• Journal of Korean Society of Water Science and Technology
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• v.26 no.6
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• pp.109-115
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• 2018

This study was conducted to solve the water shortage problem by reclaiming urine from homes or public places and using it as cleaning water for toilets. The process used in this experiment is a chemical oxidation process combining ozone, hydrogen peroxide, and UV. We set the key substance that is to be removed as chromaticity and conducted the experiment to remove it. If the quantity or concentration of injected ozone, UV, and hydrogen peroxide is insufficient, then the chromaticity will initially increase due to low oxidizing power, and will later decrease. In addition, the efficiency of removing chromaticity appeared to be higher, depending on the quantity of ozone injected, for medium concentrated urine than highly concentrated urine. However, the absolute quantity of removed chromaticity was about 68% higher for highly concentrated urine, when 16 g/hr of ozone was injected. The higher the pH level, the reaction time and efficiency of removing chromaticity were higher, and in normal conditions, in reference to a pH of 8.55, there was a 6% difference in efficiency between a pH level of 5.05 and a pH level of 10.12. Finally, when processing urine through an ozone-only process, COD decreased steadily over time, but DOC did not decrease. This is because ozone reacts selectively with organic matter.

• The KSFM Journal of Fluid Machinery
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• v.20 no.2
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• pp.69-74
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• 2017

Sodium hypochlorite, used as water disinfectant, is generated by electrolysis of salt. Compared to chlorine gas disinfection, it is free from high-pressure gas regulation and does not generate toxic gas, so it is increasingly used as a safe disinfectant. Despite these advantages, the concentration of sodium hypochlorite decreases with temperature during long-term storage, and the amount of chlorate increases when a large amount is added, it has mainly been applied to small-scale waterworks. To solve this problem, high sodium hypochlorite generation was developed. In this study, the changes of concentration and chlorate of sodium hypochlorite with time has been studied. As a result of the test, it was found that the usable period of sodium hypochlorite produced at a certain temperature or less was increased from 1.5 days to 13 days. Overall, sodium hypochlorite can be applied even in large-scale waterworks, which makes operation more stable and also reduces the disinfection byproducts, thus it contributed greatly to securing water quality.

• Analytical Science and Technology
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• v.22 no.5
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• pp.386-394
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• 2009

Formaldehyde is used in lether manufacture, a dry plate and an explosive. It is by-product of ozonizing process in filtration plant. The effects of exposure are eye pruritus, tickle, runing nose, blocking nasal passages and headache. It also makes a dried throat and causes inflammation. It is classified as B1 group for inhalation by US. EPA, which can cause cancer in human. For analysis of formaldehyde, formaldehydes-DNPH derivative was extracted with solid cartridge and was analyzed by High Performance Liquid Chromatography/Diode Array Detector (HPLC/DAD). The detection limit was $3{\mu}g/L$ and the recoveries were 72.3~109.1% (RSD 2.9~11.5%). Water samples were collected in four Korean rivers, four times per year seasonally for 10 years from 1998 to 2007. The monitoring results were 48.8% (630/1291), $5.15{\sim}101.9{\mu}g/L$ in purified water. Because of non-carcinogen in drinking water, hazard index is calculated with RfD. Results of excess cnacer risk was below 1 and was considered as safe value.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.3
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• pp.183-189
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• 2017

Sodium hypochlorite used in water disinfection processes is generally in the production of chlorine to 0.8％. As the dose of chlorine increases, disinfection by-products (Chlorate) also increase simultaneously and exceed water quality standards. In this study, the electrolytic cell of a sodium hypochlorite generator (12％ chlorine) was adjusted to control the production of the disinfection by-products. As a result, it was possible to reduce Chlorate concentrations by more than 95％ by adjusting the pH of the electrolytic cell from 1.53 to 4.2 (normal pH of the electrolytic cell). As a low current is required to obtain these results, a 15％ improvement in the efficiency of the positive electrode is also observed. For the development of High Sodium Hypochlorite Generation can be used in a safe sodium hypochlorite solution, which is expected to contribute to improvement in the safety of the disinfection process.

• Journal of the Korean Society of Urban Environment
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• v.18 no.4
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• pp.439-453
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• 2018

The purpose of this study is to evaluate water quality characteristics of main drinking waters in natural parks, for providing the basic information of water quality and to propose the appropriate management method. to maintain the water quality standards. As a result of the analysis, microorganisms were mostly detected in the nature of natural park. And some sites are currently using UV sterilizer and ozone treatment, and it is considered appropriate to extend the use to other main drinking water. It is also good to boil drinking water at home. Turbidity is expected to improve through environmental cleanup. Overall, the main drinking water in the natural park is suitable for water quality standards, and it is considered that maintenance such as cleaning is necessary.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.4
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• pp.453-458
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• 2008

Laboratory experiments were conducted to investigate disinfection as well as removal of color and residual organics from reclaimed municipal wastewater by electrochemical processes with Nb/Pt anode installed. RNO was rapidly bleached by OH$\cdot$ and the second order rate constants of RNO removal were $\frac{0.223l}{mg{\cdot}min}$, $\frac{1.679l}{mg{\cdot}min}$ and $\frac{2.322l}{mg{\cdot}min}$ with for 5 A, 10 A, and 15 A, respectively, with r$^2$ of > 96%. In batch electrochemical processes, after 15 min at currency of 15 A and initial pH of 5, 7,5 and 9, COD$_{Mn}$ was below 4 mg/L, color unit below 5 degree and general bacteria was not detected, the concentration of which are suitable for drinking water regulation. In the continuous electrochemical process, with HRT of 3.7$\sim$49.2 min, free chlorine were 0.2$\sim$0.7 mg/L, general bacteria was not detected, color unit below 5 degree and THMs was 0.017 mg/L. Therefore, electrochemical process with Nb/Pt anode was employed satisfactory to meet for reusing biologically treated water as well as disinfection.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.1
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• pp.1-6
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• 2012

Down Stream K River has high COD (4-10 mg/L) and high $NH_3$-N concentration (3.5 mg/L during winter period). Although $NH_3$-N itself is not reported harmful at this level, it must be removed to meet drinking water standard (0.5 mg/L). We constructed a pilot plant modifying the processes of conventional drinking water facilities. Prechlorination and powdered activated carbon (PAC) dechlorination was adopted prior to a flocculation tank to remove ammonia and prevent disinfection byproducts (DBPs) formation. Also, GAC processes was included after sand filter to remove residual DOC. This pilot having a capacity of 36 ton/day was operated for one year. The GAC processes were successful to remove ammonia and many organic pollutants (DOC, MBAS, UV-254 nm absorbance, etc). Influent DOC concentrations were very high as 3~6 mg/L throughout the plant operation. It was impossible to achieve 1.0 mg/L effluent DOC, indicating that bed depth (2 m) should be increased to achieve more strict DOC quality standards. When $Cl_2$ dose was well controlled ($Cl_2/NH_3$-N ratio 10~11 on a weight basis), $NH_3$-N removal was 98% and THMs was very low possibly due to low free residual chlorine and PAC dechlorination.

• Korean Journal of Ecology and Environment
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• v.36 no.3 s.104
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• pp.356-368
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• 2003

Water quality of effluent from wastewater treatment plants (WWTPS) was reviewed to examine the feasibility of agricultural reuse using USEPA and WHO guidelines. It might meet the guidelines for BOD and SS, however, the most critical microbiological concentration was too high and further treatment is required. The pilot study of three treatments were performed to reduce microbiological concentrations. The UV irradiation was proved to be very effective in disinfection of secondary level effluent, and about 30 mW ${\cdot}$ s/$cm^2$ of dose was suggested to meet the even most stringent USEPA guidelines. Slow sand filter demonstrated effective removal of bacteria, and effluent concentration of total coliform (TC), fecal coliform (FC), and E. coli. dropped from about 10,000/100 mL to 300, 200, and 150 MPN/100 mL, respectively, showing over 95% removal. These level of bacterial concentration sufficiently meet the WHO guidelines ($10^3\;{\sim}\;10^5$ FC/100 mL), and could meet the more stringent USEPA guidelines (200 FC/100 mL) if properly applied. Slow sand filter also provided about 50% removal of SS, turbidity, and BOD in addition to bacterial removal. The removal efficiency of pond system was relatively poor, but still showed over 85% removal and effluent concentration of TC, FC, and E. coli was all below 10,000/100 mL. The pond system alone could meet the WHO guidelines, but hardly meet the USEPA guidelines and further treatment might be necessary. Overall, three methods evaluated in the study treat the effluent to meet the WHO microbiological guidelines for agricultural reuse. The UV disinfection and slow sand filter might also could the USEPA guidelines, while the pond system can hardly meet the USEPA guidelines if applied alone. The WHO and USEPA guidelines were made based on data from upland field agricultural system and may not be directly applicable to the paddy field agricultural system. Therefore, national standards for agricultural reuse of reclaimed water should be made considering domestic agricultural systems as well as international guidelines. Also, further investigation is recommended to develop optimum and feasible treatment measures for agricultural reuse of effluent from WWTPs.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.8
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• pp.534-541
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• 2014

This study investigated a method to determine an efficient operating condition for the $UV/H_2O_2$ process. The OH radical scavenging factor is the most important factor to predict the removal efficiency of the target compound and determine the operating condition of the $UV/H_2O_2$ process. To rapidly and simply measure the scavenging factor, Rhodamine B (RhB) was selected as a probe compound. Its reliability was verified by comparing it with a typical probe compound (para-chlorobenzoic acid, pCBA); the difference between RhB and pCBA was only 1.1%. In a prediction test for the removal of Ibuprofen, the RhB method also shows a high reliability with an error rate of about 5% between the experimental result and the model prediction using the measured scavenging factor. In the monitoring result, the scavenging factor in the influent water of the $UV/H_2O_2$ pilot plant was changed up to 200% for about 8 months, suggesting that the required UV dose could be increased about 1.7 times to achieve 90% caffeine removal. These results show the importance of the scavenging factor measurement in the $UV/H_2O_2$ process, and the operating condition could simply be determined from the scavenging factor, absorbance, and information pertaining to the target compound.

• The Journal of Engineering Geology
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• v.23 no.1
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• pp.37-46
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• 2013

Leakage of leachate from animal carcass disposal is a significant issue because disease can easily spread to humans and other livestock. In this study, we analyzed the physicochemical properties of leachate and tested for the presence of aerobic bacteria in leachate using molecular biology methods, for 16 animal carcass disposals in the first stage (after burial for 5 months). Leachate physicochemical analysis revealed higher total coliforms, TOC, $NH^{4+}$, and $NO^{3-}$ concentrations compared with previously published data. In most leachate samples, the concentrations of $NH^{4+}$ and $NO^{3-}$ exceeded the Korean guideline values for drinking water. In 16S rRNA sequence analysis of the distribution of leachate under aerobic conditions, Bacillus pumilus, Lysinibacillus sphaericus, and B. sphaericus were observed with high frequency, whereas no food-poisoning-related bacteria such as B. cereus or Salmonella were detected. The present findings improve our knowledge of the transport of leachate from animal carcass disposal sites through geologic media, and are useful in risk analysis and for subsequent studies.