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Melt Grafting of EPDM and Itaconic Acid: Effect of Reaction Conditions and Initiator Type/Concentration (Ethylene-propylene-diene terpolymer (EPDM)와 itaconic acid의 melt grafting: 반응조건과 개시제 종류 및 농도의 영향)

  • Kim, Ki-Jae;Bae, Jong-Woo;Kim, Jung-Soo;Lee, Jin-Hyok;Kim, Gu-Ni;Oh, Sang-Taek;Kim, Wonho
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.181-190
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    • 2014
  • Melt grafting of itaconic acid (IA) onto an ethylene-propylene-diene terpolymer (EPDM) with various organic peroxide initiators was performed. Finding the optimum mixing conditions and concentration of ingredients is critical for effective grafting and optimum properties of grafted materials. This study focused on the effects of mixing conditions (temperature and time), initiator type/concentration and monomer concentration on the grafting degree and efficiency, melt flow index, and gel content of EPDM-g-IA. The initiator, 2,5-dimethyl-2,5-di(tert-butyl peroxy)-hexane (T-101), appeared to meet for the best grafting degree (1.91%). The grafting degree increased markedly by increasing the amounts of monomer IA and initiator T-101. The grafting degree also increased by increasing mixing temperature and time. The optimum monomer and initiator concentrations and reaction temperature and time were found to be about 5wt%/0.05wt% and $160^{\circ}C$/15min, respectively. It was found that the physical properties of EPDM-g-IA were higher than those of the pristine EPDM.

Effects of Divided Crown Size on the Growth and Quality of Paeonia lactiflora Pallas (작약(芍藥) 분주묘(分株苗) 크기에 따른 생육(生育)과 품질(品質))

  • Kim, Se-Jong;Park, Jun-Hong;Kim, Ki-Jae;Park, So-Deuk;Choi, Boo-Sull
    • Korean Journal of Medicinal Crop Science
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    • v.6 no.3
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    • pp.198-203
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    • 1998
  • This experiment was conducted to determine the effect of different size of divided crowns used as planting material on the growth characteristics, yield and quality of Paeania lactiflora Pallas (P. lactiflora Pallas). The ratio of sprouting, rooting, and growth of above-ground parts increased with the increase of crown size. The root yields of under-ground parts from different size of divided crown were 2,674kg/10a for large size and 2,304kg/10a for medium size and the yield index was improved by 39% and 30%, respectively, compared to 1,921kg/10a in small size. Commodity ratio of roots over 10mm in diameter were higher for large and medium size crown: index increased by 26 % and 11 %, respectively, compared to 1,406kg/10a in small size. Income analyzed by crown size was \ 1,133,000 per 10a at the use of small crown size but income were increased 25 % and 48 %, respectively. by using medium and large size crown as compared with small crown.

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Effects of Removing Time of Flower Buds on Root Yield and Paeoniflorin Content in Paeonia lactiflora Pallas (작약(芍藥) 화뇌제거시기에 따른 근수량(根收量)과 Paeoniflorin함량(含量) 변화(變化))

  • Kim, Ki-Jae;Park, Chun-Hong;You, Oh-Jong;Shin, Jong-Hee;Park, So-Deuk;Choi, Boo-Sull;Yeo, Soo-Kab
    • Korean Journal of Medicinal Crop Science
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    • v.6 no.3
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    • pp.193-197
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    • 1998
  • This experiment was carried out to determine the proper time for flower bud removing to improve growth, yield and paeoniflorin content of root in peony(Paeonia lactiflora Pallas). The flower buds removement caused short stem length by $7{\sim}9cm$ compared with control, but number of stem and stem diameter were similar to that of control. The number of root, fresh root weight and paeoniflorin content in peony increased when their flower buds were removed at earlier stages. The root dry weight was highest of 1.647kg/10a, and increased by 27% compared with control when their flower buds were removed at early stage (bud diameter was less than 10mm). The root dry weight increased by 13% and 10%, respectively. when their flower buds were removed prior to flowering and at flowering stage. Paeoniflorin content in leaf was higher than that in stem, and was higher at early stage. Leaf and stem showed higher paeonif1orin content when their flower buds were removed.

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Correlation between Growth Characteristics and Root Yield in Collected Peony Lines (수집작약(蒐集芍藥)의 생육특성(生育特性)과 뿌리 수량(收量)과의 관계(關係))

  • Kim, Jae-Chul;Kim, Jeong-Hye;Kim, Ki-Jae;Ryu, Joung-Ki;Park, So-Deuk;You, Oh-Jong
    • Korean Journal of Medicinal Crop Science
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    • v.6 no.3
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    • pp.188-192
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    • 1998
  • The correlations between growth charateristics and root yield were investigated in 74 peony lines collected from chief producing place in Korea. Among these peony lines, single flower type was 61% and the rest were double type. And pink flower was in majority. Stem length, stem diameter and number of stem per plant were $50{\sim}60cm$, $7{\sim}8mm$ and $5{\sim}6$, respectively. Generally, disease tolerance and root yield were better in single flower type peonies than double type. Among single flower type peonies, the correlation coefficients between each characteristics and root yield were as follows : number of stem $(0.676^{**})$, number of roots $(0.646^{**})$, stem length $(0.617^{**})$, root diameter $(0.590^{**})$ and root length $(0.443^{**})$. Correlation between root yield and paeoniflorin content was highly significant $(0.383^{**})$ among single flower type peonies and significant $(-0.382^*)$ among double flower type peonies. Correlation between stem diameter and root yield was not significant (0.066).

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Effects of Irrigation and Sowing Time on Growth and Yield of Bupleurum falcatum L. (시호(柴胡) 생육(生育)과 수량(收量)에 대한 파종기(播種期) 및 초기관수(初期灌水) 효과(效果))

  • Kim, Jae-Chul;Kim, Jung-Hye;Ryu, Joung-Ki;Kim, Ki-Jae;Park, Jun-Hong
    • Korean Journal of Medicinal Crop Science
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    • v.5 no.4
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    • pp.318-324
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    • 1997
  • When Bupleurum falcatum field was irrigated three times with 20mm at intervals of 10days after sowing, establishment was inproved (64%) and root yield increased to 58kg/10a. And in early growing stage, 30mm irrigation six times at intervals of 10days increased the number of harvested plants per square meter and resulted in yield increase by 26% over yield from natural plot. 20mm irrigation in sowing time at intervals of 10days and 30mm irrigation in early growing stage at intervals of 10days kept adequate soil moisture content (soil moisture tension: $0.39{\sim}0.49bar)$ and resulted in better establishment, growth and yield of Buleurum falcatum.

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Changes of Characteristic in the Roots of Paeonia lactiflora Pallas with Different Process of Drying and Cutting (작약(芍藥)의 건조(乾燥) 및 절제방법(切制方法)에 따른 근(根) 특성(特性) 변화(變化))

  • Kim, Ki-Jae;You, Oh-Jong;Park, So-Deuk;Shin, Jong-Hee;Choi, Boo-Sull
    • Korean Journal of Medicinal Crop Science
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    • v.4 no.4
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    • pp.308-313
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    • 1996
  • The appropriate drying method in medicinal compounds and color of peony root was that predrying at briquet fire $(40{\sim}60^{\circ}C)$ for 6 hours or more, and then hot air drying at $40^{\circ}C$ during 60 hours. But this method needs too much time in drying. And the method that drying at $40^{\sim}C$ with hot air drying has bad result in color. In case Peony was seld by cutting product, before cutting, the Peony root was retted for 30 min. and sealed for 12 hrs. is good for drying time, Peoniflorin content and commodity.

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Effects of Peeling and Sample types on Drying Time and Paeoniflorin Contents of Peony Root (작약근의 박피와 시료형태가 건조시간 및 Paeoniflorin 함량에 미치는 영향)

  • Kim, Ki-Jae;Park, Chun-Hong;Park, So-Deuk;Kim, Jae-Cheol;Park, Kyeng-Sok
    • Korean Journal of Medicinal Crop Science
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    • v.10 no.1
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    • pp.24-28
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    • 2002
  • Effect of pretreatment processing (peeling time, drying temperature, sample type) on the quality of hot air drying peony roots was investigated. Peony roots were peeled for 0, 10, 20, 30, 60, 90 and 120 minute in the peeling machine after water washing. Sample types were whole or cut (thickness of 3mm). Temperatures of hot air drying were 30, 40, 50 and $60^{\circ}C$ The level of water contents in dried sample was $14{\sim}15%$. Drying time was muth reduced as the peeling time, cutting sample types and higher temperature. Contents of paeoniflorin were maintained highest amount (3.48%) in the non-peeling cut sample dried at $30^{\circ}C$ and lowest amount (2.29%) in the 120min-peeling whole one dried at $60^{\circ}C$. Skin color of dried peony roots was heavily discolored in the sample of non-peeling whole type dried at $60^{\circ}C$ and the color was dark brown $({\Delta}E\;was\;46.1)$. When considering shortening of drying time, preservation of active compounds and maintenance of color, the best pretreatment method of drying in peony roots was non-peeling, cut type processing.

Development and Applications of Pore-filled Ion-exchange Membranes (세공충진 이온교환막의 개발 및 응용)

  • Kim, Do-Hyeong;Kang, Moon-Sung
    • Membrane Journal
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    • v.28 no.5
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    • pp.307-319
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    • 2018
  • Ion-exchange membrane (IEM) has fixed charge groups and is a separation membrane which is capable of selectively transporting ions of the opposite polarity. Recently, the interest in IEMs has been increasing as the importance of the desalination and energy conversion processes using them as the key components has increased. Since the IEMs determine the efficiency of the above process, it is necessary to improve the separation performance and durability of them and also to lower the expensive membrane price, which is a hindrance to the widening application of the IEM process. Therefore, it is urgent to develop high-performance and low-cost IEMs. Among various types of IEMs, pore-filled membranes prepared by filling ionomer into a porous polymer substrate are intermediate forms of homogeneous membranes and heterogeneous membranes. The production cost would be cheap like the case of heterogeneous membranes because of the use of inexpensive supports and the reduction of the amount used of raw materials, and at the same time, they exhibit excellent electrochemical characteristics close to homogeneous membranes. In this review, major research and development trends of pore-filled IEMs, which are attracting attention as high-performance and low-cost IEMs, have been summarized and reported according to the application fields.

Geochemistry of Granitic Rocks Around the Southern Part of the Yangsan Fault (양산단층 남부일원에 분포하는 화강암질암의 지화학적 연구)

  • Hwang Byoung-Hoon;Yang Kyounghee
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.3 s.45
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    • pp.165-181
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    • 2005
  • The granitic rocks distributed in the southern part of the Yangsan Fault are classified into five distinct rock facies based on the field relation, petrography and geochemical characteristics. These five different rock facies can be grouped into two considering their origins. Group I, which reveals various evidences of magma mixing, includes three rock facies of granodiorite, enclave-rich porphyritic granite, and enclave-poor porphyritic granite. Group H intruding Croup I includes equigranular granite and micrographic granite with no evidence of magma mixing. It is suggested that the distinctively different trace element and isotopic chemistries between group I and II, support evolution from the different parental magma. It is suggested that the three rock facies in group I were generated by different degrees of magma mixing in addition to fractionation of plagioclase. MMEs experienced fractionation of biotite. The two facies in group H seem to have been generated from different parent magma from group I and evolved by fractionation of K-feldspar. The Rb-Sr whole-rock ages of the group I rocks yield $59.2\~58.9Ma$, and those of the group II rocks give 53. $3\~51.7Ma$, regardless of their distribution whether they occur in the eastern or western parts of the Yangsan Fault. Based on Sm-Nd isotope compositions, depleted mantle model ages $(T_2DM)$ of the group I range $0.8\~0.9Ga$, while those of the group II$0.6\~0.7Ga$.

The Political Fandom of Korean and the Acceptance of the Film : ,(2013) vs.,(2014) (한국인의 정치적 팬덤 정서와 영화의 수용 : <변호인>,(2013)과 <국제시장>,(2014)을 중심으로)

  • Choi, Bae Suk
    • The Journal of the Korea Contents Association
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    • v.18 no.1
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    • pp.289-304
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    • 2018
  • The fandom phenomenon of political emotion originated from ideological conflicts between the conservative and the progressive amplifies social conflicts in South Korea in interpreting and accepting films as culture media. The purpose of this paper is to examine why the structure of political consciousness in South Korea is fandomized, what is the acceptance of cinema at the center of the controversy of political ideology, and what is the desirable attitude of film reception. I conducted a discourse analysis that closely examined the debates and articles on the internet regarding ,(2013) and ,(2014) which were controversial in terms of conservatism and progressivism. As a result, First, while Korean society has not constituted a consensus on modern and contemporary history, it has easily led the acceptance of cinema to the controversy surrounding the political ideology. Second, the failure of constructing consensual memories of modern and contemporary history has made the conservative and the progressive not acknowledge the other's achievements. Third, film interpretation and meaning production are ultimately the roles of the audience, and on interpretation, diversity should be respected but conformity would be rejected. Film acceptance and interpretation should focus on rational awareness of social reality and would reflect on the social ideal objectively.