• Title/Summary/Keyword: 부식 억제제

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Studies on Physicochemical and Biological Properties of Depolymerized Alginate from Sea Tangle, Laminaria japonicus by Heating Hydrolysis -4. Inhibition Effects of Acute Gastritis Induced by $HCl{\cdot}ethanol$ Solution and Gastric Ulcer Induced- (다시마 (Laminaria japonicus) Alginate의 가열가수분해에 따른 물리${\cdot}$화학적 및 생물학적 특성에 관한 연구 -4. $HCl{\cdot}ethanol$용액과 침수스트레스에 의해 유발되는 랫드 위궤양의 억제효과-)

  • KIM Yuck-Yong;CHO Young-Je
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.6
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    • pp.520-523
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    • 2000
  • Anti-ulcer effects of depolymerized alginate (HAG-10, average molecular weight 10,000; HAG-50, average molecular weight 50,000; HAG-100, average molecular weight 100,000) obtained by hydrolysis of alginate by heating at $121^{\circ}C$, against $HCl{\cdot}ethanol$ and water-immersion stress in rats were investigated. The acute gastritis, induced by $HCl{\cdot}ethanol$, and the gastric ulcer, induced by water-immersion stress, were inhibited dose-dependently by administration of HAG-50, HAG-100 and alginate. Histopathological lesions of the gastritis and gastric ulcer in rats treated with HAG-50, HAG-100 and alginate were significantly lower than those in rats fed with HAG-10. The inhibition rates (${\%}$) on acute gastritis induced by $HCl{\cdot}ethanol$ and gastritis ulcer induced by water-immersion stress in rats, were $13.00{\%}\;and\;15.74{\%}$of HAG-10, $41.15{\%}\;and\;35.72{\%}$ of HAG-50, $41.58{\%}\;and\;35.37{\%}$ of HAG-100, and $45.17{\%}\;and\;41.11{\%}$ of alginate, respectively. These results suggested that HAG-50, HAG-100 and slginate had a protective effect against the gastritis and gastric ulcer. The effect was not as visible when using HAG-10 in rats. From the present results, it was suggested that HAG-50 was an effective anti-ulcer agent against $HCl{\cdot}ethanol$and water-immersion stress in rats.

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EFFECT OF CHLORHEXIDINE ON MICROTENSILE BOND STRENGTH OF DENTIN BONDING SYSTEMS (Chlorhexidine 처리가 상아질 접착제의 미세인장결합강도에 미치는 영향)

  • Oh, Eun-Hwa;Choi, Kyoung-Kyu;Kim, Jong-Ryul;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.33 no.2
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    • pp.148-161
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    • 2008
  • The purpose of this study was to evaluate the effect of chlorhexidine (CHX) on microtensile bond strength (${\mu}TBS$) of dentin bonding systems. Dentin collagenolytic and gelatinolytic activities can be suppressed by protease inhibitors, indicating that MMPs (Matrix metalloproteinases) inhibition could be beneficial in the preservation of hybrid layers. Chlorhexidine (CHX) is known as an inhibitor of MMPs activity in vitro. The experiment was proceeded as follows: At first, flat occlusal surfaces were prepared on mid-coronal dentin of extracted third molars. GI (Glass Ionomer) group was treated with dentin conditioner, and then, applied with 2 % CHX. Both SM (Scotchbond Multipurpose) and SB (Single Bond) group were applied with CHX after acid-etched with 37% phosphoric acid. TS (Clearfil Tri-S) group was applied with CHX, and then, with adhesives. Hybrid composite Z-250 and resin-modified glass ionomer Fuji-II LC was built up on experimental dentin surfaces. Half of them were subjected to 10,000 thermocycle, while the others were tested immediately. With the resulting data, statistically two-way ANOVA was performed to assess the ${\mu}TBS$ before and after thermo cycling and the effect of CHX. All statistical tests were carried out at the 95 % level of confidence. The failure mode of the testing samples was observed under a scanning electron microscopy (SEM). Within limited results, the results of this study were as follows; 1. In all experimental groups applied with 2 % chlorhexidine, the microtensile bond strength increased, and thermo cycling decreased the micro tensile bond strength (P > 0.05). 2. Compared to the thermocycling groups without chlorhexidine, those with both thermocycling and chlorhexidine showed higher microtensile bond strength, and there was significant difference especially in GI and TS groups. 3. SEM analysis of failure mode distribution revealed the adhesive failure at hybrid layer in most of the specimen. and the shift of the failure site from bottom to top of the hybrid layer with chlorhexidine groups. 2 % chlorhexidine application after acid-etching proved to preserve the durability of the hybrid layer and microtensile bond strength of dentin bonding systems.

Service Life Prediction and Cost Estimation of Repaired Concrete Structures Under Marine Environment (염해 환경 하 보수된 콘크리트 구조물의 사용수명 예측 및 보수 비용 평가)

  • Shim, Hyun Bo;Ann, Ki Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.226-234
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    • 2011
  • The service life of concrete structures exposed to a marine environment can be extended by controlling the amount of chloride in cover concrete. Patching is one of the appropriate maintenance techniques for chloride contamination. Chloride-contaminated cover concrete is removed and replaced with sound one. It can provide less risk of corrosion of steel, so that the structure can be maintained for required service life. In this study, a quantitative assessment of the service life subjected to the chloride attack is proposed to determine the effective repair options such as repair depth, repair material and timing of repair. The Crank-Nicolson based finite difference formulation from Fick's second law is proposed to predict the profiles of chloride ion in a repaired concrete structure, considering ingress of chloride from outer and redistribution of residual chloride from the substrate concrete. Therefore, the repair application times and maintenance cost for the target service life can be estimated. Finally, the numerical examples are presented to ensure its applicability.

Measurement and Prediction of Combustuion Properties of di-n-Buthylamine (디노말부틸아민의 연소특성치 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of Energy Engineering
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    • v.28 no.4
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    • pp.42-47
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    • 2019
  • In this study, combustion characteristics were measured by selecting di-n-buthylamine, which is widely used as an emulsifier, insecticide, additive, rubber vulcanization accelerator, corrosion inhibitor, and raw material for dye production. The flash point of the di-n-buthylamine was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of the di-n-buthylamine was measured by ASTM 659E. The explosion limits of the di-n-buthylamine was calculated using the measured flash points by Setaflash tester. The flash point of the di-n-buthylamine by using Setaflash and Pensky-Martens closed-cup testers were experimented at 38 ℃ and 43 ℃, respectively. The flash points of the di-n-buthylamine by Tag and Cleveland open cup testers were experimented at 48 ℃. The AIT of the di-n-buthylamine was experimented at 247 ℃. The LEL and UEL calculated by using lower and upper flash points of Setaflash tester were calculated at 0.69 vol% and 7.7 vol%, respectively. The measurement of the flash point measurement and the calculation method of the explosion limit prediction presented in this study can be used to study the fire and explosion characteristics of the other combustible liquids.

Convergence Study on FTO Film Etchant (FTO 필름 식각액에 관한 융합연구)

  • Han, Doo-Hee;Yang, Ui-Dong
    • Journal of Convergence for Information Technology
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    • v.8 no.6
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    • pp.43-48
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    • 2018
  • An etchant capable of forming a circuit in an FTO film that can replace ITO, which depends on full imports, was prepared. The etching solution is composed of 1 to 30% by weight of fluoride, 1 to 20% by weight of acid, 0.5 to 5% by weight of surfactant, 5 to 20% by weight of solvent, 0.5 to 10% by weight of corrosion inhibitor and the balance of water. This etchant can be etched using a dry film, thereby reducing the cost, and is free from bubbles and residue of the etchant. The characteristics of the etchant were etched in a time of 2 minute with a 100 nm thick FTO, and the etchant temperature was maintained at $50^{\circ}C$. An undercut of -0.00364% was obtained when put into a 2 minute etching solution. No harmful substances such as Cd, Pb, Hg and Cr components were measured. The use of FTO in Korea where rare earths do not exist can achieve localization and import substitution effect.

Synthesis and Performance of Dialkylamine (di-)nitrobenzoates for Vapor Corrosion Inhibitor (기화성방청제 Dialkylamine (di-)nitrobenzoates 합성 및 방청성능)

  • Chun, Yong-Jin;Park, Yong-Sung;Soh, Soon-Young
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.6-11
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    • 1999
  • Dialkylamine (di-)nitrobenzoates as vapor corrosion inhibitor were synthesized with dialkylamines and (di-)nitrobenzoic acids. The compounds were analyzed by elemental analyzer, FT-IR and $^1H$-NMR spectrophotometer. Corrosion inhibition of synthetic compounds and additives [$(NH_4)_2CO_3$, $NaHCO_3$] against ferrous and non-ferrous metal was investigated by potentiostatic method [1% (w/v) corrosion inhibitor in 1M $Na_2SO_4$ aqueous solution] respectively. For corrosion inhibition of ferrous metal, dialkylamine 4-nitrobenzoates were better inhibitor than dialkylamine 3, 5-dinitrobenzoates, the passivating current density ($i_p$) of dialkylamine 4-nitrobenzoate was shown $4.78mA/cm^2$. While, for non-ferrous metal, dialkylamine 3, 5-dinitrobenzoates were better, those of dipropylamine 3, 5-dinitrobenzoate and hexamethyleneimine 3, 5-dinitrobenzoate were shown 36 and $37mA/cm^2$. Additive effect of $(NH_4)_2CO_3$ and $NaHCO_3$ for corrosion inhibition of ferrous metal was excellent but that of non-ferrous metal was not. Optimum ratios of diethylamine 4-nitrobenzoate with $(NH_4)_2CO_3$ and $NaHCO_3$ were 4 : 6 and 5 : 5 (V/V), and passivating current densities ($i_p$) of the mixtures were shown 0.26 and $0.85mA/cm^2$, respectively.

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The effect on dispersibility of additive elements in Cr+6 free chemical conversion coating solution (Cr+6 free 화성피막 용액의 분산성에 미치는 첨가 원소의 영향)

  • Park, Jeong-Hwan;Kim, Tae-Won;Jo, Dae-Hyeong;Kim, Jeong-Su;Han, Su-Min;Jeong, Dae-Hui;Jeon, Gyu-Seong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.104-104
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    • 2017
  • 유럽의 폐차 처리 지침, RoHs 및 국내 친환경 소재 부품의 개발이 날로 가속화 되면서 종래 사용해 오던 인산염 피막 등 중금속이 함유된 코팅 재료는 점차 친환경 코팅 용액으로 전환이 되었다. 최근 자동차 산업 등에서 종래 중금속인 $Cr^{+6}$을 함유하지 않는 다양한 코팅 용액이 상용화 되고 있다. 그 중 가장 효율적으로 적용되고 있는 용액이 아연 flake를 첨가하여 희생 양극효과를 가능하게 하여 내식용 코팅 용액으로 상용화 하고 있다. 이 용액에는 내식성을 확보하기 위하여 희생양극이 가능한 소재 인 아연 분말을 첨가하며, 이 분말의 분산성이 소재와 코팅 층의 밀착성, 내식성에 결정적인 영향을 미친다. 특히 산업 현장에서는 아연 분말의 효율적인 분산을 위하여 24시간 이상 교반해야하기 때문에 생산성을 감소시키는 결정적인 요인으로 작용을 한다. 아연 분말의 분산은 용액 내에 첨가하는 각종 첨가제의 종류와 첨가량에 따라 현저하게 분산성이 다르기 때문에 첨가 원소에 대한 연구가 매우 중요하다. 본 연구에서는 서로 다른 이종 합금을 첨가하여 각종 첨가제의 종류 및 첨가량이 분산에 미치는 영향을 조사하였고, 첨가량이 코팅 층의 밀착성 및 내식성에 미치는 영향에 대하여 연구하였다. 분산제 첨가량이 낮을 경우 용액은 두껍게 코팅이 되며 분산 거리가 짧아졌다. 이 경우 코팅 층의 박리가 쉽게 발생하며, 코팅 층이 불균일하였다. 1.7% 첨가량에서 최적분산효과를 얻을 수 있었으며, 1,000시간 이상의 내식성을 확보할 수 있었다. 분산성과 동시에 유동성 확보가 중요하며, 유동성 확보를 위하여 점증제의 첨가량에 대한 변화를 주었다. 최적의 첨가량은 1.5% 이상으로 이 경우 부식 발생시간을 억제할 수 있었다.

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Acid Drainage and Damage Reduction Strategy in Construction Site: An Introduction (건설현장 산성배수의 발생현황 및 피해저감대책)

  • Kim, Jae-Gon
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.651-660
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    • 2007
  • Acid drainage has been recognized as an environmental concern in abandoned mine sites for long time. Recently, the environmental and structural damage by acid drainage is a current issue in construction sites in Korea. Here, the author introduces the type of damages by acid drainage in construction sites and emphasizes the importance of geoscience discipline in solving the problem. Metasedimentary rock of Okcheon group, coal bed of Pyeongan group, Mesozoic volcanic rock. and Tertiary sedimentary and volcanic rocks are the major rock types with a high potential for acid drainage upon excavation in Korea. The acid drainage causes the acidification and heavy metal contamination of soil, surface water and groundwater, the reduction of slope stability, the corrosion of slope structure, the damage on plant growth, the damage on landscape and the deterioration of concrete and asphalt pavement. The countermeasure for acid drainage is the treatment of acid drainage and the prevention of acid drainage. The treatment of acid drainage can be classified into active and passive treatments depending on the degree of natural process in the treatment. Removal of oxidants, reduction of oxidant generation and encapsulation of sulfide are employed for the prevention of acid drainage generation.

Microbiological Characteristics of Whitening Tyrosinase Inhibitor-producing Wild Yeasts, Saccharomyces cerevisiae WJSL0191 and Papiliotrema laurentii ON30 and Production (미백성 Tyrsoinase 저해물질 생산 비병원성 야생효모 Saccharomyces cerevisiae WJSL0191와 Papiliotrema laurentii ON30의 균학적 특성과 Tyrosinase 저해물질의 생산)

  • Kim, Ji-Yoon;Lee, Jong-Soo
    • The Korean Journal of Mycology
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    • v.48 no.3
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    • pp.285-296
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    • 2020
  • The goal of this study and potent whitening tyrosinase inhibitor-producing wild yeasts and further optimiz production of tyrosinase. Among non-pathogenic wild yeasts obtained from soils in Daejeon city and spice field of Geumsan in Chungcheongnam-do, Korea, we selected Saccharomyces cerevisiae(S. cerevisiae) WJSL0191 and Papiliotrema laurentii (P. laurentii) ON30 show 33.2% and 27.3% respectively. These selected strains formed and not pseudomycelium. S. cerevisiae WJSL0191 was sugar-tolerant as well as halophilic in 20% glucose-containing yeast (YPD) medium and 15% NaCl-containing YPD medium. S. cerevisiae WJSL0191 and P. laurentii ON30 showed 26.2% and 18.6% anti-wrinkle elastase inhibitory activities, respectively. aximal production of tyrosinase inhibitors obtained when S. cerevisiae WJSL0191 was cultured at 30 for 72h in YPD medium and P. laurentii ON30 was incubated at 20℃ for 24hr.

음향공에 의한 LOX-RP1 고주파 음향-연소안정화에 관한 연구

  • 이길용;윤웅섭;조용호
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2000.04a
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    • pp.5-5
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    • 2000
  • 액체 추진 로켓 엔진의 고주파 연소 불안정 관련 이론은 대체로 연소기 내부의 음향 공명 모드와 분무 연소 과정의 상호 작용을 구동 메커니즘으로 전제하며 Rayleigh Criterion의 재해석에 기초하여 불안정성 평가를 위한 매개변수를 도입하고 연소 불안정성을 예측한다. 여기에는 음향장 분석 이론, 음향 불안정 이론, 연소응답 및 기화반응 이론 등이 포함된다. 본 연구에서는 LOX/RPl 추진제 조합의 액체 추진 로켓 엔진 연소기를 대상으로 다차원 순수 음향장 해석과 연소-음향장 분석을 통해 대상 엔진의 고주파 연소 불안정 특성을 예측하였다. 수동 제어 기기인 음향공 설치에 따른 연소기의 음향장 및 연소-음향장의 특성 변화를 고찰하고 위 결과를 종합하여 음향공의 연소 불안정 억제 성능 및 대상 엔진의 연소 불안정성을 평가하였다. 연소기 형상 및 음향공 설치에 따른 다차원 순수 음향장 해석은 상용코드인 ANSYS를 사용하여 수행하였다. 내부 유체는 압축성, 비점성 유체로 유체의 평균 유동은 무시하며 위치에 관계없이 균일한 물성치를 부여하였다. 정상상태 연소과정을 가정하고 평형 화학을 이용한 분석 결과로부터 연소 기체의 관련 물성치를 결정하였다. 연소기 길이 방향, 반경 방향, 원주 방향 격자점들의 음향 특성을 주파수 영역에 대해 해석하고 3차원 음향 모드 형상을 토대로 음향장을 분석하였다. 연소-음향장 해석은 음향 불안정 이론 중 n- $\tau$ 2 매개변수 기법을 사용하였다. 연료 액적의 분무 연소 과정을 1차원적으로 가정하고 정상상태의 평형 화학 계산 결과를 이용하여 엔진의 연소면을 1차원적으로 설정하였다. 상류 연소응답과 중립 안정 곡선을 토대로 대상 엔진의 연소 불안정 특성을 분석하였다.구 분석 결과 기술적 문제점으로는 배기 가스온도가 낮은데 따른 출구 부분의 Bearing, Sealing이 문제가 될 수 있다고 판단되며 배기 가스 자체에 대기 공기중에 함유되어 있던 습기가 얼어붙는(Icing화) 문제가 발생하기 때문에 배기가스의 Icing을 방지하기 위하여 압축기 끝단에서 공기를 추출하여 배기부분에 송출할 필요성이 있는 것으로 판단되었다. 출구가스의 기체 유동속도가 매우 빠르므로 (100-l10m.sec) 이를 완화하기 위한 디퓨저의 설계가 요구된다고 판단된다. 또 연소기 후방에 물을 주입하는 경우 열교환기 및 기타 부분품에 발생할 수 있는 부식 및 열교환 효율 저하도 간과할 수 없는 문제로 파악되었다. 이러한 기술적 문제가 적절히 해결되는 경우 비활성 가스 제너레이터는 민수용으로는 대형 빌딩, 산림, 유조선 등의 화재에 매우 적절히 사용되어 질 수 있을 뿐 아니라 군사적으로도 군사작전 중 및 공군 기지의 화재 그리고 지하벙커에 설치되어 있는 고급 첨단 군사 장비 등의 화재 뿐 아니라 대간첩작전 등에 효과적으로 활용될 수 있을 것으로 판단된다.가 작으며, 본 연소관에 충전된 RDX/AP계 추진제의 경우 추진제의 습기투과에 의한 추진제 물성 변화는 미미한 것으로 나타났다.의 향상으로, 음성개선에 효과적이라고 사료되었으며, 이 방법이 편측 성대마비 환자의 효과적인 음성개선의 치료방법의 하나로 응용될 수 있으리라 생각된다..7%), 혈액투석, 식도부분절제술 및 위루술·위회장문합술을 시행한 경우가 각 1례(2.9%)씩이었다. 13) 심각한 합병증은 9례(26.5%)에서 보였는데 그중 식도협착증이 6례(17.6%), 급성신부전증 1례(2.9%), 종격동기흉과 폐염이 병발한 경우와 폐염이 각 1례(2.9%)였다. 14)

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