• Title/Summary/Keyword: 그라이트

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The Influence of Fillers (Zeolite, Serpentine and Talc) and their Fineness on Granulation of Sulfate of Potash (광물질(鑛物質)의 종류(種類) 및 입도(粒度)가 황산가리(黃酸加理) 조립(造粒)에 미치는 영향(影響))

  • Lee, Yun-Hwan;Lee, In-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.15 no.3
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    • pp.188-193
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    • 1982
  • Granulation formed from mixture of sulfate of potash (SOP) powder and pulverized silica minerals (Zeolite, Serpentine and Talc) was studied to establish granulation rate and physical properties of granules. These mixtures were granulated in a pan granulator with water and granules of SOP were coated with minerals powder. Mixture of SOP and mineral powder by half (w/w) were increased granulation rate compared with pure SOP powder, and talc was superior to them with SOP. Water was needed about 14% to granulate SOP powder alone, but it decreased by 2% with talc and increased by 4% and 2% with zeolite and serpentine, respectively. Granules of mixture of SOP with zeolite were harder than pure SOP granules but with another minerals powder decreased in hardness. Also breaking rate of granules in vinyl parcel falling from 2m height and abrasion rate of granules by agitation were improved by mixing and coating with zeolite but with the other were of inferior.

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Synthesis of Hectorite by Hydrothemal Method (저온 수열법에 의한 헥토라이트 합성)

  • Jang, Young-Nam;Chae, Soo-Chun;Ryu, Gyoung-Won;Kim, You-Dong;Jang, Hee-Dong;Bae, In-Kook
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.1 s.51
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    • pp.1-6
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    • 2007
  • Hectorite was synthesized by a two-step hydrothermal process from $Mg(OH)_{2}$, water glass (${\sim}30\;wt%\;SiO_{2}$) and Li-compound at $90{\pm}5^{\circ}C$. The product shows excellent dispersion and swelling properties. The mixture of the starting materials was heated in a glass vessel for the first reaction with continuous stirring and the pH of the solution was adjusted to $6{\sim}8$, resulting in the formation of a precursor of hectorite. The excess salt components were washed out from the resulting slurry and then was matured in the glass vessel for the 2nd reaction. Li compound was added during the reaction. After a 10 h retention, the gel of hectorite was formed. The XRD pattern of the synthesized one was coincided with that of natural hectorite and SEM study revealed uniform grains 50 m in diameter. The d001 basal spacing of the product moved from 12 to $17.4\;{\AA}$ after glycolation treatment. The measured value of CEC and the swelling capacity was 90 cmol/kg and $60{\sim}70\;mL/2\;g$, respectively.

Preparation of nanosized TPA-silicalite-1 with various crystallization promoters (다양한 결정화 촉진제를 이용한 나노크기의 TPA-silicalite-1 제조)

  • 김호동;정상진;김명훈;김영희;김수룡;이영무
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.48-48
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    • 2003
  • 미세기공(microporous)을 가진 제올라이트는 다양한 유기질 분리의 촉매제 및 광학, 화학 센서, 기체 분리 등의 고기능 소재로서 크게 주목받고 있으며, 비표면적의 증가, 새로운 기능의 발현 둥으로 최근 들어 나노크기를 갖는 제올라이트 합성에 관한 연구가 활발히 진행되고 있다. 본 연구에서는 기체 분리에 응용하기 위한 제올라이트 분리막 개발에 앞서 분리막 제조에 유리할 것으로 판단되어지는 적합한 크기와 형상을 갖춘 나노크기의 제올라이트를 합성하였으며 그 특성을 분석하였다. 출발물질로서 실리카 원으로는 TEOS, LUDOX AS-40, Cab-O-SIL 등을 사용하였으며, 템프레이트(TPAOH)와 함께 특정조성의 TPAOH/SiO$_2$,/$H_2O$ 겔을 만들었다. 합성시간을 단축할 수 있는 방법의 연구로서 저온하의 2단계 온도 변화법을 적용하였으며, 결정성장속도의 향상을 목적으로 NaH$_2$PO$_4$, H$_2$SO$_4$, NH$_4$OH 등의 결정화 촉진제로 사용하여 수열합성법으로 Silicalite-1를 합성하였다.

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Preparation and characterization of MFI type Zeolite membranes on porous alumina supports (다공질 알루미나 지지체 위에 코팅한 MFI type제올라이트 분리막의 제조 및 특성 연구)

  • 정상진;김호동;김명훈;김영희;김수룡
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.110-110
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    • 2003
  • 제올라이트는 다양한 유기질 분리의 촉매제 및 광학, 화학 센서, 기체 분리 등의 고기능 소재로서 크게 주목받고 있으며, 그 중 MFI type(ZSM-5, Silicalite-1) 제올라이트는 주로 석유화학공정에 주로 이용되고 있고, 분리막으로서 이산화탄소의 분리/회수 및 물/유기 혼합물의 분리 등에 대한 연구가 활발히 진행되고 있다. 본 연구에서는 분리막 제조에 유리할 것으로 판단되어지는 적합한 크기와 형상을 갖춘 나노크기의 제올라이트 분말을 수열합성법과 마이크로웨이브 합성법을 이용하여 합성하였으며, 위의 조건으로 다공질 알루미나 지지 체 위에서 알루미나/제올라이트 분리막 제조를 하는데 성공하였다. 또 한 다양한 조건(시간, 온도, 조성)에 따른 막의 두께변화와 균열발생정도를 관찰한 결과 합성시간, 건조온도에 따라서 같은 조건의 분리막 사이에서도 현격한 차이가 나타남을 알 수 있었다. 얻어진 MFI type제올라이트 분말과 분리막은 XRD, SEM, BET, TGA, FT-IR등의 분석수단을 이용하여 물성평가를 실시하였다.

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The Existence of Mathematical Objects and Contingency (수학적 대상의 존재와 우연성)

  • Choi, Won-Bae
    • Korean Journal of Logic
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    • v.12 no.2
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    • pp.1-29
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    • 2009
  • According to Field, mathematical objects do not exist but they might have existed. In this paper I examine how persuasive this 'contingent' nominalism could be. For this I give a detailed analysis of the recent debate on the contingency of mathematical objects. I argue that the putative connection between contingency and explanation could still be sustained, but an independent argument is needed in order to support a general principle underlying the connection. I show that the attacks based on the anti-insularity principles already reflect their own positions on the modal status of the existence of mathematical objects.

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Preparations and Applications of Zeolite Membranes (제올라이트 막의 제조 및 응용)

  • 박상언;장종산;노현석;정광순
    • Membrane Journal
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    • v.8 no.4
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    • pp.177-190
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    • 1998
  • 화학산업이 발전함에 따라 많은 양의 에너지가 요구되면서 전세계적으로 에너지 고갈문제가 급부상하였다. 그에 따라 최근에는 효율적으로 에너지를 활용 할 수 있는 경제적으로 선택적인 화학공정을 필요로 하고 있으며, 높은 전환율과 선택적인 화학공정의 도입으로 에너지 효율을 증대시켜 에너지를 절약하고 부산물이 적은 보다 청결한 화학공정으로의 전환을 필요로 하고 있다. 이러한 목적을 위해 무기막의 분리 능력과 촉매의 활성을 결합하여 촉매반응과 반응물 및 생성물의 분리기능을 동시에 수행할 수 있는 무기막 촉매 기술이 최근 들어 광범위하게 연구되고 있다. 이와 함께 3차원의 미세세공 세공구조를 갖는 결정성 제올라이트를 무기막 형태의 필름으로 제조해 제올라이트의 분자체로서의 기능과 함게 소재로서 활용하고자 하은 연구가 최근에 활발히 진행되고 있다. 본 고찰에서는 최근에 연구가 활발히 진행되고 있는 제올라이트 막과 필름의 제조, 그리고 분리막 및 촉매로서의 응용 기술의 연구 현황을 살펴보고 향후 연구방향의 토대를 마련하고자 한다.

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LCD BLU Defects Detection System with Sidelight (측면조명을 이용한 LCD 백라이트 불량검출 시스템)

  • Moon, Chang-Bae;Bark, Jee-Woong;Lee, Hae-Yeoun;Kim, Byeong-Man;Shin, Yoon-Sik
    • The KIPS Transactions:PartB
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    • v.17B no.6
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    • pp.445-458
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    • 2010
  • A Cold Cathode Fluorescent Lamp(CCFL) is used as a LCD Monitor's backlight widely. The most common way to check CCFL's defects is an examination with the naked eye. This naked eye examination can cause examination inconsistencies and industrial disasters. A shooting environment and detection algorithms are important for finding CCFL defects automatically. This paper presents CCFL defect detection algorithms using images captured under the shooting environment with sidelight which is one of the shooting environment we have suggested. The experimental result shows 4.65% of overdetection and 5.37% of unsuccessful defect detection of CCFL.

Deployable Communication Antenna Alignment for Geostationary Satellite (정지궤도 위성의 전개형 통신 안테나 정밀정렬)

  • Choi, Jung-Su;Moon, Sang-Mu;Yoon, Yong-Sik;Kim, Hyung-Wan;Choi, Sung-Bong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.39 no.3
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    • pp.279-288
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    • 2011
  • This paper will discuss the alignment techniques and measurement results of geostationary satellite communication antennas for correct antenna pointing and also the fixtures. To get the best performance in terms of antenna pointing and fixtures, zero G condition have been simulated and laser tracker and theodolite system have been applied. As a result, alignment stability was verified within the tolerance, ${\pm}\;0.25mm$ and ${\pm}\;0.013^{\circ}$ and finally Ka-band deployable antenna alignment has been accomplished within the tolerance, ${\pm}\;0.5mm$ and ${\pm}\;0.015^{\circ}$.

Pseudotachylyte Developed in Granitic Gneiss around the Bulil Waterfall in the Jirisan, SE Korea: Its Occurrence and Characteristics (지리산 불일폭포 일원의 화강암질편마암에 발달한 슈도타킬라이트: 산상과 특성)

  • Kang, Hee-Cheol;Kim, Chang-Min;Han, Raehee;Ryoo, Chung-Ryul;Son, Moon;Lee, Sang-Won
    • The Journal of the Petrological Society of Korea
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    • v.28 no.3
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    • pp.157-169
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    • 2019
  • Pseudotachylytes, produced by frictional heating during seismic slip, provide information that is critical to understanding the physics of earthquakes. We report the results of occurrence, structural characteristics, scanning electron microscopic observation and geochemical analysis of pseudotachylytes, which is presumed to have formed after the Late Cretaceous in outcrops of the Paleoproterozoic granitic gneiss on the Bulil waterfall of the Jirisan area, Yeongnam massif, Korea. Fault rocks, which are the products of brittle deformation under the same shear stress regime in the study area, are classified as pseudotachylyte and foliated cataclasite. The occurrences of pseudotachylyte identified on the basis of thickness and morphology are fault vein-type and injection vein-type pseudotachylyte. A number of fault vein-type pseudotachylytes occur as thin (as thick as 2 cm) layers generated on the fault plane, and are cutting general foliation and sheared foliation developed in granitic gneiss. Smaller injection vein-type pseudotachylytes are found along the fault vein-type pseudotachylytes, and appear in a variety of shapes based on field occurrence and vein geometry. At a first glance fault vein-type seudotachylyte looks like a mafic vein, but it has a chemical composition almost identical to the wall rock of granitic gneiss. Also, it has many subrounded clasts which consist predominantly of quartz, feldspar, biotite and secondary minerals including clay minerals, calcite and glassy materials. Embayed clasts, phenocryst with reaction rim, oxide droplets, amygdules, and flow structures are also observed. All of these evidences indicate the pseudotachylyte formed due to frictional melting of the wall rock minerals during fault slip related to strong seismic faulting events in the shallow depth of low temperature-low pressure. Further studies will be conducted to determine the age and mechanical aspect of the pseudotachylyte formation.

Natural Monument Cretaceous Stromatolite at the Daegu Catholic University, Gyeongsan: Occurrences, Natural Heritage Values, and Plan for Preservation and Utilization (천연기념물 경산 대구가톨릭대학교 백악기 스트로마톨라이트: 산상, 자연유산적 가치 및 보존·활용 방안)

  • KONG Dal-Yong;LEE Seong-Joo
    • Korean Journal of Heritage: History & Science
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    • v.56 no.3
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    • pp.214-232
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    • 2023
  • Stromatolite at the Daegu Catholic University, Gyeongsan was designated as a natural monument in December 2009 because it was very excellent in terms of rarity, accessibility, preservation and scale. From the time of designation, the necessity of confirming the lateral extension of the stromatolite beds with the excavation of the surrounding area, and preparing a preservation plan was raised. Accordingly, the Cultural Heritage Administration conducted an investigation of the scale, production pattern, and weathering state of stromatolites with an excavation from April to December 2022, and based on this, suggested natural heritage values and conservation and use plans. The excavation was carried out in a 1,186m2 area surrounding the exposed hemispherical stromatolite (approximately 30m2). Stromatolites are continuously distributed over the entire excavation area, and hemispherical stromatolites predominate in the eastern region, and the distribution and size of hemispherical domes tend to decrease toward the west. These characteristics are interpreted as a result of long-term growth in large-scale lakes, where stratiform or small columnar domes continued to grow and connect with each other, finally forming large domes. Consequently, large and small domes were distributed on the bedding plane in clusters like coral reefs. The growth of plants and lichens, as well as small-scale faults and joints developed on the stromatolite bedding surface, is the main cause of accelerated weathering. However, preservation treatment with chemicals as with dinosaur footprints or dinosaur egg fossil sites is not suitable due to the characteristics of stromatolites, and preservation with the installation of closed protection facilities should be considered. This excavation confirmed that the distribution, size and value of stromatolites are much larger and higher than at the time of designation as a natural monument. Therefore, additional excavation of areas by experts that could not be excavated due to the discovery of buried cultural properties (stone chamber tombs) and reexamination of the expansion designation of natural monuments are required.