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Metal-organic Chemical Vapor Deposition of Uniform Transition Metal Dichalcogenides Single Layers and Heterostructures (유기금속화학기상증착법을 이용한 전이금속 칼코게나이드 단일층 및 이종구조 성장)

  • Jang, Suhee;Shin, Jae Hyeok;Park, Won Il
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.119-125
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    • 2020
  • Transition metal dichalcogenides (TMDCs), two-dimensional atomic layered materials with direct bandgap in the range of 1.1-2.1 eV, have attracted a lot of research interest due to their high response to light and capability to build new types of artificial heterostructures. However, the large-area synthesis of high-quality and uniform TMDC films with vertical-stacked heterostructure still remains challenge. In this study, we have developed a metal-organic chemical vapor deposition (MOCVD) system for TMDCs and conducted a systematic study on the growth of single-layer TMDCs and their heterostructures. In particular, using a bubbler-type organometallic compound sources, the concentration and flow rate of each source can be precisely controlled to obtain uniformly single-layered MoS2 and WS2 films over the centimeter scale. In addition, the MoS2/WS2 vertical heterostructure was achieved by growing WS2 film directly on the MoS2 film, as confirmed by electron microscopy, UV-visible spectrophotometer, Raman spectroscopy, and photoluminescence spectroscopy.

Effect of Die Attach Film Composition for 1 Step Cure Characteristics and Thermomechanical Properties (다이접착필름의 조성물이 1단계 경화특성과 열기계적 물성에 미치는 영향에 관한 연구)

  • Sung, Choonghyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.261-267
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    • 2020
  • The demand for faster, lighter, and thinner portable electronic devices has brought about a change in semiconductor packaging technology. In response, a stacked chip-scale package(SCSP) is used widely in the assembly industry. One of the key materials for SCSP is a die-attach film (DAF). Excellent flowability is needed for DAF for successful die attachment without voids. For DAF with high flowability, two-step curing is often required to reduce a cure crack, but one-step curing is needed to reduce the processing time. In this study, DAF composition was categorized into three groups: cure (epoxy resins), soft (rubbers), hard (phenoxy resin, silica) component. The effect of the composition on a cure crack was examined when one-step curing was applied. The die-attach void and flowability were also assessed. The cure crack decreased as the amount of hard components decreased. Die-attach voids also decreased as the amount of hard components decreased. Moreover, the decrease in cure component became important when the amount of hard component was small. The flowability was evaluated using high-temperature storage modulus and bleed-out. A decrease in the amount of hard components was critical for the low storage modulus at 100℃. An increase in cure component and a decrease in hard component were important for the high bleed-out at 120℃(BL-120).

Photocatalytic Degradation of Rhodamine B, Methyl Orange and Methylene Blue with CdS and CdZnS/ZnO Catalysts under Visible Light Irradiation (가시광선하에서 CdS와 CdZnS/ZnO 광촉매를 이용한 로다민 B, 메틸 오렌지 및 메틸렌 블루의 광분해 반응)

  • Jeon, Hyun Woong;Jeong, Min Gyo;An, Byeong Yun;Hong, Min Seong;Seong, Sang Hyeok;Lee, Gun Dae
    • Clean Technology
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    • v.26 no.4
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    • pp.311-320
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    • 2020
  • In this study, the photocatalytic degradation of rhodamine B (RhB), methyl orange (MO) and methylene blue (MB) was carried out under visible light irradiation using CdS and CdZnS/ZnO photocatalysts prepared by a simple precipitation method. This study focused on examining the effect of physicochemical properties of dye and photocatalyst on the reaction pathway of photocatalytic degradation. The prepared photocatalysts were characterized by XRD, UV-vis DRS and XPS. Both the CdS and CdZnS/ZnO photocatalysts exhibit an excellent absorption in the visible light and the UV light regions. It was observed that the photocatalytic degradation of MO proceeds via the same reaction mechanism on both the CdS and CdZnS/ZnO photocatalysts. However, the photocatalytic degradation of RhB and MB was found to proceed through a different reaction pathway on the CdS and CdZnS/ZnO catalysts. It is interesting to note that MB dimer was formed on the CdS catalyst at the beginning of the photocatalytic reaction, while the MB monomer was degraded during the overall photocatalytic reaction on CdZnS/ZnO. The above results may be mainly ascribed to the difference of band edge potential of the conduction band in the CdS and CdZnS/ZnO semiconductors and the adsorption property of dye on the catalysts.

Performance Evaluation of Lead (II) Oxide Dosimeter for Digital Quality Assurance in Brachytherapy (방사선 근접치료의 디지털 정도관리를 위한 Lead (II) Oxide 선량계 성능 평가)

  • Han, Moo-Jae;Yang, Seung-Woo;Park, Sung-Kwang
    • Journal of the Korean Society of Radiology
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    • v.15 no.4
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    • pp.429-435
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    • 2021
  • In intracavitary radiotherapy, incorrect location of the source can cause excessive dose to normal tissue, so it is essential to evaluate the location accuracy of the source. In this study, basic research was performed on digital line dosimeter based on lead (II) oxide (PbO) to improve analog verification method. Therefore, a polycrystalline PbO unit cell dosimeter was manufactured and the measurement performance for Ir-192 sources was evaluated. As a result, the reproducibility satisfies the evaluation criteria of 1.5% with a relative standard deviation of 0.85%. Linearity showed excellent results with a linear coefficient of R2 of 0.9998. In the case of distance dependence evaluation, the power function R2 showed 0.9855 for PbO and 0.9974 for diode, and the overall average difference was 1.66% for PbO and 2.18% for diode. This study presents the basic detection performance of the polycrystalline PbO dosimeter for the Ir-192 source and can provide basic data in the field of radiation measurement.

A Study on The Effect of Current Density on Copper Plating for PCB through Electrochemical Experiments and Calculations (전기화학적 해석을 통한 PCB용 구리도금에 대한 전류밀도의 영향성 연구)

  • Kim, Seong-Jin;Shin, Han-Kyun;Park, Hyun;Lee, Hyo-Jong
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.1
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    • pp.49-54
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    • 2022
  • The copper plating process used to fabricate the submicron damascene pattern of Cu wiring for Si wafer was applied to the plating of a PCB pattern of several tens of microns in size using the same organic additives and current density conditions. In this case, the non-uniformity of the plating thickness inside the pattern was observed. In order to quantitatively analyze the cause, a numerical calculation considering the solution flow and electric field was carried out. The calculation confirmed that the depletion of Cu2+ ions in the solution occurred relatively earlier at the bottom corner than the upper part of the pattern due to the plating of the sidewall and the bottom at the corner of the pattern bottom. The diffusion coefficient of Cu2+ ions is 2.65 10-10 m2/s, which means that Cu2+ ions move at 16.3 ㎛ per second on average. In the cases of small damascene patterns, the velocity of Cu2+ ions is high enough to supply sufficient ions to the inside of the patterns, while sufficient time is required to replenish the exhausted copper ions in the case of a PCB pattern having a size of several tens of microns. Therefore, it is found that the thickness uniformity can be improved by reducing the current density to supply sufficient copper ions to the target area.

Analysis of the Surface Urban Heat Island Changes according to Urbanization in Sejong City Using Landsat Imagery (Landsat영상을 이용한 토지피복 변화에 따른 행정중심복합도시의 표면 열섬현상 변화분석)

  • Lee, Kyungil;Lim, Chul-Hee
    • Korean Journal of Remote Sensing
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    • v.38 no.3
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    • pp.225-236
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    • 2022
  • Urbanization due to population growth and regional development can cause various environmental problems, such as the urban heat island phenomenon. A planned city is considered an appropriate study site to analyze changes in urban climate caused by rapid urbanization in a short-term period. In this study, changes in land cover and surface heat island phenomenon were analyzed according to the development plan in Sejong City from 2013 to 2020 using Landsat-8 Operational Land Imager/Thermal Infrared Sensor (OLI/TIRS) satellite imagery. The surface temperature was calculated in consideration of the thermal infrared band value provided by the satellite image and the emissivity, and based on this the surface heat island effect intensity and Urban Thermal Field Variance Index (UTFVI) change analysis were performed. The level-2 land cover map provided by the Ministry of Environment was used to confirm the change in land cover as the development progressed and the difference in the surface heat island intensity by each land cover. As a result of the analysis, it was confirmed that the urbanized area increased by 15% and the vegetation decreased by more than 28%. Expansion and intensification of the heat island phenomenon due to urban development were observed, and it was confirmed that the ecological level of the area where the heat island phenomenon occurred was very low. Therefore, It can suggest the need for a policy to improve the residential environment according to the quantitative change of the thermal environment due to rapid urbanization.

Fabrication and Evaluation of Mercury(II) Iodide Unit Cell Dosimeter to Confirm the Feasibility of Digital Quality Assurance in Intracavitary Radiotherapy (방사선 근접치료의 디지털 정도관리 가능성 확인을 위한 HgI2 Unit Cell 선량계의 제작 및 평가)

  • Jung, Jae-Hoon;Park, Sung-Kwang
    • Journal of the Korean Society of Radiology
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    • v.16 no.3
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    • pp.257-263
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    • 2022
  • In intracavitary radiotherapy, it is essential to verify the correct location of radiation source among quality control items because an incorrect location will irradiate an unnecessary dose to normal tissues. As a basic study of digital line dosimeters, this study fabricated a unit cell dosimeter based on polycrystalline mercury (II) iodide (HgI2) and compared its performance with a diode. The study result showed that for reproducibility, the relative standard deviation (RSD) was 1.21%, satisfying the RSD evaluation criterion of within 1.5%. Considering linearity, the coefficient of determination R2 showed an excellent result of 0.9997. Regarding the evaluation of distance dependence, it showed a similar trend in general with a difference of 0.035 cm for intensity 50% when compared with the inverse square value. This study suggests the applicability of a digital dosimeter for brachytherapy quality control by evaluating the performance of the HgI2 dosimeter. This study on dosimeter for candidate photoconductor materials can be used as basic data in all areas using radiation.

Forest Burned Area Detection Using Landsat 8/9 and Sentinel-2 A/B Imagery with Various Indices: A Case Study of Uljin (Landsat 8/9 및 Sentinel-2 A/B를 이용한 울진 산불 피해 탐지: 다양한 지수를 기반으로 다시기 분석)

  • Kim, Byeongcheol;Lee, Kyungil;Park, Seonyoung;Im, Jungho
    • Korean Journal of Remote Sensing
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    • v.38 no.5_2
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    • pp.765-779
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    • 2022
  • This study evaluates the accuracy in identifying the burned area in South Korea using multi-temporal data from Sentinel-2 MSI and Landsat 8/9 OLI. Spectral indices such as the Difference Normalized Burn Ratio (dNBR), Relative Difference Normalized Burn Ratio (RdNBR), and Burned Area Index (BAI) were used to identify the burned area in the March 2022 forest fire in Uljin. Based on the results of six indices, the accuracy to detect the burned area was assessed for four satellites using Sentinel-2 and Landsat 8/9, respectively. Sentinel-2 and Landsat 8/9 produce images every 16 and 10 days, respectively, although it is difficult to acquire clear images due to clouds. Furthermore, using images taken before and after a forest fire to examine the burned area results in a rapid shift because vegetation growth in South Korea began in April, making it difficult to detect. Because Sentinel-2 and Landsat 8/9 images from February to May are based on the same date, this study is able to compare the indices with a relatively high detection accuracy and gets over the temporal resolution limitation. The results of this study are expected to be applied in the development of new indices to detect burned areas and indices that are optimized to detect South Korean forest fires.

A Study on the Entry of the Domestic Cold Chain Industry into the UN Procurement Market (국내 콜드체인 산업의 유엔 조달시장 진출방안)

  • Shin, Seok-Hyun
    • Journal of Navigation and Port Research
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    • v.45 no.6
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    • pp.333-345
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    • 2021
  • Amid the rapidly changing logistics environment and demand changes in the post-corona-19 era, the importance of the cold chain logistics sector is being highlighted. The scope of cold chain is not limited to food, but is expanding to various fields such as pharmaceuticals, semiconductors, and flowers. The demand on the storage and transportation of corona vaccines is rapidly increasing. The rapid increase in domestic low-temperature facility construction and renovation may lead to the saturation of the cold chain related industry in the future and slow growth. In preparation for this, it is necessary to accumulate infrastructure know-how using IT technologies, and to consider entering into the UN procurement market as a potential niche market, by taking advantage of Korea's recent global status. The demand for cold chain in the UN procurement market is increasing mainly in underdeveloped countries, and it is expected to continue to grow. In this paper, the capabilities of domestic cold chain related companies were analyzed, domestic and overseas cold chain logistics market trends and overseas market entry status were investigated. An in-depth survey was conducted to present strategies for domestic cold chain logistics related companies to enter the UN procurement market.

Active Front End Rectifier Control of DC Distribution System Using Neural Network (신경회로망을 적용한 직류배전시스템의 AFE 정류기 제어에 관한 연구)

  • Kim, Seongwan;Jeon, Hyeonmin;Kim, Jongsu
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.7
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    • pp.1124-1128
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    • 2021
  • As regulations of emissions from ships become more stringent, electric propulsion systems have been increasingly used to solve this problem in vessels ranging from large merchant ships to small and medium-sized ships. Methods for improving the efficiency of the electric propulsion system include the improvement of power sources; the use of a system linked to environmentally friendly power sources, such as batteries, fuel cells, and solar power; and the development of hardware and control methodology for rectifiers, power conversion devices, and propulsion motors. The method using a phase-shifting transformer with diodes has been widely used for rectification. Power semiconductor devices with grid connection to an environmentally friendly power source using DC distribution, a variable speed power source, and the application of small and medium-sized electric propulsion systems have been developed. Accordingly, the demand for active front-end (AFE) rectifiers is increasing. In this study, a method using a neural network rather than a conventional proportional-integral controller was proposed to control the AFE rectifier. Tested controller data were used to design a neural network controller trained through MATLAB/Simulink. The neural network controller was applied to a rectification system designed using PSIM software. The results indicated the effectiveness of improving the waveform and power factor DC output stage according to the load variation. The proposed system can be applied as a rectification system for small and medium-sized environmentally friendly ships.