• Proceedings of the KAIS Fall Conference
• /
• 2007.11a
• /
• pp.341-343
• /
• 2007

본 연구개발에서는 은나노를 포함한 비오염성 석재용 실리콘 실란트를 제조하였다. 기본적인 실리콘 실란트 Formulation에 오일에 의한 오염성을 최소화하기 위해 편말단 폴리머를 사용하였다. 폴리머 가교를 통해 접착성과 작업성 등의 물성을 향상시켰으며, 나노크기의 은 powder를 사용하여 항균성을 부여하였다. 가장 큰 관건은 nano size의 은을 가장 균일하게 실란트에 분산시키는 것이 실란트 제품화의 주요 기술이었다.

• Proceedings of the KAIS Fall Conference
• /
• 2008.05a
• /
• pp.309-312
• /
• 2008

We have prepared the silicone sealant using non silicone oil without silicone oil for solvent and using adhesion promotor against various substrate. We are replaced the silicone oil by the mineral oil and the normal adhesion promotor by mixed adhesion promotor at the multi purpose silicone sealant.

• Journal of Adhesion and Interface
• /
• v.2 no.4
• /
• pp.1-9
• /
• 2001

Silicone sealants are composed of polymer, plasticizer, crosslinker, catalyst and filler. Types and compositions of components are effected on sealant performances. In recent, use of alkoxy type silicone sealant increased due to environmental advantage. In this study, we investigated effects of component types and ratios on one-part room temperature curable alkoxy type silicone sealant preparation and adhesion properties. Alkoxy type silicone sealants were prepared with various PDMS (polydimethylsiloxane) viscosities. In addition, the effect of plasticizer, crosslinkers, and catalyst on sealant obtained from by mixture of PDMS viscosities of 20000 and 80000 was investigated. Reaction temperature on change of mixing time was observed, and then proper crosslinking systems were found. Adhesion (properties) of silicone sealants were measured. In the sealants preparation, stable reaction was achieved by adjusting composition variance ratio in the sealant mixture temperature below $40^{\circ}C$. The adhesion properties of sealant differ from substrate composition. The order of adhesion strength was glass/glass > glass/aluminum > aluminum/aluminum system. The elongation of sealant was increased as polymer viscosity and plasticizer content increased. The strength was increased as crosslinker and plasticizer decreased, while catalyst increased.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2014.11a
• /
• pp.75-77
• /
• 2014

Using sealant for window installation is sealing the gap between the window frame and outer wall (such as concrete). A sealant serves to prevent external environmental impacts such as moisture, rain, sand, and dust entering inside of the building and make the building durable. In order to fulfill basic jointing function of sealing, at least 6 mm joint gap between two bonding surfaces are required. Also, adhesion performance between sealant and surfaces and the compatibility with other building materials are required to check before installation. In general, 2 part polyurethane sealant and 1 part silicone sealant are most common materials for sealing the joint of window. In this study, adhesion performances of those two generic sealants reflecting actual application conditions and the compatibility evaluations with other building materials are conducted to propose proper window installation procedures.

• Journal of the Korea Institute of Building Construction
• /
• v.24 no.1
• /
• pp.43-53
• /
• 2024

This research undertook the assessment of six types of silicone sealants prepared. Their resistance to fungi was evaluated according to ASTM G 21, LH specification(LHCS 41 40 12), and the newly instituted KS F ISO 21265 test methods. The findings showed that KS F ISO 21265 test method exhibited the superior discriminative capability in assessing fungal resistance when compared to ASTM G 21 and LH specification(LHCS 41 40 12) test methods. Additionally, it was confirmed that oxime curing sealants demonstrated higher fungal resistance than alkoxy curing sealants. Furthermore, The introduction of a condition to assess fungal resistance after 4 weeks of immersion at 50℃ in KS F ISO 21265 is expected to enable long-term fungal resistance evaluation of sealants.

• 한국도로학회:학술대회논문집
• /
• 2010.09a
• /
• pp.211-216
• /
• 2010

• Polymer(Korea)
• /
• v.31 no.1
• /
• pp.86-91
• /
• 2007

Polydimethylsiloxane branched HEMA (SH) was Prepared by reacting polydimethylsilorane prepolymer and 2-hydroxyethyl methacrylate (HEMA). Polyacrylate modified Polyorganosiloxane (SMPA) was prepared by polymerization of methacrylic acid(MA), allyl glycidyl ether(AGE), aminopro- pyltrimethoxysilane (APTS), and SH. Their structures were confirmed by the measurement of FTIR and $^1H-NMR$ and thermal properties of SMPA were studied from TGA. Residual weight of SMPA at $400^{\circ}C$ increased according to increasing content of the APTS to 63 from 55%. SMPA sealant was prepared by adding additives, such as viscosity increasing agent, crosslinking agent, and fillers. Adhesion characteristics of SMPA-3 sealant was determined to be maximum load elongation, 2.01 %, and break load elongation, 2.28%. Adhesion characteristics for SMPA sealant prepared from SMPA-3 were better than those for SMPA sealant prepared from SMPA-1 and SMPA-2.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2014.11a
• /
• pp.63-64
• /
• 2014

In this study, we has a purpose to estimate the joint movement responsiveness performance for the domestic products of one-component structural silicon sealants. For this purpose, we make a comparative study for the four domestic products focused on tensile properties after allowed the cyclic-movements for three days at initial step of curing phase. A joint movement range ±10% and the rate of compression and extension 3.2mm/h were assumed in those tests. As a result, the large space were induced inside the sealant by rupture, and then adhesion and cohesion failures were caused by stress concentration. The tensile properties were reduced by 15~60% in comparison with physical properties. In this case, the generating defect was caused and the service-life was decreased. Thus, further researches as relationship of test condition and products properties on this behavior would be studied.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
• /
• 2010.10a
• /
• pp.37-41
• /
• 2010

스프링클러설비와 방화구획 구성요소는 화재시 매우 중요한 역할을 한다. 그러나 기존에 15층이하 아파트는 스프링클러설비가 없어 화재시 방화구획에 의존해야 되는데 방화구획 관련 설계, 시공, 감리가 미비하여 화재에 쉽게 노출되어 있다. 설비슬리브, 전선관, 덕트등이 방화구획으로 되어 있는 부분을 관통하는 경우 그틈을 시멘트모르타르나 기타 불연재료로 메우도록 규정하고 있으나 화재발생시 관통부를 메운 재료의 내화성능 부실, 균열, 탈락 등으로 화재안전성이 떨어진다. 현장에서의 설계, 시공, 감리등 대응하는 자세가 너무 허술하다. 설계에 방화댐퍼, 관통부 틈새의 내용이 반영 되지 않고 건축, 기계, 전기, 통신, 소방등 각 분야의 허가 도면에 도장이 날인되어 나타난다. 시공자는 잘못된 설계도면을 가지고 허가 도면이라며 도면되로 시공한다. 또한 실리콘, 우레탄폼등을 방화구획 관통부 틈새에 주입하며, 작업자도 비숙련자로서 개념도 없이 방화용실란트와 우레탄폼을 혼용해가며 작업을 한다.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.9
• /
• pp.279-287
• /
• 2018

Sealants are an important element of modern architecture and serve as a building protection against weathering by providing barriers against ingress of moisture, air, and other materials. Exposure to a variety of environments often reduces lifespan due to changes in physical, chemical and mechanical characteristics, and UV, humidity, and temperature expansion are important issues that are directly related to durability. In this study, a combined deterioration test chamber was developed to simulate the environment of the open air as an instrument for verifying the durability of structural sealing materials indoors. In order to replicate special weather conditions, such as yellow dust, acid rain, and contamination by microorganisms, it was deemed impossible to replicate the outdoor environment by 100 %, and the results of the results of the results of the external exposure test of the structural sealant and the combined deterioration testing device. As a result of the displacement test of the outdoor exposure test, it was determined that the sealant was breaking apart and that it would be smooth, and the displacement would be up to three times greater than the initial material value of 1 year. The displacement test results of the combined deterioration test device show the tendency to deteriorate, decreasing the elasticity and tensile characteristics. In the case of denatured silicon, the current 400 cycles have been completed to confirm 12 months of degradation of the external exposure. The deformation of the test specimen cannot be verified with the naked eye, so it is considered that the conditions of the specimen are more stable than the silicon sealant. As a result of the outdoor exposure test, if the combined deterioration test device is structured and proposed in the relevant guidance or specification, the anticipated lifespan of 12 months in the actual use environment can be verified indoors and below 3 months later, economically.