• Title/Summary/Keyword: 시멘트계

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Improvement of the Quality on High Volume Fly-Ash Concrete Corresponding to the Addition of Various Admixtures (각종 혼합재료의 첨가에 따른 플라이애쉬 다량 사용 콘크리트의 초기품질 향상)

  • Lee, Ju-Sun;Pei, Chang-Chun;Ryu, Gum-Sung;Koh, Kyung-Taek;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.737-740
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    • 2008
  • This study, with the purpose for early quality improvement of concrete which used large quantity of fly ash, changed various admixture material type and reviewed the basic characteristics. First off, the flow overall was highest when polycarb onic Acid high early strength AE water reducing agent was displaced, while air amount satisfied target level only in the case of plain, and setting time was shown best by getting 30 more minutes than plain and about 3 more hours than conventional when KOH is displaced. Compressive strength was shown best at age 1 day and 3 days when KOH was displaced, and at age 28 days when fine particle cement was displaced. By and large, this study concludes that concrete quality improvement admixture material that used large amount of fly ash showed worse effects than plain, therefore it is determined that there need be more study for development of concrete early quality improvement admixture material that used large amount of fly ash.

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An Experimental Study on Compression Strength and Carbonation Resistance for Ternary High-Performance Concrete with fly-sah, granulated blast furnace (플라이애쉬와 고로슬래그를 사용한 3성분계 고성능 콘크리트의 강도 및 촉진 중성화에 대한 실험적 고찰)

  • Kwon, Young-Rak;Kim, Hong-Sam;Lee, Chang-Young;Cheng, Hai-Moon;Ahn, Tae-Song
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.445-448
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    • 2008
  • It is essential that concrete component is made up with aggregate, cement and water. But today, Public concern is increasing of a variety structure and ocean environmental, resource recycle. Also, According to heat of hydration rising, Concrete is make a causative of concrete-crack. Concrete-crack cause a falling-off in quality of concrete. consequently, High-performance concrete is evaluated by concrete material properties and carbonation resistance with different admixture(fixing fly-ash 20%), granulated blast furnace slag replacement ratio (30%, 45%) different W/B (26%, 30%, 34%) and XRD(X-ray Diffraction) analysis.

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Properties of Reaction Rim on Blast Furnace Slag Grain with Alkali Activator according to Hydration Reaction (알칼리 자극제(刺戟劑)에 의해 고로(讀爐) 수쇄(水碎) 슬래그의 주위(周圍)에 형성(形成)된 Reaction Rim의 특성(特性))

  • Lee, Seung-Heun;Mun, Young-Bum
    • Resources Recycling
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    • v.18 no.3
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    • pp.42-48
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    • 2009
  • Since there are $OH^-,\;[SiO_4]^{4-}$ ion of high concentration at early hydration in the system added with activator (NaOH+$Na_2OSiO_2$) in the blast furnace slag, different from cement hydration, hydration progresses fast without induction period and forms reaction rim around the blast furnace slag grain. $0.6{\mu}m$ reaction rim was formed around the blast furnace slag grain from the 1 day of reaction period, and the thickness of reaction rim increases over the reaction time, growing to $1{\mu}m$ on the 28 days. Unreacted blast furnace slag grain deformed from angular shape to the spherical shape. Mole ratio of Ca/Si tends to decrease from inside of blast furnace slag grain to reaction rim. Difference of Ca/Si mole ratio between reaction rim and inside the blast furnace slag grain decreased and generated hydrate was a poor crystalline CSH(I) with Ca/Si mole ratio less than 1.5.

Characteristics of Carbon Capture by the Accelerated Carbonation Method of Circulating Fluidized Bed Combustion Ash (순환 유동층 보일러 애시의 촉진탄산화에 의한 탄소포집 특성)

  • Choi, Young-Cheol;Yoo, Sung-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.165-172
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    • 2021
  • The purpose of this study is to investigate the carbon capture capacity of various inorganic materials. For this purpose, the change in property of ordinary Portland cement (OPC), blast furnace slag fine powder (GGBS), and circulating fluidized bed boiler ash (CFBC) due to carbonation were analyzed. Carbonation curing was performed on all specimens through the accelerated carbonation experiment, and the amount of carbon capture was quantitatively analyzed by thermogravimetric analysis according to the age of carbonation. From the results, it is confirmed that the carbon capture capacity was shown in all specimens. The carbon capture amount was shown in the order of CFBC, OPC, and GGBS. The 28-day carbon capture of CFBC, OPC, and GGBS was 3.9%, 1.3%, and 9.4%, respectively. Carbon capture reaction occurred rapidly at the beginning of carbonation, and occurred slowly with increasing age. SEM image analysis revealed that an additional product generated by carbonation curing in all specimens was calcium carbonate.

Current Status of Lime Bordeaux Mixture Research using Properties of Lime based Minerals (석회계 광물 특성을 활용한 석회보르도액 연구 현황)

  • Kim, Young-Jin;Seo, Jun-Hyung;Kim, Yang-Soo;Cho, Kye-Hong;Cho, Jin-Sang
    • Resources Recycling
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    • v.31 no.3
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    • pp.16-26
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    • 2022
  • Limestone is the largest mineral resource in South Korea and is used in various industries, particularly as a primary raw material in the cement and iron industries. However, research on the utilization of limestone in fields such as agriculture, powder, and green chemistry is severely lacking. In this review, studies concerning the crop antibacterial industry using unslaked or slaked lime produced from limestone were analyzed. Reports regarding lime bordeaux mixture were also considered. By compiling research results, processing technologies for improving the antibacterial efficiency of lime bordeaux mixture are discussed. In addition, plans for the revitalization of research on crop antibacterial agents through the limestone processing industry were summarized.

The Density and Strength Properties of Lightweight Foamed Concrete Using Stone-Powder Sludge in Hydrothermal Reaction Condition (수열반응 조건에서 석분 슬러지를 사용한 경량 기포 콘크리트의 밀도와 강도 특성)

  • Kim, Jin-Man;Jeong, Ji-Yong;Choi, Se-Jin;Kim, Bong-Joo
    • Journal of the Korea Concrete Institute
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    • v.18 no.5 s.95
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    • pp.687-693
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    • 2006
  • The Stone Powder Sludge(below SPS) is the by-product from the process that translates stone power of 8mm under as crushed fine aggregate. It is the sludge as like cake that has average particle size of $7{\mu}m$, absorbing water content of 20 to 60%, and $SiO_2$ content of 60% over. Because of high water content of SPS, it is not only difficult to handle, transport, and recycle, but also makes worse the economical efficiency due to high energy consuming to drying. This study is aim to recycle SPS as it is without drying. Target product is the lightweight foamed concrete that is made from the slurry mixed with pulverized mineral compounds and foams through hydro-thermal reaction of CaO and $SiO_2$. Although in the commercial lightweight foamed concrete CaO source is the cement and $SiO_2$ source is high purity silica powder with $SiO_2$ of 90%, we tried to use the SPS as $SiO_2$ source. From the experiments with factors such as foam addition rate and replacement proportion of SPS, we find that the lightweight foamed concrete with SPS shows the same trends as the density and strength of lightweight foamed concrete increases according to decrease of foam addition rate. But in the same condition, the lightweight foamed concrete with SPS is superior strength and density to that with high purity silica. This trends is distinguished according to increase of replacement proportion of SPS, also the analysis of XRF shows that the hydro thermal reaction translates SPS to tobermorite. Although SPS has low $SiO_2$ contents, the lightweight foamed concrete with SPS has superior strength and density, because it reacts well with CaO due to extremely fine particles. We conclude that it is possible to replace the high purity silica as SPS in the lightweight foamed concrete experimentally.

Mechanical Properties of Granulated Ground Blast Furnace Slag on Blended Activator of Sulfate and Alkali (황산염 및 알칼리계의 혼합 활성화제에 대한 고로슬래그미분말의 역학적 특성)

  • Kim, Tae-Wan;Jun, Yu-Bin;Eom, Jang-Sub
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.5
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    • pp.104-111
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    • 2015
  • This study shows the mechanical properties of alkali-activated slag cement (AASC) synthesized using sulfate with NaOH solution. The used sulfates were calcium sulfate ($CaSO_4$, denoted CS) and sodium sulfate ($Na_2SO_4$, denoted SS). The replacement ratio of sulfates was 2.5, 5.0, 7.5 and 10.0% by weight of slag. NaOH solution of 2M and 4M concentration was used. A sample was activated with sulfate and activated with blended activator (blending NaOH solution with sulfate) respectively. 24 mix ratios were used and the water-binder weight ratio for the test was set 0.5. This research carried out the compressive strength, flexural strength, ultrasonic pulse velocity (UPV), absorption and X-ray diffraction (XRD). In the case of samples with CS, sample with 7.5% CS, sample with 2M NaOH+5.0% CS and sample with 4M NaOH+5.0% CS showed the good performance in the strength development. In the case of samples with SS, sample with 10.0% SS, sample with 2M NaOH+7.5% SS and sample with 4M NaOH+2.5% SS obtained good performance in strength. The results of UPV and water absorption showed a similar tendency to the strength properties. The XRD analysis of samples indicated that the hydration products formed in samples were ettringite, CSH and silicate phases. In this study, it is indicated that when compared to the use of sulfate only, the use of both sulfate and NaOH solution makes mechanical properties of AASC better.

Analysis of the Cause of Waterleakage in Residential Apartment Underground Parking Ground and the Review of the Repare Methods (공동주택 지하주차장의 누수원인 분석 및 보수방안 검토)

  • Oh, Sang-Keun;Choi, Sung-Min;Song, Je-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.3
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    • pp.255-264
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    • 2014
  • This study analyzes the cause and the repairing method of water leak by parts of basement parking lot which is recorded to have a high defect frequency in apartment buildings. It has been assessed that the cause of water leakage on the first floor upper substrate is due to such factors as landscaping and weights. During construction or through other cases, it has been determined that cracks were produced in the apartment structure because the structure was weak and exposed to the effects of the substrate movement. The base floor and underground external walls are areas that are exposed to water pressure (uplife pressure), thus in normal cases the rear surface repair of the structure using sythetic rubberized polymer gel should be considered as an effective method. However, in cases where application of waterproofing layer is required in the structure due to high water pressure, using asystolic cement milk grout to form the waterproofing layer and applying water-swelling acrylic material into the cracked areas is considered to be highly effective.

Properties of Retard Type Stabilizing Agent for Reuse of Sludge Water of Ready Mixed Concrete (레미콘 회수수의 재활용을 위한 지연형 안정화제의 특성)

  • Lee Mun-Hwan;Lee Sea-Hyun;Park Young-Shin;Park Jae-Myung
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.105-112
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    • 2005
  • Stabilizing and rousing sludge water generated from washing truck mixer and batcher plant can resolve inconsistency in quality and improve strength, therefore it is essential to review how to utilize it. This research conducted experiments and studied on solids of sludge water to find out the types of stabilizing agents available in conditions of producing ready mixed concretes in Korea. The result showed that oxy carboxylic acid retarder dedicated for stabilizing sludge water was most effective in decreasing solid. However, the setting time of cement paste was retarded due to surplus reactants, but it did not impede application of ready mixed concretes. When we left the sludge water mixed with stabilizing agent, it has been noted that initial retard effect recovered to the level using just service water in 7${\~}$8 days and that it is effective to use stabilized sludge water in 2${\~}$3 days. On the other hand, saccharic type super retarding agent was also outstanding in applicability by showing similar effect. The sludge water stabilizing agents currently marketed depend on imports, therefore it is necessary to locally manufacture usable stabilizing agents and to review its usability with multi-dimensional view.

Development of High Performance Curing Agent and Effective Dispersion Method of Nanomaterials (고성능 피막양생제 개발 및 나노물질의 분산방안 평가)

  • Son, Ho-Jung;Yoo, Byung-Hyun;Lee, Dong-Gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.230-236
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    • 2019
  • Recently, issues related to the quality of concrete have continuously resulted in surface quality problems, such as the exfoliation of concrete surfaces due to the cost reduction of cement and poor quality fine aggregate, scaling of surfaces caused by laitance, and plastic shrinkage cracks. Prompted by social issues, the application of a photo catalyst to road structures is being attempted to solve the environmental problems caused by fine dust and automobile exhaust. In this study, chemical admixtures were developed to improve the surface quality of concrete and to apply and distribute titanium dioxide in nanoscale sizes to provide basic data for the development of a photocatalyst-curing agent. As a result of the experiment, silicon and silane were reviewed as a raw material as a curing agent to develop a high performance curing agent with better film performance than conventional curing agents because they could form a film quickly on a fresh concrete surface. The distributed stability of the ultrasonic disperser showed the best performance through an outdoor test for four weeks to review the dispersion measures for the application of nanomaterials.