. This paper aims to evaluate experimentally and analytically the flexural behavior of RC beams using 50 MPa alkali activated slag concrete. To achieve such a goal, flexural tests on three types of RC beam specimens were conducted. A nonlinear analysis model is proposed using the modulus of elasticity and stress-strain relationship of alkali activated slag concrete. The analysis results obtained by the proposed model agree well with the experimental results, which could verify the validity of the proposed model.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.1
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• pp.58-63
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• 2015

Several researches on cement zero concrete using alkali-activators have been conducted to investigate its fundamental material properties such as slump, strength and durability, however, research on the structural behavior of relevant members involving the elastic modulus, stress-strain relationship is essential for the application of this cement zero concrete to structural members. In this paper the shear behavior of reinforced concrete beams using 50 MPa-alkali activated slag concrete was experimentally evaluated. To achieve such a goal, six reinforced concrete beam specimens were fabricated and their shear behaviors were observed. The maximum difference between test results and analysis results in crack shear stress for beam specimens without stirrups is 31%, while that for beam specimens with stirrup is 15%. Furthermore, it is also found that the shear strength of alkali activated slag concrete is by 22~57% greater than the nominal shear strength calculated by design code, implying that shear design equations would provide conservative results on the safety side.