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http://dx.doi.org/10.3795/KSME-B.2017.41.3.183

A Study on Control Disinfection By-products in High Sodium Hypochlorite Generation  

Cho, Haejin (K-water)
Shin, Hyunsoo (Techwin)
Ko, Sungho (School of Mechanical Engineering, Chungnam Nat'l Univ.)
Publication Information
Transactions of the Korean Society of Mechanical Engineers B / v.41, no.3, 2017 , pp. 183-189 More about this Journal
Abstract
Sodium hypochlorite used in water disinfection processes is generally in the production of chlorine to 0.8%. As the dose of chlorine increases, disinfection by-products (Chlorate) also increase simultaneously and exceed water quality standards. In this study, the electrolytic cell of a sodium hypochlorite generator (12% chlorine) was adjusted to control the production of the disinfection by-products. As a result, it was possible to reduce Chlorate concentrations by more than 95% by adjusting the pH of the electrolytic cell from 1.53 to 4.2 (normal pH of the electrolytic cell). As a low current is required to obtain these results, a 15% improvement in the efficiency of the positive electrode is also observed. For the development of High Sodium Hypochlorite Generation can be used in a safe sodium hypochlorite solution, which is expected to contribute to improvement in the safety of the disinfection process.
Keywords
Control Disinfection By-products; Drinking Water Treatment; Disinfection Process; Electrolytic Cell; High Sodium Hypochlorite Generation;
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1 D. Lantagne, P.E., Preston, K., Blanton, E., Kotlarz, N., Gezagehn, H., van Dusen, E., Berens, J. and Jellison, K., 2011, "Hypochlorite Solution Expiration and Stability in Household Water Treatment in Developing Countries," Journal of Environmental Engineering, 137, Vol. 2, pp. 131- 136.   DOI
2 Snyder, S.A., Stanford, B.D. and Pisarenko, A.N., 2009, "HYPOCHLORITE-. An Assessment of Factors That Influence the Formation of Perchlorate and Other Contaminants," American Water Works Association.
3 Taube, H. and Dodgen, H., 1949, "Application of Radioactive Chlorine to the Study of the Mechanisms of Reactions Involving Changes in the Oxidation State of Chlorine," Journal of the American Chemical Society, 71, Vol. 10, pp 3330- 3336.   DOI
4 Vivion de Valera, 1953, "On the Theory of Electrochemical Chlorate Formation," 1953, Transactions of the Faraday Society, Vol. 49, pp. 1338-1351.   DOI
5 Emmenegger, F. and Gordon, G., 1967, "The Rapid Interaction between Sodium Chlorite and Dissolved Chlorine," Vol. 6, No. 3, pp. 633-635.   DOI
6 View issue TOC, De Nora V, 1975 "Der Beitrag der Dimensionsstabilen Anoden (DSA) zur Chlor- Technologie," Chemie-Ingenieur-Technik, 4, Vol. 47, pp. 125-128.
7 Foti, G., Mousty, C., Reid, V. and Comninells, Ch., 1998, "Characterization of DSA Type Electrode Prepared by Rapid Themal Decomposition of the Metal Precursor," Electrochimica Acta, 5, Vol. 44, pp. 813-818.   DOI
8 Mousty, C., Foti, G., Comninellis, Ch. and Reid, V., 1999, "Electrodhemical Behaviour of DSA Type Electrodes Prepared by Induction Heating," Electrochimica Acta, 3, Vol. 45, pp. 451-456.   DOI
9 Ihos, M., Bocea, G. and Manea, F., 2006, "DSA Type Electrodes Characterisation by Cyclic Voltammetry in the Presence of Surfactants," Chem. Bull. Politehnica Univ., 65, Vol. 51, pp. 54-56.
10 House, J. E. and House, K. A., 2015, "Descriptive Inorganic Chemistry," 3rd, Academic Press, Cambridge, Messachusetts, pp. 279-280.
11 European Commission, 2010, "Best Available Technique(BAT) Reference Document for the Production of Chlor-Alkali," JRC Science and Policy Reports.