• 제목/요약/키워드: 금속합금

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액체금속로 KALIMER 노심설계 및 특성 분석

  • 김영인;김영균;송훈;김의광;김영철
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1997년도 추계학술발표회논문집(1)
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    • pp.129-134
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    • 1997
  • 국내개발 액체금속로 KALIMER(전기출력 150 MWe)의 노심설계를 수행하고, 이에 대한 핵ㆍ열수력 특성을 분석하였다. 2농축U-Zr(15.0/20.0 %) 이원합금핵연료의 균질노심으로서, 핵연료 재장전주기는 12개월, 평균증식비는 0.68이다. 평형주기에서의 최대연소도는 47.3 MWD/kg이며, 음의 소듐 void 반응도가를 가진다. 동일한 설계기준으로 설계한 전기출력 333 MWe의 중형노심과 노심 특성을 비교ㆍ분석한 결과, 소형노심(전기출력 155 MWe)이 상대적으로 짧은 핵연료 재장전주기와 낮은 노심출력밀도를 갖고 있음을 알 수 있었다.

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금속입자가 전도성 잉크의 전도도에 미치는 영향 (Effect of Metal Powders on the Conductivity of Conductive Inks)

  • 권두효;정태의;김남수;한국남
    • 한국공작기계학회논문집
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    • 제17권2호
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    • pp.97-103
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    • 2008
  • In this investigation, conductivity of conductive inks was measured. A particular attention has been given to the effect of metal powders with various conductivity on the overall conductivity of the bulk ink. The conductivity of various solutions simulating conductive inks consisting of copper and silver was measured and the results have been discussed in relation to various applications of conductive inks in practice. A conductivity model simulating systems consisting of various materials has been introduced and the results were discussed. Materials of good conductivity are adversely affected by mixing with materials of poor conductivity simply through serial connection. However, parallel connection has rather little effect on the overall conductivity. The practical implication of various mixtures of materials on conductive inks has been discussed.

폐산화은 전지로부터 유가금속의 침출에 관한 연구 (A Study on the Leaching of Valuable Metals from Spent Silver-Oxide Battery)

  • 박경호;손정수
    • 자원리싸이클링
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    • 제4권1호
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    • pp.46-51
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    • 1995
  • 증류공정으로 수은을 제거한 폐산화은 전지에는 은이 약 30% 이상 함유되어 있는데 이를 효과적으로 분리, 회수할 목적으로 폐전지 잔사를 질산으로 침출시켜 전지중에 함유된 금속이온들(은, 아연, 철, 니켈)의 침출율을 조사하였다. 잔사의 침출공정시 반응온도, 반응시간, 질산농도, 고액농도 등에 의한 영향을 살펴보았으며 실험결과 반응온도 40~6$0^{\circ}C$, 질산농도 2N, 고액농도 10g/200ml의 조건에서 6시간 반응 시 가장 좋은 침출율을 나타내었다. 이때 은과 아연은 99% 이상의 침출율을 나타낸 반면, 철과 니켈은 전지의 외부 합금용기로 남아있어 50% 이하의 낮은 침출율을 나타내었다.

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강의 대기 중 1050~1200℃의 산화에 미치는 합금원소 Si, Mn, Ni, Cr의 영향 (Effect of Alloying Elements of Si, Mn, Ni, and Cr on Oxidation of Steels between 1050℃ and 1200℃ in Air)

  • 이동복
    • 대한금속재료학회지
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    • 제50권4호
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    • pp.300-309
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    • 2012
  • Low-carbon steels and a stainless steel were oxidized isothermally and cyclically between $1050^{\circ}C$ and $1200^{\circ}C$ for up to 100 min in air to find the effect of alloying elements of Si, Mn, Ni, and Cr on their oxidation. The most active alloying element of Si was scattered inside the oxide scale, at the scale-alloy interface and as internal oxide precipitates beneath the oxide scale. Manganese, which could not effectively improve the oxidation resistance, was rather uniformly distributed in the oxide scale. Nickel and chromium tended to present at the lower part of the oxide scale. Excessively thick porous scales formed on the low-carbon steels, whereas thin but non-adherent scales containing $Cr_2O_3$ formed on the stainless steel.

인발률에 따른 자동차 냉각 배관용 Al 합금의 부식 특성에 관한 연구 (Effect of Drawing Rate on the Corrosion Behavior of Al Alloy Tubes for Automotive Cooling System)

  • 박병준;김정구;안승호;곽동호;손현수
    • 대한금속재료학회지
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    • 제46권8호
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    • pp.489-494
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    • 2008
  • The effect of drawing rate on the electrochemical properties of 3003 Al alloys in 5 wt.% NaCl solution was investigated by electrochemical techniques (potentiodynamic polarization test, potentiostatic polarization test, electrochemical impedance spectroscopy (EIS)) and surface analyses (OM, SEM, EDS). Four kinds of automotive pipe materials were prepared (raw material, drawing rate = 5, 10, 15%). As the drawing rate of Al alloy tube increased, the pitting corrosion resistance increased due to the enrichment of Al oxides on the surface.

Micro-droplet cell을 이용한 Fe-17Cr 합금의 공식 발생에 대한 연구 (A Study on the Initiation of Pitting Corrosion of Fe-17Cr Alloy Using Micro-Droplet Cell Technique)

  • 김재중;이재봉
    • 대한금속재료학회지
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    • 제46권12호
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    • pp.809-816
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    • 2008
  • The influences of various parameters such as inclusions, surface roughness, exposed areas and chloride ion concentrations on the initiation of pitting of Fe-17Cr alloy were investigated, using micro-droplet cell technique. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local currents with the potentiodynamic polarization. Micro electrochemical tests were carried out at the inclusions after EDX analysis of inclusion. EDX analysis identified inclusions as Cr-oxides. It was found that some active inclusions among Cr-oxide inclusions acted as initiation sites for pitting corrosion. In addition, the rougher surface and the denser chloride ion concentration offered easier pit initiation sites, causing the more susceptible to pitting corrosion.

벌크 비정질 합금의 초저온 소성 (Enhanced Plasticity of Bulk Amorphous Alloys at Cryogenic Temperature)

  • 윤규상;이미림;이재철
    • 대한금속재료학회지
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    • 제48권8호
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    • pp.699-704
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    • 2010
  • We investigated the cryogenic temperature plasticity of a bulk amorphous alloy. Experiments showed that as temperature decreases, the plasticity of the alloy increases, such that the alloy exhibited ~20% of plastic strain when tested at $-196^{\circ}C$. This enhancement in the plasticity at cryogenic temperatures was associated with the formation of abundant shear bands distributed uniformly over the entire surface of the sample. Nonetheless, the serrations, the characteristic feature of the plastic deformation of amorphous alloys, were unclear at $-196^{\circ}C$. In this study, both the enhanced plasticity and the unclear serrations exhibited by the amorphous alloy at cryogenic temperatures were clarified by exploring shear banding behaviors in the context of the velocity and the viscosity of a propagating shear band.

비정질 합금의 구조완화 및 구조무질서화 (Structural Disordering and Relaxation Process in an Amorphous Alloy)

  • 김현수;윤규상;이재철
    • 대한금속재료학회지
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    • 제49권11호
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    • pp.823-830
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    • 2011
  • Structural change in an amorphous alloy was measured by applying a load below the global yield stregth at ambient temperatures. It was observed that the magnitude of the apparent structural change occuring in the amorphous alloy is determined by the compatative relationship between the stress-induced disordering process and the thermally-activated relaxation process. Structural disorder was observed to take place even at a stress well below the global yield, and the degree of the disorder was increased abruptly at the earlier stage of loading and saturated with time. In the mean time, unlike the previous belief, the relaxation process was observed to occur even at embient temperatures, and the degree of the relaxation was observed to increase linearly with time. The analytical equation predicting the structural change was proposed.

티타늄 용접 모니터링 시스템 연구 (Research of Titanium Weld Monitoring Systems)

  • 류진보;김관형
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2016년도 추계학술대회
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    • pp.674-675
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    • 2016
  • 원자번호 22번에 해당하는 티타늄(titanium)은 매우 단단하며 가볍고, 부식에도 강한 금속이다. 티타늄은 비슷한 강도의 강철에 비해서 가볍고 알루미늄 합금에 비해 2배나 강력하다. 뿐만 아니라 티타늄은 바닷물에도 부식되지 않아 선박이다 해양플랜트 산업에서 많이 쓰이는 금속이기도 하다. 본 연구는 해양플랜트 건설 사업에 쓰이는 티타늄 용접에 대한 모니터링 시스템을 연구하는데 있다. 티타늄 용접공정에 사용되는 용접 파라메타는 용접 전압, 전류, 용접 토치의 위빙속도 및 와이어 공급 속도로 선정하였으며, 이러한 용접 파라메타를 계측할 수 있는 MCU 기반의 계측 보드를 설계하여 TCP/IP 통신을 기반으로 원격지로 용접 데이터를 전송하도록 하였으며, 이러한 데이터를 실시간으로 데이터를 그래프로 표현하도록 개발하였다. 이러한 용접 데이터에 대한 모니터링을 통하여 용접 시 발생하는 다양한 현상을 파악할 수 있도록 하였다. 본 연구를 통해서 티타늄 용접 시 발생하는 각종 데이터를 실시간으로 모니터링 할 수 있도록 개발하였으며, 데이터베이스에 저장된 기록을 통해서 용접 시 발생한 전체적인 용접 과정을 날짜와 시간별로 저장하여 용접과정에서 발생하는 전 과정을 관리할 수 있도록 하여 어떤 부분에서 잘못된 용접이 발생했는지 파악할 수 있음을 확인하였다.

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비정질 합금의 부식저항성에 미치는 열처리의 영향 (Effect of Isothermal annealing on the Corrosion Resistance of an Amorphous Alloy)

  • 신상수;이창면;양재웅;이재철
    • 대한금속재료학회지
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    • 제46권2호
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    • pp.53-57
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    • 2008
  • This study examined the role of excess free volume on the corrosion resistance of an amorphous alloy. Corrosion behaviors were monitored on the amorphous alloys, of which amount of free volume was controlled via the isothermal annealing below the glass transition temperature, using immersion tests and potentiodynamic polarization tests in HCl aqueous solutions. It was found that the corrosion resistance of the amorphous alloy is improved by reducing the amount of excess free volume. The possible reason explaining the experimental result was discussed from the viewpoint of the internal energy associated with the annihilation of excess free volume.