• Title/Summary/Keyword: 교환 결합

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Magnetic and Magneto-optical Characteristics for Nd-RE-TM Amorphous Alloy Films (Nd 치환 RE-TM 막의 자기 및 자기광학적 특성)

  • 이정구;최영준;임은식;이세광;김순광
    • Journal of the Korean Magnetics Society
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    • v.4 no.3
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    • pp.244-248
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    • 1994
  • Magnetic and Magneto-optical characteristics of NdTbFeCo alloy films and NdTbFeCo/TbFeCo double-layered films have been investigated. It was observed that the Kerr rotation(${\theta}_{k}$) in the short wavelength region increased and the coercivity decreased as the substitutional amount of Nd for Tb in NdTbFeCo film at the constant FeCo content. In spite of the increased ${\theta}_{k}$, a small coercivity of NdTbFeCo film made this medium unsuitable for magneto-optical recording medium at short wavelength. An effort was made to improve coercivity by exchange coupling with TbFeCo film of high coercivity. In the exchange-coupled $Nd_{16.9}Tb_{15.2}Fe_{50.4}Co_{17.5}(150\;{\AA})/Tb_{21.1}Fe_{65.0}Co_{13.9}(300\;{\AA})$ double-layered film, the magnetization reversal switching field and the Kerr rotation angle were increased to about 6.0 KOe and $0.32^{\circ}$ at 500 nm, respectively. This result indicates that exchange-coupled NdTbFeCo/TbFeCo film can be a promising candidate for agneta-optical rerding medium short wavelenhth.

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Giant Magnetoresistance Behavior and the Effect of Ferromagnetic Layer on the Co-Ag Nano-granular Alloy Films (Co - Ag 합금박막의 거대자기저항 및 강자성 상하지층의 효과)

  • 김용혁;이성래
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.31-37
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    • 1997
  • The magnetoresistance and the saturation field behavior of the Co-Ag nano granular films as a function of the composition and the ferromagnetic underlayer and overlayermaterials were investigated. The maximum magnetoresistance of 23% and the saturation field of 2.3 kOe at room temperature were obtained in the as-deposited 3000$\AA$ $Co_{30}Ag_{70}$ single alloy films. The magnetoresistance and the saturation field of 100$\AA$ $Co_{30}Ag-{70}$ alloy film were 3.65 % and 3.0 kOe respectively. Those of the sandwiched films with 200$\AA$ Fe were 3.3 % and 1.23 kOe respectively. The saturation field of the sandwiched alloy films could be reduced by the exchange coupling between the ferromagnetic layers and the alloy layer. The effective depth of the exchange coupling was approximately 150$\AA$ in each Fe layer. Among the Fe, Co, and FeNi, the most effective materials to reduce the saturation field of the sandwiched alloy films was Fe.

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Magnetoresistance Properties of Hybrid GMR-SV Films with Nb Buffer Layers (Nb 버퍼층과 거대자기저항-스핀밸브 하이브리드 다층박막의 자기저항 특성)

  • Yang, Woo-Il;Choi, Jong-Gu;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.27 no.3
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    • pp.82-86
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    • 2017
  • The IrMn based GMR-SV films with three different buffer layers were prepared on Corning glass by using ion beam deposition and DC magnetron sputtering method. The major and minor magnetoresistance curves for three different buffer layers beneath the structure of NiFe(15 nm)/CoFe(5 nm)/Cu(2.5 nm)/CoFe(5 nm)/NiFe(7 nm)/IrMn(10 nm)/Ta(5 nm) at room temperature have shown different magnetoresistance properties. When the samples were annealed at $250^{\circ}C$ in vacuum, the magnetoresistance ratio, the coercivity of pinned ferromagnetic layer, and the interlayer coupling field of free ferromagnetic layer were enhanced while the exchange bias coupling field did not show noticeable changes.

An Analysis of Third Graders' Understanding of the Properties of Multiplication by Elementary Mathematics Instruction (곱셈의 연산 성질을 강조한 초등 수학 수업에 따른 3학년 학생들의 이해 분석)

  • Sunwoo, Jin;Pang, JeongSuk
    • Journal of Elementary Mathematics Education in Korea
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    • v.23 no.1
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    • pp.143-168
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    • 2019
  • Along with the significance of algebraic thinking in elementary school, it has been recently emphasized that the properties of number and operations need to be explored in a meaningful way rather than in an implicit way. Given this, the purpose of this study was to analyze how third graders could understand the properties of operations in multiplication after they were taught such properties through a reconstructed unit of multiplication. For this purpose, the students from three classes participated in this study and they completed pre-test and post-test of the properties of operations in multiplication. The results of this study showed that in the post-test most students were able to employ the associative property, commutative property, and distributive property of multiplication in (two digits) × (one digit) and were successful in applying such properties in (two digits) × (two digits). Some students also refined their explanation by generalizing computational properties. This paper closes with some implications on how to teach computational properties in elementary mathematics.

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Sonochemical Synthesis of Copper-silver Core-shell Particles for Conductive Paste Application (초음파를 이용한 구리-은 코어-쉘의 합성 및 전도성 페이스트 적용)

  • Sim, Sang-Bo;Han, Jong-Dae
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.782-788
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    • 2018
  • Submicron copper-silver core-shell (Cu@Ag) particles were synthesized using the sonochemical combined transmetallation reaction and the application to printed electronics as a low cost conductive paste was evaluated. $Cu_2O$ of the $Cu_2O/Cu$ composite used as a core in the reaction for the synthesis of core-shell was sonochemically reduced to Cu, and Cu atoms functioned as a reducer for silver ions in transmetallation to achieve the copper-silver core-shell structure. The characterization of submicron particles by TEM-EDS and TG-DSC confirmed the core-shell structure. Conductive pastes in which 70 wt% Cu@Ag was dispersed in solvents were prepared using a binder and wetting agents, and coated on the polyamide film using a screen-printing method. Printed paste films containing synthesized Cu@Ag particles with 8 at% and 16 at% Ag exhibited low resistivity of 96.2 and $38.4{\mu}{\Omega}cm$ after sintering at $180^{\circ}C$ in air, respectively.

Structure and Reactivity of Alkylchloroformates. MO Theoretical Interpretations on Halide Exchange Reaction (염화 포름산 알킬의 구조와 반응성. 할로겐화 이온 교환반응에 대한 분자궤도론적 고찰)

  • Lee, Bon Su;Lee, Ik Choon
    • Journal of the Korean Chemical Society
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    • v.18 no.4
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    • pp.223-238
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    • 1974
  • CNDO/2 MO theoretical studies and kinetic studies of halide exchange reactions for alkylchloroformates have been carried out in order to investigate structure-reactivity relationship of alkylchloroformates. From the result of energetics, it was concluded that the most stable configuration of alkylchloroformate is that in which alkyl group and chlorine are trans to each other, and that the hindered rotation about the bond between the carbonyl carbon and alkoxy-oxygen bond is attributed to the ${\pi}-$electron delocalization. It has been found that the large charge separation is due to -M effect of carbonyl and alkoxy oxygens and-I effect of chlorine. The order of rates in solvents studied was $(CH_3)_2 > CO > CH_3CN{\gg}MeOH.$$I^->Br^->Cl^-$ in protic solvent, and of Cl^->Br^- >I^-$ in dipolar aprotic solvents. Alkyl group contribution has the decreasing order of $CH_3-> C_2H-{\gg}i-C_3H_7-.$ The solvent effect has been interpreted on the basis of initial and final state contribution. A transition state model has been suggested, and it has been proposed that the most favorable mechanism is the addition-elimination. From the results of activation parameters and electronic properties, an energy profile has been proposed. Structural factors determining reactivities of alkylchloroformates have been shown to be charge, energy level of ${\alpha}^*LUMO$ to C-Cl bond and ${\alpha}^{\ast} $antibonding strength with respect to C-Cl bond in this MO. Charge and polarizability of nucleophile, and the interaction of these effects with solvent structures are also found to be important.

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A STUDY ON THE EFFECT OF DENTIN ADHESIVE TO FLUORIDE RELEASE OF COMPOMER (상아질 결합제가 컴포머의 불소유리에 미치는 영향에 관한 연구)

  • Yoon, Yeo-Sang;Kim, Jong-Soo;Kwon, Soon-Won;Kim, Yong-Kee
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.2
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    • pp.228-237
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    • 2001
  • It is well known that glass-ionomer cement and compomer can release fluoride which can inhibit the progression of dental caries. The purposes of this study were to evaluate whether the fluoride from fluoride-containing filling materials can penetrate the dentin bonding adhesive and the dentin bonding adhesive can increase the bond strength of resin-modified glass ionomer. The amount of fluoride release from resin-modified glass ionomer and compomer was measured during 28 days of period and statistically analyzed by t-test. The bond strength of each material with/without dentin bonding adhesive was measured and also statistically analyzed by t-test. The distribution of fluoride from each material into the tooth was explored by electron probe microanalysis system(EPMA). The experimental teeth used were second primary molars about to exfoliate. The amount of fluoride release from each material was diminished by dentin bonding adhesive during 28 days(p<0.05) and the bond strength was not increased by dentin adhesive in resin-modified glass ionomer. The bond strength of group VI was not detectable. The distribution of fluoride from each material into teeth was according to dentino-enamel junction and dispersed into pulp from pulpal floor. The widest distribution was shown in resin-modified glass ionomer cement filled without the application of dentin bonding adhesive.

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Tunable Interlayer Exchange Coupling Energy (조절 가능한 층간교환상호작용에 관한 연구)

  • Ha, Seung-Seok;You, Chun-Yeol
    • Journal of the Korean Magnetics Society
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    • v.16 no.2
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    • pp.130-135
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    • 2006
  • We theoretically demonstrate that the interlayer exchange coupling (IEC) energy can be manipulated by means of an external bias voltage in a $F_1/NM/F_2/S$$(F_1:ferromagnetic,\;NM:nonmagnetic\;metallic,\;F_2:ferromagnetic,\;S:semiconductor\;layers)$ four-layer system. It is well known that the IEC energy between two ferromagnetic layers separated by nanometer thick nonmagnetic layer depends on the spin-dependence of reflectivity to the $F_1/NM/F_2/S$ four-layer system, where the reflectivities at the interface in $NM/F_2$ interface also depends on $F_2/S$ interface due to the multiple reflection of an electron-like optics. Finally, the IEC energy depends on the spin-dependent electron reflectivity not only at the interfaces of $F_1/NM/F_2$, but also at the interface of $F_2/S$. Naturally the Schottky barrier is formed at the interface between metallic ferromagnetic layer and semiconductor, the Schottky barrier height and thickness can be tailored by an external bias voltage, which causes the change of the spin-dependent reflectivity at $F_2/S$ interface. We show that the IEC energy between two ferromagnetic layers can be controlled by an external bias voltage due ti the electron-optics nature using a simple free-electron-like one-dimensional model.

제어시스템 ICCP 프로토콜 사이버 보안 현황

  • Kim, SungJin;Shon, Taeshik
    • Review of KIISC
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    • v.24 no.5
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    • pp.32-38
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    • 2014
  • 전력시스템에 IT를 결합한 스마트그리드에 대한 연구가 최근 활발히 진행되고 있다. 스마트그리드 중 전력시스템의 핵심이라 할 수 있는 전력시스템 제어센터 간 통신을 담당하는 것이 ICCP 프로토콜이며, 주로 중앙급전소와 지역급전소간의 전력망 정보들을 교환하는데 사용되고 있다. 이 프로토콜은 단지 전력망의 정보교환 뿐 아니라 전력기기제어 기능도 가지고 있다. ICCP 프로토콜은 TCP/IP 프로토콜을 기반으로 동작하기 때문에 잠재적으로 다양한 형태의 사이버 공격이 가능하다. 또한 이 프로토콜을 사용하는 중앙급전소의 경우 주요 국가기반시설로써 사이버테러에 더욱더 공고한 대응체계를 갖추어야 할 필요가 있다. 현재 ICCP 프로토콜을 사용하는 통신 구간은 일반적으로 외부 네트워크와 분리되어 그 안전성을 담보하고 있지만, 네트워크 분리를 통한 보안성 향상 기법이 체계적인 관리와 함께 수반되지 않으면 인적 취약성이나 새로운 형태의 모바일 기기를 통한 물리적 취약성에 지속적으로 노출 될 수 있는 잠재적 위험을 내포하고 있다. 따라서 이러한 보안 사고의 잠재적 발생 가능성으로 인해 외부네트워크와 분리된 제어센터들도 향후 더욱더 높은 수준의 보안 기술을 적용할 필요성이 강조되고 있다. 본 논문에서는 전력 제어센터 사이에서 사용되고 있는 ICCP 프로토콜의 사이버 보안 현황에 대해 살펴보고 해당 프로토콜의 보안 위험성과 이에 대한 대응방안을 고찰한다.

Recovery of Precious Metals in Plating Rinsed Wastewater Generated from Lead Frame Manufacturing Process (Lead Frame 제조공정에서 발생되는 도금세정폐수 중 유가금속회수)

  • Kim, Jae-Yong;Um, Myeong-Heon;An, Dae-Hyun;Shim, Myeong-Jin
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.343-348
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    • 2006
  • The object of this experiment is to recover precious metals from plating rinsed wastewater generated from Lead Frame manufacturing process using electrolysis coupled hybrid process. This was achieved from Amberlite IRA 400 at 1.15 V electrolysis potential using the oxide electrode and at 1.30 V using the Al electrode and from Amberlite IRA 402 at 1.10 V using the oxide electrode and at 1.20 V using the Al electrode. During the first 10~30 min of the process, 90~95% of the silver can be recovered.