• Title/Summary/Keyword: 반응성 상호작용

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Molecular holographic QSPR analysis on the reactivity between glycine and ninhydrin analogues as latent fingerprints detector (잠재지문 검출제로서 Ninhydrin 유도체들과 Glycine과의 반응성에 관한 분자 홀로그래픽적인 QSPR 분석)

  • Kim, Se-Gon;Jang, Seok-Chan;Cho, Yun-Gi;Hwang, Tae-Yeon;Park, Sung-Woo;Sung, Nack-Do
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.339-346
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    • 2007
  • To search the ninhydrin derivatives that have high chromogenic and fluorogenic properties, molecular holographic quantitative structure property relationship (HQSPR) models on the reactivity between glycine and ninhydrin analogues as latent fingerprint detector were derived and investigated quantitatively. The ${\varepsilon}LUMO$ (e.v.) energy of ninhydrin molecule was an important factor to reactivity of ninhydrin. And, it is suggested that the nucleophilic reaction by orbital-controlled reaction from the frontier molecular orbital (FMO) interaction between glycine and ninhydrin derivatives was more superior than that of electrophilic reaction by charged controlled reaction. The analytical results in atomic contribution maps also shows that the reactivity of ninhydrin was increased by meta-substituents as strong electron withdrawing groups on the benzo ring. Therefore, it is sugested by HQSPR and QSPR model that the 5,6-dinitroninhydrin molecule would increase the reactivity as much as three times as compared to none substituted ninhydrin molecule.

Reactive sound system suitable for platform genre games (플랫폼 게임에 적용될 수 있는 반응성 사운드 시스템)

  • Park, Dae-Hwan;Lee, Dong Lyor;Lee, Wan Bok
    • Journal of the Korea Convergence Society
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    • v.4 no.4
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    • pp.7-12
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    • 2013
  • Presence of music in the modern game is getting bigger and bigger, and storytelling in the area of game play a leading role in many cases. Platform game is one type of action game genre. In its nature, the character and the object in a game are closely coupled, thus they have intermate relation with reactive sound system. In this study, we tried to build a effective and reactive sound system which is suitable for the storytelling of platform game. In addition, we speculated various aspects of game including psychological, musical and social aspects, finally investigating the future aspects of the game music.

Design and Implementation of the Smart AR System based on Contextual UX for Expansion of the Interaction (상호작용 확장을 위한 상황적 UX 기반의 스마트 증강현실 시스템 설계 및 구현)

  • Lee, Hye-Mi;Ryu, Nam-Hoon;Kim, Eung-Kon
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.2
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    • pp.439-445
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    • 2012
  • IT convergence technology is gradually becoming anthropocentric and evolving based on the low-carbon green growth. Augmented reality technique is a contents convergence technology that can mix virtual objects while maintaining a sense of the real world. For that reason, interaction between user and system is possible, can make various applications, and has a high possibility for expandability. To expand the scope of existing interaction, this paper suggests contextual UX-based augmented reality system. It is a system which creates virtual objects that respond to the changes in the real world environment, and users can directly apply their personal preferences to virtual objects. Also, several virtual objects can be registered all at once, and even shows animations corresponding to either day and night according to the brightness of illumination. As said, it improves user's satisfaction through a system of mixed usability, and leads to a continuous use of augmented reality contents.

Strategies for Emotional Regulation in Infancy and Maternal Responsiveness (영아의 정서조절 전략과 어머니의 반응유형 간의 관련성)

  • Kwak, Keumjoo;Kim, Minhwa;Hahn, Eun Joo
    • Korean Journal of Child Studies
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    • v.26 no.6
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    • pp.173-187
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    • 2005
  • This study examined relations between infants' strategies for emotional regulation and maternal responsiveness. Fifty 24-month-olds were observed for six kinds of emotional regulation strategy during four negative emotion-eliciting tasks; their mothers were observed for five styles of maternal responsiveness during toy-centered free play. Infants used different strategies according to the kinds of negative emotioneliciting tasks; their strategies correlated with maternal responsive styles. In the anger-eliciting tasks, infants used "distraction" and "self soothing." In the fear-eliciting tasks, they used "avoidance" and "problem solving." Infants who received more negative feedback from their mothers used the "irritation" strategy. Infants who got received more positive feedback from their mother used the "getting reference" strategy.

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Proposal on the Enhancement of Real-time Processing and Interaction in a Camera-tracked Laser Pointer System (카메라 추적 기반 레이저 포인터 시스템의 실시간 처리와 상호작용 개선을 위한 제안)

  • Lim, Jong-Gwan;Sohn, Young-Il;Sharifi, Farrokh;Kwon, Dong-Soo
    • 한국HCI학회:학술대회논문집
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    • 2008.02a
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    • pp.332-336
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    • 2008
  • For reliable real-time interaction in a camera-tracked laser pointer system, a new idea is proposed and its feasibility is tested in this paper. In order to improve response time in the system and remove useless visual overload, the function of a laser pointer in the system is divided, the Region of Functional Interest is defined and subsequently its new interactions are introduced. Finally the experiments to measure reliability, accuracy, latency and usability are conducted and the results are presented.

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Selectivity Changes in CO Hydrogenation over Potassium Added Titania-supported Cobalt Catalysts (티타니아 담지 코발트 촉매를 이용한 일산화탄소 수소화 반응에서 칼륨첨가에 의한 선택성 변화)

  • Lee, Dong-Keun;Ahn, Jou-Hyeon
    • Applied Chemistry for Engineering
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    • v.1 no.1
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    • pp.100-105
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    • 1990
  • Small amounts of potassium were added to the titania - supported cobalt catalysts in order to produce higher and olefinic hydrocarbons in CO hydrogenation. Titania and potassium played important roles not only for the enhancement of the production of higher and olefinic hydrocarbons, but also for the prevention of the catalyst deactivation by carbon deposits. Titania support induced the so - called SMSI, and potassium seemed to act as an electronic modifier, giving rise to an electron enrichment of the metallic phase.

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Effect of Interactivity on Cognitive-affective-behavioral User Responses: Focusing on Korean and Chinese Mobile Users (상호작용성이 사용자의 인지-정의-행위적 반응에 미치는 영향: 한국과 중국 모바일 사용자를 중심으로)

  • Um, Myoung-Yong
    • The Journal of the Korea Contents Association
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    • v.16 no.6
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    • pp.135-150
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    • 2016
  • This study aims to investigate how perceived interactivity between the mobile messenger application and its user gives rise to user's enjoyment and continuous usage intention. Perceived interactivity was assumed to be formed by the combination of control, share, and responsiveness in light of the previous studies. The relations between perceived interactivity, enjoyment, and usage intention are hypothesized on the basis of the pleasure-arousal-dominance emotional state model, the theory of reasoned action, and the theory of planned behavior. Survey data were collected from 481 mobile messenger users in Korea and China. In order to test hypotheses, structural equation modeling analyses were conducted. As a result, perceived interactivity concerning connectedness and responsiveness not only positively affected enjoyment, but also had a significant effect on usage intention. However, while control positively influenced usage intention, it was not significantly related to enjoyment. In addition, there was a positive relation between enjoyment and usage intention. Incidentally, multi-group analysis was conducted to explore the differences between Korean and Chinese users. The findings would provide managerial implications for mobile messenger corporations on causal effects of perceived interactivity and the differences of the path coefficients between in Korea and China.

Interactions between Hydrodenitrogenation of Pyridine and Hydrodeoxygenation of m-Cresol over sulfided CoMo/γ-Al2O3 Catalyst (황화 CoMo/γ-Al2O3 촉매상에서 수첨탈질반응과 수첨탈산소 반응의 상호작용)

  • Kim, Hak-Soo;Park, Hea-Kyung;Kim, Kyung-Lim
    • Applied Chemistry for Engineering
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    • v.2 no.2
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    • pp.108-118
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    • 1991
  • Interactions between pyridine hydrodenitrogenation (HDN) and m-cresol hydrodeoxygenation(HDO), and the kinetic analysis were studied over sulfided $CoMo/{\gamma}-Al_2O_3$ catalyst at the range of temperatures between 473 K and 723 K, the total pressures between $10{\times}10^5Pa$ and $50{\times}10^5Pa$, and the contact times between 0.0125 g-cat. hr/ml-feed and 0.03g-cat. hr/ml-feed. HDN of pyridine and HDO of m-cresol were inhibited by each other and the inhibition effect of HDO by pyridine is higher than that of HDN by m-cresol. But reactivity of m-cresol is higher than that of pyridine. The rate equations of pyridine and m-cresol were given to be ${\gamma}_{HDN}=k_{HDN}{\cdot}K_pC_p/(1+K_cC_c+K_pC_p)$ and ${\gamma}_{HDO}=k_{HDO}{\cdot}K_cC_c/(1+K_cC_c+K_pC_p)$ in terms of Langmuir-Hinshellwood-Hougen-Watson model. At each temperature, reaction rate constants and adsorption equilibrium constants were determined and activation energies of pyridine HDN and m-cresol HDO are 13.83kcal/mol, respectively and the heat of adsorption are -6.458 and -5.045kcal/mol, respectively.

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Cyanine 및 Merocyanine색소의 분광특성 및 광전특성(2)

  • 손세모;권태선;김성훈
    • Proceedings of the Korean Printing Society Conference
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    • 1995.11a
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    • pp.13-17
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    • 1995
  • 헤테로원자(X=O, S, Se)의 변환에 따라 용액상에서 Merocyanine색소 및 Cyanine색소의 헤테로원자X는 p궤도의 원자보다 d궤도의 원자가 공명에 관여하여 공역계확장에 기여하였고, 유전률이 큰 용매 일수륵 Merocyanine색소는 장파장으로 흡수극대치가 이동하였다. 또 Cyanine색소의 기저상태는 $I^-$이온과 정전하 발색단을 가진 이온성 화합물로 되어 있으므로 극성용매에서 $I^-$ 이온의 전하가 색소본체로 전하 이동전이가 발생하여 단파장화 하였다. 고상에서 색소의 농도가 높을 수록 색소분자간의 거리가 가까워져 색소 상호작용이 변화하여 흡수스펙트럼에서는 전체적으로 폭이 넓은 형태로 나타났으며 이것은 농도가 높을 수록 색소분자간의 거리가 가까워져 색소 상호작용이 변화한 때문이라고 생각된다. 또한 3차원 형광의 저농도에서 보이지 않는 새로운 스펙트럼이 Cyanine색소에서 나타났으며 이 스펙트럼은 색소고유의 흡수에 기인한 것으로 Eximer형광으로 생각된다. 광전특성에 있어서는 Merocyanine색소가 Cyanine색소보다 활성화에너지가 낮아 전하이동도가 커짐에 따라 높은 광전특성을 나타내었다. 그리고 Merocyanine색소 헤테로원자(X)의 비교에서 광전특성은 O

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Effect of Nonlinear Interaction to the Response of a Wave Spectrum to a Sudden Change in Wind Direction (풍속변화에 따른 파랑 스펙트럼 반응에서의 비선형 효과)

  • 윤종태
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.8 no.2
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    • pp.151-160
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    • 1996
  • To construct the third generation model, nonlinear interaction was included in source terms. To calculate the nonlinear interaction, discrete interaction approximation to Boltzmann integral was used, as in WAM model. The general behavior and characteristics of nonlinear interaction were analyzed through the experiments for the durational growth and turning winds.

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