• Title/Summary/Keyword: 광 이동도

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Preparation of Silica Coated Zinc Oxide and UV Protection Effect (이산화규소가 코팅된 산화아연의 제조와 자외선 차단 특성)

  • Kim, Won Jong;Kang, Kuk Hyoun;Lee, Gi Yong;Kim, Tae Won;Choi, Jong Wan;Lee, Dong Kyu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.2
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    • pp.121-131
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    • 2014
  • Due to the high UV light scattering effect of Zinc oxide (ZnO), it is frequently used in sunscreen skincare products. Recently ZnO coated with silica has been used in cosmetics to improve UV protection, texture, decreased photocatalytic activity, dispersibility and stability of the skin care product. In this study, we developed a ZnO composite powder coated with silica for the future application to skincare products to block UV rays that could cause photoaging. To improve consumer's satisfaction rating, we used ZnO microparticles which are widely used in the cosmetics industry. The silica was coated using hydrothermal method with sodium silicate and acid hydrolysis. UV protection of the composite powder was analyzed by UV-Vis and in-vitro test and the advantages for practical use of this powder as a skincare product were determined.

Hydrogen Bond Effect on Chain Behavior at the Semidilute Regime of Poly(vinyl alcohol) Aqueous Solution (폴리(비닐 알코올) 수용액의 준희박농도 영역에서 사슬 거동에 대한 수소결합의 효과)

  • Park Il-Hyun;Yu Young-Chol;Park Ki-Sang;Lee Dong-Il;Lyoo Won-Seok
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.271-278
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    • 2006
  • In order to investigate the structure and dynamics of atatic poly (vinyl alcohol) (PVA)/water system, laser light scattering experiment has been done in the semi-dilute concentration regime at $25^{\circ}C$. The scattering intensity I(q) can be analyzed with the fractal equation of $I(q){\sim}q^{-m}$ instead of Onstein-Zernike type equation. The fractal dimensionality m was found to be constant after reaching the plateau value of $m=2.6{\pm}0.3$ above C=3wt%. The time correlation function of dynamic light scattering has always two different modes such as fast mode and slow one. The cooperative diffusion of fast mode showed concentration independence contrary 4o the reptation theory's concentration dependent exponent of 3/4. The slow mode can be interpreted as the motion of large scale heterogeneities and its strong concentration dependence is apparent with a large negative exponent of -3.0. It is considered that the stereo-regular arrangement with four successive meso units of -OH plays as a key role in forming such heterogeneity.

A Clinical Analysis of Patients Who Visited Emergency Department due to Chemical Incident Occurred at Industrial Place: A Retrospective Study (산업장 화학 사고로 응급실에 내원한 환자의 임상적 고찰: 일개병원의 후향적 연구)

  • Shin, Hee Jun;Oh, Se Kwang;Yoo, Byeong Dai;Jun, Duck Ho;Lee, Dong Ha;Woo, Kuck Hyeun;Yoon, Seong Yong;Choi, Sung Yong
    • Journal of The Korean Society of Clinical Toxicology
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    • v.13 no.2
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    • pp.78-86
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    • 2015
  • Purpose: The purpose of this study is to understand what kinds of chemical substances have been used annually and to investigate incidents that occurred due to chemical hazard release and to analyze statistically clinically chemical injury patients who visited one regional emergency medical center in Gumi city with documented references review. Methods: Annual chemical waste emission quantity (Kg/Year) (Cwep) was reproduced using national web site data governed by the Ministry of Environment and 5 years (from 1 .Jan. 2010 to 31. Dec. 2014) of medical records of chemical injury patients who visited our emergency department were reviewed retrospectively. By applying exclusion criteria, 446 patients of 460 patients were selected. Results: Dichloromethane, Toluene, Trichloroethylene, and Xylene were always included within Top 5 of Cweq. Six cases of chemical incidents were reported and in 3 of 6 cases involving Hydrogen fluoride were included during the study period. Male gender and twenties were the most prevalent group. Injury evoking chemicals were Hydrogen fluoride, unknown, complex chemicals (over 2 substances) in sequence. The most frequent site of wounds and injuries was the respiratory tract. Gas among status, intoxication among diagnosis, and discharge among disposition was most numerous in each group. Conclusion: There have been no uniform clinical protocols for chemical wounds and injuries due to various kinds of chemicophysical properties and ignorance of antidotes. Therefore conduct of a multicenter cohort study and experiments for ruling out chemicals according to chemicophysical priority as well as development of antidotes and clinical protocols for chemical injury patients is needed.

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Effects of Light and Temperature on Nitrate Uptake, Germling Growth and Fatty Acid Composition of Enteromorpha compressa (Chlorophyta) (녹조 납작파래 (Enteromorpha compressa)의 질산염 흡수, 배아 생장 및 지방산 조성에 대한 광 및 온도의 영향)

  • LEE Dong Hoon;LEE Soon Jeong;RYU Jina;PARK Eunjeong;NAM Ki Wan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.37 no.1
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    • pp.57-64
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    • 2004
  • Effects of light and temperature on the nitrate uptake and germling growth of Enteromorpha compressa (L.) Greville (Chlorophyta) were studied based on samples from Cheongsapo near Busan, Korea. In addition, their effects on fatty acids composition in thallus were examined. Nitrate uptake showed saturation kinetics. $V_{max}$ (maximal uptake rate) and its $K_s$ (half-saturation constant) at $20^{\circ}C,\;80\;{\mu}mol\;m^{-2}s^{-1},$ white light were $1.571\;{\mu}mol{\cdot}g\;fr\;wt^{-1}{\cdot}h^{-1}$ and 3.56 ${\mu}M$, respectively. In nitrate uptake with irradiance, wavelength and temperature, its rate represented respectively the highest value as $1.405\pm0.020,\;0.623\pm0.040,\;1.422\pm0.022\;{\mu}mol{\cdot}g\;fr\;wt^{-1}{\cdot}h^{-1}\;at\;100\;{\mu}mol\;m^{-2}s^{-1},$ red light, $20^{\circ}C$ and exhibited significant difference among the examined conditions (p<0.001). Germling growth of E. compressa also showed saturation kinetics, and $V_{max}$ and its $K_s$ value at $20^{\circ}C,\;100\;{\mu}mol\;m^{-2}s^{-1},$ 12:12 h were $56.18\%\;day^{-1}$ and 0.33 ${\mu}M$, respectively. SGR (specific growth rate) recorded a maximal value as 49.33-54.80, 39.07-50.72, $47.20-54.53\%\;dat^{-1}$ at $120\;{\mu}mol\;m^{-2}s^{-1},$ blue light and $18^{\circ}C$ respectively, and showed significant difference (p<0.001). Red light made the effective nitrate uptake, but germling growth was largely limited by the light. In fatty acids analysis, PUFAs (polyunsaturated fatty acids) were high at blue light, $18^{\circ}C,\;100\;{\mu}M\;NO_3^-.$ However, irradiance did not affect the production of PUFAs. In conclusion, nitrate uptake and germling growth of E. compressa showed saturation kinetics to external nitrate concentration, and were significantly affected by irradiance, wave length and temperature. Fatty acid composition was also influenced by the factors except for irradiance. Their maximal values, together with the highest production of PUFAs, were found at blue light band, $20^{\circ}C,\;100\;{\mu}mol\;m^{-2}s^{-1},\;and\;100\;{\mu}M\;NO_3^-.$

Estimation of Bathymetry Changes using Hyperspectral Measurements -Focused on Haeundae beach- (초미세분광 측정치를 이용한 해저지형 변화산정 - 해운대를 중심으로 -)

  • Yang, Intae;Jo, Young-Heon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.4
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    • pp.1335-1342
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    • 2014
  • Shallow water depths were estimated using Compact Airborne Spectrographic Imager (CASI)-1500 and mapped to analyze the bottom bathymetry changes due to the rip currents in Haeundae beach, South Korea for the first time. The depths were estimated empirically using the maximum reflectances from 420nm to 597nm wavelength of CASI and 47 in situ water depth measurements, which were compared with ground-truth bathymetry measurements. The comparisons showed that the RMSE was 1.1m with a correlation coefficient of 0.76. In addition, CASI imagery showed remarkably detailed bottom features, especially those resulting from the rip currents within the beach. Two different channels carved by the rip current were analyzed and characterized with respect to the width and slope compared to surrounding regions. While the west side of the channel showed a wide and gentle slope, the east side of the channel showed a narrow and steep slope. The estimated bathymetry map revealed that the uneven offshore bottom features were related to the transport and accumulation of sediments by the rip current, which reaches hundreds of meters offshore. Accordingly, the accumulated sediments were estimated by adding topography changes compared to the depths of the non-rip current regions. The sediments were accumulated in off channels as much as almost twice the amount of annual sand supplements along the Haeundae beach.

Mineralogical Properties of Asian Dust Sampled at Deokjeok Island, Incheon, Korea in February 22, 2015 (2015년 2월 22일 인천광역시 덕적도에서 포집된 황사의 광물학적 특성)

  • Park, Mi Yeon;Jeong, Gi Young
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.2
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    • pp.79-87
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    • 2016
  • Asian dust (Hwangsa) interacts with light, atmospheric gas, aerosol, and marine ecosystem, affecting Earth climate. Mineralogical properties are essential to understand the interaction between the dust and environments. In this study, we examined the mineralogical properties of Asian dust collected at Deokjeok Island, Incheon, Korea in February 22, 2015. X-ray diffraction (XRD) analyses showed that phyllosilicate minerals (62 wt%) dominate the Asian dust. Illite-smectite series clay minerals (55%) were common with minor chlorite (5%) and kaolinite (2%). Non-phyllosilicate minerals were quartz (18%), plagioclase (10%), K-feldspar (4%), calcite (4%), and gypsum (1%). Similar results were obtained by mineral quantification using scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS). Transmission electron microscopy combined with EDS confirmed illite-smectite series clay minerals as the dominant phyllosilicate type. Morphological analyses using SEM showed clay agglomerates, clay-coated quartz, feldspars, and micas. Gypsum grains were common on the particle surface, while calcite nanofibers, previously reported as common on the surface, were rare, indicating the reaction of calcite and acidic atmospheric pollutants to form gypsum. The analytical result of 2015 Asian dust would contribute to the establishment of mineralogical base for the modeling of the interaction between Asian dust and environments.

Luminescence characterization of $EU^{3+}$ and $Bi^{3+}$ co-doped in ${Y_2}{SiO_5}$ red emitting phosphor by solid state reaction method (고상 반응법으로 합성한 ${Y_2}{SiO_5}:\;EU^{3+}$, $Bi^{3+}$ 적색 형광체의 발광 특성)

  • Moon, J.W.;Song, Y.H.;Park, W.J.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.1
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    • pp.15-18
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    • 2009
  • To enhance near UV-visible absorption region and to applied phosphor convert-white LEOs (PC-WLEDs), a red phosphor composed of ${Y_2}{SiO_5}:\;EU^{3+}$, $Bi^{3+}$ compounds was prepared by the conventional solid-state reaction. The photoluminescence (PL) shown that samples were excited by near UV light 395 nm for measurement of PL spectra. Emission spectra of samples have shown red emissions at 612 nm ($^5D_0{\to}^7F_2$). The enhanced near $UV{\sim}$ visible excitation spectrum with a broad band centered at 258 nm and 282 nm originated in the transitions toward the charge transfer state (CTS) due to the $Eu^{3+}-Bi^{3+}-O^{2-}$ interaction. The other excitation band at $350\;nm{\sim}480\;nm$, corresponding to the transitions $^7F_0{\to}^5L_9$ (364 nm), $^7F_0{\to}^5G_3$ (381 nm), $^7F_0{\to}^5L_6$ (395 nm), $^7F_0{\to}^5D_3$, (415 nm) and $^7F_0{\to}^5D_2$ (466 nm), occurred due to enhanced the f-f transition increasing $Bi^{3+}$ and $Eu^{3+}$ ions. The PL intensity increased with increased as concentration of $Bi^{3+}$ and the emission intensity becomes with a maximum at 0.125 mol.

Superparamagnetic Properties of MnFe2O4 Nanoparticles (초미세 나노분말 MnFe2O4의 초상자성 성질 연구)

  • Lee, Seung-Wha;Lee, Jae-Gwang;Chae, Kwang-Pyo;Kwon, Woo-Hyun;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.19 no.2
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    • pp.57-61
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    • 2009
  • $MnFe_2O_4$ nanoparticles have been prepared by a sol-gel method. The structural and magnetic properties have been investigated by XRD, SEM, and $M{\ddot{o}}ssbauer$ spectroscopy, VSM. $MnFe_2O_4$ powder that was annealed at $250^{\circ}C$ has spinel structure and behaved superparamagnetically at room temperature. $MnFe_2O_4$ annealed at 400 and $500^{\circ}C$ has a typical spinel structure and is ferrimagnetic in nature. The estimated size of superparammagnetic $MnFe_2O_4$ nanoparticle is around 17 nm. The hyperfine fields of the A and B patterns at 4.2 K were found to be 508 and 475 kOe, respectively. The blocking temperature ($T_B$) of superparammagnetic $MnFe_2O_4$ nanoparticle is about 120 K. The magnetic anisotropy constant and relaxation time constant of $MnFe_2O_4$ nanoparticle were calculated to be $4.9{\times}10^5erg/cm^3$.

조광기능을 갖춘 전자식 형광등용 IC

  • 최낙춘;신동명;김덕중
    • 전기의세계
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    • v.43 no.1
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    • pp.13-19
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    • 1994
  • 전자식 안정기는 최근 에너지 절약 정책과 관련하여 조명기기분야의 관심의 대상이 되었고, 절전 효율이 높은 고품질의 전자식 안정기에 대한 연구 개발 및 보급이 점점 더 확대되고 있는 추세이다. 일반적으로 전자식 안정기는 수십 KHz의 고주파에서 형광등을 구동시킴으로써 빛의 깜박거림과 가청잡음이 없으며, 저주파(60Hz)에서 사용하는 재래식 안정기(choke coil 방식)에 비해 높은 절전 효과를 얻을 수 있다[1-4]. 특히, 빌딩 사무실의 경우 낮에도 창가의 형광등이 켜져 있어서 막대한 전력을 낭비하고 있는 실정이므로, 일조량에 따른 자동 전력 조절이 가능한 전자식 형광등의 출현이 기대되고 있다. 전자식 안정기의 보급 확대를 위해서는 절전 효과 뿐만 아니라, 품질 문제, 수명 문제등을 고려하여야 하는 바, 예를 들면 순간 점등으로 방전초기의 sputtering 현상에 의한 lamp의 수명 단축, 미소 입력전압 변동에 따른 급격한 광출력의 변화로 절전 효과의 상실과 이상동작에 의한 스위칭 소자의 파괴 현상, 고주파 스위칭시 발생되는 전력손실과 noise등에 대한 대책이 요구되고 있다. 이러한 점을 개선하기 위해 추가되는 회로는 전자식 안정기 시스템을 더욱 복잡하게 만들고, 경제적으로 원가 부담을 주기 때문ㅇ 고품질의 전자식 안정기를 보급하는데 어려운 점으로 부각되고 있다. 본 고에서는 이러한 문제를 해결하기 위하여 조광기능을 포함한 다양한 제어회로와 보호회로를 조광기능을 포함한 다양한 제어회로와 보호회로를 1 chip에 수용하는 고품질의 전자식 안정기 제어용 집적회로에 대해서 기술하고자 한다.되어 나아갈 기술의 조류에도 부합하는 형태라 하겠다. 그러나 이 방식은 기 언급한 바와 같이 분산처리를 관장하는 운영체계의 개발에 상당한 고전이 따르리라 보여지며, 또한 보다 상세한 연구가 선행되어야 하겠지만 개발된 상용의 통신 프로토콜로서는 병렬처리의 성능을 극대화 하기에는 여러가지 제약이 있을 것으로 예측된다.기기들이 어떻게 응용되고 있는지 살펴보기로 하자. real informations would be available. Results are compared with those of optimal power flows.기능시험을 완료했으며 실제 line-of-sight(LOS) 시스템 구현에 적용중이다. 시대를 살아 갈 회원들이다. '컨텐츠의 시대'가 개막되는 것이며, 신세기통신과 SK텔레콤은 선의의 경쟁 과 협력을 통해 이동인터넷 서비스의 컨텐츠를 개발해 나가게 될 것이다. 3배가 높았다. 효소 활성에 필수적인 물의 양에 따른 DIAION WA30의 라세미화 효율에 관하여 실험한 결과, 물의 양이 증가할수록 그 효율은 감소하였다. DIAION WA30을 라세미화 촉매로 사용하여 아이소옥탄 내에서 라세믹 나프록센 2,2,2-트리플로로에틸 씨오에스터의 효소적 DKR 반응을 수행해 보았다. 그 결과 DIAION WA30을 사용하지 않은 경우에 비해 반응 전환율과 생성물의 광학 순도는 급격히 향상되었다. 전통적 광학분할 반응의 최대 50%라는 전환율의 제한이 본 연구에서 찾은 DIAION WA30을 첨가함으로써 성공적으로 극복되었다. 또한 고체 염기촉매인 DIAION WA30의 사용은 라세미화 촉매의

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Internal Flow and Evaporation Characteristic inside a Water Droplet on a Vertical Vibrating Hydrophobic Surface (수직 진동하는 소수성 표면 위 액적의 내부유동 및 증발특성 연구)

  • Kim, Hun;Lim, Hee-Chang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.7
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    • pp.579-589
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    • 2015
  • This study aims to understand the internal flow and the evaporation characteristics of a deionized water droplet subjected to vertical forced vibrations. To predict and evaluate its resonance frequency, the theories of Lamb, Strani, and Sabetta have been applied. To visualize the precise mode, shape, and internal flow inside a droplet, the experiment utilizes a combination of a high-speed camera, macro lens, and continuous laser. As a result, a water droplet on a hydrophobic surface has its typical shape at each mode, and complicated vortices are observed inside the droplet. In particular, large symmetrical flow streams are generated along the vertical axis at each mode, with a large circulating movement from the bottom to the top and then to the triple contact line along the droplet surface. In addition, a bifurcation-shaped flow pattern is formed at modes 2 and 4, whereas a large ellipsoid-shape flow pattern forms at modes 6 and 8. Mode 4 has the fastest internal flow speed and evaporation rate, followed by modes 8 then 6, with 2 having the slowest of these properties. Each mode has the fastest evaporation rate amongst its neighboring frequencies. Finally, the droplet evaporation under vertical vibration would lead to more rapid evaporation, particularly for mode 4.