• Proceedings of the KIEE Conference
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• 1990.07a
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• pp.221-223
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• 1990

In this study, we have studied the optioal properties and $I_2$ doping effect of Poly(3-Akkylthiophene) solution. The end of speotrum absorbance on the solutions of Poly(3 - Octylthiophene), Poly (3-Dodecylthiophene) and Poly(3-Dooooylthiophene) was dependent on temperature. It is bellved that conrod-coil transition dependent on temperature was rod-coil transition. And absortance peak of Poly (3-Dodecylthiophene) in dichloromethane solution increased with increasing the $I_2$ dopant.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.4
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• pp.323-327
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• 2001

The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. The radius of semicircle of CP composite cell with polyaniline(PAn) composite electrode adding 30wt% acetylene black was small. The total resistance of supercapacitor cell mainly depended on internal resistance of he electrode. The discharge capacitance of supercapacitor cell with PAn composite electrode adding 30wt% acetylene black in 1st and 50th cycles was 27F/g and 31F/g at current density of 1mA/$\textrm{cm}^2$, respectively. Supercapacitor cell with PAn composite electrode adding 30wt% acetylene black showed a good cycliability. Supercapacitor cell of CP composite electrode with 1M LiClO$_4$/PC brings out god capacitor performance below 4V.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.602-605
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• 1999

We dried emitting layer of EL device at 30, 80, I20 and $150^{\circ}C$ for Ihr to investigate the effects to the emission characteristics of devices. PL intensity of P3HT thin film decreased with increasing the drying temperature. But, the EL intensity and stability of device with emitting layer dried at $150^{\circ}C$ were the best. We think it s because of absence of water and remaining solvent in P3HT emitting layer. So, We suggest that the drying temperature of emitting layer of EL device should be select slightly low temperature than its glass transition temperature.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.332-334
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• 2000

The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Supercapacitor cell of CP composite electrode with 1M LiClO$_4$/ PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding 30wt% acetylene black was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PAn composite electrode adding 30wt% acetylene black in 1st and 50th cycles was 27F/g and 31F/g at current density of 1mA/$\textrm{cm}^2$. Supercapacitor cell with PAn composite electrode adding 30wt% acetylene black performed a good cycliability.

• Composites Research
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• v.19 no.5
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• pp.7-11
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• 2006

The improved SWNTs/PANi composite actuator films applicable to an artificial muscle were fabricated successfully using a new process of manufacture that consists of 90% pure single-walled carbon nanotubes (SWNT) and chemical polymerization. PANi is electrically conducting polyaniline polymer. The conductivities of the composite SWNTs/PANi film-type actuators and the pure PANi films fabricated were measured as 56.15 S/cm and 17.38 S/cm, respectively, by the 4-prove method. The conductivity of the composite actuator is 3.2 times higher than the pure PANi film. The fabricated composite actuator showed higher conductivity than any other similar ones. The quality of samples was investigated by an electron scanning microscope (SEM). To measure the actuating strains, a specially designed beam balance apparatus was developed and strains of the composite actuators was measured by a laser displacement sensor subjected to electric currents. During the operation, the sample was soaked in the $NaNO_3$ solution and the sine-wave voltage in the range of $+1V{\sim}-1V$ was applied. The length of the composite actuator changed from $l_0=12.690$ mm to $l_1=12.733$ so that the change of length was l=0.043 mm and the strain was 0.34 %. This is a very high strain for this kind of a composite actuator. Other result reported by Tahhan showed 0.23 % strain, so that the present result is improved by 48%.

• Journal of the Korean Electrochemical Society
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• v.19 no.3
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• pp.87-94
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• 2016

In order to improve performances of submicrometer-sized Si negative electrode which shows larger volumetric change than nano-sized Si, composite binders are introduced by blending between poly(phenanthrenequinone) (PPQ) conductive polymer binder and poly(acrylic acid) (PAA) having good adhesion strength due to its carboxyl functional group. Blending between PPQ and PAA shows an effect that the adhesion strength of the Si electrode with the composite conductive binder is greatly improved after blending and this makes its better stable cycle performance. Blending ratios between PPQ and PAA in this work are 2:1, 1:1, 1:2 (by weight) and the best capacity retention at 50th cycle is observed in the electrode with the blending ratio 2:1 (named QA21). This is because that PPQ plays a role of conductive carbon among the Si particles or between Si particles and Cu current collector and PAA binds effectively the particles and the current collector. According to this synergetic effect, the internal resistance of the Si electrode with the blending ratio 2:1 is the smallest value. In addition, the Si electrode with PPQ-PAA composite binder shows the better stable cycle performance than the electrode with conventional super-P conductive carbon (20 wt.%).

• Polymer(Korea)
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• v.31 no.1
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• pp.74-79
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• 2007

Polypyrrole (PPy) was made by an emulsion polymerization using iron (III) chloride ($FeCl_3$) as an initiator and dodecyl benzene sulfuric acid (DBSA) as an emulsifier and dopant. Poly (2,6-dimethyl-1,4-phenylene oxide) (PPO) was sulfonated by chlorosulfonic acid (CSA). The cathode was composed of $PPy^+DBS^-$ complex, conductor powder, and PPO or sulfonated poly (2,6-dimethyl-1,4-phenylene oxide) (SPPO) as a binder or dopant. The charge-discharge performance of $PPy^+DBS^-/SPPO$ cathode was increased as the extent of about 50%, than $PPy^+DBS^-/PPO$. This is because SPPO played a role as a binder as well as a dopant. In addition, sulfonation brings out the increase of miscibility between PPy and SPPO, and the increase of contact area between cathode and electrolyte.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.220-221
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• 2006

We investigated the electrical properties of polymer-carbon composite materials for temperature sensitive resistor applications. Cu/polymer/Cu sheets were fabricated by laminating low density polyethylene(LDPE) containing carbon powders. Weight ratio of carbon powder to LDPE was varied in a range of 0.9~2. With increasing the carbon concentration, the electrical resistance of the composite material was decreased from 0.75 to $0.08\;{\Omega}cm$. The composite layer showed a abrupt increase in the electrical resistance at $115^{\circ}C$ because of the softening of the polymer.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2009.05a
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• pp.376-379
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• 2009

본 논문에서는 다양한 사용목적을 가지고 물성적 특징의 변화 및 발전이 지속적으로 이루어지고 있는 고분자 유기소재의 응용범위를 중량과 기계적 강도면에서 우수한 유기전선으로 활용하기 위한 기초 연구로서 유기도전성 섬유인 아크릴-F의 전기적 특성을 분석하였다. 아크릴-F의 저항값을 길이와 단면적에 대하여 각각 6단계 또는 5단계로 변화시켜 측정하였으며, 기존의 구리전선의 저항값에 대하여 지수함수 2차항에 의한 특성비교를 수행하였다. 실험결과 아크릴-F는 일반 구리전선과 비교하여 저항값은 매우 높게 나타났지만 전선과 매우 유사한 저항 특성을 가지는 것을 확인하였다.

• Membrane Journal
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• v.29 no.4
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• pp.191-201
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• 2019

Before the commercialization of polymeric membranes applicable for industrial application, the homework remains for the high-performance polymers to overcome the practical challenge: long-term stability for prolonged service time. Polymers of intrinsic microporosity (PIMs), exhibiting exceptionally high fractional free volume and high permeability, are susceptible to physical aging where the extra volume created by the inefficient ladder-type packing will lead them from the volumetric equilibrium and reduce the free volume/permeability over time. Here, we will re-examine the physical aging of polymers of intrinsic microporosity, and discuss some of the most prominent attempts to mitigate physical aging in PIMs.