• Title/Summary/Keyword: 분극모델

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Simulation of Electrorheological Fluids by the Extended Maxwell-Wagner Polarization Model with Onsager Theory (Onsager 이론으로 확장한 Maxwell-Wagner 분극 모델에 의한 전기유변 현상 모사)

  • Kim, Young Dae
    • Korean Chemical Engineering Research
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    • v.58 no.3
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    • pp.480-485
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    • 2020
  • The extended Maxwell-Wagner polarization model is employed to describe the ER behavior of the conducting particle ER suspensions, and solutions to the equation of motion are obtained by dynamic simulation. The simulation results show the nonlinear ER behavior (Δτ∝En, n≈1.5) of the conducting particle ER suspensions. The response point, where shear stress reaches steady-state, is the point where stable break-up and rebuild of the chain-like structure of particles reaches. Also, it shows the minimum of shear stress, which corresponds the start-up of random particle configuration. The shear stress reaches plateau as particle volume fraction increases.

New Equivalent Circuit Model for Interpreting Spectral Induced Polarization Anomalous Data (광대역유도분극 이상 자료의 해석을 위한 새로운 등가회로 모델)

  • Shin, Seungwook;Park, Samgyu;Shin, Dongbok
    • Geophysics and Geophysical Exploration
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    • v.17 no.4
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    • pp.242-246
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    • 2014
  • Spectral induced polarization (SIP) is a useful technique, which uses electrochemical properties, for exploration of metallic sulfide minerals. Equivalent circuit analysis is commonly conducted to calculate IP parameters from SIP data. An equivalent circuit model, which indicates the SIP response of rock, has a non-uniqueness problem. For this reason, it is very important to select the proper model for accurate analysis. Thus, this study focused on suggesting a new model, which suitable for the analysis of an anomalous SIP response, such as ore. A suitability of the new model was verified by comparing it with the existing Dias model and Cole-Cole models. Analysis errors were represented as a normalized root mean square error (NRMSE). The analysis result using the Dias model was the NRMSE of 10.50% and was the NRMSE using the Cole-Cole model of 17.03%. Howerver, because the NRMSE of the new model is 0.87%, it is considered that the new model is more useful for analyzing the anomalous SIP data than other models.

Characteristics of Quasi-MFISFET Device with Various Ferroelectric Thin Films (강유전체 박막의 특성에 따른 Quasi-MFISFET 소자의 특성)

  • Lee, Guk-Pyo;Yun, Yeong-Seop;Gang, Seong-Jun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.3
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    • pp.166-173
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    • 2001
  • Hysteresis loops of the ferroelectric thin films such as PLZT(10/30/70), PLT(10) and PZT(30/70) was simulated using the field-dependent polarization model and compared to the measured loops. In case of PZT(30/70) thin film, as the real saturation or polarization at the applied voltage or larger than 5V appears slack and its value is quite different from the simulated one, it is deduced that the ferroelectric polarization of PZT(30/70) is generated not only by the pure dipoles but also by various electric charges. The drain current of quasi-MFISFET is expressed by using the square-law FET and field-dependent polarization models. The modeling results are analogous to the experimental values. The channel of quasi-MFISFET using PZT(30/70) forms more quickly compared to that of quasi-MFISFET using PLZT(10/30/70) or PLT(10) in the state of 'write' gate voltage of -10V. This may be because the decrease rate of the polarization in the PZT(30/70) thin film is 3~4 times more rapid than that of the polarization in the PLZT(10/30/70) or the PLT(10) thin film in the retention characteristics.

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A Circuit Simulation Model of Ferroelectric Capacitors and its AHDL Implementation (강유전체 캐패시터의 회로 시뮬레이션 모델과 이의AHDL 구현)

  • Kim, Shi-Ho
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.10
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    • pp.25-32
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    • 2000
  • We provided a model for accurately computing the Hysteresis characteristics of the ferrelectric thin film capacitors. This model is developed form the semi-empirical ferroelectric model based on the double well harmonic oscillator. We have seen that this model is consistent with physical analysis using the Preisach's hysteresis distribution. This model includes the parameters representing the slope of changing Hysteresis curves and the imprint of ferroelectric capacitors. Besides, we showed that this model could predict accurate sub-hystersis loop by the turning points when the polarities of applied voltage were changed before saturation. The simulation and measurement result showed that this model is well applicable to both PZT and SBT materials. This model has been described by AHDL and successfully implemented into Spectre simulator to provide circuit design environment of commercial CAD tools such as Cadence software.

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Evaluation of Concentration Polarization at Feed in the Permeation of VOCs/$N_2$ mixtures through PDMS membrane (VOCs/질소 혼합물 증기투과시 공급액부 경계층에서의 농도분극 분석을 위한 모델식 확립)

  • 염충균;이상학;최정환;이정민
    • Membrane Journal
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    • v.11 no.2
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    • pp.74-82
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    • 2001
  • By using a phenomenological approach, model equations incorporating the resistance-in¬series concept were established to evaluate quantitatively concentration polarization in the boundary layer in feed adjacent to the membrane surface in the vapor permeation and separation of volatile organic compounds (VOCS)/$N_2$ mixture through po]y(dimethylsiloxane) (PDMS) membrane. The vapor permeations of various VOCS/$N_2$ mixtures through PDMS membrane were carried out at various feed flow rates. Chlorinated hydrocarbons, such as, methylene chloride, chlorofonn, 1,2-clichloroethane and 1,1,2-trichloroethane were used as organic vapor. By fitting the model equations to the experimental penneation data. the model parameters were detennined. respectively. Both the mass transfer coefficient of VOC across tbe boundary layer and concentration polarization modulus as a measure of the extent of concentration polarization were eitimated Quantitatively by the mooe1 equations with the determined model parameters. From the analysis on the detennined model parameters, the boundary layer resistance due to the concentration polarization of VOCs component was found to be more significant when the condensability of voe was greater. This study seeks to emphasize the importance of the boundary resistance on the vapor penneation of the vapor/gas mixtures with high permeability and high selectivity towards the minor component VOC.

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Chlorakali Electrolysis에서 한계전류밀도의 변화

  • 황민재;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.10a
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    • pp.52-53
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    • 1995
  • 전해질용액에 있는 이온교환막을 통해 전류가 흐를 때 막표면에는 경계층이 형성된다. 희석실쪽 막표면에서 전해질의 농도는 감소하고 농축실쪽에서 증가 하는 농도분극현상이 일어난다. 이와 같은 농도분극현상은 전류밀도에 벼놔를 주어 에너지 소비를 증가시키고 막표면에 스케일을 형성할 수도 있다. ED에서는 농축실보다는 희석실쪽의 농도분극현상이 더 많은 관심을 갖게 되며 이 부분 연구가 활발하게 진행된다. 따라서 전기 투석을 이용한 물질분리는 항상 한계전류밀도이하에서 이루어져야 하는데 i$_{lim)$은 막자체의 성능 외에도 용액의 종류및 농도, 온도, pH, 전압등에 의해 변화한다. 따라서 i$_{lim)$이 각 변수에 의해 얼마만큼 변화하는지를 살펴봄으로써 임의의 환경에서 i$_{lim)$을 추정할 수 있는 모델을 제시하고자 한다.

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Electrorheological effect on the dispersive system consisting of polarizable fine powder/dielectric oil (분극성을 갖는 미세 입자/유전유체 분산계에서의 전기유변효과)

  • Kim, Sang-Guk;Choe, Yun-Dae
    • Korean Journal of Materials Research
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    • v.3 no.2
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    • pp.185-192
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    • 1993
  • Abstract Electrorheological effect on the dispersive system of polarizable fine powder/dielectric oil has been investigated. ER effect was explained divided into following 3 mechanisms; (1) surface conductance, (2) bulk conductance, and (3) induced polarization. Mathematical model which predicts the interactive force between two fine particles in the electrorheological fluid has been introduced based on the induced polarization mechanism. This model may provide guide to select materials for strong ER effect. The attractive force between two particles was calculated using the above model for the selected 7 materials such as ceramics, ferrites, polymers etc. From the calculation result, it was found that the ceramics and ferrites are good materials which show a strong ER effect.

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Numerical Analysis of the electrochemical performance of a zinc-air fuel cell (수치해석을 이용한 아연공기전지의 전기화학적 성능 연구)

  • Kim, Jungyun;Park, Sangmin;Oh, Taeyoung;Lee, Hoil
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.74.1-74.1
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    • 2010
  • 수치해석을 이용하여 형상 및 운전 조건에 따른 금속공기전지의 전기화학적 성능 변화를 조사하였다. 저전류밀도 영역에서의 전지 성능은 농도손실에 의한 영향이 미미하므로 활성화 손실과 저항손실만을 고려한 수치해서 모델을 적용하였다. 지배방정식은 전기전도식을 이용하였으며 전극 표면의 활성화손실을 모사하기위해 아연극(음극)에는 butler-volmer식을, 공기극(양극)에는 tafel식을 적용하였다. 실험결과와의 비교/분석을 통하여 수치해석 모델의 타당성을 검증하였다. 또한, 아연극과 공기극 사이의 간격과 전해질 농도 변화에 따른 아연공기전지 내부에서의 전류밀도분포를 조사하였으며, 분극곡선을 통해 전기화학적 성능을 평가하였다.

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Analyses of Spectral IP Responses over 20-Degree Dipping Structure (20도 경사구조에 대한 스펙트럴 IP응답의 해석)

  • Kim, Hee Joon
    • Economic and Environmental Geology
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    • v.19 no.3
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    • pp.219-224
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    • 1986
  • Spectral induced polarization (IP) responses for 20-degree dipping body are obtained by both numerical and scale models. The IP responses for the dipping body vary not only with current frequencies but also with resistivity ratios between the body and the surrounding medium. If the ion concentration related to polarizable reaction is constant, the resistivity of polarizable body depends only on the current frequency. This implies that the IP responses to the resistivity ratio are qualitatively equivalent to those to the current frequency. The numerical results with wide-range resistivity ratios, therefore, can be used as standard curves for the interpretation of spectral IP data.

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