• Title/Summary/Keyword: 발화온도

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The Investigation of Combustible Hazard by Measurement of Flash Point and Autoignition Temperature of n-Dodecane (노말도데칸의 인화점과 최소발화온도 측정에 의한 연소위험성 고찰)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.25 no.2
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    • pp.120-125
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    • 2011
  • For the safe handling of n-dodecane, the explosion limits were investigated and the lower flash points and AITs (autoignition temperatures) by ignition delay time were experimented. By using the literatures data, the lower and upper explosion limits of n-dodecanee recommended 0.6 Vol.% and 4.7 Vol.%, respectively. The lower flash points of n-dodecane by using closed-cup tester were experimented $77^{\circ}$ and $80^{\circ}C$. The lower flash points of n-dodecane by using open cup tester were experimented $84^{\circ}C$ and $87^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for n-dodecane. The experimental AIT of n-dodecane was $222^{\circ}C$.

Measurement and Prediction of Autoignition Temperature of n-Butanol and sec-Butanol System (노말부탄올과 2차부탄올 계의 최소자연발화온도의 측정 및 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.26 no.5
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    • pp.48-53
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    • 2012
  • The autoignition temperature (AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-Butanol+sec-Butanol system by using ASTM E659 apparatus. The AITs of n-Butanol and sec-Butanol which constituted binary system were $340^{\circ}C$ and $447^{\circ}C$, respectively. The experimental AITs of n-Butanol+sec-Butanol system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

A Study of Minimum Autoignition Temperature Behavior (MAITB) of Benzene and n-Hexane Mixture (벤젠과 노말헥산 혼합물의 최소자연발화온도 거동에 관한 연구)

  • Ha, Dong-Myeong;Kim, Kyu-Hyun
    • Fire Science and Engineering
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    • v.27 no.1
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    • pp.8-13
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    • 2013
  • The autoignition temperature (AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for Benzene and n-Hexane system by using ASTM E659 apparatus. The AITs of Benzene and n-Hexane which constituted binary system were $583^{\circ}C$ and $240^{\circ}C$, respectively. The experimental AITs of Benzene and n-Hexane system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

Combustion Characteristics of Edible Oils (식용 유류의 연소특성)

  • Song, Young-Ho;Ko, Sang-Seom;Ha, Dong-Myeong;Chung, Kook-Sam
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2009.04a
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    • pp.460-466
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    • 2009
  • 식용유 화재는 일반유류와는 달리 연소형태나 소화작업에 있어 큰 차이를 보이고 있다. 최근 5년간 특수화재 가운데 원인별 화재 통계를 보면 식용유 화재의 발생빈도는 점점 증가하고 있지만, 식용유에 대한 화재 위험성에 관한 연구는 거의 전무한 실정이다. 본 연구에서는 식용유의 연소특성 알아보기 위하여 종류별 인화점, 연소점, 발연점에 대하여 클리블랜드 인화점 시험기를 사용하여 측정하였고, 최소자연발화온도 및 발화 비발화 영역 비교를 통한 발화한계 온도 곡선을 도출하였으며, 자연발화온도와 발화지연시간과의 관계를 측정하였다. 이 결과를 통하여 식용유의 화재 위험성 평가에 대한 기초적인 자료로써 제시할 수 있었다.

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Measurement and Prediction of Autoignition Temperature(AIT) of n-Decane+Ethylbenzene System (노말데칸과 에틸벤젠 계의 최소자연발화온도 측정 및 예측)

  • Lee, Jae-Hwa;Kim, Gui-Ju;Hong, Soon-Kang;Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.19 no.5
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    • pp.54-60
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    • 2015
  • The autoignition temperature (AIT) of a material is the lowest temperature at which the material will spontaneously ignite. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs of n-decane+ethylbenzene system by using ASTM E659 apparatus. The AITs of n-decane and ethylbenzene which constituted binary system were $210^{\circ}C$ and $430^{\circ}C$, respectively. The experimental AITs of n-decane+ethylbenzene mixture were a good agreement with the calculated AITs by the proposed equations with about $11^{\circ}C$ A.A.D.(average absolute deviation).

A Study on Characteristics of Auto Ignition and Activation Energy of Ethylene Glycol and Diethylene Glycol (Ethylene Glycol과 Diethylene Glycol의 자연발화 특성과 활성화에너지에 관한 연구)

  • Kim, Jung-Hun;Choi, Jae-Wook
    • Journal of the Korean Institute of Gas
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    • v.20 no.2
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    • pp.16-22
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    • 2016
  • Auto ignition characteristic is an important factor for handling combustible substance and fire prevention. This research studied about auto ignition characteristic and activation energy of Ethylene Glycol (EG) and Diethylene Glycol (DEG) by using ASTM D2155 type ignition temperature measuring apparatus. As the auto ignition temperatures, it was possible to get $434^{\circ}C$ for EG within sample amount range of $75{\sim}160{\mu}l$ and $387^{\circ}C$ for DEG within sample amount range of $130{\sim}150{\mu}l$. Also, it was possible to get $579^{\circ}C$ and $569^{\circ}C$ as instantaneous ignition temperatures with sample amount of $140{\mu}l$ for EG and DEG respectively. By using least square method from Semenov equation on measured ignition temperature and ignition delay time from this study, it was possible to calculate activation energy of EG as 25.41 Kcal/mol and DEG as 14.07 Kcal/mol. Therefore, it was possible to claim that DEG has more risk of auto ignition since the auto ignition temperature, instantaneous ignition temperature and activation energy of DEG is lower than EG.

The Effect of Heat on the Spiking Patterns of the Cells in Aplysia (군소 세포의 발화 형태에 미치는 열자극 효과)

  • Hyun, Nam-Gyu
    • Progress in Medical Physics
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    • v.18 no.2
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    • pp.73-80
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    • 2007
  • Fruitful findings have been produced from five out of sixty cells which were obtained from each 63 individual Aplisia caught at the Jeju coast. Spiking patterns of three out of five cells, such as relaxation oscillator, bursting within a short time of the inter-burst interval, chaotic bursting, period doubling sequences, bursting with long trains of action potentials separated by short silent periods, regular repeated beating or elliptic bursting, and silent states had been changed in order as the temperature was lowered to $10^{\circ}C\;from\;32^{\circ}C$. In the intervals of every about 40 minutes repeated ups and downs of temperature produced similar firing patterns at the allowable temperature ranges. The other two cells showed difference from these. The amplitudes of the action potentials of the two cells will not be highly decreased in 24 hours. Average spike frequencies, the inter-burst interval, peak to peak spike amplitude of action potentials, minimum potential values are compared and analyzed by using the computer programme. The spike frequencies according to temperature show the distribution of bell type, with maximal spike frequencies at intermediate temperatures and minimal ones at either end. The most common pattern consist of high spike frequency during failing and low one during rising temperatures.

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A Study on the Spontaneous Ignition Characteristics of Wood Pellets related to Change in Flow Rate (공기유량의 변화에 대한 우드펠릿의 자연발화 특성에 관한 연구)

  • Kim, Hyeong-Seok;Choi, Yu-Jung;Choi, Jae-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.590-596
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    • 2019
  • Uses of fossil fuels like coal and oil increases with industrial development, and problems like abnormal climate come up as greenhouse gas increases. Accordingly, studies are actively conducted on eco-friendly renewable energy as a replacement for the main resources, and especially, wood pellets with high thermal efficiency are in the limelight as an alternative fuel in thermal power stations and gas boilers. However, despite a constant increase in their usage, few studies are conducted on their risks like fire and spontaneous combustion. Thus, this study found the auto-ignition temperature and critical ignition temperature of wood pellets with a change in flow rate in a thermostatic bath, using a sample vessel with 20 cm in length, 20 cm in height and 14 cm in thickness to predict their ignition characteristics. Consequently, at the flow rate of 0 NL/min, as the core temperature of the sample increased to higher than the ambient temperature, they ignited at $153^{\circ}C$, when the critical ignition temperature was $152.5^{\circ}C$. At the flow rates of 0.5 NL/min and 1.0 NL/min, it was $149.5^{\circ}C$, and at the flow rate of 1.5 NL/min, it was $147.5^{\circ}C$. Consequently, at the same storage, the more the flow rate, the lower the critical ignition temperature became.

A Study on Spontaneous Ignition Temperature and Activation Energy of Hydroxypropyl Methyl Cellulose (Hydroxypropyl Methyl Cellulose의 자연발화온도와 활성화 에너지에 관한 연구)

  • Lim, Woo-Sub;Choi, Jae-Wook
    • Journal of the Korean Society of Safety
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    • v.22 no.5
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    • pp.77-83
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    • 2007
  • This study is conducted on spontaneous ignition temperature and activation energy of Hydroxypropyl Methyl Cellulose(HMC) powder. HMC is a kind of cellulose derivative and used as additives for building material, surface coating, printing ink, adhesives, cosmetics and medical supplies. So this material has been widely used as important additive in the chemical industry fields and a mount of production has increased year by year. Therefore, it is very important to find out the thermal ignition characteristics of its danger and the critical ignition temperature. This study was performed by the Spontaneous Ignition Tester(SIT) and so on. Based on the data of the SIT-II, the critical ignition point of HMC is about $186^{\circ}C$ which is slightly lower than normal cellulose.

Measurement of Autoignition Temperature of n-Propanol and Formic acid System (n-Propanol과 Formic acid계의 최소자연발화온도의 측정)

  • Cho, Young-Se;Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.27 no.5
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    • pp.64-69
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    • 2013
  • The autoignition temperatures (AITs) of solvent mixture was important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-propanol and formic acid system by using ASTM E659 apparatus. The AITs of n-Propanol and Formic acid which constituted binary system were $435^{\circ}C$ and $498^{\circ}C$, respectively. The experimental AITs of n-propanol and formic acid system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation). And n- Propanol and formic acid system was shown the minimum autoignition temperature behavior (MAITB).