• Title/Summary/Keyword: 복합 소재

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A Study on the Effects of the Home-Linked Indirect Smoking Prevention Program for Early Childhood (유아기 간접흡연예방 가정연계교육 프로그램의 효과)

  • Kim, Jung-Mi;Kim, Hyeon-Young
    • Journal of Digital Convergence
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    • v.18 no.7
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    • pp.411-419
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    • 2020
  • This study was conducted to prove the effectiveness of home-linked indirect smoking prevention education in early childhood in improving the awareness, skills, attitudes and willingness to protect themselves from smoking. 208 5-year-old children were recruited from three kindergartens located in Seoul and Gyeonggi-do. Children in the experimental group received home-linked indirect smoking prevention education. Children in the comparative group, received indirect smoking prevention education in kindergarten. Children in the control group received general health education. The results revealed that all groups showed significant differences between pretest and posttest in awareness of second-smoke, attitudes and willingness to stop smoking. However, the skills to protect oneself from second-smoke showed a significant difference in the experimental group and the comparative group. The values of changes among the groups showed high increases in the order of experimental, comparative, and control groups. This shows that home-linked education had considerable positive effects on indirect smoking prevention.

Preparation and Characterization of Grafted Maleic Anhydride onto Polypropylene by Reactive Extrusion (반응 압출을 통한 PP-g-MA 제조 및 특성평가)

  • Kang, Dong-Jin;Lee, Sung-Hyo;Pal, Kaushik;Park, Chan-Young;Zhang, Zhen Xiu;Bang, Dae-Suk;Kim, Jin-Kuk
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.358-363
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    • 2009
  • Maleic anhydride-grafted polypropylene has been widely used to improve the interfacial interaction between the components in PP/polar polymer blends and PP/filler composites and to maximize the physical properties and thermal properties. In this paper. the maleic anhydride (MAH)-grafted polypropylene (co-PP) was fabricated through reactive extrusion process with di-cumyl peroxide (DCP) as an initiator. The grafting degree of MAH depending on the contents of DCP and MAH was investigated by FT-IR spectra and chemical titration. The grafting degree increased with increasing MAH concentration and also showed maximum value at 0.06 wt% of DCP concentration. Melt flow index (MFI) of the grafted copolymer was increased with increasing the contents of MAH. The DSC and TGA analysis data indicate the melting temperature and thermal degradation of PP depending on the grafting degree of MAH.

Synthesis and Effect of Plasma Treatment of Acrylic Composite Particle Binder (아크릴계 복합입자 바인더의 제조와 플라즈마 처리영향)

  • Sim, Dong-Hyun;Seul, Soo-Duk
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.276-283
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    • 2008
  • Kind of monomer(MMA, EA, BA, St)and the monomer ratio(80/20 to 20/80) where changed in the preparation of the core shell binder, and property was improved the plasma processing. Each material changed by plasma treatment time($1{\sim}10\;s$) to change to measure the tensile strength, contact angle and adhesion peel strength for the core shell binder optimal conditions for handling the output of the surface treatment. The type of polymerization and composition of the binder is a regardless initiator of APS, the reaction temperature of $85^{\circ}C$ to 0.3 wt% of the surfactant used to indicate when the conversion rate was the highest, core shell composite particle binder got two glass temperature curves. Core shell binder after the plasma processing contact angle change is the PEA/PSt 38 percent of cases within five seconds to indicate slight decrease was a decline rapidly if not handled $0^{\circ}$ to reach. Tensile strength PSt/PMMA varies $46.71{\sim}46.27\;kg_f$/2.5 cm and adhesion strength PEA/PMMA varies $7.89{\sim}14.44\;kg_f$/2.5 cm increases. Overall, adhesion strength of core shell composite particle is in the order of order PEA>PBA>PSt for shell monomer MMA.

Weatherability of Organic-Inorganic Hybrid Coating Agents with N-Triethoxy silyl propyl quinine urethane (N-Triethoxy silyl propyl quinine urethane을 도입한 유-무기 복합 코팅제의 내후성)

  • Lee, Man Sung;Jo, Nam-Ju
    • Journal of Adhesion and Interface
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    • v.2 no.2
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    • pp.20-27
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    • 2001
  • Recently polycarbonate material has been utilized as windows in aircraft, buildings, and optical lens. However, while polycarbonate has excellent optical transparency, impact strength and many beneficial mechanical properties, it possesses poor abrasion resistance and weatherability. Then, there is a need for developing optically clear, anti-abrasive and weather resistant hard coating agents for polycarbonate. In this study, N-triethoxy silyl propyl quinine urethane(TESPQU) was synthesized with quinine and 3-isocyanato propyl triethoxy silane(3-IPTES). In order to introduce optically active silane in the main siloxane network, TESPQU was co-hydrolysed and co-condensed with methyl triethoxy silane(MTES) under acidic conditions. Polycarbonate sheets were coated with silica coating agents by the sol-gel method, and their abrasion resistance, ability of UV absorption and weatherability were evaluated. Coating agents containing hydroxybenzophenone as a UV absorber were also prepared to compare weatherability with TESPQU containing coating agent. TESPQU containing coating agent had good weatherability in accelerated QUV test.

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Improvement of High-fat Diet-induced Obesity by Xanthigen in C57BL/6N Mice (잔티젠(Xanthigen)에 의한 고지방식이로 유도된 비만 개선 효과)

  • Choi, Kyeong-Mi;Lee, Youn-Sun;Kim, Wonkyun;Choi, Yung-Hyun;Kwak, Youn-Gil;Jung, Jae-Chul;Lee, Jeongrai;Yoo, Hwan-Soo
    • Journal of Life Science
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    • v.22 no.12
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    • pp.1697-1703
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    • 2012
  • Obesity is a risk factor for numerous metabolic diseases. Recently, naturally occurring compounds that may improve obesity have received increasing attention. Xanthigen is a mixture of fucoxanthin and punicic acid derived from brown seaweed and pomegranate seed, respectively, which have been traditionally used for lipid-lowering effects in humans. In this study, we investigated whether Xanthigen attenuates high-fat diet-induced obesity in C57BL/6N mice. The mice were fed on a normal diet (ND), high-fat diet (HFD), HFD plus 1% Xanthigen or HFD plus 1% green tea extract (GTE) for 11 weeks. Food efficiency ratio (FER) and body weight were significantly reduced in mice fed HFD plus Xanthigen compared to HFD-fed mice. Consistent with the results in body weight change, Xanthigen also significantly decreased the weights of epididymal adipose tissue, retroperitoneal adipose tissue, and liver in HFD plus 1% Xanthigen-fed mice. The serum level of low-density lipoprotein (LDL)-cholesterol was significantly decreased in HFD plus Xanthigen-fed mice compared to HFD-fed mice. These results suggest that Xanthigen may be useful in the development of a functional health food for anti-obesity.

Current Status and Future Research Directions of Separator Membranes for Lithium-Ion Rechargeable Batteries (리튬이차전지용 분리막 이해 및 최신 연구 동향)

  • Kim, Jung-Hwan;Lee, Sang-Young
    • Membrane Journal
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    • v.26 no.5
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    • pp.337-350
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    • 2016
  • Lithium-ion rechargeable batteries (LIBs) have garnered increasing attention with the rapid advancements in portable electronics, electric vehicles, and grid-scale energy storage systems which are expected to drastically change our future lives. This review describes a separator membrane, one of the key components in LIBs, in terms of porous structure and physicochemical properties, and its recent development trends are followed. The separator membrane is a kind of porous membrane that is positioned between a cathode and an anode. Its major functions involve electrical isolation between the electrodes while serving as an ionic transport channel that is filled with liquid electrolyte. The separator membranes are not directly involved in redox reactions of LIBs, however, their aforementioned roles significantly affect performance and safety of LIBs. A variety of research approaches have been recently conducted in separator membranes in order to further reinforce battery safeties and also widen chemical functionalities. This review starts with introduction to commercial polyolefin separators that are currently most widely used in LIBs. Based on this understanding, modified polyolefin separators, nonwoven separators, ceramic composite separators, and chemically active separators will be described, with special attention to their relationship with future research directions of advanced LIBs.

Mixed Carbon/Polypyrrole Electrodes Doped with 2-Naphthalenesulfonic Acid for Supercapacitor (2-Naphthalenesulfonic Acid로 도핑된 혼합카본/폴리피롤을 이용한 Supercapacitor용 전극)

  • Jang, In-Young;Kang, An-Soo
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.425-431
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    • 2005
  • New type of supercapacitor using high surface area activated carbons mixed with high conductivity polypyrrole (Ppy) has been prepared in order to achieve low impedance and high energy density. Mixed carbons of BP-20 and MSP-20 were used as the active electrode material, and polypyrrole doped with 2-naphthalenesulfonic acid (2-NSA) and carbon black (Super P) as conducting agents were added to activated carbons in order to enhance good electric conductivity. Electrodes prepared with the activated electrode materials and the conducting agents were added to a solution of organic binder [P(VdF-co-HFP) / NMP]. The ratio of optimum electrode composition was 78 : 17 : 5 wt.% of (MSP20 : BP-20=1 : 1), (Super P : Ppy=10 : 7) and P(VdF-co-HFP) respectively. The performance of unit cell with addition of 7 wt% Ppy have shown specific capacitance of 28.02 F/g, DC-ESR of $1.34{\Omega}$, AC-ESR of $0.36{\Omega}$, specific energy of 19.87 Wh/kg and specific power of 9.77 kW/kg. With addition of Ppy, quick charge-discharge of unit cell was possible because of low ESR, low charge transfer resistance and quick reaction rate. And good stability up to 500 chargedischarge cycles were retained about 80% of their original capacity. It was concluded that the specific capacitance originated highly from compound phenomena of the pseudocapacitance by oxidation-reduction of polypyrrole and the nonfaradaic capacitance by adsorption-desorption of activated carbons.

Tailoring Low-field Strain Properties of [0.97Bi1/2(Na0.78K0.22)1/2TiO3-0.03LaFeO3]-Bi1/2(Na0.82K0.18)1/2TiO3 Lead-Free Relaxor/Ferroelectric Composites (무연 완화형/정규 강유전체 복합소재 [0.97Bi1/2(Na0.78K0.22)1/2TiO3-0.03LaFeO3]-Bi1/2(Na0.82K0.18)1/2TiO3의 저전계 전계유기 변형 특성 연구)

  • Hong, Chang-Hyo;Kang, Jin-Kyu;Jo, Wook;Lee, Jae-Shin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.342-347
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    • 2016
  • We investigated the effect of $Bi_{1/2}(Na_{0.82}K_{0.18})_{1/2}TiO_3$ (BNKT) modification on the ferroelectric and electric-field-induced strain (EFIS) properties of lead-free $0.97Bi_{1/2}(Na_{0.82}K_{0.18})_{1/2}TiO_3-0.03LaFeO_3$ (BNKTLF) ceramics as a function of BNKT content (x= 0, 0.1, 0.2, 0.3, 0.5, and 1). BNKT-modified BNKTLF powders were synthesized using a conventional solid-state reaction method. As the BNKT content x increased from 0 to 1 the normalized electric-field-induced strain ($S_{max}/E_{max}$) was observed to increase at relatively low fields, i.e., below the poling field. Moreover, BNKTLF-30BNKT showed about 460 pm/V as low as at 3 kV/mm, which is a considerably high value among the lead-free systems reported so far. Consequently, it was confirmed that ceramic-ceramic composite, a mixture of an ergodic relaxor matrix and embedded ferroelectric seeds, is a salient way to make lead-free piezoelectrics practical with enhanced EFIS at low field as well as less hysterical.

Characterization of Insulation Finish Material Using Inorganic Wet Treatment Fly Ash (무기성 습식 처리 플라이애시를 활용한 단열 외피 마감재의 특성 평가)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Song, Sung-Young;Kim, Deuak-Mo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.389-394
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    • 2019
  • In this study, a functional inorganic insulation as TiO2 and inorganic wet fly ash were used to evaluate the physical performance and thermal environment of an exterior finish that can improve the thermal environment of a building. The performance evaluation of the finish was based on the KS F 4715 thin coating material and the thermal environment. When TiO2 was added, the physical performance was lowered at 10% or more, and the inorganic wet-treated fly ash increased the physical performance by 10%. In the thermal environmental evaluation, the surface temperature reduction effect of the inorganic wet-treated fly ash was low, but when used in combination with TiO2, it was effective to reduce the surface temperature and the internal temperature. As a result, the optimum combination of TiO2 and inorganic wet-treated fly ash for thermal environment control was found to be optimal when 5% of each mixture was used.

Trend of the welding technology for surface modification (표면개질을 위한 오버레이용접 기술개발 현황)

  • 백응률
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.11a
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    • pp.19-20
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    • 1998
  • 오버레이용접에 의한 표면개질기술(Weld Surfacing or Hardfacing Technology)은 내식성, 내 마모성, 또는 내열성을 갖는 합금의 용접재료를 모재 표면에 균일하게 용착(오버레이:Ovedayer)시킴으로써 목적하는 재료의 표면성질을 향상시키는 표면처리의 한 방법이으로써 1922년 Stoody가 Steel Tube에 Cr합금 분말을 충진한 용접봉을 제조하여 석유시추용 회전드릴의 선단 표면을 오버 레이 용접시켜 내마모성을 획기적으로 개선시킴으로써 이루어 졌다. 초기 오버레이 용접기술은 발전설비I 제철설비I 시벤트설비, 그리고 제지설비 등 주로 설비 부품들의 표면부 내마모성을 개선시키는 방향으로 주로 연구 개발이 이루어졌으나, 기술개발의 진전으로 탈황설비 둥의 표면부 내식성 향상, 연속주조롤 표면부의 내산화성, 내열피로성, 내마모 성 향상 둥을 위해 점차 산업전반에 널리 이용되고 있으며, 설비의 고도화 및 장수명화가 요구되 면서 본 기술의 중요성 또한 점차 부각되고 있다. 그림 1은 연강의 모재 위에 셀프쉴드플럭스코어드와이어(Self-Shield Flux Cored Wire:SS-FCW, 이하 55-FCW라 기술함)를 사용하여 오버레이 용접올 하는 장면을 도식적으로 나 타낸 것이다. 모재와 전극재인 용접봉(S5-FCW) 사이에서 아크가 발생되고, 아크열에 의해서 용접 봉 및 모재 일부가 용융되면서 모재 표면에 새로운 오버레이 표면층이 형성된다. 통상 오버레이 층의 1층 두께는 2-6mm 내외이며, 단층 혹은 다충 오버레이를 자유롭게 실시한다. 오버레이층의 물성은 아크열에 의한 모재로의 용입정도에 따라 1층부에서는 모재의 영향을 크게 받지만 오버레 이충 수가 증가된 3층부에서 부터는 전적으로 용접봉의 성분에 좌우된다. 사진 1은 연강(55-41)의 모재위에 크롬탄화물이 다량 함유된 고크롬 탄화물형 내마모재가 오버 레이된 내마모 복합강판 (wear plate)의 단면 미세조직 사진으로써 모재부와 오버레이충을 함께 보여주고 있다. 모재와 오버레이 충간의 경계면은 모재 일부가 용융된 후 웅고하면서 형성됨으로 인해서 도금이나 용사층과는 달리 매우 견고하게 결합되어 있다. 따라서 계면부의 탈락이라는 문 제점은 거의 없어 심한 응력을 받는 기계구조물 및 부품에도 본 기술은 널리 적용되고 있다. 그리고 사진 1에서 알 수 있는 바와 같이 모재와는 전혀 상이한 재료를 자유로이 선택하여 표면 유효층 일부만 오버레이시키며I 주조 및 단조가 불가능한 재료까지도 표면부에 오버레이 시킴으로 서 부품 및 설비의 제조에 있어 재료비의 절감과 제품의 수명이 획기적으로 개선될 수 있다. 그리고 최근에는 도금 빛 용사 둥과 같은 표면처리를 할 경우임의 소재 표면에 도금 및 용 사에 용이한 재료를 오버레이용접시킨 후 표면처리를 함으로써 보다 고품질의 표면층을 얻기위한 시도가 이루어지고 있다. 따라서 국내, 외의 오버레이 용접기술의 적용현황 및 대표적인 적용사례, 오버레이 용접기술 및 용접재료의 개발현황 둥을 중심으로 살펴봄으로서 아직 국내에서는 널리 알려지지 않은 본 기 술의 활용을 넓이고자 한다.

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