• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.248.1-248.1
• /
• 2010

수송용 바이오연료로써 바이오디젤의 보급 활성화에 따른 원료인 식물성 기름의 가격 상승 및 수급 불안정성 문제를 해결하고자 그동안 활용되지 않았던 폐유지를 바이오디젤 생산 원료로 사용하여 바이오디젤 생산 단가를 낮추고 원료의 수급 안정성도 확보하려는 시도가 이루어지고 있다. 폐유지의 경우 대부분 유리지방산 함량이 높아 염기 촉매를 적용하는 방법으로는 비누의 생성으로 전환이 힘들며 산 촉매를 적용하여 유리지방산을 에스테르화하는 공정을 필요로 한다. 에스테르화 반응에서는 반응 부산물로 물이 생성되며, 생성된 물은 바이오디젤 생산 반응을 저해하고 역반응을 유도하며 촉매의 활성을 감소시킨다. 본 연구에서는 고유리지방산 함량 오일의 에스테르화 반응에서 수분의 영향을 검토하였다. 산 촉매로 액상 촉매인 황산과 고체 산 촉매인 Amberlyst-15를 사용하였다. 초기 수분 함량이 0, 1, 2, 5, 10, 20%로 증가하였을 때, 지방산 메틸 에스테르 함량이 크게 감소하였으며, 1%의 수분 함량에서도 반응이 크게 저해받는 것으로 나타났다. 따라서 고유리지방산 함량 오일의 에스테르화 반응에서 수분에 의한 저해가 중요한 변수라는 것을 알 수 있다. Amberlyst-15는 황산보다 수분의 영향에 의해 지방산 메틸 에스테르 함량이 빠르게 감소하였다. 이는 다공성의 Amberlyst-15에서 생성된 물이 반응물질들이 active site에 접근하는 것을 방해하였기 때문인 것으로 생각된다. 황산을 사용하였을 경우에는 오일 대 메탄올 몰비를 1:3에서 1:6으로 증가시킴으로써 정반응 속도가 증가하여 수분에 대한 영향이 감소하는 현상이 나타났다. 에스테르화 반응 종료 12시간 후에 바이오디젤과 메탄올 내에 수분 함량을 분석한 결과 12%의 수분이 바이오디젤 층에 존재하며 88%의 수분은 메탄올 층에 존재하였다. 반응 중에 생성된 수분을 제거하기 위해, 에스테르화 반응 30분 후에 물을 포함하는 메탄올과 촉매 층을 새 메탄올과 촉매로 교환하는 2단계 반응을 수행함으로써 지방산 메틸 에스테르 함량을 향상시킬 수 있었다. 반응 초기에는 황산이 Amberlyst-15보다 높은 활성을 보였지만, 시간이 지날수록 두 촉매 사이의 에스테르화 성능 차이는 감소하였다. 따라서 2단계 에스테르화 반응이 수분의 저해작용을 줄이는 한 가지 대안으로 제안될 수 있다. 또한 에스테르화 반응에서 물의 저해 작용을 줄이기 위해 앞으로 투과증발막의 적용 또는 물에 저해작용을 받지 않는 구조의 촉매 사용을 검토할 필요가 있다.

• Journal of Korea Water Resources Association
• /
• v.31 no.4
• /
• pp.363-373
• /
• 1998

In this study, random flow field in a nonstationary porous formation is characterized through cross covariances of the velocity with the log conductivity and the head. The hydraulic head and the velocity in saturated aquifers are found through stochastic analysis of a steady, two-dimensional flow field without recharge. Expression for these cross covariances are obtained in quasi-analytic forms all in terms of the parameters which characterize the nonstationary conductivity field and the average head gradient. The cross covariances with a Gaussian correlation function for the log conductivity are presented for two particular cases where the trend is either parallel or perpendicular to the mean head gradient and for separation distances along and across the mean flow direction. The results may be of particular importance in transport predictions and conditioning on field measurements when the log conductivity field is suspected to be nonstationary and also serve as a benchmark for testing nonstationary numerical codes. Keywords : cross covariance, nonstationary conductivity field, saturated aquifer, stochastic analysis.

• Membrane Journal
• /
• v.14 no.1
• /
• pp.57-65
• /
• 2004

The effect of porous support layer resistance and PDMS (polydimethylsiloxane) coating thickness on ethylene/nitrogen separation of composite membranes was studied with the model of Pinnau and Wijmans〔1〕. To control the support resistance (or permeance), PES porous membranes were prepared by phase inversion process with various PES/NMP dope concentrations. The thickness of selective PDMS top layer was controlled by using a spin coater. Its cross-section and coating thickness were observed by scanning electron microscope (SEM). Pure gas permeation test was done with ethylene and nitrogen, respectively. The experimental result for olefin/nitrogen separation process matched well with theoretical result from the model used. The result shows that optimization between PDMS coating thickness and support resistance is important to get PDMS composite membranes with best performance.

• Membrane Journal
• /
• v.6 no.1
• /
• pp.53-57
• /
• 1996

Polysulfone ultrafiltration membrane was coated with polyisobutylene(PIB) as a top layer to separate chlorinated hydrocarbons. The solubility parameter differences between PIB, water and perchloroethylene(PCE) or trichloroethylene(TCE) show that the solubility parameter difference between PIB and TCE or PCE is similar while that between PIB and water is far less, indicating that PIB is selective to chlorinated hydrocarbons. The pervaporation separation of TCE and PCE shows that TCE is concentrated more than four times, by PIB composite membrane, while PCE is concentrated more than thirteen times. This result shows that PIB composite membrane in this study seems to be an appropriate selective layer for the separation of TCE and PCE from aqueous organic solutions.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.11
• /
• pp.5384-5391
• /
• 2011

The computational fluid dynamics was analyzed for the pressure distribution, stream velocity distribution, stream line field, retention time and temperature distribution which are applied to the catalyst layer in the RCO reactor to derive the optimum operating condition of the heat condensing type catalytic oxidation (RCO) reactor. The results from the computational analysis revealed that the pressure loss due to the ceramic honeycomb in the catalytic bed of the reactor which is operating currently is not significant and the stream velocity (1.8~2.7 m/s) after the ceramic filter is working in stability without big channeling. To improve the stream velocity distribution of the air stream, it is necessary to extension of the connecting range between the plenum and catalytic bed inside the facility. However, the method of attaching the air stream guide vane or the perforated plate inside the reactor was not so effective.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.26 no.8
• /
• pp.1172-1182
• /
• 2002

In the present study a general criterion for local thermal equilibrium is presented in terms of parameters of engineering importance which include the Darcy number, the effective Prandtl number of fluid, and the Reynolds number. For this, an order of magnitude analysis is performed for the case when the effect of convection heat transfer is dominant in a porous structure. The criterion proposed in this study is more general than the previous criterion suggested by Carbonell and Whitaker, because the latter is applicable only when conduction is the dominant heat transfer mode in a porous medium while the former can be applied even when convection heat transfer prevails. In order to check the validity of the proposed criterion for local thermal equilibrium, the forced convection phenomena in a porous medium with a microchanneled structure subject to an impinging jet are studied using a similarity transformation. The proposed criterion is also validated with the existing experimental and numerical results for convection heat transfer in various porous materials that include some of the parameters used in the criterion such as a microchannel heat sink with a parallel flow, a packed bed, a cellular ceramic, and a sintered metal. It is shown that the criterion presented in this work well-predicts the validity of the assumption of local thermal equilibrium in a porous medium.

• Water for future
• /
• v.29 no.5
• /
• pp.215-222
• /
• 1996

An expression for the cross covariance of the logconductivity and the head in nonstationary porous formation is obtained. This cross covariance plays a key role in the inverse problem, i.e., in inferring the statistical characteristics of the conductivity field from head data. The nonstationary logconductivity is modeled as superposition of definite linear trend and stationary fluctuation and the hydraulic head in saturated aquifers is found through stochastic analysis of a steady, two-dimensional flow. The cross covariance with a Gaussian correlation function is investigated for two particular cases where the trend is either parallel or normal to the head gradient. The results show that cross covariances are stationary except along separation distances parallel to the mean flow direction for the case where the trend is parallel to head gradient. Also, unlike the stationary model, the cross covariance along distances normal to flow direction is non-zero. From these observations we conclude that when a trend in the conductivity field is suspected, this information must be incorporated in the analysis of groundwater flow and solute transjport.

• Journal of the Korean Electrochemical Society
• /
• v.4 no.2
• /
• pp.41-46
• /
• 2001

The effect of organic additives such as PEG ind MPS on throwing power have been studied in the fabrication of porous reticular metal by electrodeposition using the mixture of cupric sulfate and sulfuric acid as electrolyte. Both the polarization test and the electrodeposition on the stacked electrodes, mean pore diameter of which was $250{\mu}m$, were performed to illustrate the behavior of throwing power quantitatively. As far as PEG was concerned, it lowered throwing power of electrodeposition on the porous electrode used in this work while the addition of MPS up to 500 ppm in electrolyte enhanced throwing power monotonously. When both MPS and PEG were added in electrolyte, the effect of MPS on throwing power was superior to that of PEG. However, the excess addition of MPS was found to cause the defect in mechanical strength of deposit layer. From the result of SEM observation, it could be concluded that less than 50 ppm of MPS in electrolyte was appropriate to avoid the breakage of deposit layer.

• Composites Research
• /
• v.29 no.4
• /
• pp.151-155
• /
• 2016

Graphene has been a valuable candidate for use as electrodes for supercapacitors. In order to improve the surface area of graphene, three-dimensional graphene was synthesized on porous Ni nanostructure using thermal chemical vapor deposition and microwave plasma chemical vapor deposition. The structural and chemical characterization of synthesized graphene was performed by scanning electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. It was confirmed that three-dimensional and high-crystalline multilayer graphene onto various substrates was synthesized successfully.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.21 no.11
• /
• pp.1496-1508
• /
• 1997

The effects of porous wind fence on the pressure characteristics around a 2-dimensional prism model of triangular cross-section were investigated experimentally. The fence and prism model were embedded in a neutral atmospheric surface boundary layer over the city suburb. In this study, various fences of different porosity, back fence, inclination angle of prism and location of additional back prisms were tested to investigate their effects on the pressure and wall shear stress of the prism surface. The fence and prism had the same height of 40 mm and Reynolds number based on the model height was Re=3.9*10$^{4}$. The porous fence with porosity 40% was found to be the best wind fence for decreasing the mean and pressure fluctuations on the prism surface. By installing the fence of porosity 40%, the wall shear stress on the windward surface of prism was largely decreased up to 1/3 of that without the fence. This indicates that the porous fence is most effective to abate the wind erosion. Pressure fluctuations on the model surface were decreased more than half when a back fence was located behind the prism in addition to the front fence. With locating several back prisms and decreasing the inclination angle of triangular prism, the pressure fluctuations on the model surface were increased on the contrary.