• Title/Summary/Keyword: 기공특성

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Effete of Ozone Uptake Rate on Photosynthesis and Antioxidant Activity in the Leaves of Betula Species (자작나무류 잎의 오존흡입량이 광합성 및 항산화효소 활성에 미치는 영향)

  • 이재천;한심희;장석성;조경진;김용율
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.4 no.2
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    • pp.72-79
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    • 2002
  • This study was conducted to compare the physiological and biochemical responses of four Betula species in response to ozone, and to find out the relationship between ozone uptake rate and photosynthesis or antioxidant activity. One-year-old seedlings of four Betula sp, B. costata, B. davurica, B. platyphylla var, japonica, and B. ermani, exposed to 100 pub ozone concentration for 8h day$^{-1}$ for 5 weeks in fumigation chamber. Ozone uptake rate, photosynthesis, SOD and GR activity were measured in the leaves of four species once a week. Cumulative ozone uptake rate was largest in the loaves of B. costata(53.8 mmol m$^{-2}$ ), smallest in the leaves of B. davurica(35.5 mmol m$^{-2}$ ). Photosynthesis of four Betula sp. exposed to ozone reduced relative to control, but the photosynthetic responses with changing stomatal conductance were different among species. Ozone exposure increased SOD activities of four species at the early exposing period, but after a critical point SOD activity decreased gradually. GR activity of B. costata was similar to the change of SOD activity, but the others showed the different patterns from B. costata. In conclusion, decreasing both SOD and GR activity at the critical point, B. costata may be sensitive species in response to ozone. In contrast, the others may be resistant species, which gradually increase GR activity following ozone exposure. GR activity was not always in accord with the change of SOD activity against ozone uptake, and the different responses between species were supposed to be affected by the cumulative ozone uptake.

Improvement of Anti-Corrosion Characteristics for Light Metal in Surface Modification with Sulfuric Acid Solution Condition (경금속 표면개질 시 황산 수용액 조건에 따른 내식성 개선 효과)

  • Lee, Seung-Jun;Han, Min-Su;Kim, Seong-Jong
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.3
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    • pp.223-229
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    • 2015
  • Surface modification is a technology to form a new surface layer and overcome the intrinsic properties of the base material by applying thermal energy or stress onto the surface of the material. The purpose of this technique is to achieve anti-corrosion, beautiful appearance, wear resistance, insulation and conductance for base materials. Surface modification techniques may include plating, chemical conversion treatment, painting, lining and surface hardening. Among which, a surface modification process using electrolytes has been investigated for a long time in connection with research on its industrial application. The technology is highly favoured by various fields because it provides not only high productivity and cost reduction opportunities, but also application availability for components with complex geometry. In this study, an electrochemical experiment was performed on the surface of 5083-O Al alloy to determine an optimal electrolyte temperature, which produces surface with excellent corrosion resistance under marine environment than the initial surface. The experiment result, the modified surface presented a significantly lower corrosion current density with increasing electrolyte temperature, except for $5^{\circ}C$ of electrolyte temperature at which premature pores was created.

Ideal Leaf Type on Leaf Shape and $\textrm{CO}_2$ Use Efficiency of Different Seed Size Cultivar in Soybean (엽형 및 $\textrm{CO}_2$ 이용효율에 따른 콩 입중별 이상초형 연구)

  • 이강세;전병무;김영진;국용인;박호기;박문수
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.3
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    • pp.243-247
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    • 2003
  • To examine ideal leaf types with higher $\textrm{CO}_2$ assimilates and different seed sizes, 12 soybean varieties were planted on the pot in a plastic house covered with glass. Leaf function based on stomatal conductance and $\textrm{CO}_2$ assimilation in soybean is different in seed size and leaflet shape. Mean $\textrm{CO}_2$ assimilation of a single leaf was 19.66 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$ and showed higher in small seed cultivars with narrow leaflet than that of small seeds with wide leaflet (18.29 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$), but within large seed groups, it was higher in wide leaflets (19.17 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$) than narrow leaflet cultivars (17.45 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$). In small seed and narrow leaflet cultivars, stomatal conductance ranged from 0.14 to 0.15 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$, while $\textrm{CO}_2$ assimilation ranged from 19 to 20 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$. The Photosynthetic rate was closely related to stomatal conductance, transpiration and water use efficiency.

Study on the Restoration of Ancient Smelting and Smithing Technologies in the Jungwon Area (재현실험을 통한 중원지역 고대 제련-단야기술의 공정별 특성 연구)

  • Lee, Eunwoo;Kwak, Byeongmoon;Kim, Eunji;Han, Youngwoo;Park, Chonglyuck
    • Journal of Conservation Science
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    • v.33 no.6
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    • pp.519-532
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    • 2017
  • Studies on ancient ironmaking technologies are primarily based on archaeological surveys and scientific analysis data, and technological systems are examined by comparing the results of restorative experiments. In this study, to examine the ancient iron production technologies such as smelting and smithing in the Jungwon area, a restoration experiment was conducted based on archaeological data, and the iron and slag, etc. produced in the experiment were analyzed. Further, the changes in physicochemical properties due to the smelting of the raw material, specifically, iron ore were determined, and the smithing process, which involves fabrication of ironwares, was analyzed along with the characteristics of each step. In the case of smelting, increasing recovery rates and production of high-quality primary iron material were important for the following processes. For the iron bars produced through the smithing process, it was found that quality improvements made by reducing physical defects such as inclusions or gas holes were more important than the composition of the iron itself. The study also yielded comparative study data for various byproducts, such as smithing slag, which could be utilized in other ironmaking technology studies.

Chemical Stability Evaluation of Ceramic Materials for Liquid Cadmium Cathode (액체카드뮴음금용 세라믹 소재의 화학적 안정성 평가)

  • Ku, Kwang-Mo;Ryu, Hong-Youl;Kim, Seung-Hyun;Kim, Dae-Young;Hwang, Il-Soon;Sim, Jun-Bo;Lee, Jong-Hyeon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.1
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    • pp.23-29
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    • 2013
  • LCC (Liquid cadmium cathode) is used for electrowinning in pyroprocessing to recover uranium and transuranic elements simultaneously. It is one of the core technologies in pyroprocessing with higher proliferation resistance than a wet reprocessing because LCC-cell does not separate TRU from uranium. The crucible which holds the LCC is technically important because it should be nonconducting material to prevent deposition of metallic elements on the crucible outer surface. The chemical stability is also crucial factor to choose crucible material due to the strong reactivities of TRU and possible incorporation of Li metal during the operation. In this study, the chemical stabilities of four kinds of representative ceramic materials such as $Al_2O_3$, MgO, $Yl_2O_3$ and BeO were thermodynamically and experimentally evaluated at $500^{\circ}C$ with simulated LCC. The contact angle of LCC on ceramic materials was measured as function of time to predict chemical reactivity. $All_2O_3$ showed poorest chemical stability and the pores in BeO contributed to a decreases in contact angle. MgO and $Y_2O_3$ have superior chemical stability among the materials.

High Concentrated Toluene Decomposition by Non-thermal Plasma-Photocatalytic (Mn-Ti-MCM-41) Hybrid System (상온 방전 플라즈마-광촉매(Mn-Ti-MCM-41) 복합 시스템에 놓인 고농도 톨루엔의 분해성능)

  • Ban, Ji-Young;Son, Yeon-Hee;Lee, Sung-Chul;Kang, Misook;Choung, Suk-Jin;Sung, Joon-Yong
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.413-421
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    • 2005
  • This study focused on the decomposition of toluene in a plasma-photocatalytic hybrid system. Hexagonally packed meso-structured Mn-titanosilicates (Mn-Ti-MCM-41), as the photocatalysts, have been prepared by the hydrothermal method. The physical properties of the photocatalysts were characterized using XRD, XPS, TEM, BET/ICP, and $NH_3$/Toluene-TPD. Experiments were carried out at the applied voltage of 9.0 kV and at room temperature of $20^{\circ}C$. In the plasma only system, the activity of the toluene decomposition was higher than that in the photocatalytic system. However, the amount of by-products, such as phenol, $C_2{\sim}C_4$ alkene, was also increased in the plasma only system. However, the by-products decreased remarkably in a plasma-photocatalytic hybrid system. When Mn5mol%-Ti-MCM-41 was used as a photocatalyst in a plasma-photocatalytic hybrid system, the $CO_2$ selectivity in products was increased dramatically compared to other catalysts. It was confirmed that a plasma-photocatalytic hybrid system was better for toluene decomposition compared to photocatalytic and plasma only systems.

Mineralogical Study on Interpretation of Firing Temperature of Ancient Bricks: Focused on the Bricks from the Songsanri Tomb Complex (고대 벽돌의 소성온도 해석을 위한 광물학적 연구: 송산리 고분군 벽돌을 중심으로)

  • Jang, Sungyoon;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.30 no.4
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    • pp.395-407
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    • 2014
  • In this study, firing temperature of bricks from the Songsanri tomb complex is interpreted based on the mineralogical and physical changes of soil samples fired at different temperature. When soil samples were burned at 500 to $1,200^{\circ}C$, phase transition of clay minerals affected the mineralogical composition and microstructure, which leaded to alteration of physical features as color, water absorption and porosity. Mineralogical composition can be assumed to vary with the temperature by mineral phase stability, however, color, water absorption, porosity and microstructure had slow change under $1,000^{\circ}C$, and had rapid change from 1,000 to $1,200^{\circ}C$. Upon the mineral and physical alteration of soil, firing temperature of bricks from the Songsanri tomb complex were estimated. Some bricks were over fired at temperature more than $1,200^{\circ}C$, some high-burned bricks were fired from 1,100 to $1,200^{\circ}C$, some bricks were fired by 900 to $1,000^{\circ}C$ and some bricks ere assumed not to be fired. Henceforward mineralogical and physical study can be applied to interpretate more precise firing temperature.

Enzyme Activity of Lipase Immobilized Non-Woven Fabric for Biodiesel Production (바이오디젤 생산을 위한 리파아제 고정 부직포의 효소활성화)

  • Kim, Ye Jin;Lee, Sung Hae;Hong, Sung Kyu;Kim, Min;Park, Sang Jin
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.121-127
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    • 2010
  • This study is to optimize the enzyme(lipase) activity for biodiesel production. The ion-exchanged non-woven fabrics(EtA, DEA-EtA non-woven fabric) containing ethanolamine, diethylamine groups are used by radiation induced grafted polymerization onto a non-woven fabric for more effective immobilization of lipase. Since the porous hollow fiber membranes are showed the low throughputibehe non-woven fabric membranes are used for biodiesel production. The physical charateristics of enzyme immobilized and the enzyme activity to EtA and DEA-EtA non-woven fabrics are studied. The EtA non-woven fabrics are quite similar to DEA-EtA non-woven fabric for the amount of enzyme immobilized(EtA non-woven fabric:15.69 mg/g, DEA-EtA non-woven fabric:14.45 mg/g) but DEA-EtA non-woven fabrics have shown the lower permeabiliquite the organic solvent than the EtA non-woven fabrics(EtA non-woven fabric:$3.50mol/h{\cdot}kg$, DEA-EtA non-woven fabric:$0.38mol/h{\cdot}kg$). Optimum characteristics of ehe non-woven fabric membranes and the limilaractivity are also investigated for the effective biodiesel production.

Effect of Forming Process and Particle Size on Properties of Porous Silicon Carbide Ceramic Candle Filters (성형공정(成形工程)과 원료입도(原料粒度)가 다공성(多孔性) 탄화규소(炭火硅素) 세라믹 캔들 필터 특성(特性)에 미치는 영향(影響))

  • Han, In-Sub;Seo, Doo-Won;Hong, Ki-Seog;Woo, Sang-Kuk
    • Resources Recycling
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    • v.19 no.5
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    • pp.31-43
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    • 2010
  • To fabricate porous SiC candle filter for filtration facility of the IGCC system, the candle type filter preforms were fabricated by ramming and vacuum extrusion process. A commercially available ${\alpha}$-SiC powders with various particle size were used as starting raw materials, and $44\;{\mu}m$ mullite, $CaCO_3$ powder were used as non-clay based inorganic sintering additive. The candle typed preforms by ramming process and vacuum extrusion were sintered at $1400^{\circ}C$ for 2h in air atmosphere. The effect of forming method and particle size of filter matrix on porosity, density, strength (flexural and compressive strength) and microstructure of the sintered porous SiC candle tilters were investigated. The sintered porous SiC filters which were fabricated by ramming process have more higher density and strength than extruded filter in same particle size of the matrix, and its maximum density and 3-point bending strength were $2.00\;g/cm^3$ and 45 MPa, respectively. Also, corrosion test of the sintered candle filter specimens by different forming method was performed at $600^{\circ}C$ for 2400h using IGCC syngas atmosphere for estimation of long-term reliability of the candle filter matrix.

Fabrication and Properties of Conductive Carbon Fiber/Polyethylene Composite Films Fabricated under High Intensity Electric Fields : Effect of Polymer Sublayer (고전기장을 이용한 도전성 탄소섬유/폴리에틸렌 복합필름의 제조 및 특성 연구 : 고분자 점착하층의 영향)

  • Park, Min;Kim, Jun-Kyung;Lim, Soon-Ho;Ko, Moon-Bae;Choe, Chul-Rim;Mironov, V.S.;Bang, Hyo-Jae;Lee, Kwang-Hee
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.268-275
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    • 2000
  • We investigated the effect of polymer sublayer on volumetric resistivity and tensile strength of carbon fiber (CF)/polyethylene composite films fabricated under high intensity electric fields. The dependence of volumetric resistivity and tensile strength of the films on the polymer sublayer thickness or mass part exhibited complex behavior according to CF content and CF layer density in the films. As the thickness of polymer sublayer increases, two groups of processes at thermo-mechanical forming stage would take effects in the properties of the films. The first group comprises the increase of polymer layer thickness having reduced CF content compared with central or upper part of the film and insufficient wetting of CF resulting in the loosened structure near upper film side. The second group, on the other hand, is the improvement of mobility of molten sublayer leading to better distribution of CF throughout the film thickness and the formation of more compact structure. The different degree of contribution of these two competing processes at varied CF content and CF layer density could explain complex dependence of the film properties on the polymer sublayer. These results are important to optimize the electrical and mechanical properties of highly conductive polymer films, which can be used as electromagnetic interference shielding materials.

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