• Title/Summary/Keyword: 물질안전보건자료

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Construction of web-based material DB and comparison of material properties using 3D graph (웹기반 재료 DB 구축 및 3D 그래프를 사용한 물성비교)

  • Chun D.M.;Ahn S.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.724-727
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    • 2005
  • Material selection is one of the important activities in design and manufacturing. A selected material at the conceptual design stage affects material properties of the designed part as well as manufacturability and cost of the final product. Unfortunately there are not many accessible material databases that can be used for design. In this research, a web-based material database was constructed. In order to assist designers to compare different materials, two-dimensional and three-dimensional graphs were provided. Using these graphical tools, multi-dimensional comparison was available in more intuitive manner. To provide environmental safety of materials, the database included National Fire Protection Association publication Standard No.704. The web-based tool is available at http://fab.snu.ac.kr/matdb.

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Benzene Contents and Reliability of Material Safety Data Sheets for Paint Thinners sold in Busan, Ulsan, and Gyeongnam (부·울·경에서 판매되는 도료 희석제의 구성성분 함량과 물질안전보건자료의 신뢰성에 관한 연구)

  • Sungjun, Woo;Kwonchul, Ha
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.32 no.4
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    • pp.340-349
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    • 2022
  • Objectives: The importance of MSDS is emphasized for communicating hazardous information due to the increase in the types and usage of chemical substances. The purpose of this study is to assess the reliability of MSDS by collecting and examining paint thinners commercially available in South Korea. Methods: Twenty-five paint thinners were purchased at paint stores and the provision of MSDS was checked. Quantitative and qualitative analysis was performed on the chemical constituents of the thinners using GC-MSD and GC-FID. Reliability was evaluated by the MSDS collection rate for the paint thinners and calculating the rate of matching between laboratory analysis results and the contents and composition of chemical constituents given in the MSDS. Results: Unlike a study conducted in 2006, MSDS were provided for all 25 thinners. As a result of qualitative analysis using GC-MSD, 104 chemical substances were detected. The substances with the highest detection rate were identified in the order of toluene, butyl acetate, acetone, xylene, and ethyl benzene. A component matching rate of 41% was found by comparing the differences between the number of substances detected in laboratory testing and the number of substances listed in the MSDS. Benzene, a carcinogen not listed in the MSDS, was detected in two thinners produced by a small company. The detected benzene contents were 0.039 and 0.040%. When benzene is used, it should be strictly handled according to the Industrial Safety and Health Act. However, since it is not listed on the MSDS, it is judged that benzene was not being managed as a carcinogen in the workplaces where it is used. Conclusions: Since the reliability of MSDS, which play an important role in hazard communication, was evaluated to be low, it is necessary to systematically and continuously secure this reliability. In particular, carcinogens should be managed more strictly.

Study on Development Method of VR Training Contents for Power Plant Safety Education - Focused on sealed space and welding fire - (발전소 안전교육 가상현실 콘텐츠 개발 방법 연구 - 밀폐공간 및 용접화재를 중심으로 -)

  • Min, Seol-hui;Park, Bong-sung;Kim, Yoo-shik;Lee, Sung-Ki;Lee, Dong-Joon;Kang, Ki-Heon
    • Proceedings of the Korea Contents Association Conference
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    • 2019.05a
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    • pp.367-368
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    • 2019
  • 여러 가지 안전사고 항목 중에 밀폐공간 작업과 관련된 사고는 다른 사고에 비해 사망으로 이어질 가능성이 매우 높으며, 사고 발생 시 2명 이상이 동시에 사망하거나 부상당할 가능성이 높은 사고다. 안전보건공단 자료에 의하면, 사고자 2명 중 1명이 밀폐공간 질식사고자이다. 또한 용접작업은 발전소 작업 현장에서는 보일러 튜브 교체 및 수리 등 다양한 부분에서 많이 사용되고 있다. 특히 발전소는 위험물질을 다량 보유하고 있는 곳으로, 고열, 불티에 의한 화재폭발은 대형 인명사고로 이어질 가능성이 매우 높다. 그러나 밀폐공간 작업 및 용접작업에 대한 안전교육은 직접 체험이 어렵기 때문에 효과적인 교육 방법에 대한 연구가 필요하다. 그러므로 본 연구에서는 가상현실 기술을 적용하여 발전소 작업 현장 인원을 대상으로 안전교육이 가능한 밀폐공간 작업 및 용접작업 시 일어날 수 있는 일을 체험할 수 있도록 한 가상현실 안전교육 콘텐츠를 개발한 내용에 대해 살펴보고자 한다.

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Study on applying to Hazard Classification Criteria of Chemicals subject to Material Safety Data Sheets (물질안전보건자료 대상물질의 유해성 분류기준 적용 연구)

  • Lee, Hye Jin;Lee, Naroo;Lee, In Seop
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.30 no.3
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    • pp.280-291
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    • 2020
  • Objectives: Hazard classification is a controversial issue in the new MSDS system in which chemical companies have to prepare and submit MSDS for chemicals that they manufacture or import to the competent authorities according to the amended Occupational Safety and Health Act. The aim of this study is to suggest how to apply and manage harmonized hazard classification criteria and results by investigating current hazard classification systems and trends. Methods: The domestic issues about different hazard classification criteria and results were investigated by reviewing the literature and business outcomes regarding KOSHA. We also checked official and unofficial reports from the UN to understand international discussion about the topic. Chemical hazard classification results from agencies providing chemical information were analyzed to compare a harmonized rate between classifications. Furthermore, a field survey of a few chemical companies was conducted. Results: Under the related competent authorities, an integrated standard proposal was developed to harmonize the domestic hazard classification criteria. Although harmonized chemical information is strongly needed, we recognized the uncertainty and difficulty of harmonized hazard classification from the UN global list project review. In practice the harmonization rate of the classification was generally low between the classification in KOSHA, MoE, and EU CLP. Among hazard classes, health hazards largely led the disharmony. The field survey revealed a change of perception that the main body of chemical information production is manufacturers. Approaches and solutions about hazard classification issues differed depending on business size, types of chemical handling, and other factors. Conclusions: We proposed reasonable ways by time and step to apply hazard classification in the new MSDS system. Chemical manufacturers should make and offer chemical information including responsible hazard classifications. The government should primarily accept these classifications, evaluate them by priority, and support or supervise workplaces in order to communicate reliable chemical information.

A Study on the Risk of Organic Solvents for Underground Area under Construction Site through a Fire Accident Case (화재사고사례를 통해서 본 건설현장 지하공간에서의 유기용제의 위험성에 대한 연구)

  • Ahn, Byung-Joon;Jung, Ki-Hyuk;Lee, Jung-Suk;Rhim, Jong-Kuk
    • Journal of the Korean Institute of Gas
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    • v.22 no.1
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    • pp.9-17
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    • 2018
  • In the consideration of the working conditions, which have several kinds of works operating at the same time, at construction sites, it is difficult to prevent industrial accidents. There are a number of works to employ flammable materials and hot works simultaneously operated without fire protection systems. It causes a huge fire and casualties. In this research to analyze an accident case, the reasonable prevention methods are suggested throughout the property tests for the organic solvents and the analysis of the behavior for vapour cloud in the underground area of the construction site.

How to improve the reliability of MSDS and labels?: A critical review on the U.S. Standard 29 CFR Part 1910 Hazard Communication (물질안전보건자료 및 표시 제도의 개선 방향 제안 - 미국 유해정보소통기준(HCS)의 비판적 고찰에 기초하여)

  • Kim, Shinbum;Lee, Yun Keun;Choi, Youngeun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.1
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    • pp.1-12
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    • 2015
  • Objectives: The major objectives of this study are to review the U.S. Standard which affected Korean worker's Right-to-Know Standard and to propose the way of improving the reliability of MSDS and labels. Methods: To review the U.S. Standard historically, we used the Federal Register, other criteria documentation and peer-reviewed literatures. Then we analysed major issues in the historical debatement on the worker's Right-to-Know Standard. Results: Korean MSDS Standard benchmarked the U.S. Hazard Communication Standard which finally established by President Reagan in 1983. Reagan's Hazard Communication Standard was aimed to preempt States Right-to-Know Acts for chemical industry and not to improve the awareness of workers on chemical hazards. Too much protection on trade secrets and low reliability of hazard information were key problems of the U.S. Standard. Conclusions: We recommend some ways to improve Korean MSDS and Label Standard. First, A new analysis frame is needed to understand the U.S Standard. Second, hazard identification is the key element of reliable information and chemical name and CAS number should be on the label of the container. Third, trade secrets should be limited to low hazardous substances and be permitted by government before the chemical product is on the market.

Assessment of the Accuracy on MSDS of Water-soluble Metalworking Fluids with Respect to Concentration of MEA, DEA and TEA (수용성 절삭유(Water-Soluble Metalworking Fluids)에서 분석한 MEA, DEA, TEA의 농도 분포 특성 및 물질안전보건자료(MSDS)에 대한 정확성 평가)

  • Lee, Kwon Seob;Sun, Ok Nam;Yoon, Kyung Sup;Park, Dong Uk
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.15 no.1
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    • pp.52-60
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    • 2005
  • This study was carried to assess the accuracy of material safety data sheets (MSDS) for some water-soluble metalworking fluid (MWF) with respect to mono- ethanolamine(MEA), di-ethanolamine(DEA) and tri-ethanolamine (TEA). 39 fresh and 52 used MWFs for this study were taken from the workplace. The quantification and qualification of MEA, DEA and TEA were done using ion-chromatography. Three main findings of this study were 1) EA that was not addressed in material safety & data sheets (MSDS) was found to be enough higher than 1%, 2) 33.3% of 39 fresh MWF showed ingredient and concentration of MEA, DEA and TEA in MSDS and 3) the concentrations of MEA(20.5%), DEA(41.3%) and TEA(15.4%) were much higher than those indicated in MSDS. Consequently, we concluded that the accuracy on ingredients and concentrations of MEA, DEA and TEA provided in MWF was very low. Our study recommends that the limit concentration of chemical except for carcinogen that employer has to indicate in MSDS should be lowered from 1% to 0.1% .

How to Improve the Reliability of MSDS and Labels?(2): A Review on the EU CLP(REGULATION(EC) No 1272/2008) (물질안전보건자료 및 표시제도의 개선 방향 제안(2) - 유럽연합의 CLP 제도 고찰에 근거하여)

  • Kim, Shinbum;Lee, Yun Keun;Choi, Youngeun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.2
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    • pp.115-125
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    • 2015
  • Objectives: The major objectives of this study are to review the EU CLP Regulations to propose ways of improving the reliability of MSDS and labels. Methods: To review the EU CLP Regulations, we used EU documents including directives and regulations on chemical management. In addition, we used EU governmental agency reports to illuminate the history and background of the CLP. We found the EU CLP's instruments for reliable hazard communication and evaluated the operations of the instruments. Results: EU CLP Regulations have four instruments for the EU CLP Regulations to make hazard communication reliable. These instruments are GHS, the harmonized CMR and respiratory sensitive substances classification list, C&L inventory and restriction of trade secrets. These are highly useful for achieving the objectives of REACH and CLP(no data-no market and changing the burden of proof). Conclusions: Changing the burden of proof is a key principle for achieving a society safe from hazardous chemicals. Chemical manufacturers and importers alone should bear the responsibility for reliable MSDS. We recommend benchmarking the EU CLP Regulations in order to change efficiently the burden of proof. Trade secrets should be limited to low-hazard substances and be approved by the government before the chemical product is on the market. Like the C&L inventory, chemical product information including substances identification and hazard properties should be notified, aggregated and be opened to public on the Internet. Finally, we recommend a MSDS registration system once again.

Examination and Suggestions on Introducing and Administering Confidential Information Review on Material Safety Data Sheets (국내 물질안전보건자료 영업비밀 심사제도의 도입·운영에 대한 검토 및 제안)

  • Lee, Kwon Seob;Jo, Ji hoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.1
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    • pp.91-99
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    • 2018
  • Objectives: From a policy perspective, the introduction of confidential information reviews is a vital task for expanding workers' right to know and improving hazardous materials information communication. In this study, rational methods for introducing and administering confidential information reviews were examined as a part of advancing chemical information communication. Methods: The domestic status, social demands, and control cases from other countries about confidential information in material safety data sheets(MSDSs) were all examined. Additionally, principles for introducing MSDS confidential information review, what needs to be revised prior to its introduction, and procedures and manners of reviewing confidential information were suggested. Results and Conclusions: When composition information on MSDS needs to be protected in the EU and Canada, confidential information should be claimed and then approved by competent authorities with a principle of reviewing confidential information prior to rescinding information from MSDS. Applying the same principle, certain information on an MSDS that needs to be protected should be reviewed and approved in Korea. As a result, the MSDS is communicated with approval numbers replacing composition information. MSDS confidential information review has five steps, including deciding whether chemicals claimed to be confidential are excluded from applying for a confidentiality exemption, the names and concentration ranges of ingredients are adequate, and the claimed information is valid in terms of confidentiality.

Factors Affecting the Recognition and Practice of Hazardous Chemical Substance & the Management of Material Safety Data Sheet (MSDS) among Workers in Dental Clinics (구강보건의료기관 종사들의 유해화학물질 인식, 실천 및 물질안전보건자료 (MSDS) 관리에 영향을 미치는 요인)

  • Jung, Hye-Young;Mun, Won-Suk;Kim, Ji-Young
    • Journal of The Korean Society of Integrative Medicine
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    • v.9 no.3
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    • pp.79-86
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    • 2021
  • Purpose : This study was conducted to provide fundamental data to prepare for countermeasure to protect health of workers in the dental clinics from hazardous chemical substance, and to assess effecting factors on management of Material Safety Date Sheet(MSDS) and handling of hazardous chemical substance among workers in dental clinics. Methods : This study was carried out a survey with structured self-administered questionnaire which was consisted of 7 questions about the management of MSDS, 9 questions about recognition and practice of hazardous chemical substances in dental clinics, and 7 questions about general characteristics. Total subjects of this study were 204 adult who workers in dental clinics located in Busan and Gyeng-nam province area. The collected data were analysed using the SPSS statistical package program (ver. 23.0). Results : The factor that positively affected factor on recognition and practice of hazardous chemical substances in dental clinics has experience that has been institutional health-care accreditation. The factor that positively affected the management of MSDS has experience that has been institutional health-care accreditation. Conclusion : It is necessary to prepare countermeasures such as campaign and education on cognition of general chemical substances, and also the author concern that it should be perform the education on handling of hazardous chemical substances in dental clinics for more effecting management of MSDS. In order to improve the management of MSDS and improve the awareness and safety of chemicals, it is necessary to encourage the implementation of the institutional health-care accreditation system or prepare guidelines for the management of MSDS.