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http://dx.doi.org/10.5806/AST.2009.22.5.386

Analysis and risk assessment of formaldehyde in water from water purification plant in korea  

Chae, Hyojin (Bioanalysis and Biotransformation Research Center, Korea Institute of Science and Technology)
Kim, Hyun Ku (Drinking water division, National Institute of Environmental Research, Environmental Research Complex)
Kim, Seungki (Bioanalysis and Biotransformation Research Center, Korea Institute of Science and Technology)
Pyo, Heesoo (Bioanalysis and Biotransformation Research Center, Korea Institute of Science and Technology)
Hong, Jongki (Department of Pharmaceutical Sience, Kyung Hee University)
Publication Information
Analytical Science and Technology / v.22, no.5, 2009 , pp. 386-394 More about this Journal
Abstract
Formaldehyde is used in lether manufacture, a dry plate and an explosive. It is by-product of ozonizing process in filtration plant. The effects of exposure are eye pruritus, tickle, runing nose, blocking nasal passages and headache. It also makes a dried throat and causes inflammation. It is classified as B1 group for inhalation by US. EPA, which can cause cancer in human. For analysis of formaldehyde, formaldehydes-DNPH derivative was extracted with solid cartridge and was analyzed by High Performance Liquid Chromatography/Diode Array Detector (HPLC/DAD). The detection limit was $3{\mu}g/L$ and the recoveries were 72.3~109.1% (RSD 2.9~11.5%). Water samples were collected in four Korean rivers, four times per year seasonally for 10 years from 1998 to 2007. The monitoring results were 48.8% (630/1291), $5.15{\sim}101.9{\mu}g/L$ in purified water. Because of non-carcinogen in drinking water, hazard index is calculated with RfD. Results of excess cnacer risk was below 1 and was considered as safe value.
Keywords
formaldehyde; 2,4-DNPH; HPLC/DAD; risk assessment; monitoring;
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