Browse > Article
http://dx.doi.org/10.5855/ENERGY.2019.28.4.042

Measurement and Prediction of Combustuion Properties of di-n-Buthylamine  

Ha, Dong-Myeong (Dept. of Occupational Health and Safety Engineering, Semyung University)
Publication Information
Abstract
In this study, combustion characteristics were measured by selecting di-n-buthylamine, which is widely used as an emulsifier, insecticide, additive, rubber vulcanization accelerator, corrosion inhibitor, and raw material for dye production. The flash point of the di-n-buthylamine was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of the di-n-buthylamine was measured by ASTM 659E. The explosion limits of the di-n-buthylamine was calculated using the measured flash points by Setaflash tester. The flash point of the di-n-buthylamine by using Setaflash and Pensky-Martens closed-cup testers were experimented at 38 ℃ and 43 ℃, respectively. The flash points of the di-n-buthylamine by Tag and Cleveland open cup testers were experimented at 48 ℃. The AIT of the di-n-buthylamine was experimented at 247 ℃. The LEL and UEL calculated by using lower and upper flash points of Setaflash tester were calculated at 0.69 vol% and 7.7 vol%, respectively. The measurement of the flash point measurement and the calculation method of the explosion limit prediction presented in this study can be used to study the fire and explosion characteristics of the other combustible liquids.
Keywords
di-n-buthylamine; combustion properties; flash point; explosion limit; autoignition temperature(AIT);
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Ha, D. M., 2018, A Study the Evaluation of Combustion Properties of Tetralin, J. of the Korean Society of Safety, Vol. 33, No. 4, pp. 8-14   DOI
2 Ha, D. M., 2018, Measurement and Prediction of Combustion Properties of Phenol, Korean J. of Hazardous Materials, Vol. 6, No. 20, pp. 23-29   DOI
3 Mitchell, J.W. et al., 1999, Experimental Flash Points of Industrial Amines, J. of Chem. Eng. Data, Vol. 44, pp. 209-211   DOI
4 Stephenson, S. M., 1987, Flash Points of Organic and Organometallic Compounds,\Elsevier, 1987.
5 KOSHA, http://msds.kosha.or.kr/kcic/msdsdetail.do.
6 Lenga. R. E. and Votoupal, K. L., 1993, The Sigma Aldrich Library of Regulatory and Safety Data, Volume I-III, Sigma Chemical Company and Aldrich Chemical Company Inc
7 Lewis, R. J.,2004, SAX's Dangerous Properties of Industrial Materials, 11th ed., John Wiley & Son, Inc., New Jersey
8 Lide, D. R., 1996, Handbook Chemistry and Physics, 76th ed., CRC Press
9 Dean, J. A., 1992, Lange's Handbook of Chemistry, 14th ed. McGraw-Hill
10 Catoire, L., Paulmier, S., and Naudet, V., 2006, Experimental Determination and Estimation of Closed Cup Flash Points of Mixtures of Flammable Solvents, Process Saf. Prog., Vol. 25, No. 1, pp. 33-39   DOI
11 Hilado, C. J. and Clark, S. W., 1972, Autoignition Temperature of Organic Chemicals, Chemical Engineering, Vol. 4, pp. 75-80
12 Ha, D. M., 2017, Measurement and Prediction of Fire and Explosion Characteristics of n-Butylacetate, J. of the Korean Society of Safety, Vol 32, No. 5, pp. 25-31   DOI
13 Reid, R. C., Prausnitz, J. M. and Sherwood T. K., 1977, The Properties of Gases and Liquids, 4nd ed. McGraw-Hill
14 Semenov, N. N., 1959, Some Problems in Chemical Kinetics and Reactivity, Vol. 2", Princeton University Press, Princeton, N.J.
15 NFPA,1991, Fire Hazard Properties of Flammable Liquid, Gases, and Volatile Solids", NFPA 325M, National Fire Protection Association