• Title/Summary/Keyword: 교환 결합

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Studies on the Metal-Exchange Reaction of Tetrahedral Cu(II) Complex with Mercuric Ion and Mercury Metal (정사면체 구조를 갖는 Cu(II) 착물과 수은(II) 및 수은(0)과의 금속 교환반응 연구)

  • Young Tae Gong;Sung Nak Choi;Yoon-Bo Shim
    • Journal of the Korean Chemical Society
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    • v.36 no.2
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    • pp.223-229
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    • 1992
  • Mechanistic studies on the metal-exchange reactions of sparteine copper(II) dichloride [$SpCuCl_2$] with Hg(II) ion and Hg(0) metal have been carried out with the aid of Cyclic Voltammetry and UV-visible spectrophotometry. The metal exchange reaction of $SpCuCl_2$ with both Hg(II) ion and Hg(0) metal follows pseudo-first order kinetics. Rate constants and activation parameters of metal exchange reaction have been evaluated and reported. Experimental results indicate that the rate determining step for the exchange reaction is the cleavage of Cu(II)-N bond in the transient binuclear complex of Cu(II) and mercury(II) bound to sparteine ligand.

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ThE Variation of Magnetoresistande Ratio and Magnetization Curve by Insertion Co Layer in the$[Ni_{80}Fe_{20}/Cu/Co/Cu]$ Multilayers (교환 결합 상태가 다른 $[Ni_{80}Fe_{20}/Cu/Co/Cu]$ 다층 박막에서 Co 계면 삽입이 자기적 특성에 미치는 영향)

  • 이정주;최상준;홍재화;권순주
    • Journal of the Korean Magnetics Society
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    • v.8 no.2
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    • pp.79-85
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    • 1998
  • The $[Ni_{80}Fe_{20}/Cu/Co/Cu]$ multilayers were grown by evaporation technique, and according to magnetic exchange coupling relation, magnetoresistance ratio and magnetization curve were studied by Co inserting $Ni_{80}Fe_{20}/Cu$ interface. Insertion of Co layer to the antiferromagnetically coupled system, i. e $t_{Cu} = 25\;{\AA}$, decrese the MR ratio contrary to previous reports. However the insertion to the ferromagneticalyl coupled $(t_{Cu} = 27\;{\AA})$ and the noncoupled $(t_{Cu} = 47\;{\AA})$ systems increase the ratio to 3.5 % and 6 % respectively. The results imply that the insertion change the magnetic exchange coupling state as well as the spin dependent scattering of conduction electrons. Besides, insertion of Co layer between Cu and $Ni_{80}Fe_{20}$ layer enhaces thermal stability to the 300 $^{\circ}C$, which indicates that insertion of Co has a role of the effective diffusion barrier.

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Study on the Improvement of Exchange Bias and Magnetoresistance in Co/Cu/Co/FeMn Spin Valve by Heat Treatment (Co/Cu/Co/FeMn 스핀밸브의 자기저항 특성 향상 연구)

  • Kim, Hong-Jin;Bae, Jun-Soo;Noh, Eun-Sun;Lee, Taek-Dong;Lee, Hyuck-Mo
    • Journal of the Korean Magnetics Society
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    • v.12 no.1
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    • pp.24-29
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    • 2002
  • It was observed that exchange bias field was increased with smooth surface and better ${\gamma}$-FeMn formation. Sputtering conditions were varied for the control of the surface roughness and ${\gamma}$-FeMn formation. From the results of Cu deposition as underlayer, it was found that ${\gamma}$-FeMn formation was closely related with the thickness of underlayer. After heat treatment, exchange bias field was increased over three times. This improvement was likely that the crystallites of ${\gamma}$-FeMn were well formed. In Co/Cu/Co/FeMn spin valve structure, magnetoresistance was increased over 1.4 times through the heat treatment. This was due to the disappearance of Co/Cu intermixed dead layer and removal of defect, and this was examined by AES analysis.

XPS Studies for O1S Electrons of Ion Exchanged Zeolite X and Y (이온교환된 X형 및 Y형 제올라이트의 O1S 전자에 대한 X선 광전자분광학적 해석)

  • Kim, Myung-chul;Kim, Jong-Taik
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.240-246
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    • 1992
  • The electronic structure of oxygen atom of cation-exchanged zeolite was investigated by utilizing X-ray photoelectron spectroscopy(XPS). The obtained $O_{1S}$ spectra of $Na^+-$, $Fe^{2+}-$ and $Fe^{3+}-$ exchanged zeolite X and Y were deconvoluted to demonstrate electronic binding energy of framework oxygens. There were 2-3 bands in each spectrum. The characteristics of separated band have been studied in terms of binding energy and relative area of $O_{1S}$ electron with respect to the exchanged cation. Those bands were assigned to the bridged oxygen in framework (band 1), cation bonded oxygen in cationic site (band 2) and oxygen in water coordinated to the cation (band 3) each other. The band 1 occupying the majority area of $O_{1S}$ spectrum was shifted to higher region on binding energy according to the decrease of Al content in zeolite.

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Thermal Stability of a Nanostructured Exchange-coupled Trilayer (나노구조 교환결합 삼층박막의 열적 안정성 예측)

  • Lee, Jong-Min;Lim, S.H.
    • Journal of the Korean Magnetics Society
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    • v.20 no.2
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    • pp.75-82
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    • 2010
  • A recent progress on the prediction of the thermal stability of a nanostructured exchange-coupled trilayer is reviewed. An analytical/numerical combined method is used to calculate its magnetic energy barrier and hence the thermal stability parameter. An important feature of the method is the use of an analytical equation for the total energy that contains the magnetostatic fields. Under an assumption of the single domain state, the effective values of all the magnetostatic fields can be obtained by averaging their nonuniform values over the entire magnetic volume. In an equilibrium state, however, it is not easy to calculate the magnetostatic fields at the saddle point due to the absence of suitable methods of the accessing its magnetic configuration. This difficulty is overcome with the use of equations that link the magnetostatic fields at the saddle point and critical fields. Since the critical fields can readily be obtained by micromagnetic simulation, the present method should provide accurate results for the thermal stability of a nanostructured exchange-coupled trilayer.

Exchange Bias Field and Coercivity of [NiFe/NiFeCuMo/NiFe]/FeMn Multilayers ([NiFe/NiFeCuMo/NiFe]/FeMn 다층박막의 교환결합력과 보자력에 관한 특성 연구)

  • Choi, Jong-Gu;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.21 no.4
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    • pp.132-135
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    • 2011
  • The exchange bias field ($H_{EX}$) and the coercivity ($H_C$) variation and change depending on the thickness of intermediately super-soft magnetic NiFeCuMo layer with different thickness of the bottom NiFe layer were investigated. The $H_{EX}$ of triple pinned NiFe(4 nm)/NiFeCuMo($t_{NiFeCuMo}$= 1 nm)/NiFe(4 nm)/FeMn multilayer has the maximum value more less than one of single pinned NiFe(8 nm)/FeMn layer. If NiFeCuMo layer is inserted each into between the pinned and free NiFe layers, we can be used as GMR-SV device for a bio-sensor that has improved magnetic sensitivity.

Rotatable Anisotropy Field in Exchange Coupled CoFe/MnIr(2.5 nm) Thin Films (교환 결합력을 갖는 CoFe/MnIr(2.5 nm) 박막의 회전 이방성 자기장 특성)

  • Yoon, Seok Soo;Kim, Dong Young
    • Journal of the Korean Magnetics Society
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    • v.27 no.3
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    • pp.77-81
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    • 2017
  • The rotatable anisotropy effect was observed in the ferromagnetic resonance measurement in exchange coupled ferromagnetic/antiferromagnetic thin films and it was due to rotation of antiferromagnetic layer by the exchange coupling energy. We analyzed the CoFe thickness dependence of rotatable anisotropy field and ferromagnetic resonance linewidth in exchange coupled $CoFe(t_F)/MnIr(2.5nm)$ thin films. The rotatable anisotropy field was inversely propositional to the CoFe thickness and it was well fitted by the rotatable anisotropy energy of $0.96erg/cm^2$. The ferromagnetic resonance linewidth were linearly propositional to the rotatable anisotropy field in $t_F$ < 50 nm, while it was more dominated by the eddy current effect in $t_F$ > 50 nm.

Modeling and fabrication of $1.31/1.55\mu\textrm{m}$ coarse WDM optical directional coupler using $Ag^+-Na^+$ ion-exchanged glass ($Ag^+-Na^+$이온교환법을 이용한 $1.31/1.55\mu\textrm{m}$ 두파장 방향성 광 결합기의 모델링 및 제작)

  • 강동성
    • Korean Journal of Optics and Photonics
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    • v.11 no.5
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    • pp.335-339
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    • 2000
  • A $1.31/1.55\mu\textrm{m}$ coarse WDM opncal dIrectional coupler that conslsls of two idenlical straight channel waveguides in BK7 glass has been fabricated. The separatIOn between two channel waveguides is $8\mu\textrm{m}$ and the wavegu.ide width is $4\mu\textrm{m}$ . Especlally, we assumed that the index profile is Gaussian function and complementary error function in the width direction and depth direction, respectrvely. This directional coupler operating at $1.31/1.55\mu\textrm{m}$ with crosstalk of 18dB is demonstrated and has the 16 mm long length with 12.6 mm coupling region.region.

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Analysis of Exchange Coupling Energy by Ferromagnetic Resonance Method in CoFe/MnIr Bilayers (강자성 공명법을 이용한 CoFe/MnIr 박막의 교환 결합 에너지 분석)

  • Kim, Dong Young
    • Journal of the Korean Magnetics Society
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    • v.22 no.6
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    • pp.204-209
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    • 2012
  • We measure the ferromagnetic resonance signals in order to analyze the exchange coupling energy due to the uncompensated antiferromagnetic spins in exchange coupled CoFe/MnIr bilayers. The exchange bias fields ($H_{ex}$) and rotatable anisotropy fields ($H_{ra}$) are obtained from the ferromagnetic resonance fields measured with in-plane angle in thermal annealed samples with $t_{AF}$= 0, 3, and 10 nm. The sum of the $H_{ex}$ and $H_{ra}$ do not depend on the MnIr thickness, which means that all the uncompensated AF spins are aligned to one direction in $300^{\circ}C$ annealed samples. Therefore, the uncompensated AF spins are divided into two different parts. One parts are fixed at the interface between CoFe/MnIr bilayers and induces the $H_{ex}$, other parts are rotatable with magnetic field and induces the $H_{ra}$. Finally, the exchange coupling energy can be expressed by the sum of the exchange bias energy and rotatable anisotropy energy.