• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.144.2-144.2
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• 2010

Bipolar plate는 고분자 전해질 연료전지(PEMFC)에서 핵심 부품 중의 하나이고, 전해질 막이나 촉매 등에 비해서는 상대적으로 쉽게 접근할 수 있기 때문에 많은 연구가 수행되고 있다. Bipolar plate를 제조하는 기술은 크게 금속을 프레스 가공하는 방법, graphite 판을 직접 밀링하는 방법 및 고분자/카본계의 press molding 법 등 3가지로 분류되며, 본 연구에서는 3번째 방법에 의해서 bipolar plate를 대량 생산하는 방법에 대해 연구하였다. 고분자 매트릭스는 에폭시계 수지를 사용하였고, 카본계 재료는 graphite 분말과 carbon nanotube를 사용하였다. 이들 재료들을 일정한 비율로 혼합한 후 differential scanning calorimetry(DSC)를 사용하여 열분석 하였고, 그 결과를 Kissinger equation에 대입하여 경화반응 속도론을 연구하였다. 또한, 경화된 에폭시/탄소 복합재료의 전기전도도, 유리전이온도, 표면에너지 특성 등을 분석하였다.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10a
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• pp.368-373
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• 1998

Prepackaged system consists out of a dry mix which contains cement, sand, redispersible polymer powder and admixtures in the right proportions. The purpose of this study is to evaluate the quality of prepackaged-type polymer-modified mortar products using redispersible poly(ethylene-vinyl acetate)(EVA) powder. Polymer-modified mortars using the redispersible polymer powder with powdered with powdered shrinkage-reducing agent were prepared with cellulose fiber contents of 0, 0.5, 1.0% and shrinkage-reducing agent contents of 0, 4%, and tested for drying shrinkage, strength, adhesion in tension, water absorption. From the test results, the prepackaged-type polymer-modified mortar products with 4% of shrinkage-reducing agent content give good properties. and that their properties largely depends on the shrinkage-reducing agent content rather than the cellulose fiber contents.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.12
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• pp.29-36
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• 2004

In this paper, a new replication technique for a real 3D microstructure was introduced, in which a master Pattern WES made of photo-curable epoxy using a microstereolithography technology, and then it was transferred onto an epoxy-copper particle composite. A helical gear was selected as one of the real 3D microstructure for this study, and it was replicated from a pure epoxy to an epoxy composite. In addition, the transferability of the microreplication process was evaluated, and the properties of :he epoxy composite were compared to that of the pure epoxy, including hardness, wear-resistance and thermal conductivity.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.93-98
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• 2002

The effects of polymer-cement ratio, antifoamer content and shrinkage-reducing agent content on the air content, setting time and drying shrinkage of polymer-modified mortars using redispersible polymer powder are examined. As a result the air content of the polymer-modified mortars using redispersible polymer powder tend to decrease with increasing polymer-cement ratio and antifoamer agent content. Regardless of the antifoamer content, the setting time of the polymer-modified mortars using redispersible polymer powder tend to delayed with increasing polymer-cement ratio. Irrespective of the antifoamer content, the drying shrinkage of the polymer-modified mortars using redispersible polymer powder tend to decrease with increasing polymer-cement ratio and shrinkage-reducing agent content.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.296-299
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• 2004

The effects of polymer-cement ratio, antifoamer content and shrinkage-reducing agent content on the setting time and drying shrinkage of high-fluidity polymer-modified mortars using redispersible polymer powder are examined. As a result, the setting time of the high-fluidity polymer-modified mortars using redispersible polymer powder tend to delayed with increasing polymer-cement ratio, regardless of the antifoamer conten,. Irrespective of the antifoamer content, the drying shrinkage of the high-fluidity polymer-modified mortars using redispersible polymer powder tend to decrease with increasing polymer-cement ratio and shrinkage-reducing agent content.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2002.10a
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• pp.165-168
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• 2002

The effects of polymer-cement ratio, antifoamer agent content and shrinkage-reducing agent content on the drying shrinkage of polymer-modified mortars using redispersible polymer powder are examined. As a result, irrespective of the antifoamer content, the drying shrinkage of the polymer-modified mortars using redispersible polymer powder tend to decrease with increasing polymer-cement ratio and shrinkage-reducing agent content. Such a drying shrinkage development is due to the effect of reducing water from incorporation of EVA redispersible polymer powder and antifoamer agent.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2001.11a
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• pp.88-92
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• 2001

This paper discusses the strength properties of the polymer-modified mortars using redispersible polymer powders, which is widely used for the manufacture of prepackaged-type polymer-modified mortar products at present. The polymer-modified mortars using redispersible polymer powders are prepared with various polymer-cement ratios, and tested for air content, flexural and compressive strengths, and tensile strength. The strength properties are almost the same as those of polymer dispersion-modified mortars, depending on the polymer-cement ratios, and are improved over unmodified mortar. In particular, between tensile strength and glass transition point of polymer powder have a high correlation. It is concluded from the test results that polymer-modified mortars using redispersible polymer powders can be used in the same manner as ordinary polymer dispersion-modified mortars.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.555-558
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• 2005

The purpose of this study is to evaluate the chemical resistance of polymer powder-modified mortars with special accelerator component. Polymer powder-modified mortars with the accelerator are prepared with various polymer-binder ratios, and tested for flexural and compressive strengths and mass change. Chemicals resistance was tested by dealing with $10\%$ HCl and $5\%\;H_2SO_4$ aqueous solution. As a result, the weight reduction ratio of the mortars decreased with increasing polymer-binder ratio. However, in the viewpoint of strength reduction by chemical attacks, the maximum chemical resistance of the mortars was shown at a polymer-binder ratio of $5\%$.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.559-562
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• 2005

The purpose of this study is to evaluate the durability and bond strength of polymer powder-modified mortars with special accelerator components. The mortars were prepared with various polymer-binder ratios and applied to the concrete substrate as a repair material. Bond strength, flexural and compressive strengths, freeze-thaw resistance and carbonation resistance were measured for the test. As a result, bond strength of the mortars was increased with an increase in the polymer-cement ratio, and freeze-thaw resistance and carbonation resistance were significantly improved with increasing polymer-cement ratio also.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.253-254
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• 2011

The purpose of this study is to investigate chloride ion adsoption property of cement mortar using nitrite type hydrocalumite(calumite) with self-corrosion inhibition function. Superior corrosion inhibition function of the VA/E/MMA-modified mortars with calumite was ascertained from accelerated corrosion test in the previous study. In this study, VA/E/MMA-modified mortars with calumite were prepared with calumite contents of 0, 5, 10% and polymer-binder ratio of 0, 10%, and tested for chloride ion adsorption to make it clear how calumite gives self-corrosion inhibition function to cement mortar. As a result, chloride ion adsorption property of VA/E/MMA-modified mortars with calumite was improved by increasing calumite contents compared to unmodified mortar regardless of using VA/E/MMA terpolymer powder or not.